WO2019100469A1 - Multifunctional polyamide composite material - Google Patents

Multifunctional polyamide composite material Download PDF

Info

Publication number
WO2019100469A1
WO2019100469A1 PCT/CN2017/116557 CN2017116557W WO2019100469A1 WO 2019100469 A1 WO2019100469 A1 WO 2019100469A1 CN 2017116557 W CN2017116557 W CN 2017116557W WO 2019100469 A1 WO2019100469 A1 WO 2019100469A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
composite material
polyamide composite
sodium
tris
Prior art date
Application number
PCT/CN2017/116557
Other languages
French (fr)
Chinese (zh)
Inventor
宋懂强
Original Assignee
南通展鹏塑料有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 南通展鹏塑料有限公司 filed Critical 南通展鹏塑料有限公司
Publication of WO2019100469A1 publication Critical patent/WO2019100469A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2231—Oxides; Hydroxides of metals of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2255—Oxides; Hydroxides of metals of molybdenum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Definitions

  • the invention relates to the field of plastic technology, in particular to a multifunctional polyamide composite material.
  • Polyamide resin is a chemical raw material with excellent performance and can be divided into two categories according to its properties: non-reactive or neutral polyamide and reactive polyamide.
  • Neutral polyamides are mainly used in the production of inks, heat-curable adhesives and coatings, reactive polyamides are used in epoxy resin curing agents, and in thermosetting surface coatings, adhesives, lining materials and cans, die casting Resin.
  • Different additives can be added according to different purposes, and polyamide plastics can exhibit different physical properties and mechanical properties.
  • the existing modified polyamide material has a single function. How to design a multifunctional polyamide composite material is an urgent problem to be solved in the industry.
  • a multifunctional polyamide composite material composed of parts by weight of a polyamide: 100 parts; polyethylene terephthalate 10-20 parts; polyvinylidene fluoride 5-15 parts; polyvinyl alcohol 10-15 parts; polyetherimide 5-10 parts; polystyrene 5-10 parts; sodium phosphate 3-6 parts; melamine 2-5 parts; benzotriazole 1- 3 parts; 2-8 parts of methyl methacrylate-butadiene-styrene copolymer; 1-4 parts of sodium hard acid; 2-6 parts of silver nanoparticles; 5-15 parts of sodium polystyrene sulfonate; 1-5 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1-0.5 parts of dibenzoyl peroxide; 1-5 parts of kaolin; 2-6 parts of silicon carbide; tin oxide ⁇ 1-3 parts; methylphenyl silicone oil 1-5 parts; molybdenum trioxide 1-3 parts; lithium fluoride
  • the multifunctional polyamide composite material is composed of parts by weight of the following components: 100 parts of polyamide; 15 parts of polyethylene terephthalate; 10 parts of polyvinylidene fluoride; 12 parts of polyvinyl alcohol; 7 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 4 parts of melamine; 2 parts of benzotriazole; 5 parts of methyl methacrylate-butadiene-styrene copolymer; 3 parts of sodium; 4 parts of silver nanoparticles; 10 parts of sodium polystyrene sulfonate; bis(3,5-tris-butyl-4-hydroxyphenyl) 3 parts of thioether; 0.3 parts of dibenzoyl peroxide; 3 parts of kaolin; 4 parts of silicon carbide; 2 parts of tin oxide; 3 parts of methylphenyl silicone; 2 parts of molybdenum trioxide; 0.3 parts of lithium fluoride; 2 parts of (8
  • the multifunctional polyamide composite material is composed of parts by weight of the following components: 100 parts of polyamide; 18 parts of polyethylene terephthalate; 12 parts of polyvinylidene fluoride; 14 parts of polyvinyl alcohol; 9 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 3 parts of melamine; 3 parts of benzotriazole; 7 parts of methyl methacrylate-butadiene-styrene copolymer; 3 parts of sodium; 5 parts of silver nanoparticles; 12 parts of sodium polystyrene sulfonate; 4 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.4 parts of dibenzoyl peroxide; 4 parts of kaolin; 5 parts of silicon carbide; 3 parts of tin oxide; 4 parts of methylphenyl silicone oil; 1 part of molybdenum trioxide; 0.5 parts of lithium fluoride; 3 parts
  • the multifunctional polyamide composite material is composed of parts by weight of the following components: 100 parts of polyamide; 12 parts of polyethylene terephthalate; 7 parts of polyvinylidene fluoride; 11 parts of polyvinyl alcohol; 6 parts of polyetherimide; 7 parts of polystyrene; 3 parts of sodium phosphate; 4 parts of melamine; 1 part of benzotriazole; 4 parts of methyl methacrylate-butadiene-styrene copolymer; 2 parts of sodium; 3 parts of silver nanoparticles; 7 parts of sodium polystyrene sulfonate; 2 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1 part of dibenzoyl peroxide; 1 part of kaolin; 4 parts of silicon carbide; 3 parts of tin oxide; 2 parts of methylphenyl silicone oil; 2 parts of molybdenum trioxide; 0.5 parts of lithium fluoride; 2 parts
  • the invention has the beneficial effects that the multi-functional polyamide composite material has excellent mechanical properties, heat resistance, abrasion resistance and antistatic property through the synergy between the components, and has good ultraviolet resistance. .
  • the multifunctional polyamide composite material of the invention is added with silver nano particles, kaolin, silicon carbide, antimony tin oxide, molybdenum trioxide, lithium fluoride, and the combination of various inorganic particles, thereby effectively improving the multifunctional polyamide composite material.
  • Thermal conductivity, antibacterial properties and antistatic properties prevent high temperature aging of multifunctional polyamide composites.
