CN106279885A - A kind of flame retardant type plastic package material - Google Patents
A kind of flame retardant type plastic package material Download PDFInfo
- Publication number
- CN106279885A CN106279885A CN201610669028.3A CN201610669028A CN106279885A CN 106279885 A CN106279885 A CN 106279885A CN 201610669028 A CN201610669028 A CN 201610669028A CN 106279885 A CN106279885 A CN 106279885A
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- flame retardant
- plastic package
- type plastic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of flame retardant type plastic package material, be prepared by the raw materials in: polyvinyl resin 40 60 parts, mutual-phenenyl two acid bromide two alcohol ester 10 20 parts, nano-Ag particles 5 10 parts, Graphene 8 12 parts, bamboo fiber 35 parts, garlicin 13 parts, alumina silicate fibre 48 parts, fire retardant 48 parts, 13 parts of barium sulfate, heat stabilizer 1 1.5 parts, aminopropyltriethoxywerene werene 5 10 parts, coupling agent 12 parts, UV absorbent 35 parts.The flame retardant type plastic package material of the present invention is by adding fire retardant, barium sulfate, heat stabilizer so that packaging material have superior flame retardant type and thermostability;By adding nano-Ag particles, Graphene, garlicin, the ethylene gas that the food such as nano-Ag particles accelerated oxidation fruit and vegerable discharge, so as the ethylene contents reduced in package interior environment, realize good fresh-keeping effect, Graphene, garlicin can effectively suppress growing and anticorrosion of antibacterial in packaged food, and freshness and the security performance of packaged food is effectively ensured.
Description
Technical field
The present invention relates to packaging material field, specifically a kind of flame retardant type plastic package material.
Background technology
Packaging for foodstuff, as the heavier part of current packaging field portion, occupies important in whole packaging field
Status.The various problems occurred in field of food safety in recent years, make people more focus on food and packaging material thereof, very
To whole production technology, the safety of packaging process, this makes to probe into packaging material for food to bring into schedule.
Plastics are widely used in packaging for foodstuff because of its light weight, the feature such as easy to use, price is low.Fruit and vegerable etc. are new
Fresh food can discharge ethylene gas when storing, and will accelerate food decay when ethylene runs up to finite concentration, therefore, as
The ethylene contents what reduces in plastic package material is urgent problem.Simultaneously along with social industrialized development, industry
Demand constantly promote.Pack at the product of some industry and packaging material are had special requirement, such as, need packing timber
Material needs have fire resistance.
Summary of the invention
It is an object of the invention to provide a kind of flame retardant type plastic package material, to solve proposition in above-mentioned background technology
Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 40-60 part, to benzene
Dioctyl phthalate butanediol ester 10-20 part, nano-Ag particles 5-10 part, Graphene 8-12 part, bamboo fiber 3-5 part, garlicin 1-3
Part, alumina silicate fibre 4-8 part, fire retardant 4-8 part, barium sulfate 1-3 part, heat stabilizer 1-1.5 part, aminopropyl triethoxysilicane
Alkane 5-10 part, coupling agent 1-2 part, UV absorbent 3-5 part.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin
40 parts, mutual-phenenyl two acid bromide two alcohol ester 10 parts, nano-Ag particles 5 parts, Graphene 8 parts, bamboo fiber 3 parts, garlicin 1 part, silicon
Acid aluminum fiber 4 parts, fire retardant 4 parts, 1 part of barium sulfate, heat stabilizer 1 part, aminopropyltriethoxywerene werene 5 parts, coupling agent 1
Part, UV absorbent 3 parts.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin
60 parts, mutual-phenenyl two acid bromide two alcohol ester 20 parts, nano-Ag particles 10 parts, Graphene 12 parts, bamboo fiber 5 parts, garlicin 3 parts,
Alumina silicate fibre 8 parts, fire retardant 8 parts, 3 parts of barium sulfate, heat stabilizer 1.5 parts, aminopropyltriethoxywerene werene 10 parts, coupling
Agent 2 parts, UV absorbent 5 parts.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin
45 parts, mutual-phenenyl two acid bromide two alcohol ester 13 parts, nano-Ag particles 7 parts, Graphene 10 parts, bamboo fiber 4 parts, garlicin 2 parts, silicon
Acid aluminum fiber 6 parts, fire retardant 6 parts, 2 parts of barium sulfate, heat stabilizer 1.2 parts, aminopropyltriethoxywerene werene 7 parts, coupling agent
1.4 parts, UV absorbent 4 parts.
