CN106283792A - The mosquito-proof environment protection type wallpaper of noctilucence - Google Patents
The mosquito-proof environment protection type wallpaper of noctilucence Download PDFInfo
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- CN106283792A CN106283792A CN201610772987.8A CN201610772987A CN106283792A CN 106283792 A CN106283792 A CN 106283792A CN 201610772987 A CN201610772987 A CN 201610772987A CN 106283792 A CN106283792 A CN 106283792A
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- noctilucence
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/14—Secondary fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/143—Agents preventing ageing of paper, e.g. radiation absorbing substances
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Architecture (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of mosquito-proof environment protection type wallpaper of noctilucence, be made up of following weight portion material: friperie 20 30 parts, waste wood 10 20 parts, Caulis et Folium Oryzae 10 20 parts, nano zine oxide 25 parts, chitosan 12 parts, 28 parts of sodium sulfide, sodium hydroxide 10 25 parts, tapioca 5 10 parts, butyl acrylate 25 parts, titanate coupling agent 12 parts, PAMC 13 parts, cocoyl Glycine sodium 12 parts, azodiisobutyronitrile 12 parts, deionized water 60 100 parts, ethyl acetate 20 30 parts, 36 parts of fluorescent material, Chinese medicine powder 5 10 parts；The mosquito-proof environment protection type wallpaper of noctilucence of the present invention uses friperie, waste wood and Caulis et Folium Oryzae as fiber base material, effectively it is beneficial to resource, avoid the wasting of resources, reach environment protecting, wallpaper contains Chinese medicine powder and plays killing action, wallpaper contains fluorescent material can attract mosquito, cooperates with Chinese medicine powder, dispels mosquito effect notable.
Description
Technical field
The present invention relates to a kind of mosquito-proof environment protection type wallpaper of noctilucence, belong to wallpaper technical field.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material the most widely.Because it is many that wallpaper has color
Other house decorative materials multiple such as sample, pattern are abundant, luxurious style, safety and environmental protection, easy construction, affordable cannot compare
The feature intended, therefore obtain considerable degree of universal at developed countries and regions such as America and Europe, Southeast Asia, Japan.Wallpaper is divided into a lot
Class, such as coating wallpaper, overlay film wallpaper, embossing wallpaper etc..Generally produce body paper, then adding through different operation with bleached wood pulp
Work processes, as be coated with, prints, emboss or surface being covered and moulded, the most cut, pack after dispatch from the factory.Because having certain intensity, U.S.
The appearance seen and good water repelling property, be widely used in the interior decoration etc. in house, office, hotel.The raw material of wallpaper is general
Being wood, bamboo etc., owing to being widely used, the usage amount of wallpaper gets more and more, and raw material is in short supply, causes trees, bamboo grove to meet with
The denudation of degree, resource excessive use.
Summary of the invention
It is an object of the invention to solve the problems referred to above, and a kind of mosquito-proof environment protection type wallpaper of noctilucence is provided, present invention night
The mosquito-proof environment protection type wallpaper of light uses friperie, waste wood and Caulis et Folium Oryzae as fiber base material, the most beneficially resource, it is to avoid resource wave
Taking, reach environment protecting, employing Chinese medicine powder is vegetable material, can kill but to human body non-hazardous, and containing calming the nerves composition, energy
Releive body and mind, make people's ataraxy, and wallpaper contains fluorescent material and can attract mosquito, cooperates with Chinese medicine powder, dispels mosquito
Effect is notable.
The technical scheme that the present invention provides is:
A kind of mosquito-proof environment protection type wallpaper of noctilucence, the mosquito-proof environment protection type wallpaper of described noctilucence is made up of following weight portion material: old
Clothes 20-30 part, waste wood 10-20 part, Caulis et Folium Oryzae 10-20 part, nano zine oxide 2-5 part, chitosan 1-2 part, sodium sulfide 2-8
Part, sodium hydroxide 10-25 part, tapioca 5-10 part, butyl acrylate 2-5 part, titanate coupling agent 1-2 part, cation are gathered
Acrylamide 1-3 part, cocoyl Glycine sodium 1-2 part, azodiisobutyronitrile 1-2 part, deionized water 60-100 part, acetic acid second
Ester 20-30 part, fluorescent material 3-6 part, Chinese medicine powder 5-10 part；Described Chinese medicine powder is made up of following material: Fructus Evodiae, Folium Artemisiae Argyi, Fructus Citri Limoniae
Skin, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia.