  • the multifunctional polyamide composite material of the invention is added with glass fiber and carbon fiber, and the above materials are cross-linked in the multifunctional polyamide composite material, thereby effectively improving the toughness and mechanical properties of the multifunctional polyamide composite material, and adding a semiconductor
  • the characteristic 3-hexylthiophene polymer further enhances its antistatic properties.
  • the multifunctional polyamide composite material of the invention is added with various auxiliary agents, and by optimizing the specific content between the components, the components are mutually complementary, and the formed multifunctional polyamide composite material has excellent comprehensive performance, and is suitable for use. In a variety of fields.
  • the present invention provides a multifunctional polyamide composite material comprising the following components by weight: 100 parts of polyamide; 10-20 parts of polyethylene terephthalate; 5-15 parts of vinyl fluoride; 10-15 parts of polyvinyl alcohol; 5-10 parts of polyetherimide; 5-10 parts of polystyrene; 3-6 parts of sodium phosphate; 2-5 parts of melamine; benzotriazole 1-3 parts; 2-8 parts of methyl methacrylate-butadiene-styrene copolymer; 1-4 parts of sodium hard acid; 2-6 parts of silver nanoparticles; 5-15 of sodium polystyrene sulfonate Parts; bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide 1-5 parts; dibenzoyl peroxide 0.1-0.5 parts; kaolin 1-5 parts; silicon carbide 2-6 parts; 1-3 parts of tin oxide bismuth; 1-5 parts of methylphenyl silicone oil; 1-3 parts of molybdenum tri
  • a multifunctional polyamide composite material comprising the following components by weight: 100 parts of polyamide; 15 parts of polyethylene terephthalate; 10 parts of polyvinylidene fluoride; 12 parts of polyvinyl alcohol; 7 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 4 parts of melamine; 2 parts of benzotriazole; methyl methacrylate-butadiene-styrene copolymer 5 parts; 3 parts of sodium hard acid; 4 parts of silver nanoparticles; 10 parts of sodium polystyrene sulfonate; 3 parts of bis(3,5-tri-butyl-4-hydroxyphenyl) sulfide; Benzoyl 0.3 parts; kaolin 3 parts; silicon carbide 4 parts; tin oxide bismuth 2 parts; methyl phenyl silicone oil 3 parts; molybdenum trioxide 2 parts; lithium fluoride 0.3 parts; tris(8-hydroxyquinoline) aluminum 2 parts; 4
  • a multifunctional polyamide composite material comprising: by weight of the following components: 100 parts of polyamide; 18 parts of polyethylene terephthalate; 12 parts of polyvinylidene fluoride; 14 parts of polyvinyl alcohol; 9 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 3 parts of melamine; 3 parts of benzotriazole; methyl methacrylate-butadiene-styrene copolymer 7 parts; 3 parts of sodium hard acid; 5 parts of silver nanoparticles; 12 parts of sodium polystyrene sulfonate; 4 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.4 parts of benzoyl; 4 parts of kaolin; 5 parts of silicon carbide; 3 parts of tin oxide; 4 parts of methylphenyl silicone oil; 1 part of molybdenum trioxide; 0.5 parts of lithium fluoride; aluminum tris(8-hydroxyquinoline
  • a multifunctional polyamide composite material comprising: by weight of the following components: 100 parts of polyamide; 12 parts of polyethylene terephthalate; 7 parts of polyvinylidene fluoride; 11 parts of polyvinyl alcohol; 6 parts of polyetherimide; 7 parts of polystyrene; 3 parts of sodium phosphate; 4 parts of melamine; 1 part of benzotriazole; methyl methacrylate-butadiene-styrene copolymer 4 parts; 2 parts of sodium hard acid; 3 parts of silver nanoparticles; 7 parts of sodium polystyrene sulfonate; 2 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1 part of benzoyl; 1 part of kaolin; 4 parts of silicon carbide; 3 parts of tin oxide; 2 parts of methylphenyl silicone oil; 2 parts of molybdenum trioxide; 0.5 part of lithium fluoride; aluminum tris(8-hydroxyquinoline
  • the invention makes the multifunctional polyamide composite material have excellent mechanical properties, heat resistance, abrasion resistance and antistatic property through the synergy between the components, and has good ultraviolet resistance.
  • the multifunctional polyamide composite material of the invention is added with silver nano particles, kaolin, silicon carbide, antimony tin oxide, molybdenum trioxide, lithium fluoride, and the combination of various inorganic particles, thereby effectively improving the multifunctional polyamide composite material.
  • Thermal conductivity, antibacterial properties and antistatic properties prevent high temperature aging of multifunctional polyamide composites.
  • the multifunctional polyamide composite material of the invention is added with glass fiber and carbon fiber, and the above materials are cross-linked in the multifunctional polyamide composite material, thereby effectively improving the toughness and mechanical properties of the multifunctional polyamide composite material, and adding a semiconductor
  • the characteristic 3-hexylthiophene polymer further enhances its antistatic properties.
  • the multifunctional polyamide composite material of the invention is added with various auxiliary agents, and by optimizing the specific content between the components, the components are mutually complementary, and the formed multifunctional polyamide composite material has excellent comprehensive performance, and is suitable for use. In a variety of fields.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A multifunctional polyamide composite material, which relates to the technical field of plastics. The multifunctional polyamide composite material uses polyamide as a matrix and contains a multi-component functional additive. By means of a synergistic effect among components, the multifunctional polyamide composite material has excellent mechanical performance, heat resistance performance, wear resistance performance, antistatic performance and good ultraviolet resistance performance.