Preferably, described a kind of flame retardant type plastic package material, it is prepared by the raw materials in: polyvinyl resin
47 parts, mutual-phenenyl two acid bromide two alcohol ester 17 parts, nano-Ag particles 8 parts, Graphene 11 parts, bamboo fiber 4.2 parts, garlicin 2.2
Part, alumina silicate fibre 7 parts, fire retardant 7 parts, 2.5 parts of barium sulfate, heat stabilizer 1.3 parts, aminopropyltriethoxywerene werene 8 parts,
Coupling agent 1.6 parts, UV absorbent 4.5 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid
Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two
One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon
One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Compared with prior art, the invention has the beneficial effects as follows:
The flame retardant type plastic package material of the present invention is by adding fire retardant, barium sulfate, heat stabilizer so that the present invention's
Packaging material have superior flame retardant type and thermostability;By adding nano-Ag particles, Graphene, garlicin, nano-Ag particles
The ethylene gas that the food such as accelerated oxidation fruit and vegerable discharge, in order to reduce the ethylene contents in package interior environment, it is achieved good
Good fresh-keeping effect, Graphene, garlicin can effectively suppress growing and anticorrosion of antibacterial in packaged food, be effectively ensured and wrapped
The freshness of dress food and usage safety performance.There is good electric conductivity, weatherability, stability, uvioresistant, anti-ageing simultaneously
The property changed, and low cost, be suitable to large-scale promotion and use.
Detailed description of the invention
Embodiment 1
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 40 parts, terephthaldehyde
Acid butanediol ester 10 parts, nano-Ag particles 5 parts, Graphene 8 parts, bamboo fiber 3 parts, garlicin 1 part, alumina silicate fibre 4 parts, resistance
Combustion agent 4 parts, 1 part of barium sulfate, heat stabilizer 1 part, aminopropyltriethoxywerene werene 5 parts, coupling agent 1 part, UV absorbent 3
Part.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid
Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two
One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon
One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Embodiment 2
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 60 parts, terephthaldehyde
Acid butanediol ester 20 parts, nano-Ag particles 10 parts, Graphene 12 parts, bamboo fiber 5 parts, garlicin 3 parts, alumina silicate fibre 8 parts,
Fire retardant 8 parts, 3 parts of barium sulfate, heat stabilizer 1.5 parts, aminopropyltriethoxywerene werene 10 parts, coupling agent 2 parts, ultraviolet are inhaled
Receive agent 5 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid
Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two
One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon
One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Embodiment 3
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 45 parts, terephthaldehyde
Acid butanediol ester 13 parts, nano-Ag particles 7 parts, Graphene 10 parts, bamboo fiber 4 parts, garlicin 2 parts, alumina silicate fibre 6 parts,
Fire retardant 6 parts, 2 parts of barium sulfate, heat stabilizer 1.2 parts, aminopropyltriethoxywerene werene 7 parts, coupling agent 1.4 parts, ultraviolet
Absorbent 4 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid
Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two
One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon
One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Embodiment 4
A kind of flame retardant type plastic package material, is prepared by the raw materials in: polyvinyl resin 47 parts, terephthaldehyde
Acid butanediol ester 17 parts, nano-Ag particles 8 parts, Graphene 11 parts, bamboo fiber 4.2 parts, garlicin 2.2 parts, alumina silicate fibre 7
Part, fire retardant 7 parts, 2.5 parts of barium sulfate, heat stabilizer 1.3 parts, aminopropyltriethoxywerene werene 8 parts, coupling agent 1.6 parts, purple
Ultraviolet absorbers 4.5 parts.
Preferably, described heat stabilizer is selected from calcium stearate, zinc stearate, sodium stearate, barium stearate, tribasic sulphuric acid
Lead, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, maleic acid two
One or more in butyl tin, lauric acid, stearic acid, organic aliphatic acid and salicylic acid.
Preferably, one or more in antimony oxide, magnesium hydroxide, aluminium hydroxide of described fire retardant.
Preferably, described coupling agent is selected from aminopropyl triethoxysilane, methacryloxypropyl trimethoxy silicon
One or more of alkane, mercaptopropyl trimethoxysilane, borate, titanate esters and Aluminate.
The particle diameter of described nano-Ag particles is 20-30nm.