Preferably, the mosquito-proof environment protection type wallpaper of described noctilucence is made up of following weight portion material: friperie 25 parts, waste wood
15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, sodium hydroxide 20 parts, tapioca 7 parts, propylene
Acid butyl ester 3 parts, titanate coupling agent 1 part, PAMC 2 parts, cocoyl Glycine sodium 1 part, azo two isobutyl
Nitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, 5 parts of fluorescent material, Chinese medicine powder 8 parts；Described Chinese medicine powder is by following weight portion material
Material is made: Fructus Evodiae 5-10 part, Folium Artemisiae Argyi 5-10 part, Fericarpium Citri Limoniae 3-8 part, Folium Pini 8-15 part, Fructus Bruceae 4-5 part, Cortex Albiziae 3-6
Part, lavandula angustifolia 2-5 part.
Preferably, described activated zinc oxide particle diameter≤50 nanometer.
Preferably, described tapioca is 2: 1 with the weight ratio of butyl acrylate.
Preferably, described Chinese medicine powder is made up of following methods: by Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, conjunction
Joyous skin, lavandula angustifolia are dried, and using pulverizer to be crushed to grain diameter is 20-100 mesh, add 10 times of weight ethanol vacuum extraction 1-2
Hour, filtration to extracting solution, after being spray-dried after extracting solution reduced-pressure backflow, obtain less than 20 microns by being ground to particle diameter
Described Chinese medicine powder.
The preparation method of a kind of described mosquito-proof environment protection type wallpaper of noctilucence, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae
After the sodium hydroxide solution using 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture
Content is less than 10%, uses fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally by friperie, Caulis et Folium Oryzae and the waste wood through pulverizing
Mixing uses high-pressure pulse nano-scale crusher to pulverize, and is crushed to grain diameter less than 10 microns, add deionized water, sodium sulfide,
Sodium hydroxide is placed in slurrying 1-2 hour in ultrasound machine, and slurrying temperature is 100-150 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide
Upper addition titanate coupling agent, uses blender to be stirred continuously 1-2 hour, and mixing speed is 100-200rmp, must arrive surface and change
Property nano zine oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid
Ethyl ester, temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to
50-60 DEG C adds azodiisobutyronitrile, stirs 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca-
Polyacrylamide copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth
Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder, fluorescent material puts into reactor, temperature
Stirring 2-4 hour for 80-90 DEG C, coating is dried stamp and obtains the mosquito-proof environment protection type wallpaper of described noctilucence.
Preferably, in step one, the running voltage of high-pressure pulse nano-scale crusher is 30-40kv, and pulse wave number is 20-
30；The frequency of ultrasound wave work is 50-100 hertz.
Preferably, in step 4, the vacuum of reactor is 0.8-0.9Mpa.
Beneficial effects of the present invention is as follows:
In the mosquito-proof environment protection type wallpaper of noctilucence of the present invention, nano zine oxide can uniformly divide by after titanate coupling agent modified
Cloth in the carrier, self is not susceptible to agglomeration, makes fiber pulp surface at friperie, waste wood and Caulis et Folium Oryzae and forms one layer of painting
Layer, plays antibacterial, mildew-resistant, radiation resistance, tapioca and butyl acrylate, PAMC copolymerization in the present invention
Reaction obtains tapioca-butyl acrylate copolymer and tapioca-polyacrylamide copolymer, and these copolymers can be with fibre
Dimension slurry forms fine and close network structure, significantly improves the moisture resistance of wallpaper, also improves the ageing resistace of wallpaper, extends wall
In the service life of paper, Chinese medicine powder contains Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae can be dispelled and be killed mosquito, plays mosquito-proof effect, its
His composition Fructus Evodiae, Cortex Albiziae, lavandula angustifolia play sedative action, and time dark, the fluorescence in wallpaper sends light and attracts mosquito and Chinese medicine
Powder cooperates, and dispels mosquito effect notable；The mosquito-proof environment protection type wallpaper of noctilucence the most of the present invention uses friperie, waste wood and rice
Grass is as fiber base material, the most beneficially resource, it is to avoid the wasting of resources, reaches environment protecting, has mosquito-proof, mildew-resistant, spoke antibacterial, anti-
Penetrate, protection against the tide, the several functions such as aging resistance.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, to make those skilled in the art with reference to saying
Bright book word can be implemented according to this.