Description

一种多功能聚酰胺复合材料Multifunctional polyamide composite material 技术领域Technical field
本发明涉及塑料技术领域，特别是涉及一种多功能聚酰胺复合材料。The invention relates to the field of plastic technology, in particular to a multifunctional polyamide composite material.
背景技术Background technique
聚酰胺树脂，是性能优良用途广泛的化工原料，按其性质可分为两大类：非反应性或中性聚酰胺及反应性聚酰胺。中性聚酰胺主要用于生产油墨、热合性粘结剂和涂料，反应性聚酰胺用于环氧树脂熟化剂，和用于热固性表面涂料、粘结剂、内衬材料及罐封、模铸树脂。根据不同的用途可以加入不同的添加剂，聚酰胺塑料可呈现不同的物理性能和力学性能。而现有的改性聚酰胺材料功能单一。如何设计一种多功能聚酰胺复合材料，是业界亟待解决的问题。Polyamide resin is a chemical raw material with excellent performance and can be divided into two categories according to its properties: non-reactive or neutral polyamide and reactive polyamide. Neutral polyamides are mainly used in the production of inks, heat-curable adhesives and coatings, reactive polyamides are used in epoxy resin curing agents, and in thermosetting surface coatings, adhesives, lining materials and cans, die casting Resin. Different additives can be added according to different purposes, and polyamide plastics can exhibit different physical properties and mechanical properties. The existing modified polyamide material has a single function. How to design a multifunctional polyamide composite material is an urgent problem to be solved in the industry.
发明内容Summary of the invention
本发明的目的在于避免现有技术中的不足之处而提供一种多功能聚酰胺复合材料。It is an object of the present invention to provide a multifunctional polyamide composite material that avoids the deficiencies in the prior art.
本发明的目的通过以下技术方案实现：The object of the invention is achieved by the following technical solutions:
提供一种多功能聚酰胺复合材料，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯10-20份；聚偏氟乙烯5-15份；聚乙烯醇10-15份；聚醚酰亚胺5-10份；聚苯乙烯5-10份；磷酸钠3-6份；三聚氰胺2-5份；苯并三唑1-3份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物2-8份；硬质酸钠1-4份；银纳米颗粒2-6份；聚苯乙烯磺酸钠5-15份；双(3,5-三级丁基-4-羟基苯基)硫醚1-5份；过氧化二苯甲酰0.1-0.5份；高岭土1-5份；碳化硅2-6份；氧化锡锑1-3份；甲基苯基硅油1-5份；三氧化钼1-3份；氟化锂0.1-0.5份；三(8-羟基喹啉)铝1-3份；三硬脂酸甘油酯2-6份；乙烯1-5份；乙烯基三乙氧基硅烷1-2份；邻苯二甲酸二辛酯1-4份；叔丁基对苯二酚1-3份，玻璃纤维2-6份；碳纤维1-5份；3-己基噻吩聚合物0.5-2份；氧化镁颗粒2-6份；亚磷酸酯1-6份；乙酸乙酯1-3份。Provided is a multifunctional polyamide composite material composed of parts by weight of a polyamide: 100 parts; polyethylene terephthalate 10-20 parts; polyvinylidene fluoride 5-15 parts; polyvinyl alcohol 10-15 parts; polyetherimide 5-10 parts; polystyrene 5-10 parts; sodium phosphate 3-6 parts; melamine 2-5 parts; benzotriazole 1- 3 parts; 2-8 parts of methyl methacrylate-butadiene-styrene copolymer; 1-4 parts of sodium hard acid; 2-6 parts of silver nanoparticles; 5-15 parts of sodium polystyrene sulfonate; 1-5 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1-0.5 parts of dibenzoyl peroxide; 1-5 parts of kaolin; 2-6 parts of silicon carbide; tin oxide锑1-3 parts; methylphenyl silicone oil 1-5 parts; molybdenum trioxide 1-3 parts; lithium fluoride 0.1-0.5 parts; tris(8-hydroxyquinoline) aluminum 1-3 parts; tristearic acid 2-6 parts of glyceride; 1-5 parts of ethylene; 1-2 parts of vinyltriethoxysilane; 1-4 parts of dioctyl phthalate; 1-3 parts of tert-butyl hydroquinone, glass 2-6 parts of fibers; 1-5 parts of carbon fibers; 0.5-2 parts of 3-hexylthiophene polymer; 2-6 parts of magnesium oxide particles; 1-6 parts of phosphite; 1-3 parts of ethyl acetate.
作为优选，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯15份；聚偏氟乙烯10份；聚乙烯醇12份；聚醚酰亚胺7份；聚苯乙烯8份；磷酸钠5份；三聚氰胺4份；苯并三唑2份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物5份；硬质酸钠3份；银纳米颗粒4份；聚苯乙烯磺酸钠10份；双(3,5-三级丁基-4-羟基苯基) 硫醚3份；过氧化二苯甲酰0.3份；高岭土3份；碳化硅4份；氧化锡锑2份；甲基苯基硅油3份；三氧化钼2份；氟化锂0.3份；三(8-羟基喹啉)铝2份；三硬脂酸甘油酯4份；乙烯3份；乙烯基三乙氧基硅烷1份；邻苯二甲酸二辛酯3份；叔丁基对苯二酚2份，玻璃纤维4份；碳纤维3份；3-己基噻吩聚合物1份；氧化镁颗粒4份；亚磷酸酯4份；乙酸乙酯2份。Preferably, the multifunctional polyamide composite material is composed of parts by weight of the following components: 100 parts of polyamide; 15 parts of polyethylene terephthalate; 10 parts of polyvinylidene fluoride; 12 parts of polyvinyl alcohol; 7 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 4 parts of melamine; 2 parts of benzotriazole; 5 parts of methyl methacrylate-butadiene-styrene copolymer; 3 parts of sodium; 4 parts of silver nanoparticles; 10 parts of sodium polystyrene sulfonate; bis(3,5-tris-butyl-4-hydroxyphenyl) 3 parts of thioether; 0.3 parts of dibenzoyl peroxide; 3 parts of kaolin; 4 parts of silicon carbide; 2 parts of tin oxide; 3 parts of methylphenyl silicone; 2 parts of molybdenum trioxide; 0.3 parts of lithium fluoride; 2 parts of (8-hydroxyquinoline)aluminum; 4 parts of glyceryl tristearate; 3 parts of ethylene; 1 part of vinyltriethoxysilane; 3 parts of dioctyl phthalate; tert-butyl-p-phenylene 2 parts of phenol, 4 parts of glass fiber; 3 parts of carbon fiber; 1 part of 3-hexylthiophene polymer; 4 parts of magnesium oxide particles; 4 parts of phosphite; 2 parts of ethyl acetate.