Claims (9)
1. a flame retardant type plastic package material, it is characterised in that be prepared by the raw materials in: polyvinyl resin 40-
60 parts, mutual-phenenyl two acid bromide two alcohol ester's 10-20 part, nano-Ag particles 5-10 part, Graphene 8-12 part, bamboo fiber 3-5 part, big
Allicin 1-3 part, alumina silicate fibre 4-8 part, fire retardant 4-8 part, barium sulfate 1-3 part, heat stabilizer 1-1.5 part, aminopropyl three
Ethoxysilane 5-10 part, coupling agent 1-2 part, UV absorbent 3-5 part.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
Become: polyvinyl resin 40 parts, mutual-phenenyl two acid bromide two alcohol ester 10 parts, nano-Ag particles 5 parts, Graphene 8 parts, bamboo fiber 3 parts,
Garlicin 1 part, alumina silicate fibre 4 parts, fire retardant 4 parts, 1 part of barium sulfate, heat stabilizer 1 part, aminopropyltriethoxywerene werene 5
Part, coupling agent 1 part, UV absorbent 3 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
Become: polyvinyl resin 60 parts, mutual-phenenyl two acid bromide two alcohol ester 20 parts, nano-Ag particles 10 parts, Graphene 12 parts, bamboo fiber 5
Part, garlicin 3 parts, alumina silicate fibre 8 parts, fire retardant 8 parts, 3 parts of barium sulfate, heat stabilizer 1.5 parts, aminopropyl triethoxy
10 parts of silane, coupling agent 2 parts, UV absorbent 5 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
Become: polyvinyl resin 45 parts, mutual-phenenyl two acid bromide two alcohol ester 13 parts, nano-Ag particles 7 parts, Graphene 10 parts, bamboo fiber 4
Part, garlicin 2 parts, alumina silicate fibre 6 parts, fire retardant 6 parts, 2 parts of barium sulfate, heat stabilizer 1.2 parts, aminopropyl triethoxy
7 parts of silane, coupling agent 1.4 parts, UV absorbent 4 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that by the raw material system of following weight portion
Become: polyvinyl resin 47 parts, mutual-phenenyl two acid bromide two alcohol ester 17 parts, nano-Ag particles 8 parts, Graphene 11 parts, bamboo fiber 4.2
Part, garlicin 2.2 parts, alumina silicate fibre 7 parts, fire retardant 7 parts, 2.5 parts of barium sulfate, heat stabilizer 1.3 parts, aminopropyl three second
TMOS 8 parts, coupling agent 1.6 parts, UV absorbent 4.5 parts.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that described heat stabilizer is selected from stearic acid
Calcium, zinc stearate, sodium stearate, barium stearate, lead sulfate tribasic, dibasic lead stearate, dibasic lead phosphite, February
Dilaurylate, dibutyitin maleate, dibutyl tin maleate, lauric acid, stearic acid, organic aliphatic acid and bigcatkin willow
One or more in acid.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that described fire retardant is selected from three oxidations two
One or more in antimony, magnesium hydroxide, aluminium hydroxide.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that described coupling agent is selected from aminopropyl three
Ethoxysilane, methacryloxypropyl trimethoxy silane, mercaptopropyl trimethoxysilane, borate, titanate esters and
One or more of Aluminate.
Flame retardant type plastic package material the most according to claim 1, it is characterised in that the particle diameter of described nano-Ag particles is
20-30nm。
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CN201610669028.3A CN106279885A (en) | 2016-08-15 | 2016-08-15 | A kind of flame retardant type plastic package material |
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CN201610669028.3A CN106279885A (en) | 2016-08-15 | 2016-08-15 | A kind of flame retardant type plastic package material |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107383704A (en) * | 2017-09-11 | 2017-11-24 | 桐城市人和包装有限公司 | One kind insulation packaging material and preparation method thereof |
CN107641243A (en) * | 2017-11-13 | 2018-01-30 | 桐城市中汇塑业有限公司 | A kind of high-strength degradable polyethylene packaging material |
CN107805329A (en) * | 2017-10-20 | 2018-03-16 | 福建恒安卫生材料有限公司 | A kind of film composite and preparation method thereof |
CN109836663A (en) * | 2019-01-22 | 2019-06-04 | 上海绿帕实业有限公司 | A kind of cold chain ice chest and its preparation process |
CN114103539A (en) * | 2021-11-11 | 2022-03-01 | 江苏学泰印务有限公司 | Flexible substrate heat transfer film and preparation method thereof |
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CN102516627A (en) * | 2011-12-03 | 2012-06-27 | 广东聚缘塑料科技有限公司 | Silver-ion antibacterial plastic |
CN105315554A (en) * | 2015-11-04 | 2016-02-10 | 桐城市人和包装有限公司 | Flame-retardant antistatic tearproof film material |
-
2016
- 2016-08-15 CN CN201610669028.3A patent/CN106279885A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102516627A (en) * | 2011-12-03 | 2012-06-27 | 广东聚缘塑料科技有限公司 | Silver-ion antibacterial plastic |
CN105315554A (en) * | 2015-11-04 | 2016-02-10 | 桐城市人和包装有限公司 | Flame-retardant antistatic tearproof film material |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107383704A (en) * | 2017-09-11 | 2017-11-24 | 桐城市人和包装有限公司 | One kind insulation packaging material and preparation method thereof |
CN107805329A (en) * | 2017-10-20 | 2018-03-16 | 福建恒安卫生材料有限公司 | A kind of film composite and preparation method thereof |
CN107805329B (en) * | 2017-10-20 | 2020-09-08 | 福建恒安卫生材料有限公司 | Film composition and preparation method thereof |
CN107641243A (en) * | 2017-11-13 | 2018-01-30 | 桐城市中汇塑业有限公司 | A kind of high-strength degradable polyethylene packaging material |
CN109836663A (en) * | 2019-01-22 | 2019-06-04 | 上海绿帕实业有限公司 | A kind of cold chain ice chest and its preparation process |
CN109836663B (en) * | 2019-01-22 | 2022-03-15 | 上海绿帕实业有限公司 | Cold chain ice box and preparation process thereof |
CN114103539A (en) * | 2021-11-11 | 2022-03-01 | 江苏学泰印务有限公司 | Flexible substrate heat transfer film and preparation method thereof |
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Application publication date: 20170104 |