The relative content being previously mentioned in the present invention is mass percent content, except having specified otherwise.
Embodiment 1:
A kind of mosquito-proof environment protection type wallpaper of noctilucence, the mosquito-proof environment protection type wallpaper of described noctilucence is made up of following weight portion material: old
20 parts of clothes, waste wood 10 parts, Caulis et Folium Oryzae 10 parts, nano zine oxide 2 parts, chitosan 1 part, 2 parts of sodium sulfide, sodium hydroxide 10 parts,
Tapioca 5 parts, butyl acrylate 2 parts, titanate coupling agent 1 part, PAMC 1 part, cocoyl glycine
1 part of sodium, azodiisobutyronitrile 1 part, deionized water 60 parts, ethyl acetate 20 parts, 3 parts of fluorescent material, Chinese medicine powder 5 parts；Described Chinese medicine
Powder is made up of following material: Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia.
The preparation method of the mosquito-proof environment protection type wallpaper of described noctilucence, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae
After the sodium hydroxide solution using 5% soaks 2 days, by carrying out rubbing 0.5 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture
Less than 10%, use fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally the friperie through pulverizing, Caulis et Folium Oryzae are mixed with waste wood
Employing high-pressure pulse nano-scale crusher is pulverized, and is crushed to grain diameter and is less than 10 microns, adds deionized water, sodium sulfide, hydrogen-oxygen
Changing sodium and be placed in slurrying 1 hour in ultrasound machine, slurrying temperature is 100 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide
Upper addition titanate coupling agent, uses blender to be stirred continuously 1 hour, and mixing speed is 100rmp, obtains surface-modified nano
Zinc oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid
Ethyl ester, temperature is heated to 80 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50 DEG C
Add azodiisobutyronitrile, stir 3 hours, obtain tapioca-butyl acrylate copolymer and tapioca-polyacrylamide
Copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth
Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder, fluorescent material puts into reactor, temperature
Being 80 DEG C to stir 2 hours, coating is dried stamp and obtains the mosquito-proof environment protection type wallpaper of described noctilucence.
Embodiment 2
A kind of mosquito-proof environment protection type wallpaper of noctilucence, the mosquito-proof environment protection type wallpaper of described noctilucence is made up of following weight portion material: old
30 parts of clothes, waste wood 20 parts, Caulis et Folium Oryzae 20 parts, nano zine oxide 5 parts, chitosan 2 parts, 8 parts of sodium sulfide, sodium hydroxide 25 parts,
Tapioca 10 parts, butyl acrylate 5 parts, titanate coupling agent 2 parts, PAMC 3 parts, cocoyl glycine
2 parts of sodium, azodiisobutyronitrile 2 parts, deionized water 100 parts, ethyl acetate 30 parts, 6 parts of fluorescent material, Chinese medicine powder 10 parts；In described
Medicated powder is made up of following material: Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia；Described active oxidation
Zinc granule footpath≤50 nanometer, described Chinese medicine powder is made up of following methods: by Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Herba Albiziae
Skin, lavandula angustifolia are dried, and using pulverizer to be crushed to grain diameter is 20-100 mesh, adds 10 times of weight ethanol vacuum extraction 2 hours,
Filter to extracting solution, after being spray-dried after extracting solution reduced-pressure backflow, obtain described less than 20 microns by being ground to particle diameter
Chinese medicine powder.