作为优选，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯18份；聚偏氟乙烯12份；聚乙烯醇14份；聚醚酰亚胺9份；聚苯乙烯8份；磷酸钠5份；三聚氰胺3份；苯并三唑3份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物7份；硬质酸钠3份；银纳米颗粒5份；聚苯乙烯磺酸钠12份；双(3,5-三级丁基-4-羟基苯基)硫醚4份；过氧化二苯甲酰0.4份；高岭土4份；碳化硅5份；氧化锡锑3份；甲基苯基硅油4份；三氧化钼1份；氟化锂0.5份；三(8-羟基喹啉)铝3份；三硬脂酸甘油酯5份；乙烯1份；乙烯基三乙氧基硅烷2份；邻苯二甲酸二辛酯3份；叔丁基对苯二酚3份，玻璃纤维5份；碳纤维4份；3-己基噻吩聚合物2份；氧化镁颗粒5份；亚磷酸酯5份；乙酸乙酯1份。Preferably, the multifunctional polyamide composite material is composed of parts by weight of the following components: 100 parts of polyamide; 18 parts of polyethylene terephthalate; 12 parts of polyvinylidene fluoride; 14 parts of polyvinyl alcohol; 9 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 3 parts of melamine; 3 parts of benzotriazole; 7 parts of methyl methacrylate-butadiene-styrene copolymer; 3 parts of sodium; 5 parts of silver nanoparticles; 12 parts of sodium polystyrene sulfonate; 4 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.4 parts of dibenzoyl peroxide; 4 parts of kaolin; 5 parts of silicon carbide; 3 parts of tin oxide; 4 parts of methylphenyl silicone oil; 1 part of molybdenum trioxide; 0.5 parts of lithium fluoride; 3 parts of aluminum tris(8-hydroxyquinoline); 5 parts of acid glyceride; 1 part of ethylene; 2 parts of vinyltriethoxysilane; 3 parts of dioctyl phthalate; 3 parts of t-butyl hydroquinone, 5 parts of glass fiber; 4 parts of carbon fiber; 2 parts of hexylthiophene polymer; 5 parts of magnesium oxide particles; 5 parts of phosphite; 1 part of ethyl acetate.
作为优选，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯12份；聚偏氟乙烯7份；聚乙烯醇11份；聚醚酰亚胺6份；聚苯乙烯7份；磷酸钠3份；三聚氰胺4份；苯并三唑1份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物4份；硬质酸钠2份；银纳米颗粒3份；聚苯乙烯磺酸钠7份；双(3,5-三级丁基-4-羟基苯基)硫醚2份；过氧化二苯甲酰0.1份；高岭土1份；碳化硅4份；氧化锡锑3份；甲基苯基硅油2份；三氧化钼2份；氟化锂0.5份；三(8-羟基喹啉)铝2份；三硬脂酸甘油酯3份；乙烯2份；乙烯基三乙氧基硅烷1份；邻苯二甲酸二辛酯4份；叔丁基对苯二酚2份，玻璃纤维3份；碳纤维2份；3-己基噻吩聚合物0.5份；氧化镁颗粒3份；亚磷酸酯2份；乙酸乙酯1份。Preferably, the multifunctional polyamide composite material is composed of parts by weight of the following components: 100 parts of polyamide; 12 parts of polyethylene terephthalate; 7 parts of polyvinylidene fluoride; 11 parts of polyvinyl alcohol; 6 parts of polyetherimide; 7 parts of polystyrene; 3 parts of sodium phosphate; 4 parts of melamine; 1 part of benzotriazole; 4 parts of methyl methacrylate-butadiene-styrene copolymer; 2 parts of sodium; 3 parts of silver nanoparticles; 7 parts of sodium polystyrene sulfonate; 2 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1 part of dibenzoyl peroxide; 1 part of kaolin; 4 parts of silicon carbide; 3 parts of tin oxide; 2 parts of methylphenyl silicone oil; 2 parts of molybdenum trioxide; 0.5 parts of lithium fluoride; 2 parts of aluminum tris(8-hydroxyquinoline); 3 parts of acid glyceride; 2 parts of ethylene; 1 part of vinyltriethoxysilane; 4 parts of dioctyl phthalate; 2 parts of t-butyl hydroquinone, 3 parts of glass fiber; 2 parts of carbon fiber; - 0.5 parts of hexylthiophene polymer; 3 parts of magnesium oxide particles; 2 parts of phosphite; 1 part of ethyl acetate.
本发明的有益效果：本发明通过各组分之间的协同作用，使得多功能聚酰胺复合材料具有优异的力学性能、耐热性能、耐磨性能以及抗静电性能，且具有良好的耐紫外线性能。The invention has the beneficial effects that the multi-functional polyamide composite material has excellent mechanical properties, heat resistance, abrasion resistance and antistatic property through the synergy between the components, and has good ultraviolet resistance. .
本发明的多功能聚酰胺复合材料中添加有银纳米颗粒、高岭土、碳化硅、氧化锡锑、三氧化钼、氟化锂，多种无机颗粒的配合作用，有效提高了多功能聚酰胺复合材料的导热性能、抗菌性能以及抗静电性能，进而防止多功能聚酰胺复合材料高温老化。The multifunctional polyamide composite material of the invention is added with silver nano particles, kaolin, silicon carbide, antimony tin oxide, molybdenum trioxide, lithium fluoride, and the combination of various inorganic particles, thereby effectively improving the multifunctional polyamide composite material. Thermal conductivity, antibacterial properties and antistatic properties prevent high temperature aging of multifunctional polyamide composites.
本发明的多功能聚酰胺复合材料中添加有玻璃纤维和碳纤维，上述材料在多功能聚酰胺复合材料中相互交联，有效提高了多功能聚酰胺复合材料的韧性和力学性能，同时添加有半导体特性的3-己基噻吩聚合物，进一步提高了其抗静电性能。 The multifunctional polyamide composite material of the invention is added with glass fiber and carbon fiber, and the above materials are cross-linked in the multifunctional polyamide composite material, thereby effectively improving the toughness and mechanical properties of the multifunctional polyamide composite material, and adding a semiconductor The characteristic 3-hexylthiophene polymer further enhances its antistatic properties.
