CN106283789A - Mosquito-proof environment protection type wallpaper - Google Patents

Mosquito-proof environment protection type wallpaper Download PDF

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Publication number
CN106283789A
CN106283789A CN201610767187.7A CN201610767187A CN106283789A CN 106283789 A CN106283789 A CN 106283789A CN 201610767187 A CN201610767187 A CN 201610767187A CN 106283789 A CN106283789 A CN 106283789A
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China
Prior art keywords
parts
mosquito
environment protection
protection type
proof environment
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庞瑜
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Advertising Co Ltd Nanning East Era
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Advertising Co Ltd Nanning East Era
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Priority to CN201610767187.7A priority Critical patent/CN106283789A/en
Publication of CN106283789A publication Critical patent/CN106283789A/en
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C01G9/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/14—Secondary fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10—Composite fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/02—Material of vegetable origin
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/143—Agents preventing ageing of paper, e.g. radiation absorbing substances
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of mosquito-proof environment protection type wallpaper; described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 20 30 parts, waste wood 10 20 parts, Caulis et Folium Oryzae 10 20 parts, nano zine oxide 25 parts, chitosan 12 parts, 28 parts of sodium sulfide, sodium hydroxide 10 25 parts, tapioca 5 10 parts, butyl acrylate 25 parts, titanate coupling agent 12 parts, PAMC 13 parts, cocoyl Glycine sodium 12 parts, azodiisobutyronitrile 12 parts, deionized water 60 100 parts, ethyl acetate 20 30 parts, Chinese medicine powder 5 10 parts；The mosquito-proof environment protection type wallpaper of the present invention uses friperie, waste wood and Caulis et Folium Oryzae as fiber base material, the most beneficially resource, it is to avoid the wasting of resources, reaching environment protecting, employing Chinese medicine powder is vegetable material, can anophelifuge but to human body non-hazardous, and containing calming the nerves composition, body and mind of releiving, make people's ataraxy.

Description

Mosquito-proof environment protection type wallpaper
Technical field
The present invention relates to a kind of mosquito-proof environment protection type wallpaper, belong to wallpaper technical field.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material the most widely.Because it is many that wallpaper has color Other house decorative materials multiple such as sample, pattern are abundant, luxurious style, safety and environmental protection, easy construction, affordable cannot compare The feature intended, therefore obtain considerable degree of universal at developed countries and regions such as America and Europe, Southeast Asia, Japan.Wallpaper is divided into a lot Class, such as coating wallpaper, overlay film wallpaper, embossing wallpaper etc..Generally produce body paper, then adding through different operation with bleached wood pulp Work processes, as be coated with, prints, emboss or surface being covered and moulded, the most cut, pack after dispatch from the factory.Because having certain intensity, U.S. The appearance seen and good water repelling property, be widely used in the interior decoration etc. in house, office, hotel.The raw material of wallpaper is general Being wood, bamboo etc., owing to being widely used, the usage amount of wallpaper gets more and more, and raw material is in short supply, causes trees, bamboo grove to meet with The denudation of degree, resource excessive use.
Summary of the invention
It is an object of the invention to solve the problems referred to above, and a kind of mosquito-proof environment protection type wallpaper is provided, the mosquito-proof ring of the present invention Guarantor's type wallpaper uses friperie, waste wood and Caulis et Folium Oryzae as fiber base material, the most beneficially resource, it is to avoid the wasting of resources, reaches ring Protecting effect, employings Chinese medicine powder is vegetable material, can anophelifuge but to human body non-hazardous, and contain and calm the nerves composition, body and mind of releiving, Make people's ataraxy.
The technical scheme that the present invention provides is:
A kind of mosquito-proof environment protection type wallpaper, described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 20-30 Part, waste wood 10-20 part, Caulis et Folium Oryzae 10-20 part, nano zine oxide 2-5 part, chitosan 1-2 part, sodium sulfide 2-8 part, sodium hydroxide 10-25 part, tapioca 5-10 part, butyl acrylate 2-5 part, titanate coupling agent 1-2 part, PAMC 1-3 Part, cocoyl Glycine sodium 1-2 part, azodiisobutyronitrile 1-2 part, deionized water 60-100 part, ethyl acetate 20-30 part, Chinese medicine powder 5-10 part；Described Chinese medicine powder is made up of following material: Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, Lavandula angustifolia.
