CN106279885A - A kind of flame retardant type plastic package material - Google Patents

A kind of flame retardant type plastic package material Download PDF

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Publication number
CN106279885A
CN106279885A CN201610669028.3A CN201610669028A CN106279885A CN 106279885 A CN106279885 A CN 106279885A CN 201610669028 A CN201610669028 A CN 201610669028A CN 106279885 A CN106279885 A CN 106279885A
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CN
China
Prior art keywords
parts
flame retardant
plastic package
type plastic
package material
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Pending
Application number
CN201610669028.3A
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Chinese (zh)
Inventor
吴江
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Tongcheng Renhe Package Co Ltd
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Tongcheng Renhe Package Co Ltd
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Priority to CN201610669028.3A priority Critical patent/CN106279885A/en
Publication of CN106279885A publication Critical patent/CN106279885A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of flame retardant type plastic package material, be prepared by the raw materials in: polyvinyl resin 40 60 parts, mutual-phenenyl two acid bromide two alcohol ester 10 20 parts, nano-Ag particles 5 10 parts, Graphene 8 12 parts, bamboo fiber 35 parts, garlicin 13 parts, alumina silicate fibre 48 parts, fire retardant 48 parts, 13 parts of barium sulfate, heat stabilizer 1 1.5 parts, aminopropyltriethoxywerene werene 5 10 parts, coupling agent 12 parts, UV absorbent 35 parts.The flame retardant type plastic package material of the present invention is by adding fire retardant, barium sulfate, heat stabilizer so that packaging material have superior flame retardant type and thermostability;By adding nano-Ag particles, Graphene, garlicin, the ethylene gas that the food such as nano-Ag particles accelerated oxidation fruit and vegerable discharge, so as the ethylene contents reduced in package interior environment, realize good fresh-keeping effect, Graphene, garlicin can effectively suppress growing and anticorrosion of antibacterial in packaged food, and freshness and the security performance of packaged food is effectively ensured.