本发明的多功能聚酰胺复合材料中添加有多种助剂，通过优化各组分之间的具体含量，使得各组分之间相辅相成，形成的多功能聚酰胺复合材料综合性能优异，适合用于多种领域。The multifunctional polyamide composite material of the invention is added with various auxiliary agents, and by optimizing the specific content between the components, the components are mutually complementary, and the formed multifunctional polyamide composite material has excellent comprehensive performance, and is suitable for use. In a variety of fields.
具体实施方式Detailed ways
以下结合实施例对本发明作进一步详细描述。The invention is further described in detail below with reference to the embodiments.
本发明提供一种多功能聚酰胺复合材料，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯10-20份；聚偏氟乙烯5-15份；聚乙烯醇10-15份；聚醚酰亚胺5-10份；聚苯乙烯5-10份；磷酸钠3-6份；三聚氰胺2-5份；苯并三唑1-3份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物2-8份；硬质酸钠1-4份；银纳米颗粒2-6份；聚苯乙烯磺酸钠5-15份；双(3,5-三级丁基-4-羟基苯基)硫醚1-5份；过氧化二苯甲酰0.1-0.5份；高岭土1-5份；碳化硅2-6份；氧化锡锑1-3份；甲基苯基硅油1-5份；三氧化钼1-3份；氟化锂0.1-0.5份；三(8-羟基喹啉)铝1-3份；三硬脂酸甘油酯2-6份；乙烯1-5份；乙烯基三乙氧基硅烷1-2份；邻苯二甲酸二辛酯1-4份；叔丁基对苯二酚1-3份，玻璃纤维2-6份；碳纤维1-5份；3-己基噻吩聚合物0.5-2份；氧化镁颗粒2-6份；亚磷酸酯1-6份；乙酸乙酯1-3份。The present invention provides a multifunctional polyamide composite material comprising the following components by weight: 100 parts of polyamide; 10-20 parts of polyethylene terephthalate; 5-15 parts of vinyl fluoride; 10-15 parts of polyvinyl alcohol; 5-10 parts of polyetherimide; 5-10 parts of polystyrene; 3-6 parts of sodium phosphate; 2-5 parts of melamine; benzotriazole 1-3 parts; 2-8 parts of methyl methacrylate-butadiene-styrene copolymer; 1-4 parts of sodium hard acid; 2-6 parts of silver nanoparticles; 5-15 of sodium polystyrene sulfonate Parts; bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide 1-5 parts; dibenzoyl peroxide 0.1-0.5 parts; kaolin 1-5 parts; silicon carbide 2-6 parts; 1-3 parts of tin oxide bismuth; 1-5 parts of methylphenyl silicone oil; 1-3 parts of molybdenum trioxide; 0.1-0.5 parts of lithium fluoride; 1-3 parts of tris(8-hydroxyquinoline) aluminum; 2-6 parts of glyceryl fatty acid; 1-5 parts of ethylene; 1-2 parts of vinyl triethoxysilane; 1-4 parts of dioctyl phthalate; 1-3 parts of t-butyl hydroquinone 2-6 parts of glass fiber; 1-5 parts of carbon fiber; 0.5-2 part of 3-hexylthiophene polymer; 2-6 parts of magnesium oxide particles; 1-6 parts of phosphite; 1-3 parts of ethyl acetate
实施例1Example 1
一种多功能聚酰胺复合材料，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯15份；聚偏氟乙烯10份；聚乙烯醇12份；聚醚酰亚胺7份；聚苯乙烯8份；磷酸钠5份；三聚氰胺4份；苯并三唑2份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物5份；硬质酸钠3份；银纳米颗粒4份；聚苯乙烯磺酸钠10份；双(3,5-三级丁基-4-羟基苯基)硫醚3份；过氧化二苯甲酰0.3份；高岭土3份；碳化硅4份；氧化锡锑2份；甲基苯基硅油3份；三氧化钼2份；氟化锂0.3份；三(8-羟基喹啉)铝2份；三硬脂酸甘油酯4份；乙烯3份；乙烯基三乙氧基硅烷1份；邻苯二甲酸二辛酯3份；叔丁基对苯二酚2份，玻璃纤维4份；碳纤维3份；3-己基噻吩聚合物1份；氧化镁颗粒4份；亚磷酸酯4份；乙酸乙酯2份。A multifunctional polyamide composite material comprising the following components by weight: 100 parts of polyamide; 15 parts of polyethylene terephthalate; 10 parts of polyvinylidene fluoride; 12 parts of polyvinyl alcohol; 7 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 4 parts of melamine; 2 parts of benzotriazole; methyl methacrylate-butadiene-styrene copolymer 5 parts; 3 parts of sodium hard acid; 4 parts of silver nanoparticles; 10 parts of sodium polystyrene sulfonate; 3 parts of bis(3,5-tri-butyl-4-hydroxyphenyl) sulfide; Benzoyl 0.3 parts; kaolin 3 parts; silicon carbide 4 parts; tin oxide bismuth 2 parts; methyl phenyl silicone oil 3 parts; molybdenum trioxide 2 parts; lithium fluoride 0.3 parts; tris(8-hydroxyquinoline) aluminum 2 parts; 4 parts of glyceryl tristearate; 3 parts of ethylene; 1 part of vinyl triethoxysilane; 3 parts of dioctyl phthalate; 2 parts of t-butyl hydroquinone, 4 parts of glass fiber 3 parts of carbon fiber; 1 part of 3-hexylthiophene polymer; 4 parts of magnesium oxide particles; 4 parts of phosphite; 2 parts of ethyl acetate.
实施例2Example 2
一种多功能聚酰胺复合材料，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯18份；聚偏氟乙烯12份；聚乙烯醇14份；聚醚酰亚胺9份；聚苯乙烯8份；磷酸钠5份；三聚氰胺3份；苯并三唑3份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物7份；硬质酸钠3份；银纳米颗粒5份；聚苯乙烯磺酸钠12份；双(3,5-三级丁基-4-羟基苯基)硫醚4份；过氧化二苯甲酰0.4份；高岭土4份；碳化硅5份；氧化锡锑3份；甲基苯基硅油4份；三氧化钼1份；氟化锂0.5份；三(8-羟基喹啉)铝3份；三硬脂 酸甘油酯5份；乙烯1份；乙烯基三乙氧基硅烷2份；邻苯二甲酸二辛酯3份；叔丁基对苯二酚3份，玻璃纤维5份；碳纤维4份；3-己基噻吩聚合物2份；氧化镁颗粒5份；亚磷酸酯5份；乙酸乙酯1份。A multifunctional polyamide composite material comprising: by weight of the following components: 100 parts of polyamide; 18 parts of polyethylene terephthalate; 12 parts of polyvinylidene fluoride; 14 parts of polyvinyl alcohol; 9 parts of polyetherimide; 8 parts of polystyrene; 5 parts of sodium phosphate; 3 parts of melamine; 3 parts of benzotriazole; methyl methacrylate-butadiene-styrene copolymer 7 parts; 3 parts of sodium hard acid; 5 parts of silver nanoparticles; 12 parts of sodium polystyrene sulfonate; 4 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.4 parts of benzoyl; 4 parts of kaolin; 5 parts of silicon carbide; 3 parts of tin oxide; 4 parts of methylphenyl silicone oil; 1 part of molybdenum trioxide; 0.5 parts of lithium fluoride; aluminum tris(8-hydroxyquinoline) 3 parts; tristearyl 5 parts of acid glyceride; 1 part of ethylene; 2 parts of vinyltriethoxysilane; 3 parts of dioctyl phthalate; 3 parts of t-butyl hydroquinone, 5 parts of glass fiber; 4 parts of carbon fiber; 2 parts of hexylthiophene polymer; 5 parts of magnesium oxide particles; 5 parts of phosphite; 1 part of ethyl acetate.
