CN107778844A - A kind of multi-functional polyamide compoiste material - Google Patents
A kind of multi-functional polyamide compoiste material Download PDFInfo
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- CN107778844A CN107778844A CN201711172209.6A CN201711172209A CN107778844A CN 107778844 A CN107778844 A CN 107778844A CN 201711172209 A CN201711172209 A CN 201711172209A CN 107778844 A CN107778844 A CN 107778844A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2255—Oxides; Hydroxides of metals of molybdenum
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
The present invention relates to a kind of multi-functional polyamide compoiste material, belongs to plastics arts, the multi-functional polyamide compoiste material is using polyamide as matrix, simultaneously containing multi-component functional additive.Pass through the synergy between each component so that the multi-functional polyamide compoiste material has excellent mechanical property, heat resistance, anti-wear performance and antistatic property, and has good UV resistant performance.
Description
Technical field
The present invention relates to plastics arts, more particularly to a kind of multi-functional polyamide compoiste material.
Background technology
Polyamide, is the widely used industrial chemicals of function admirable, can be divided into two major classes by its property：It is non-reacted
Or neutral polyamide and reactive polyamide.Neutral polyamide is mainly for the production of ink, heat sealer binding agent and coating, reaction
Property polyamide be used for epoxy resin curing agent, and for thermosetting surface's coating, binding agent, inner lining material and potting, molding tree
Fat.Different additives can be added according to different purposes, different physical properties and mechanical property can be presented in Maranyl
Energy.And existing modified polyamide material function is single.How to design a kind of multi-functional polyamide compoiste material, be industry urgently
Solve the problems, such as.
The content of the invention
A kind of multi-functional polyamide composite wood is provided it is an object of the invention to avoid weak point of the prior art
Material.
The purpose of the present invention is achieved through the following technical solutions：
A kind of multi-functional polyamide compoiste material is provided, the multi-functional polyamide compoiste material by following components parts by weight group
Into：100 parts of polyamide；Polyethylene terephthalate 10-20 parts；Kynoar 5-15 parts；Polyvinyl alcohol 10-15 parts；
PEI 5-10 parts；Polystyrene 5-10 parts；Sodium phosphate 3-6 parts；Melamine 2-5 parts；BTA 1-3 parts；Methyl
Methylacrylate-butadiene-styrol copolymer 2-8 parts；Stearic acid sodium 1-4 parts；Silver nano-grain 2-6 parts；Polystyrene sulphur
Sour sodium 5-15 parts；It is double（3,5- three-level butyl -4- hydroxy phenyls）Thioether 1-5 parts；Dibenzoyl peroxide 0.1-0.5 parts；Kaolinite
Native 1-5 parts；Carborundum 2-6 parts；Tin-antiomony oxide 1-3 parts；Methyl phenyl silicone oil 1-5 parts；Molybdenum trioxide 1-3 parts；Lithium fluoride 0.1-
0.5 part；Three（8-hydroxyquinoline）Aluminium 1-3 parts；Glyceryl tristearate 2-6 parts；Ethene 1-5 parts；VTES
1-2 parts；Dioctyl phthalate 1-4 parts；TBHQ 1-3 parts, glass fibre 2-6 parts；Carbon fiber 1-5 parts；3-
Hexyl thiophene polymer 0.5-2 parts；Magnesium oxide particle 2-6 parts；Phosphite ester 1-6 parts；Ethyl acetate 1-3 parts.
Preferably, the multi-functional polyamide compoiste material is made up of the parts by weight of following components：100 parts of polyamide；
15 parts of polyethylene terephthalate；10 parts of Kynoar；12 parts of polyvinyl alcohol；7 parts of PEI；Polystyrene 8
Part；5 parts of sodium phosphate；4 parts of melamine；2 parts of BTA；5 parts of MBS；Firmly
3 parts of matter acid sodium；4 parts of silver nano-grain；10 parts of kayexalate；It is double（3,5- three-level butyl -4- hydroxy phenyls）Thioether 3
Part；0.3 part of dibenzoyl peroxide；3 parts of kaolin；4 parts of carborundum；2 parts of tin-antiomony oxide；3 parts of methyl phenyl silicone oil；Three oxidations
2 parts of molybdenum；0.3 part of lithium fluoride；Three（8-hydroxyquinoline）2 parts of aluminium；4 parts of glyceryl tristearate；3 parts of ethene；The ethoxy of vinyl three
1 part of base silane；3 parts of dioctyl phthalate；2 parts of TBHQ, 4 parts of glass fibre；3 parts of carbon fiber；3- hexyls
1 part of thiophen polymer；4 parts of magnesium oxide particle；4 parts of phosphite ester；2 parts of ethyl acetate.