Description

A kind of flame retardant type plastic package material
Technical field
The present invention relates to packaging material field, specifically a kind of flame retardant type plastic package material.
Background technology
Packaging for foodstuff, as the heavier part of current packaging field portion, occupies important in whole packaging field Status.The various problems occurred in field of food safety in recent years, make people more focus on food and packaging material thereof, very To whole production technology, the safety of packaging process, this makes to probe into packaging material for food to bring into schedule.
Plastics are widely used in packaging for foodstuff because of its light weight, the feature such as easy to use, price is low.Fruit and vegerable etc. are new Fresh food can discharge ethylene gas when storing, and will accelerate food decay when ethylene runs up to finite concentration, therefore, as The ethylene contents what reduces in plastic package material is urgent problem.Simultaneously along with social industrialized development, industry Demand constantly promote.Pack at the product of some industry and packaging material are had special requirement, such as, need packing timber Material needs have fire resistance.
Summary of the invention
It is an object of the invention to provide a kind of flame retardant type plastic package material, to solve proposition in above-mentioned background technology Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 40-60 part, to benzene Dioctyl phthalate butanediol ester 10-20 part, nano-Ag particles 5-10 part, Graphene 8-12 part, bamboo fiber 3-5 part, garlicin 1-3 Part, alumina silicate fibre 4-8 part, fire retardant 4-8 part, barium sulfate 1-3 part, heat stabilizer 1-1.5 part, aminopropyl triethoxysilicane Alkane 5-10 part, coupling agent 1-2 part, UV absorbent 3-5 part.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin 40 parts, mutual-phenenyl two acid bromide two alcohol ester 10 parts, nano-Ag particles 5 parts, Graphene 8 parts, bamboo fiber 3 parts, garlicin 1 part, silicon Acid aluminum fiber 4 parts, fire retardant 4 parts, 1 part of barium sulfate, heat stabilizer 1 part, aminopropyltriethoxywerene werene 5 parts, coupling agent 1 Part, UV absorbent 3 parts.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin 60 parts, mutual-phenenyl two acid bromide two alcohol ester 20 parts, nano-Ag particles 10 parts, Graphene 12 parts, bamboo fiber 5 parts, garlicin 3 parts, Alumina silicate fibre 8 parts, fire retardant 8 parts, 3 parts of barium sulfate, heat stabilizer 1.5 parts, aminopropyltriethoxywerene werene 10 parts, coupling Agent 2 parts, UV absorbent 5 parts.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin 45 parts, mutual-phenenyl two acid bromide two alcohol ester 13 parts, nano-Ag particles 7 parts, Graphene 10 parts, bamboo fiber 4 parts, garlicin 2 parts, silicon Acid aluminum fiber 6 parts, fire retardant 6 parts, 2 parts of barium sulfate, heat stabilizer 1.2 parts, aminopropyltriethoxywerene werene 7 parts, coupling agent 1.4 parts, UV absorbent 4 parts.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin 47 parts, mutual-phenenyl two acid bromide two alcohol ester 17 parts, nano-Ag particles 8 parts, Graphene 11 parts, bamboo fiber 4.2 parts, garlicin 2.2 Part, alumina silicate fibre 7 parts, fire retardant 7 parts, 2.5 parts of barium sulfate, heat stabilizer 1.3 parts, aminopropyltriethoxywerene werene 8 parts, Coupling agent 1.6 parts, UV absorbent 4.5 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Compared with prior art, the invention has the beneficial effects as follows:
The flame retardant type plastic package material of the present invention is by adding fire retardant, barium sulfate, heat stabilizer so that the present invention's Packaging material have superior flame retardant type and thermostability;By adding nano-Ag particles, Graphene, garlicin, nano-Ag particles The ethylene gas that the food such as accelerated oxidation fruit and vegerable discharge, in order to reduce the ethylene contents in package interior environment, it is achieved good Good fresh-keeping effect, Graphene, garlicin can effectively suppress growing and anticorrosion of antibacterial in packaged food, be effectively ensured and wrapped The freshness of dress food and usage safety performance.There is good electric conductivity, weatherability, stability, uvioresistant, anti-ageing simultaneously The property changed, and low cost, be suitable to large-scale promotion and use.
Detailed description of the invention
Embodiment 1
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 40 parts, terephthaldehyde Acid butanediol ester 10 parts, nano-Ag particles 5 parts, Graphene 8 parts, bamboo fiber 3 parts, garlicin 1 part, alumina silicate fibre 4 parts, resistance Combustion agent 4 parts, 1 part of barium sulfate, heat stabilizer 1 part, aminopropyltriethoxywerene werene 5 parts, coupling agent 1 part, UV absorbent 3 Part.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Embodiment 2
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 60 parts, terephthaldehyde Acid butanediol ester 20 parts, nano-Ag particles 10 parts, Graphene 12 parts, bamboo fiber 5 parts, garlicin 3 parts, alumina silicate fibre 8 parts, Fire retardant 8 parts, 3 parts of barium sulfate, heat stabilizer 1.5 parts, aminopropyltriethoxywerene werene 10 parts, coupling agent 2 parts, ultraviolet are inhaled Receive agent 5 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Embodiment 3
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 45 parts, terephthaldehyde Acid butanediol ester 13 parts, nano-Ag particles 7 parts, Graphene 10 parts, bamboo fiber 4 parts, garlicin 2 parts, alumina silicate fibre 6 parts, Fire retardant 6 parts, 2 parts of barium sulfate, heat stabilizer 1.2 parts, aminopropyltriethoxywerene werene 7 parts, coupling agent 1.4 parts, ultraviolet Absorbent 4 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Embodiment 4
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 47 parts, terephthaldehyde Acid butanediol ester 17 parts, nano-Ag particles 8 parts, Graphene 11 parts, bamboo fiber 4.2 parts, garlicin 2.2 parts, alumina silicate fibre 7 Part, fire retardant 7 parts, 2.5 parts of barium sulfate, heat stabilizer 1.3 parts, aminopropyltriethoxywerene werene 8 parts, coupling agent 1.6 parts, purple Ultraviolet absorbers 4.5 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.

Claims (9)