实施例3Example 3
一种多功能聚酰胺复合材料，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯12份；聚偏氟乙烯7份；聚乙烯醇11份；聚醚酰亚胺6份；聚苯乙烯7份；磷酸钠3份；三聚氰胺4份；苯并三唑1份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物4份；硬质酸钠2份；银纳米颗粒3份；聚苯乙烯磺酸钠7份；双(3,5-三级丁基-4-羟基苯基)硫醚2份；过氧化二苯甲酰0.1份；高岭土1份；碳化硅4份；氧化锡锑3份；甲基苯基硅油2份；三氧化钼2份；氟化锂0.5份；三(8-羟基喹啉)铝2份；三硬脂酸甘油酯3份；乙烯2份；乙烯基三乙氧基硅烷1份；邻苯二甲酸二辛酯4份；叔丁基对苯二酚2份，玻璃纤维3份；碳纤维2份；3-己基噻吩聚合物0.5份；氧化镁颗粒3份；亚磷酸酯2份；乙酸乙酯1份。A multifunctional polyamide composite material comprising: by weight of the following components: 100 parts of polyamide; 12 parts of polyethylene terephthalate; 7 parts of polyvinylidene fluoride; 11 parts of polyvinyl alcohol; 6 parts of polyetherimide; 7 parts of polystyrene; 3 parts of sodium phosphate; 4 parts of melamine; 1 part of benzotriazole; methyl methacrylate-butadiene-styrene copolymer 4 parts; 2 parts of sodium hard acid; 3 parts of silver nanoparticles; 7 parts of sodium polystyrene sulfonate; 2 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1 part of benzoyl; 1 part of kaolin; 4 parts of silicon carbide; 3 parts of tin oxide; 2 parts of methylphenyl silicone oil; 2 parts of molybdenum trioxide; 0.5 part of lithium fluoride; aluminum tris(8-hydroxyquinoline) 2 parts; 3 parts of glyceryl tristearate; 2 parts of ethylene; 1 part of vinyl triethoxysilane; 4 parts of dioctyl phthalate; 2 parts of t-butyl hydroquinone, 3 parts of glass fiber 2 parts of carbon fiber; 0.5 part of 3-hexylthiophene polymer; 3 parts of magnesium oxide particles; 2 parts of phosphite; 1 part of ethyl acetate.
本发明通过各组分之间的协同作用，使得多功能聚酰胺复合材料具有优异的力学性能、耐热性能、耐磨性能以及抗静电性能，且具有良好的耐紫外线性能。本发明的多功能聚酰胺复合材料中添加有银纳米颗粒、高岭土、碳化硅、氧化锡锑、三氧化钼、氟化锂，多种无机颗粒的配合作用，有效提高了多功能聚酰胺复合材料的导热性能、抗菌性能以及抗静电性能，进而防止多功能聚酰胺复合材料高温老化。本发明的多功能聚酰胺复合材料中添加有玻璃纤维和碳纤维，上述材料在多功能聚酰胺复合材料中相互交联，有效提高了多功能聚酰胺复合材料的韧性和力学性能，同时添加有半导体特性的3-己基噻吩聚合物，进一步提高了其抗静电性能。本发明的多功能聚酰胺复合材料中添加有多种助剂，通过优化各组分之间的具体含量，使得各组分之间相辅相成，形成的多功能聚酰胺复合材料综合性能优异，适合用于多种领域。The invention makes the multifunctional polyamide composite material have excellent mechanical properties, heat resistance, abrasion resistance and antistatic property through the synergy between the components, and has good ultraviolet resistance. The multifunctional polyamide composite material of the invention is added with silver nano particles, kaolin, silicon carbide, antimony tin oxide, molybdenum trioxide, lithium fluoride, and the combination of various inorganic particles, thereby effectively improving the multifunctional polyamide composite material. Thermal conductivity, antibacterial properties and antistatic properties prevent high temperature aging of multifunctional polyamide composites. The multifunctional polyamide composite material of the invention is added with glass fiber and carbon fiber, and the above materials are cross-linked in the multifunctional polyamide composite material, thereby effectively improving the toughness and mechanical properties of the multifunctional polyamide composite material, and adding a semiconductor The characteristic 3-hexylthiophene polymer further enhances its antistatic properties. The multifunctional polyamide composite material of the invention is added with various auxiliary agents, and by optimizing the specific content between the components, the components are mutually complementary, and the formed multifunctional polyamide composite material has excellent comprehensive performance, and is suitable for use. In a variety of fields.
最后应当说明的是，以上实施例仅用于说明本发明的技术方案而非对本发明保护范围的限制，尽管参照较佳实施例对本发明作了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的实质和范围。 It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and are not intended to limit the scope of the present invention. Although the present invention is described in detail with reference to the preferred embodiments, those skilled in the art The technical solutions of the present invention are modified or equivalently substituted without departing from the spirit and scope of the technical solutions of the present invention.

