CN106281770A - A kind of hard water resistance fabric detergent and preparation method thereof - Google Patents

A kind of hard water resistance fabric detergent and preparation method thereof Download PDF

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Publication number
CN106281770A
CN106281770A CN201610643137.8A CN201610643137A CN106281770A CN 106281770 A CN106281770 A CN 106281770A CN 201610643137 A CN201610643137 A CN 201610643137A CN 106281770 A CN106281770 A CN 106281770A
Authority
CN
China
Prior art keywords
sodium
disodium
polyoxyethylene ether
hard water
under conditions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610643137.8A
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Chinese (zh)
Inventor
王从伟
李化真
程伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Yongjia New Mstar Technology Ltd
Original Assignee
Hefei Yongjia New Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Yongjia New Mstar Technology Ltd filed Critical Hefei Yongjia New Mstar Technology Ltd
Priority to CN201610643137.8A priority Critical patent/CN106281770A/en
Publication of CN106281770A publication Critical patent/CN106281770A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Abstract

The invention discloses a kind of hard water resistance fabric detergent and preparation method thereof, be made up of the raw material of following weight portion: cocos nucifera oil acyl both sexes base oxalic acid disodium 10 15, N oleoyl N N-methyltaurine sodium 8 12, lauroyl monoethanolamine 6 11, Coco-Glucoside 49, fatty alcohol-polyoxyethylene ether carboxylic acid sodium 7 13, isomerous tridecanol polyoxyethylene ether phosphate ester 5 10, dodecanamide propyl hydroxy sulfo lycine 9 14, Fatty acid methyl ester sodium sulfonate 5 10, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 47, water 85 95.Detergent detergency of the present invention is good, and resistance to hard water is strong, it is adaptable to coastal resident uses in the seawater.

Description

A kind of hard water resistance fabric detergent and preparation method thereof
Technical field
The present invention relates to a kind of hard water resistance fabric detergent and preparation method thereof, belong to articles for washing technical field.
Background technology
Modern detergent is the complex mixture containing Multiple components, and wherein surfactant has been the main of cleaning action Composition, other compositions or for improving and increase the clenaing effect of surfactant or some is special in order to adapt in detergent Need or add for making required and product form.Various surfactants and various auxiliary agent have respective characteristic, These distinct compositions mix, owing to their interphase interaction will produce more preferably clean result.Mesh On front market, the detergent for the dandruff is of a great variety, but most of detergent also exists clean result difference in hard water Shortcoming, it is impossible to meet the market demand.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention be to provide a kind of hard water resistance fabric detergent and Preparation method.
For solving prior art problem, the present invention provides following technical scheme:
A kind of hard water resistance fabric detergent, is made up of the raw material of following weight portion: cocos nucifera oil acyl both sexes base oxalic acid disodium 10- 15, N-oleoyl-N methyl taurine sodium 8-12, lauroyl monoethanolamine 6-11, Coco-Glucoside 4-9, fatty alcohol polyoxy Vinyl Ether carboxylic acid sodium 7-13, isomerous tridecanol polyoxyethylene ether phosphate ester 5-10, dodecanamide propyl hydroxy sulfo lycine 9-14, Fatty acid methyl ester sodium sulfonate 5-10, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 4-7, water 85-95.
The preparation method of a kind of hard water resistance fabric detergent, comprises the following steps:
(1) take 1/4-1/2 amount water heating in water bath to 30-50 DEG C, be sequentially added into N-oleoyl-N-first under mechanical stirring Base sodium taurocholate, isomerous tridecanol polyoxyethylene ether phosphate ester, Coco-Glucoside and Fatty acid methyl ester sodium sulfonate, then adding Thermal power is 200-300W, and rotating speed is magnetic agitation 6-9min under conditions of 200-300r/min, obtains compound A；
(2) take remaining water heating in water bath to 40-60 DEG C, be sequentially added into cocos nucifera oil acyl both sexes base oxalic acid under mechanical stirring Disodium, fatty alcohol-polyoxyethylene ether carboxylic acid sodium and disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, be then 300-400W at microwave power, Rotating speed is microwave stirring 3-6min under conditions of 300-400r/min, obtains compound B；
(3) compound A and compound B being mixed, be 700-900W at power, frequency is ultrasonic under conditions of 30-50KHz Stirring 6-10min, then adjustment solution temperature is to 40-45 DEG C, adds remaining raw material, is the condition of 300-400r/min at rotating speed Lower stirring 4-6min, gets product.
The method have the benefit that
The lauroyl monoethanolamine of interpolation, fatty alcohol-polyoxyethylene ether carboxylic acid sodium, dodecanamide propyl in raw material of the present invention The raw material such as hydroxy sulfo lycine, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, can significantly improve the hard water resistance performance of detergent, firmly Water has the clean result of excellence.Detergent detergency of the present invention is good, and resistance to hard water is strong, it is adaptable to coastal resident is at sea water Middle use.
Detailed description of the invention
Embodiment
A kind of hard water resistance fabric detergent, is made up of the raw material of following weight (kg): cocos nucifera oil acyl both sexes base oxalic acid disodium 12, N-oleoyl-N methyl taurine sodium 10, lauroyl monoethanolamine 9, Coco-Glucoside 7, fatty alcohol-polyoxyethylene ether carboxylic Acid sodium 11, isomerous tridecanol polyoxyethylene ether phosphate ester 8, dodecanamide propyl hydroxy sulfo lycine 11, Fatty acid methyl ester sulfonic acid Sodium 8, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 6, water 90.
The preparation method of a kind of hard water resistance fabric detergent, comprises the following steps:
(1) take the water heating in water bath of 1/3 amount to 40 DEG C, be sequentially added into N-oleoyl-N-methyl cattle sulphur under mechanical stirring Acid sodium, isomerous tridecanol polyoxyethylene ether phosphate ester, Coco-Glucoside and Fatty acid methyl ester sodium sulfonate, then at heating power For 250W, rotating speed is magnetic agitation 7min under conditions of 250r/min, obtains compound A；
(2) take remaining water heating in water bath to 50 DEG C, be sequentially added into cocos nucifera oil acyl both sexes base oxalic acid two under mechanical stirring Sodium, fatty alcohol-polyoxyethylene ether carboxylic acid sodium and disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, be then 350W at microwave power, and rotating speed is Under conditions of 350r/min, microwave stirring 4min, obtains compound B；
(3) being mixed by compound A and compound B, be 800W at power, frequency is ultrasonic agitation under conditions of 40KHz 8min, then adjustment solution temperature is to 44 DEG C, adds remaining raw material, stirs 5min, i.e. under conditions of rotating speed is 350r/min Obtain finished product.
The main performance testing result of the hard water resistance fabric detergent that above-described embodiment prepares is as shown in the table:

Claims (2)

1. a hard water resistance fabric detergent, it is characterised in that be made up of the raw material of following weight portion: cocos nucifera oil acyl both sexes base diethyl Acid disodium 10-15, N-oleoyl-N methyl taurine sodium 8-12, lauroyl monoethanolamine 6-11, Coco-Glucoside 4-9, fat Fat polyoxyethylenated alcohol carboxylic acid sodium 7-13, isomerous tridecanol polyoxyethylene ether phosphate ester 5-10, dodecanamide propyl hydroxyl sulfo group are sweet Dish alkali 9-14, Fatty acid methyl ester sodium sulfonate 5-10, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate 4-7, water 85-95.
The preparation method of a kind of hard water resistance fabric detergent the most according to claim 1, it is characterised in that include following step Rapid:
(1) take 1/4-1/2 amount water heating in water bath to 30-50 DEG C, be sequentially added into N-oleoyl-N-methyl cattle under mechanical stirring Sodium sulfonate, isomerous tridecanol polyoxyethylene ether phosphate ester, Coco-Glucoside and Fatty acid methyl ester sodium sulfonate, then adding hot merit Rate is 200-300W, and rotating speed is magnetic agitation 6-9min under conditions of 200-300r/min, obtains compound A；
(2) take remaining water heating in water bath to 40-60 DEG C, be sequentially added into cocos nucifera oil acyl both sexes base oxalic acid two under mechanical stirring Sodium, fatty alcohol-polyoxyethylene ether carboxylic acid sodium and disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, be then 300-400W at microwave power, turns Speed is microwave stirring 3-6min under conditions of 300-400r/min, obtains compound B；
(3) being mixed by compound A and compound B, be 700-900W at power, frequency is ultrasonic agitation under conditions of 30-50KHz 6-10min, then adjustment solution temperature is to 40-45 DEG C, adds remaining raw material, stirs under conditions of rotating speed is 300-400r/min Mix 4-6min, get product.
CN201610643137.8A 2016-08-08 2016-08-08 A kind of hard water resistance fabric detergent and preparation method thereof Withdrawn CN106281770A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610643137.8A CN106281770A (en) 2016-08-08 2016-08-08 A kind of hard water resistance fabric detergent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610643137.8A CN106281770A (en) 2016-08-08 2016-08-08 A kind of hard water resistance fabric detergent and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110079399A (en) * 2019-05-31 2019-08-02 深圳市润贝化工有限公司 One kind being used for aircraft passenger compartment carpet cleaner
CN110818208A (en) * 2019-10-31 2020-02-21 麦王环境技术股份有限公司 Oil-water-solid three-phase separation cleaning agent for oily sludge and preparation method thereof
CN111690475A (en) * 2020-05-15 2020-09-22 泉后(广州)生物科技研究院有限公司 Hard water-resistant high-efficiency active matter composition and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0569028A2 (en) * 1992-05-07 1993-11-10 Lonza Inc. Shampoos containing polyglyceryl esters
CN103468418A (en) * 2012-06-07 2013-12-25 太仓棨淂服装有限公司 Liquid detergent for clothes
CN103897881A (en) * 2012-12-28 2014-07-02 青岛锦涟鑫商贸有限公司 Method for preparing detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0569028A2 (en) * 1992-05-07 1993-11-10 Lonza Inc. Shampoos containing polyglyceryl esters
CN103468418A (en) * 2012-06-07 2013-12-25 太仓棨淂服装有限公司 Liquid detergent for clothes
CN103897881A (en) * 2012-12-28 2014-07-02 青岛锦涟鑫商贸有限公司 Method for preparing detergent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110079399A (en) * 2019-05-31 2019-08-02 深圳市润贝化工有限公司 One kind being used for aircraft passenger compartment carpet cleaner
CN110818208A (en) * 2019-10-31 2020-02-21 麦王环境技术股份有限公司 Oil-water-solid three-phase separation cleaning agent for oily sludge and preparation method thereof
CN111690475A (en) * 2020-05-15 2020-09-22 泉后(广州)生物科技研究院有限公司 Hard water-resistant high-efficiency active matter composition and application thereof
CN111690475B (en) * 2020-05-15 2021-08-31 泉后(广州)生物科技研究院有限公司 Hard water-resistant high-efficiency active matter composition and application thereof

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Application publication date: 20170104

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