Preferably, described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 25 parts, waste wood 15 Part, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, sodium hydroxide 20 parts, tapioca 7 parts, acrylic acid Butyl ester 3 parts, titanate coupling agent 1 part, PAMC 2 parts, cocoyl Glycine sodium 1 part, azodiisobutyronitrile 2 Part, deionized water 80 parts, ethyl acetate 25 parts, Chinese medicine powder 8 parts；Described Chinese medicine powder is made up of following weight portion material: Fructus Evodiae 5-10 part, Folium Artemisiae Argyi 5-10 part, Fericarpium Citri Limoniae 3-8 part, Folium Pini 8-15 part, Fructus Bruceae 4-5 part, Cortex Albiziae 3-6 part, lavandula angustifolia 2-5 part.
Preferably, described activated zinc oxide particle diameter≤50 nanometer.
Preferably, described tapioca is 2: 1 with the weight ratio of butyl acrylate.
Preferably, described Chinese medicine powder is made up of following methods: by Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, conjunction Joyous skin, lavandula angustifolia are dried, and using pulverizer to be crushed to grain diameter is 20-100 mesh, add 10 times of weight ethanol vacuum extraction 1-2 Hour, filtration to extracting solution, after being spray-dried after extracting solution reduced-pressure backflow, obtain less than 20 microns by being ground to particle diameter Described Chinese medicine powder.
The preparation method of a kind of described mosquito-proof environment protection type wallpaper, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae After the sodium hydroxide solution using 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture Content is less than 10%, uses fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally by friperie, Caulis et Folium Oryzae and the waste wood through pulverizing Mixing uses high-pressure pulse nano-scale crusher to pulverize, and is crushed to grain diameter less than 10 microns, add deionized water, sodium sulfide, Sodium hydroxide is placed in slurrying 1-2 hour in ultrasound machine, and slurrying temperature is 100-150 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide Upper addition titanate coupling agent, uses blender to be stirred continuously 1-2 hour, and mixing speed is 100-200rmp, must arrive surface and change Property nano zine oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid Ethyl ester, temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50-60 DEG C adds azodiisobutyronitrile, stirs 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca- Polyacrylamide copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder puts into reactor, and temperature is 80-90 DEG C stirring 2-4 hour, coating be dried stamp obtain described mosquito-proof environment protection type wallpaper.
Preferably, in step one, the running voltage of high-pressure pulse nano-scale crusher is 30-40kv, and pulse wave number is 20- 30；The frequency of ultrasound wave work is 50-100 hertz.
Preferably, in step 4, the vacuum of reactor is 0.8-0.9Mpa.
Beneficial effects of the present invention is as follows:
In the mosquito-proof environment protection type wallpaper of the present invention, nano zine oxide can be evenly distributed on by after titanate coupling agent modified In carrier, self it is not susceptible to agglomeration, makes fiber pulp surface at friperie, waste wood and Caulis et Folium Oryzae and form one layer of coating, Playing antibacterial, mildew-resistant, radiation resistance, tapioca and butyl acrylate in the present invention, PAMC copolymerization are anti- Tapioca-butyl acrylate copolymer and tapioca-polyacrylamide copolymer should be obtained, these copolymer energy and fibers Slurry forms fine and close network structure, significantly improves the moisture resistance of wallpaper, also improves the ageing resistace of wallpaper, extends wallpaper Service life, Chinese medicine powder contains Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae can dispel mosquito, plays mosquito-proof effect, other compositions Fructus Evodiae, Cortex Albiziae, lavandula angustifolia play sedative action；Simultaneously the mosquito-proof environment protection type wallpaper of the present invention use friperie, waste wood and Caulis et Folium Oryzae is as fiber base material, the most beneficially resource, it is to avoid the wasting of resources, reaches environment protecting, has mosquito-proof, mildew-resistant, antibacterial, anti- The several functions such as radiation, protection against the tide, aging resistance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, to make those skilled in the art with reference to saying Bright book word can be implemented according to this.
The relative content being previously mentioned in the present invention is mass percent content, except having specified otherwise.