The preparation method of the mosquito-proof environment protection type wallpaper of described noctilucence, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae
After the sodium hydroxide solution using 5% soaks 3 days, by carrying out rubbing 1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture low
In 10%, use fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally the friperie through pulverizing, Caulis et Folium Oryzae are mixed with waste wood and adopt
Pulverize with high-pressure pulse nano-scale crusher, be crushed to grain diameter and be less than 10 microns, add deionized water, sodium sulfide, hydroxide
Sodium is placed in slurrying 2 hours in ultrasound machine, and slurrying temperature is 150 DEG C, prepares fiber pulp；The work of high-pressure pulse nano-scale crusher
Being 30kv as voltage, pulse wave number is 20；The frequency of ultrasound wave work is 50 hertz；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide
Upper addition titanate coupling agent, uses blender to be stirred continuously 2 hours, and mixing speed is 200rmp, obtains surface-modified nano
Zinc oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid
Ethyl ester, temperature is heated to 90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 60 DEG C
Add azodiisobutyronitrile, stir 4 hours, obtain tapioca-butyl acrylate copolymer and tapioca-polyacrylamide
Copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth
Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder, fluorescent material puts into reactor, reaction
The vacuum of still is 0.8Mpa, and temperature is 90 DEG C and stirs 4 hours, and coating is dried stamp and obtains described noctilucence mosquito-proof environment-friendly type wall
Paper.
Embodiment 3
A kind of mosquito-proof environment protection type wallpaper of noctilucence, the mosquito-proof environment protection type wallpaper of described noctilucence is made up of following weight portion material: old
25 parts of clothes, waste wood 15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, sodium hydroxide 20 parts,
Tapioca 6 parts, butyl acrylate 3 parts, titanate coupling agent 1 part, PAMC 2 parts, cocoyl glycine
1 part of sodium, azodiisobutyronitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, 5 parts of fluorescent material, Chinese medicine powder 8 parts；Described Chinese medicine
Powder is made up of following weight portion material: Fructus Evodiae 5 parts, Folium Artemisiae Argyi 5 parts, Fericarpium Citri Limoniae 3 parts, 8 parts of Folium Pini, Fructus Bruceae 4 parts, Cortex Albiziae 3
Part, lavandula angustifolia 2 parts, described activated zinc oxide particle diameter≤50 nanometer, described Chinese medicine powder is made up of following methods: by Fructus Evodiae, Chinese mugwort
Grass, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia are dried, and using pulverizer to be crushed to grain diameter is 20-100 mesh, adds
Enter 10 times of weight ethanol vacuum extraction 1-2 hour, filtration to extracting solution, after being spray-dried after extracting solution reduced-pressure backflow, pass through
It is ground to particle diameter and obtains described Chinese medicine powder less than 20 microns.
The preparation method of the mosquito-proof environment protection type wallpaper of described noctilucence, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae
After the sodium hydroxide solution using 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture
Content is less than 10%, uses fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally by friperie, Caulis et Folium Oryzae and the waste wood through pulverizing
Mixing uses high-pressure pulse nano-scale crusher to pulverize, and is crushed to grain diameter less than 10 microns, add deionized water, sodium sulfide,
Sodium hydroxide is placed in slurrying 1-2 hour in ultrasound machine, and slurrying temperature is 100-150 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide
Upper addition titanate coupling agent, uses blender to be stirred continuously 1-2 hour, and mixing speed is 100-200rmp, must arrive surface and change
Property nano zine oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid
Ethyl ester, temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to
50-60 DEG C adds azodiisobutyronitrile, stirs 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca-
Polyacrylamide copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth
Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder, fluorescent material puts into reactor, temperature
Stirring 2-4 hour for 80-90 DEG C, coating is dried stamp and obtains the mosquito-proof environment protection type wallpaper of described noctilucence.