Preferably, the multi-functional polyamide compoiste material is made up of the parts by weight of following components：100 parts of polyamide；
18 parts of polyethylene terephthalate；12 parts of Kynoar；14 parts of polyvinyl alcohol；9 parts of PEI；Polystyrene 8
Part；5 parts of sodium phosphate；3 parts of melamine；3 parts of BTA；7 parts of MBS；Firmly
3 parts of matter acid sodium；5 parts of silver nano-grain；12 parts of kayexalate；It is double（3,5- three-level butyl -4- hydroxy phenyls）Thioether 4
Part；0.4 part of dibenzoyl peroxide；4 parts of kaolin；5 parts of carborundum；3 parts of tin-antiomony oxide；4 parts of methyl phenyl silicone oil；Three oxidations
1 part of molybdenum；0. 5 parts of lithium fluoride；Three（8-hydroxyquinoline）3 parts of aluminium；5 parts of glyceryl tristearate；1 part of ethene；The ethoxy of vinyl three
2 parts of base silane；3 parts of dioctyl phthalate；3 parts of TBHQ, 5 parts of glass fibre；4 parts of carbon fiber；3- hexyls
2 parts of thiophen polymer；5 parts of magnesium oxide particle；5 parts of phosphite ester；1 part of ethyl acetate.
Preferably, the multi-functional polyamide compoiste material is made up of the parts by weight of following components：100 parts of polyamide；
12 parts of polyethylene terephthalate；7 parts of Kynoar；11 parts of polyvinyl alcohol；6 parts of PEI；Polystyrene 7
Part；3 parts of sodium phosphate；4 parts of melamine；1 part of BTA；4 parts of MBS；Firmly
2 parts of matter acid sodium；3 parts of silver nano-grain；7 parts of kayexalate；It is double（3,5- three-level butyl -4- hydroxy phenyls）2 parts of thioether；
0.1 part of dibenzoyl peroxide；1 part of kaolin；4 parts of carborundum；3 parts of tin-antiomony oxide；2 parts of methyl phenyl silicone oil；Molybdenum trioxide 2
Part；0.5 part of lithium fluoride；Three（8-hydroxyquinoline）2 parts of aluminium；3 parts of glyceryl tristearate；2 parts of ethene；Vinyl triethoxyl silicon
1 part of alkane；4 parts of dioctyl phthalate；2 parts of TBHQ, 3 parts of glass fibre；2 parts of carbon fiber；3- hexyl thiophenes
0.5 part of polymer；3 parts of magnesium oxide particle；2 parts of phosphite ester；1 part of ethyl acetate.
Beneficial effects of the present invention：The present invention passes through the synergy between each component so that multi-functional polyamide is compound
Material has excellent mechanical property, heat resistance, anti-wear performance and antistatic property, and has good ultra-violet resistance
Energy.
Added with silver nano-grain, kaolin, carborundum, tin oxide in the multi-functional polyamide compoiste material of the present invention
Antimony, molybdenum trioxide, lithium fluoride, the mating reaction of a variety of inorganic particles, effectively increase leading for multi-functional polyamide compoiste material
Hot property, anti-microbial property and antistatic property, and then prevent multi-functional polyamide compoiste material high temperature ageing.
Glass fibre and carbon fiber are added with the multi-functional polyamide compoiste material of the present invention, above-mentioned material is multi-functional
It is cross-linked with each other in polyamide compoiste material, effectively increases the toughness and mechanical property of multi-functional polyamide compoiste material, simultaneously
3- hexyl thiophene polymer added with characteristic of semiconductor, further increases its antistatic property.
A variety of auxiliary agents are added with the multi-functional polyamide compoiste material of the present invention, it is specific between each component by optimizing
Content so that complement each other, the multi-functional polyamide compoiste material excellent combination property of formation, be suitable for more between each component
Kind field.
Embodiment
The present invention is described in further detail with reference to embodiments.
The present invention provides a kind of multi-functional polyamide compoiste material, and the multi-functional polyamide compoiste material is by following components
Parts by weight composition：100 parts of polyamide；Polyethylene terephthalate 10-20 parts；Kynoar 5-15 parts；Polyethylene
Alcohol 10-15 parts；PEI 5-10 parts；Polystyrene 5-10 parts；Sodium phosphate 3-6 parts；Melamine 2-5 parts；BTA
1-3 parts；MBS 2-8 parts；Stearic acid sodium 1-4 parts；Silver nano-grain 2-6 parts；
Kayexalate 5-15 parts；It is double（3,5- three-level butyl -4- hydroxy phenyls）Thioether 1-5 parts；Dibenzoyl peroxide 0.1-
0.5 part；Kaolin 1-5 parts；Carborundum 2-6 parts；Tin-antiomony oxide 1-3 parts；Methyl phenyl silicone oil 1-5 parts；Molybdenum trioxide 1-3 parts；
Lithium fluoride 0.1-0.5 parts；Three（8-hydroxyquinoline）Aluminium 1-3 parts；Glyceryl tristearate 2-6 parts；Ethene 1-5 parts；Vinyl three
Ethoxysilane 1-2 parts；Dioctyl phthalate 1-4 parts；TBHQ 1-3 parts, glass fibre 2-6 parts；Carbon is fine
Tie up 1-5 parts；3- hexyl thiophene polymer 0.5-2 parts；Magnesium oxide particle 2-6 parts；Phosphite ester 1-6 parts；Ethyl acetate 1-3 parts.