Embodiment 1:
A kind of mosquito-proof environment protection type wallpaper, described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 20 parts, Waste wood 10 parts, Caulis et Folium Oryzae 10 parts, nano zine oxide 2 parts, chitosan 1 part, 2 parts of sodium sulfide, sodium hydroxide 10 parts, tapioca 5 Part, butyl acrylate 2 parts, titanate coupling agent 1 part, PAMC 1 part, cocoyl Glycine sodium 1 part, azo Bis-isobutyronitrile 1 part, deionized water 60 parts, ethyl acetate 20 parts, Chinese medicine powder 5 parts；Described Chinese medicine powder is made up of following material: Wu Zhu Cornel, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia.
The preparation method of described mosquito-proof environment protection type wallpaper, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae After the sodium hydroxide solution using 5% soaks 2 days, by carrying out rubbing 0.5 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture Less than 10%, use fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally the friperie through pulverizing, Caulis et Folium Oryzae are mixed with waste wood Employing high-pressure pulse nano-scale crusher is pulverized, and is crushed to grain diameter and is less than 10 microns, adds deionized water, sodium sulfide, hydrogen-oxygen Changing sodium and be placed in slurrying 1 hour in ultrasound machine, slurrying temperature is 100 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide Upper addition titanate coupling agent, uses blender to be stirred continuously 1 hour, and mixing speed is 100rmp, obtains surface-modified nano Zinc oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid Ethyl ester, temperature is heated to 80 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50 DEG C Add azodiisobutyronitrile, stir 3 hours, obtain tapioca-butyl acrylate copolymer and tapioca-polyacrylamide Copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder puts into reactor, and temperature is 80 DEG C and stirs Mixing 2 hours, coating is dried stamp and obtains described mosquito-proof environment protection type wallpaper.
Embodiment 2
A kind of mosquito-proof environment protection type wallpaper, described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 30 parts, Waste wood 20 parts, Caulis et Folium Oryzae 20 parts, nano zine oxide 5 parts, chitosan 2 parts, 8 parts of sodium sulfide, sodium hydroxide 25 parts, tapioca 10 Part, butyl acrylate 5 parts, titanate coupling agent 2 parts, PAMC 3 parts, cocoyl Glycine sodium 2 parts, azo Bis-isobutyronitrile 2 parts, deionized water 100 parts, ethyl acetate 30 parts, Chinese medicine powder 10 parts；Described Chinese medicine powder is made up of following material: Wu The Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia；Described activated zinc oxide particle diameter≤50 nanometer, described in Medicated powder is made up of following methods: Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia are dried, and uses powder It is 20-100 mesh that broken machine is crushed to grain diameter, adds 10 times of weight ethanol vacuum extraction 2 hours, filtration to extracting solution, will carry After being spray-dried after taking liquid reduced-pressure backflow, obtain described Chinese medicine powder by being ground to particle diameter less than 20 microns.
The preparation method of described mosquito-proof environment protection type wallpaper, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae After the sodium hydroxide solution using 5% soaks 3 days, by carrying out rubbing 1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture low In 10%, use fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally the friperie through pulverizing, Caulis et Folium Oryzae are mixed with waste wood and adopt Pulverize with high-pressure pulse nano-scale crusher, be crushed to grain diameter and be less than 10 microns, add deionized water, sodium sulfide, hydroxide Sodium is placed in slurrying 2 hours in ultrasound machine, and slurrying temperature is 150 DEG C, prepares fiber pulp；The work of high-pressure pulse nano-scale crusher Being 30kv as voltage, pulse wave number is 20；The frequency of ultrasound wave work is 50 hertz；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide Upper addition titanate coupling agent, uses blender to be stirred continuously 2 hours, and mixing speed is 200rmp, obtains surface-modified nano Zinc oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid Ethyl ester, temperature is heated to 90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 60 DEG C Add azodiisobutyronitrile, stir 4 hours, obtain tapioca-butyl acrylate copolymer and tapioca-polyacrylamide Copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder puts into reactor, the vacuum of reactor Degree is 0.8Mpa, and temperature is 90 DEG C and stirs 4 hours, and coating is dried stamp and obtains described mosquito-proof environment protection type wallpaper.