Claims (4)

  1. 一种多功能聚酰胺复合材料，其特征在于，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯10-20份；聚偏氟乙烯5-15份；聚乙烯醇10-15份；聚醚酰亚胺5-10份；聚苯乙烯5-10份；磷酸钠3-6份；三聚氰胺2-5份；苯并三唑1-3份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物2-8份；硬质酸钠1-4份；银纳米颗粒2-6份；聚苯乙烯磺酸钠5-15份；双(3,5-三级丁基-4-羟基苯基)硫醚1-5份；过氧化二苯甲酰0.1-0.5份；高岭土1-5份；碳化硅2-6份；氧化锡锑1-3份；甲基苯基硅油1-5份；三氧化钼1-3份；氟化锂0.1-0.5份；三(8-羟基喹啉)铝1-3份；三硬脂酸甘油酯2-6份；乙烯1-5份；乙烯基三乙氧基硅烷1-2份；邻苯二甲酸二辛酯1-4份；叔丁基对苯二酚1-3份，玻璃纤维2-6份；碳纤维1-5份；3-己基噻吩聚合物0.5-2份；氧化镁颗粒2-6份；亚磷酸酯1-6份；乙酸乙酯1-3份。A multifunctional polyamide composite material characterized in that the multifunctional polyamide composite material is composed of parts by weight of a polyamide: 100 parts; polyethylene terephthalate 10-20 parts; 5-15 parts of vinylidene fluoride; 10-15 parts of polyvinyl alcohol; 5-10 parts of polyetherimide; 5-10 parts of polystyrene; 3-6 parts of sodium phosphate; 2-5 parts of melamine; 1-3 parts of azole; 2-8 parts of methyl methacrylate-butadiene-styrene copolymer; 1-4 parts of sodium hard acid; 2-6 parts of silver nanoparticles; sodium 5-styrene sulfonate 15 parts; 1-5 parts of bis(3,5-tris-butyl-4-hydroxyphenyl) sulfide; 0.1-0.5 parts of dibenzoyl peroxide; 1-5 parts of kaolin; 2-6 parts of silicon carbide 1-3 parts of tin oxide bismuth; 1-5 parts of methylphenyl silicone oil; 1-3 parts of molybdenum trioxide; 0.1-0.5 parts of lithium fluoride; 1-3 parts of tris(8-hydroxyquinoline) aluminum; 2-6 parts of glyceryl stearate; 1-5 parts of ethylene; 1-2 parts of vinyltriethoxysilane; 1-4 parts of dioctyl phthalate; tert-butyl hydroquinone 1-3 Parts, glass fiber 2-6 parts; carbon fiber 1-5 parts; 3-hexyl thiophene polymer 0.5-2 parts; magnesium oxide particles 2-6 parts; phosphite 1-6 parts; ethyl acetate 1-3 .
  2. 根据权利要求1所述的多功能聚酰胺复合材料，其特征在于，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯15份；聚偏氟乙烯10份；聚乙烯醇12份；聚醚酰亚胺7份；聚苯乙烯8份；磷酸钠5份；三聚氰胺4份；苯并三唑2份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物5份；硬质酸钠3份；银纳米颗粒4份；聚苯乙烯磺酸钠10份；双(3,5-三级丁基-4-羟基苯基)硫醚3份；过氧化二苯甲酰0.3份；高岭土3份；碳化硅4份；氧化锡锑2份；甲基苯基硅油3份；三氧化钼2份；氟化锂0.3份；三(8-羟基喹啉)铝2份；三硬脂酸甘油酯4份；乙烯3份；乙烯基三乙氧基硅烷1份；邻苯二甲酸二辛酯3份；叔丁基对苯二酚2份，玻璃纤维4份；碳纤维3份；3-己基噻吩聚合物1份；氧化镁颗粒4份；亚磷酸酯4份；乙酸乙酯2份。The multifunctional polyamide composite according to claim 1, wherein the multifunctional polyamide composite is composed of parts by weight of a polyamide: 100 parts; polyethylene terephthalate 15 Parts; polyvinylidene fluoride 10 parts; polyvinyl alcohol 12 parts; polyetherimide 7 parts; polystyrene 8 parts; sodium phosphate 5 parts; melamine 4 parts; benzotriazole 2 parts; methyl methacrylate - 5 parts of butadiene-styrene copolymer; 3 parts of sodium hard acid; 4 parts of silver nanoparticles; 10 parts of sodium polystyrene sulfonate; bis (3,5-tris-butyl-4-hydroxyphenyl) 3 parts of thioether; 0.3 parts of dibenzoyl peroxide; 3 parts of kaolin; 4 parts of silicon carbide; 2 parts of tin oxide; 3 parts of methylphenyl silicone oil; 2 parts of molybdenum trioxide; 0.3 parts of lithium fluoride; 2 parts of tris(8-hydroxyquinoline)aluminum; 4 parts of glyceryl tristearate; 3 parts of ethylene; 1 part of vinyltriethoxysilane; 3 parts of dioctyl phthalate; tert-butyl-p-benzene 2 parts of diphenol, 4 parts of glass fiber; 3 parts of carbon fiber; 1 part of 3-hexylthiophene polymer; 4 parts of magnesium oxide particles; 4 parts of phosphite; 2 parts of ethyl acetate.
  3. 根据权利要求1所述的多功能聚酰胺复合材料，其特征在于，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯18份；聚偏氟乙烯12份；聚乙烯醇14份；聚醚酰亚胺9份；聚苯乙烯8份；磷酸钠5份；三聚氰胺3份；苯并三唑3份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物7份；硬质酸钠3份；银纳米颗粒5份；聚苯乙烯磺酸钠12份；双(3,5-三级丁基-4-羟基苯基)硫醚4份；过氧化二苯甲酰0.4份；高岭土4份；碳化硅5份；氧化锡锑3份；甲基苯基硅油4份；三氧化钼1份；氟化锂0.5份；三(8-羟基喹啉)铝3份；三硬脂酸甘油酯5份；乙烯1份；乙烯基三乙氧基硅烷2份；邻苯二甲酸二辛酯3份；叔丁基对苯二酚3份，玻璃纤维5份；碳纤维4份；3-己基噻吩聚合物2份；氧化镁颗粒5份；亚磷酸酯5份；乙酸乙酯1份。 The multifunctional polyamide composite material according to claim 1, wherein the multifunctional polyamide composite material is composed of parts by weight of a polyamide: 100 parts; polyethylene terephthalate 18 Parts; polyvinylidene fluoride 12 parts; polyvinyl alcohol 14 parts; polyetherimide 9 parts; polystyrene 8 parts; sodium phosphate 5 parts; melamine 3 parts; benzotriazole 3 parts; methyl methacrylate - 7 parts of butadiene-styrene copolymer; 3 parts of sodium hard acid; 5 parts of silver nanoparticles; 12 parts of sodium polystyrene sulfonate; bis (3,5-tris-butyl-4-hydroxyphenyl) 4 parts of thioether; 0.4 parts of dibenzoyl peroxide; 4 parts of kaolin; 5 parts of silicon carbide; 3 parts of tin oxide; 4 parts of methylphenyl silicone oil; 1 part of molybdenum trioxide; 0.5 parts of lithium fluoride; 3 parts of tris(8-hydroxyquinoline)aluminum; 5 parts of glyceryl tristearate; 1 part of ethylene; 2 parts of vinyltriethoxysilane; 3 parts of dioctyl phthalate; tert-butyl-p-benzene 3 parts of diphenol, 5 parts of glass fiber; 4 parts of carbon fiber; 2 parts of 3-hexylthiophene polymer; 5 parts of magnesium oxide particles; 5 parts of phosphite; 1 part of ethyl acetate.
  4. 根据权利要求1所述的多功能聚酰胺复合材料，其特征在于，所述多功能聚酰胺复合材料由以下组分的重量份组成：聚酰胺100份；聚对苯二甲酸乙二醇酯12份；聚偏氟乙烯7份；聚乙烯醇11份；聚醚酰亚胺6份；聚苯乙烯7份；磷酸钠3份；三聚氰胺4份；苯并三唑1份；甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物4份；硬质酸钠2份；银纳米颗粒3份；聚苯乙烯磺酸钠7份；双(3,5-三级丁基-4-羟基苯基)硫醚2份；过氧化二苯甲酰0.1份；高岭土1份；碳化硅4份；氧化锡锑3份；甲基苯基硅油2份；三氧化钼2份；氟化锂0.5份；三(8-羟基喹啉)铝2份；三硬脂酸甘油酯3份；乙烯2份；乙烯基三乙氧基硅烷1份；邻苯二甲酸二辛酯4份；叔丁基对苯二酚2份，玻璃纤维3份；碳纤维2份；3-己基噻吩聚合物0.5份；氧化镁颗粒3份；亚磷酸酯2份；乙酸乙酯1份。 The multifunctional polyamide composite material according to claim 1, wherein the multifunctional polyamide composite material is composed of parts by weight of a polyamide: 100 parts; polyethylene terephthalate 12 Parts; polyvinylidene fluoride 7 parts; polyvinyl alcohol 11 parts; polyetherimide 6 parts; polystyrene 7 parts; sodium phosphate 3 parts; melamine 4 parts; benzotriazole 1 part; methyl methacrylate - 4 parts of butadiene-styrene copolymer; 2 parts of sodium hard acid; 3 parts of silver nanoparticles; 7 parts of sodium polystyrene sulfonate; bis (3,5-tris-butyl-4-hydroxyphenyl) 2 parts of thioether; 0.1 part of dibenzoyl peroxide; 1 part of kaolin; 4 parts of silicon carbide; 3 parts of tin oxide; 2 parts of methylphenyl silicone oil; 2 parts of molybdenum trioxide; 0.5 parts of lithium fluoride; 2 parts of tris(8-hydroxyquinoline)aluminum; 3 parts of glyceryl tristearate; 2 parts of ethylene; 1 part of vinyltriethoxysilane; 4 parts of dioctyl phthalate; tert-butyl-p-benzene 2 parts of diphenol, 3 parts of glass fiber; 2 parts of carbon fiber; 0.5 part of 3-hexylthiophene polymer; 3 parts of magnesium oxide particles; 2 parts of phosphite; 1 part of ethyl acetate.
PCT/CN2017/116557 2017-11-22 2017-12-15 Multifunctional polyamide composite material WO2019100469A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201711172209.6 2017-11-22
CN201711172209.6A CN107778844A (en) 2017-11-22 2017-11-22 A kind of multi-functional polyamide compoiste material