1. a flame retardant type plastic package material, it is characterised in that be prepared by the raw materials in: polyvinyl resin 40- 60 parts, mutual-phenenyl two acid bromide two alcohol ester's 10-20 part, nano-Ag particles 5-10 part, Graphene 8-12 part, bamboo fiber 3-5 part, big Allicin 1-3 part, alumina silicate fibre 4-8 part, fire retardant 4-8 part, barium sulfate 1-3 part, heat stabilizer 1-1.5 part, aminopropyl three Ethoxysilane 5-10 part, coupling agent 1-2 part, UV absorbent 3-5 part.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion Become: polyvinyl resin 40 parts, mutual-phenenyl two acid bromide two alcohol ester 10 parts, nano-Ag particles 5 parts, Graphene 8 parts, bamboo fiber 3 parts, Garlicin 1 part, alumina silicate fibre 4 parts, fire retardant 4 parts, 1 part of barium sulfate, heat stabilizer 1 part, aminopropyltriethoxywerene werene 5 Part, coupling agent 1 part, UV absorbent 3 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion Become: polyvinyl resin 60 parts, mutual-phenenyl two acid bromide two alcohol ester 20 parts, nano-Ag particles 10 parts, Graphene 12 parts, bamboo fiber 5 Part, garlicin 3 parts, alumina silicate fibre 8 parts, fire retardant 8 parts, 3 parts of barium sulfate, heat stabilizer 1.5 parts, aminopropyl triethoxy 10 parts of silane, coupling agent 2 parts, UV absorbent 5 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion Become: polyvinyl resin 45 parts, mutual-phenenyl two acid bromide two alcohol ester 13 parts, nano-Ag particles 7 parts, Graphene 10 parts, bamboo fiber 4 Part, garlicin 2 parts, alumina silicate fibre 6 parts, fire retardant 6 parts, 2 parts of barium sulfate, heat stabilizer 1.2 parts, aminopropyl triethoxy 7 parts of silane, coupling agent 1.4 parts, UV absorbent 4 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion Become: polyvinyl resin 47 parts, mutual-phenenyl two acid bromide two alcohol ester 17 parts, nano-Ag particles 8 parts, Graphene 11 parts, bamboo fiber 4.2 Part, garlicin 2.2 parts, alumina silicate fibre 7 parts, fire retardant 7 parts, 2.5 parts of barium sulfate, heat stabilizer 1.3 parts, aminopropyl three second TMOS 8 parts, coupling agent 1.6 parts, UV absorbent 4.5 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that described heat stabilizer is selected from stearic acid Calcium, zinc stearate, sodium stearate, barium stearate, lead sulfate tribasic, dibasic lead stearate, dibasic lead phosphite, February Dilaurylate, dibutyitin maleate, dibutyl tin maleate, lauric acid, stearic acid, organic aliphatic acid and bigcatkin willow One or more in acid.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that described fire retardant is selected from three oxidations two One or more in antimony, magnesium hydroxide, aluminium hydroxide.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that described coupling agent is selected from aminopropyl three Ethoxysilane, methacryloxypropyl trimethoxy silane, mercaptopropyl trimethoxysilane, borate, titanate esters and One or more of Aluminate.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that the particle diameter of described nano-Ag particles is 20-30nm。
CN201610669028.3A 2016-08-15 2016-08-15 A kind of flame retardant type plastic package material Pending CN106279885A (en)

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Application Number Priority Date Filing Date Title
CN201610669028.3A CN106279885A (en) 2016-08-15 2016-08-15 A kind of flame retardant type plastic package material

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107383704A (en) * 2017-09-11 2017-11-24 桐城市人和包装有限公司 One kind insulation packaging material and preparation method thereof
CN107641243A (en) * 2017-11-13 2018-01-30 桐城市中汇塑业有限公司 A kind of high-strength degradable polyethylene packaging material
CN107805329A (en) * 2017-10-20 2018-03-16 福建恒安卫生材料有限公司 A kind of film composite and preparation method thereof
CN109836663A (en) * 2019-01-22 2019-06-04 上海绿帕实业有限公司 A kind of cold chain ice chest and its preparation process
CN114103539A (en) * 2021-11-11 2022-03-01 江苏学泰印务有限公司 Flexible substrate heat transfer film and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516627A (en) * 2011-12-03 2012-06-27 广东聚缘塑料科技有限公司 Silver-ion antibacterial plastic
CN105315554A (en) * 2015-11-04 2016-02-10 桐城市人和包装有限公司 Flame-retardant antistatic tearproof film material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516627A (en) * 2011-12-03 2012-06-27 广东聚缘塑料科技有限公司 Silver-ion antibacterial plastic
CN105315554A (en) * 2015-11-04 2016-02-10 桐城市人和包装有限公司 Flame-retardant antistatic tearproof film material

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107383704A (en) * 2017-09-11 2017-11-24 桐城市人和包装有限公司 One kind insulation packaging material and preparation method thereof
CN107805329A (en) * 2017-10-20 2018-03-16 福建恒安卫生材料有限公司 A kind of film composite and preparation method thereof
CN107805329B (en) * 2017-10-20 2020-09-08 福建恒安卫生材料有限公司 Film composition and preparation method thereof
CN107641243A (en) * 2017-11-13 2018-01-30 桐城市中汇塑业有限公司 A kind of high-strength degradable polyethylene packaging material
CN109836663A (en) * 2019-01-22 2019-06-04 上海绿帕实业有限公司 A kind of cold chain ice chest and its preparation process
CN109836663B (en) * 2019-01-22 2022-03-15 上海绿帕实业有限公司 Cold chain ice box and preparation process thereof
CN114103539A (en) * 2021-11-11 2022-03-01 江苏学泰印务有限公司 Flexible substrate heat transfer film and preparation method thereof

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Application publication date: 20170104