Embodiment 4
A kind of mosquito-proof environment protection type wallpaper of noctilucence, the mosquito-proof environment protection type wallpaper of described noctilucence is made up of following weight portion material: old
25 parts of clothes, waste wood 15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, 4 parts of sodium sulfide, sodium hydroxide 20 parts,
Tapioca 7 parts, butyl acrylate 3 parts, titanate coupling agent 1 part, PAMC 2 parts, cocoyl glycine
1 part of sodium, azodiisobutyronitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, 5 parts of fluorescent material, Chinese medicine powder 8 parts；Described Chinese medicine
Powder is made up of following weight portion material: Fructus Evodiae 10 parts, Folium Artemisiae Argyi 10 parts, Fericarpium Citri Limoniae 8 parts, 15 parts of Folium Pini, Fructus Bruceae 5 parts, Herba Albiziae
Skin 6 parts, lavandula angustifolia 5 parts.
The preparation method of the mosquito-proof environment protection type wallpaper of described noctilucence, comprises the following steps:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, by Caulis et Folium Oryzae
After the sodium hydroxide solution using 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture
Content is less than 10%, uses fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally by friperie, Caulis et Folium Oryzae and the waste wood through pulverizing
Mixing uses high-pressure pulse nano-scale crusher to pulverize, and is crushed to grain diameter less than 10 microns, add deionized water, sodium sulfide,
Sodium hydroxide is placed in slurrying 1-2 hour in ultrasound machine, and slurrying temperature is 100-150 DEG C, prepares fiber pulp；Nanometer high-tension pulse
The running voltage rushing pulverizer is 30-40ky, and pulse wave number is 20-30；The frequency of ultrasound wave work is 50-100 hertz；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add horse after sodium hydroxide
Upper addition titanate coupling agent, uses blender to be stirred continuously 1-2 hour, and mixing speed is 100-200rmp, must arrive surface and change
Property nano zine oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, add acetic acid
Ethyl ester, temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to
50-60 DEG C adds azodiisobutyronitrile, stirs 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca-
Polyacrylamide copolymer；
Step 4, by the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-acrylic acid fourth
Ester copolymer and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder, fluorescent material puts into reactor, reaction
The vacuum of still is 0.8-0.9Mpa, and temperature is 80-90 DEG C and stirs 2-4 hour, and it is mosquito-proof that the dry stamp of coating obtains described noctilucence
Environment protection type wallpaper.
Although embodiment of the present invention are disclosed as above, but it is not restricted in description and embodiment listed
Using, it can be applied to various applicable the field of the invention completely, for those skilled in the art, and can be easily
Realizing other amendment, therefore under the general concept limited without departing substantially from claim and equivalency range, the present invention does not limit
In specific details with shown here as the embodiment with description.
Claims (8)
1. the mosquito-proof environment protection type wallpaper of noctilucence, it is characterised in that the mosquito-proof environment protection type wallpaper of described noctilucence is by following weight portion material
Material is made: friperie 20-30 part, waste wood 10-20 part, Caulis et Folium Oryzae 10-20 part, nano zine oxide 2-5 part, chitosan 1-2 part, sulfur
Change sodium 2-8 part, sodium hydroxide 10-25 part, tapioca 5-10 part, butyl acrylate 2-5 part, titanate coupling agent 1-2 part, sun
Cationic polyacrylamide 1-3 part, cocoyl Glycine sodium 1-2 part, azodiisobutyronitrile 1-2 part, deionized water 60-100 part,
Ethyl acetate 20-30 part, fluorescent material 3-6 part, Chinese medicine powder 5-10 part；Described Chinese medicine powder is made up of following material: Fructus Evodiae, Chinese mugwort
Grass, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia.
2. the mosquito-proof environment protection type wallpaper of noctilucence as claimed in claim 1, it is characterised in that the mosquito-proof environment protection type wallpaper of described noctilucence by
Following weight portion material is made: friperie 25 parts, waste wood 15 parts, Caulis et Folium Oryzae 12 parts, nano zine oxide 3 parts, chitosan 2 parts, sulfur
Change 4 parts of sodium, sodium hydroxide 20 parts, tapioca 7 parts, butyl acrylate 3 parts, titanate coupling agent 1 part, cation polypropylene acyl
Amine 2 parts, cocoyl Glycine sodium 1 part, azodiisobutyronitrile 2 parts, deionized water 80 parts, ethyl acetate 25 parts, fluorescent material 5
Part, Chinese medicine powder 8 parts；Described Chinese medicine powder is made up of following weight portion material: Fructus Evodiae 5-10 part, Folium Artemisiae Argyi 5-10 part, Fericarpium Citri Limoniae 3-8
Part, Folium Pini 8-15 part, Fructus Bruceae 4-5 part, Cortex Albiziae 3-6 part, lavandula angustifolia 2-5 part.