Embodiment 3
A kind of mosquito-proof environment protection type wallpaper, described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 25 parts, Waste wood 15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, sodium hydroxide 20 parts, tapioca 6 Part, butyl acrylate 3 parts, titanate coupling agent 1 part, PAMC 2 parts, cocoyl Glycine sodium 1 part, azo Bis-isobutyronitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, Chinese medicine powder 8 parts；Described Chinese medicine powder is by following weight portion material system Become: Fructus Evodiae 5 parts, Folium Artemisiae Argyi 5 parts, Fericarpium Citri Limoniae 3 parts, 8 parts of Folium Pini, Fructus Bruceae 4 parts, Cortex Albiziae 3 parts, lavandula angustifolia 2 parts, described activity Zinc oxide particle diameter≤50 nanometer, described Chinese medicine powder is made up of following methods: by Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia are dried, and using pulverizer to be crushed to grain diameter is 20-100 mesh, add 10 times of weight ethanol vacuum extraction 1- 2 hours, filtration to extracting solution, after being spray-dried after extracting solution reduced-pressure backflow, by being ground to particle diameter less than 20 microns To described Chinese medicine powder.
The preparation method of described mosquito-proof environment protection type wallpaper, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae After the sodium hydroxide solution using 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture Content is less than 10%, uses fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally by friperie, Caulis et Folium Oryzae and the waste wood through pulverizing Mixing uses high-pressure pulse nano-scale crusher to pulverize, and is crushed to grain diameter less than 10 microns, add deionized water, sodium sulfide, Sodium hydroxide is placed in slurrying 1-2 hour in ultrasound machine, and slurrying temperature is 100-150 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide Upper addition titanate coupling agent, uses blender to be stirred continuously 1-2 hour, and mixing speed is 100-200rmp, must arrive surface and change Property nano zine oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid Ethyl ester, temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50-60 DEG C adds azodiisobutyronitrile, stirs 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca- Polyacrylamide copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder puts into reactor, and temperature is 80-90 DEG C stirring 2-4 hour, coating be dried stamp obtain described mosquito-proof environment protection type wallpaper.
Embodiment 4
A kind of mosquito-proof environment protection type wallpaper, described mosquito-proof environment protection type wallpaper is made up of following weight portion material: friperie 25 parts, Waste wood 15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, sodium hydroxide 20 parts, tapioca 7 Part, butyl acrylate 3 parts, titanate coupling agent 1 part, PAMC 2 parts, cocoyl Glycine sodium 1 part, azo Bis-isobutyronitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, Chinese medicine powder 8 parts；Described Chinese medicine powder is by following weight portion material system Become: Fructus Evodiae 10 parts, Folium Artemisiae Argyi 10 parts, Fericarpium Citri Limoniae 8 parts, 15 parts of Folium Pini, Fructus Bruceae 5 parts, Cortex Albiziae 6 parts, lavandula angustifolia 5 parts.
The preparation method of described mosquito-proof environment protection type wallpaper, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae After the sodium hydroxide solution using 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture Content is less than 10%, uses fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally by friperie, Caulis et Folium Oryzae and the waste wood through pulverizing Mixing uses high-pressure pulse nano-scale crusher to pulverize, and is crushed to grain diameter less than 10 microns, add deionized water, sodium sulfide, Sodium hydroxide is placed in slurrying 1-2 hour in ultrasound machine, and slurrying temperature is 100-150 DEG C, prepares fiber pulp；Nanometer high-tension pulse The running voltage rushing pulverizer is 30-40kv, and pulse wave number is 20-30；The frequency of ultrasound wave work is 50-100 hertz；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide Upper addition titanate coupling agent, uses blender to be stirred continuously 1-2 hour, and mixing speed is 100-200rmp, must arrive surface and change Property nano zine oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid Ethyl ester, temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50-60 DEG C adds azodiisobutyronitrile, stirs 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca- Polyacrylamide copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder puts into reactor, the vacuum of reactor Degree is 0.8-0.9Mpa, and temperature is 80-90 DEG C and stirs 2-4 hour, and coating is dried stamp and obtains described mosquito-proof environment protection type wallpaper.
Although embodiment of the present invention are disclosed as above, but it is not restricted in description and embodiment listed Using, it can be applied to various applicable the field of the invention completely, for those skilled in the art, and can be easily Realizing other amendment, therefore under the general concept limited without departing substantially from claim and equivalency range, the present invention does not limit In specific details with shown here as the embodiment with description.