Publications (1)

Publication Number Publication Date
WO2019100469A1 true WO2019100469A1 (en) 2019-05-31

Family

ID=61430759

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/116557 WO2019100469A1 (en) 2017-11-22 2017-12-15 Multifunctional polyamide composite material

Country Status (2)

Country Link
CN (1) CN107778844A (en)
WO (1) WO2019100469A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112431377B (en) * 2020-11-27 2021-11-12 曾跃申 Anti-static super-wear-resistant thin-layer material special for gas station and oil depot ground and construction method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680093B1 (en) * 1997-05-15 2004-01-20 Degussa Ag Multilayer composites
CN101302337A (en) * 2008-07-03 2008-11-12 杭州临安宏凯工程塑料有限公司 High temperature resistant low water absorption polyamide 66 composite material and preparation thereof
CN103059556A (en) * 2011-10-19 2013-04-24 合肥杰事杰新材料股份有限公司 Polyamide composition and preparation method thereof
CN105504800A (en) * 2014-10-08 2016-04-20 Ems专利股份公司 Flowable polyamides
CN106280408A (en) * 2016-08-27 2017-01-04 朱燕华 A kind of modified resin of plate type heat exchanger

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680093B1 (en) * 1997-05-15 2004-01-20 Degussa Ag Multilayer composites
CN101302337A (en) * 2008-07-03 2008-11-12 杭州临安宏凯工程塑料有限公司 High temperature resistant low water absorption polyamide 66 composite material and preparation thereof
CN103059556A (en) * 2011-10-19 2013-04-24 合肥杰事杰新材料股份有限公司 Polyamide composition and preparation method thereof
CN105504800A (en) * 2014-10-08 2016-04-20 Ems专利股份公司 Flowable polyamides
CN106280408A (en) * 2016-08-27 2017-01-04 朱燕华 A kind of modified resin of plate type heat exchanger

Also Published As

Publication number Publication date
CN107778844A (en) 2018-03-09

Similar Documents

Publication Publication Date Title
CN106047073B (en) A kind of graphene oxide based high-temp-resistant bicomponent epoxy resin coating
WO2016101678A1 (en) High-flowability glass fibre reinforced polyphenyl thioether composite based on nano forming technology
CN106380683A (en) Slip polypropylene film
CN104788839A (en) High abrasion-resistant engineering plastic
WO2019100468A1 (en) Formula of pp-abs composite material
CN106336574A (en) BOPP film
WO2019100469A1 (en) Multifunctional polyamide composite material
JP2016108526A5 (en) Polycarbonate resin composition
JP2019505605A5 (en)
CN106543598A (en) A kind of wear-resistant antibacterial CABLE MATERIALS
CN106279885A (en) A kind of flame retardant type plastic package material
CN204027314U (en) A kind of graphite crucible
CN104945899A (en) Modified nylon composite material
CN104804572A (en) Heat dissipation coating for electrical appliances
CN104945864A (en) Anti-static polyethylene terephthalate (PET) composite material
WO2019100470A1 (en) High-performance polycarbonate composite material
CN106916388A (en) A kind of Modification of kaolin CABLE MATERIALS and preparation method thereof
CN106479135A (en) A kind of PET with bacteriostasis
CN104356577A (en) Novel heat-resistant plastic alloy formula
CN105694355A (en) Resin based composite
CN104356607A (en) Corrosion-resistant polymer material
CN104109283B (en) A kind of PP heat conduction UV resistant agent and heat conduction uvioresistant PP materials prepared therefrom
CN104262738A (en) Flame-retardant, anti-ageing and anti-bacterial PE pipe
CN107778632A (en) A kind of composite polyethylene material
CN108456440A (en) A kind of plastic spanner high-temperature resistant coating

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17932702

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17932702

Country of ref document: EP

Kind code of ref document: A1