3. the mosquito-proof environment protection type wallpaper of noctilucence as claimed in claim 1, it is characterised in that described activated zinc oxide particle diameter≤50 are received
Rice.
4. the mosquito-proof environment protection type wallpaper of noctilucence as claimed in claim 1, it is characterised in that described tapioca and butyl acrylate
Weight ratio be 2: 1.
5. the mosquito-proof environment protection type wallpaper of noctilucence as claimed in claim 1, it is characterised in that described Chinese medicine powder is by following methods system
Become: Fructus Evodiae, Folium Artemisiae Argyi, Fericarpium Citri Limoniae, Folium Pini, Fructus Bruceae, Cortex Albiziae, lavandula angustifolia are dried, use pulverizer to be crushed to particle
Footpath is 20-100 mesh, add 10 times weight ethanol vacuum extraction 1-2 hour, filtration to extracting solution, after extracting solution reduced-pressure backflow
After spray drying, obtain described Chinese medicine powder by being ground to particle diameter less than 20 microns.
6. the preparation method of the mosquito-proof environment protection type wallpaper of noctilucence as described in arbitrary in claim 1-5, it is characterised in that include with
Lower step:
Step one, the plastics on friperie and metal are removed after, use fabric cutting machine to be pulverized by friperie, Caulis et Folium Oryzae used
After the sodium hydroxide solution of 5% soaks 2-3 days, by carrying out rubbing 0.5-1 hour through the Caulis et Folium Oryzae soaked, it is dried to moisture
Less than 10%, use fabric cutting machine to be pulverized by dried Caulis et Folium Oryzae, finally the friperie through pulverizing, Caulis et Folium Oryzae are mixed with waste wood
Employing high-pressure pulse nano-scale crusher is pulverized, and is crushed to grain diameter and is less than 10 microns, adds deionized water, sodium sulfide, hydrogen-oxygen
Changing sodium and be placed in slurrying 1-2 hour in ultrasound machine, slurrying temperature is 100-150 DEG C, prepares fiber pulp；
Step 2, nano zine oxide, deionized water and ethyl acetate are mixed and heated to 80 DEG C add sodium hydroxide after add at once
Entering titanate coupling agent, use blender to be stirred continuously 1-2 hour, mixing speed is 100-200rmp, obtains surface modification and receives
Rice zinc oxide；
Step 3, tapioca is added deionized water, cocoyl Glycine sodium, after stirring 0.5 hour, adds ethyl acetate,
Temperature is heated to 80-90 DEG C and adds butyl acrylate, PAMC, and after stirring 0.5 hour, temperature drops to 50-60 DEG C
Add azodiisobutyronitrile, stir 3-4 hour, obtain tapioca-butyl acrylate copolymer and tapioca-polyacrylamide
Amine copolymer thing；
Step 4, by common to the fiber pulp of step one, the Modified Nano-ZnO of step 2, tapioca-butyl acrylate
Polymers and tapioca-polyacrylamide copolymer mix with chitosan, Chinese medicine powder, fluorescent material puts into reactor, and temperature is 80-
90 DEG C are stirred 2-4 hour, and coating is dried stamp and obtains the mosquito-proof environment protection type wallpaper of described noctilucence.
7. the preparation method of the mosquito-proof environment protection type wallpaper of noctilucence as claimed in claim 6, it is characterised in that in step one, nanometer
The running voltage of high-voltage pulse pulverizer is 30-40kv, and pulse wave number is 20-30；The frequency of ultrasound wave work is that 50-100 is conspicuous
Hereby.