Claims (8)

1. a mosquito-proof environment protection type wallpaper, it is characterised in that described mosquito-proof environment protection type wallpaper is made up of following weight portion material: old Clothes 20-30 part, waste wood 10-20 part, Caulis et Folium Oryzae 10-20 part, nano zine oxide 2-5 part, chitosan 1-2 part, sodium sulfide 2-8 Part, sodium hydroxide 10-25 part, tapioca 5-10 part, butyl acrylate 2-5 part, titanate coupling agent 1-2 part, cation are gathered Acrylamide 1-3 part, cocoyl Glycine sodium 1-2 part, azodiisobutyronitrile 1-2 part, deionized water 60-100 part, acetic acid second Ester 20-30 part, Chinese medicine powder 5-10 part；Described Chinese medicine powder is made up of following material: Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, crow gallbladder Son, Cortex Albiziae, lavandula angustifolia.
Mosquito-proof environment protection type wallpaper the most as claimed in claim 1, it is characterised in that described mosquito-proof environment protection type wallpaper is by following weight Part material is made: friperie 25 parts, waste wood 15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, Sodium hydroxide 20 parts, tapioca 7 parts, butyl acrylate 3 parts, titanate coupling agent 1 part, PAMC 2 parts, coconut palm Oleoyl Glycine sodium 1 part, azodiisobutyronitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, Chinese medicine powder 8 parts；In described Medicated powder is made up of following weight portion material: Fructus Evodiae 5-10 part, Folium Artemisiae Argyi 5-10 part, Fericarpium Citri Limoniae 3-8 part, Folium Pini 8-15 part, crow gallbladder Sub-4-5 part, Cortex Albiziae 3-6 part, lavandula angustifolia 2-5 part.
Mosquito-proof environment protection type wallpaper the most as claimed in claim 1, it is characterised in that described activated zinc oxide particle diameter≤50 nanometer.
Mosquito-proof environment protection type wallpaper the most as claimed in claim 1, it is characterised in that described tapioca and the weight of butyl acrylate Amount ratio is 2: 1.
Mosquito-proof environment protection type wallpaper the most as claimed in claim 1, it is characterised in that described Chinese medicine powder is made up of following methods: will Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia are dried, and use pulverizer to be crushed to grain diameter and are 20-100 mesh, adds 10 times of weight ethanol vacuum extraction 1-2 hour, filtration to extracting solution, will spray after extracting solution reduced-pressure backflow After drying, described Chinese medicine powder is obtained less than 20 microns by being ground to particle diameter.
6. the preparation method of the mosquito-proof environment protection type wallpaper as described in arbitrary in claim 1-5, it is characterised in that include following step Rapid:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, Caulis et Folium Oryzae used After the sodium hydroxide solution of 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture Less than 10%, use fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally the friperie through pulverizing, Caulis et Folium Oryzae are mixed with waste wood Employing high-pressure pulse nano-scale crusher is pulverized, and is crushed to grain diameter and is less than 10 microns, adds deionized water, sodium sulfide, hydrogen-oxygen Changing sodium and be placed in slurrying 1-2 hour in ultrasound machine, slurrying temperature is 100-150 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add sodium hydroxide after add at once Entering titanate coupling agent, use blender to be stirred continuously 1-2 hour, mixing speed is 100-200rmp, obtains surface modification and receives Rice zinc oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, adds ethyl acetate, Temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50-60 DEG C Add azodiisobutyronitrile, stir 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca-polyacrylamide Amine copolymer thing；
Step 4, by common to the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-butyl acrylate Polymers and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder puts into reactor, and temperature is 80-90 DEG C and stirs Mixing 2-4 hour, coating is dried stamp and obtains described mosquito-proof environment protection type wallpaper.
The preparation method of mosquito-proof environment protection type wallpaper the most as claimed in claim 6, it is characterised in that in step one, nanometer high pressure The running voltage of pulse crusher is 30-40kv, and pulse wave number is 20-30；The frequency of ultrasound wave work is 50-100 hertz.
The preparation method of mosquito-proof environment protection type wallpaper the most as claimed in claim 6, it is characterised in that in step 4, reactor Vacuum is 0.8-0.9Mpa.
CN201610767187.7A 2016-08-30 2016-08-30 Mosquito-proof environment protection type wallpaper Pending CN106283789A (en)

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CN111657285A (en) * 2020-06-19 2020-09-15 福建省宇诚环保科技有限公司 Sterilizing and disinfecting mosquito repellent liquid and preparation method thereof
CN111657285B (en) * 2020-06-19 2022-02-22 福建省宇诚环保科技有限公司 Sterilizing and disinfecting mosquito repellent liquid and preparation method thereof

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