8. the preparation method of the mosquito-proof environment protection type wallpaper of noctilucence as claimed in claim 6, it is characterised in that in step 4, reaction
The vacuum of still is 0.8-0.9Mpa.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107401082A (en) * | 2017-06-30 | 2017-11-28 | 广西点图包装有限公司 | Wallpaper paper pulp |
| CN107988850A (en) * | 2017-12-12 | 2018-05-04 | 佛山早稻田环保节能科技有限公司 | A kind of environmental protection wall paper |
| CN108797172A (en) * | 2018-06-30 | 2018-11-13 | 泾县汇鼎锋建筑装饰工程有限公司 | A kind of manufacturing method of resistance to deformation high efficiency filter paper |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403202A (en) * | 2002-09-11 | 2003-03-19 | 田永丰 | High-pressure pulse nano-scale crusher |
| CN1869089A (en) * | 2006-07-03 | 2006-11-29 | 浙江工业大学 | Preparation method of graft starch |
| WO2007076703A1 (en) * | 2005-12-30 | 2007-07-12 | Yi, Qizun | Starch-(meth)acrylate graft copolymer, oil-absorbing expansion meterial as well as oil and water-absorbing expansion meterial containing the copolymer, both sealer and packer made of the meterial |
| CN103012679A (en) * | 2012-12-10 | 2013-04-03 | 浙江大学 | Synthetic method of starch modified graft copolymer emulsion for surface sizing |
| CN104404658A (en) * | 2014-10-29 | 2015-03-11 | 合肥新桥制衣有限公司 | Wallpaper production method through waste and used cloth |
| CN105064642A (en) * | 2015-08-14 | 2015-11-18 | 苏州绿汇环境科技有限公司 | Surface decoration wallpaper |
| CN105297531A (en) * | 2015-11-16 | 2016-02-03 | 上海畅厘信息科技有限公司 | Paper pulp |
| CN105696408A (en) * | 2016-04-05 | 2016-06-22 | 哈尔滨理工大学 | Nano modified paper based on surface modification and preparation method thereof |
| CN105803860A (en) * | 2016-04-22 | 2016-07-27 | 安徽索亚装饰材料有限公司 | Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof |
-
2016
- 2016-08-30 CN CN201610772987.8A patent/CN106283792A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1403202A (en) * | 2002-09-11 | 2003-03-19 | 田永丰 | High-pressure pulse nano-scale crusher |
| WO2007076703A1 (en) * | 2005-12-30 | 2007-07-12 | Yi, Qizun | Starch-(meth)acrylate graft copolymer, oil-absorbing expansion meterial as well as oil and water-absorbing expansion meterial containing the copolymer, both sealer and packer made of the meterial |
| CN1869089A (en) * | 2006-07-03 | 2006-11-29 | 浙江工业大学 | Preparation method of graft starch |
| CN103012679A (en) * | 2012-12-10 | 2013-04-03 | 浙江大学 | Synthetic method of starch modified graft copolymer emulsion for surface sizing |
| CN104404658A (en) * | 2014-10-29 | 2015-03-11 | 合肥新桥制衣有限公司 | Wallpaper production method through waste and used cloth |
| CN105064642A (en) * | 2015-08-14 | 2015-11-18 | 苏州绿汇环境科技有限公司 | Surface decoration wallpaper |
| CN105297531A (en) * | 2015-11-16 | 2016-02-03 | 上海畅厘信息科技有限公司 | Paper pulp |
| CN105696408A (en) * | 2016-04-05 | 2016-06-22 | 哈尔滨理工大学 | Nano modified paper based on surface modification and preparation method thereof |
| CN105803860A (en) * | 2016-04-22 | 2016-07-27 | 安徽索亚装饰材料有限公司 | Anti-flaming wallpaper body stock with mosquito repelling effect and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107401082A (en) * | 2017-06-30 | 2017-11-28 | 广西点图包装有限公司 | Wallpaper paper pulp |
| CN107988850A (en) * | 2017-12-12 | 2018-05-04 | 佛山早稻田环保节能科技有限公司 | A kind of environmental protection wall paper |
| CN108797172A (en) * | 2018-06-30 | 2018-11-13 | 泾县汇鼎锋建筑装饰工程有限公司 | A kind of manufacturing method of resistance to deformation high efficiency filter paper |
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