Embodiment 1
A kind of multi-functional polyamide compoiste material, the multi-functional polyamide compoiste material are made up of the parts by weight of following components：
100 parts of polyamide；15 parts of polyethylene terephthalate；10 parts of Kynoar；12 parts of polyvinyl alcohol；PEI 7
Part；8 parts of polystyrene；5 parts of sodium phosphate；4 parts of melamine；2 parts of BTA；MBS
5 parts of copolymer；3 parts of stearic acid sodium；4 parts of silver nano-grain；10 parts of kayexalate；It is double（3,5- three-level butyl -4- hydroxyls
Phenyl）3 parts of thioether；0.3 part of dibenzoyl peroxide；3 parts of kaolin；4 parts of carborundum；2 parts of tin-antiomony oxide；Methyl phenyl silicone oil
3 parts；2 parts of molybdenum trioxide；0.3 part of lithium fluoride；Three（8-hydroxyquinoline）2 parts of aluminium；4 parts of glyceryl tristearate；3 parts of ethene；Second
1 part of alkenyl triethoxysilane；3 parts of dioctyl phthalate；2 parts of TBHQ, 4 parts of glass fibre；Carbon fiber 3
Part；1 part of 3- hexyl thiophenes polymer；4 parts of magnesium oxide particle；4 parts of phosphite ester；2 parts of ethyl acetate.
Embodiment 2
A kind of multi-functional polyamide compoiste material, the multi-functional polyamide compoiste material are made up of the parts by weight of following components：
100 parts of polyamide；18 parts of polyethylene terephthalate；12 parts of Kynoar；14 parts of polyvinyl alcohol；PEI 9
Part；8 parts of polystyrene；5 parts of sodium phosphate；3 parts of melamine；3 parts of BTA；MBS
7 parts of copolymer；3 parts of stearic acid sodium；5 parts of silver nano-grain；12 parts of kayexalate；It is double（3,5- three-level butyl -4- hydroxyls
Phenyl）4 parts of thioether；0.4 part of dibenzoyl peroxide；4 parts of kaolin；5 parts of carborundum；3 parts of tin-antiomony oxide；Methyl phenyl silicone oil
4 parts；1 part of molybdenum trioxide；0. 5 parts of lithium fluoride；Three（8-hydroxyquinoline）3 parts of aluminium；5 parts of glyceryl tristearate；1 part of ethene；Second
2 parts of alkenyl triethoxysilane；3 parts of dioctyl phthalate；3 parts of TBHQ, 5 parts of glass fibre；Carbon fiber 4
Part；2 parts of 3- hexyl thiophenes polymer；5 parts of magnesium oxide particle；5 parts of phosphite ester；1 part of ethyl acetate.
Embodiment 3
A kind of multi-functional polyamide compoiste material, the multi-functional polyamide compoiste material are made up of the parts by weight of following components：
100 parts of polyamide；12 parts of polyethylene terephthalate；7 parts of Kynoar；11 parts of polyvinyl alcohol；PEI 6
Part；7 parts of polystyrene；3 parts of sodium phosphate；4 parts of melamine；1 part of BTA；MBS
4 parts of copolymer；2 parts of stearic acid sodium；3 parts of silver nano-grain；7 parts of kayexalate；It is double（3,5- three-level butyl -4- hydroxyls
Phenyl）2 parts of thioether；0.1 part of dibenzoyl peroxide；1 part of kaolin；4 parts of carborundum；3 parts of tin-antiomony oxide；Methyl phenyl silicone oil
2 parts；2 parts of molybdenum trioxide；0.5 part of lithium fluoride；Three（8-hydroxyquinoline）2 parts of aluminium；3 parts of glyceryl tristearate；2 parts of ethene；Second
1 part of alkenyl triethoxysilane；4 parts of dioctyl phthalate；2 parts of TBHQ, 3 parts of glass fibre；Carbon fiber 2
Part；0.5 part of 3- hexyl thiophenes polymer；3 parts of magnesium oxide particle；2 parts of phosphite ester；1 part of ethyl acetate.
The present invention passes through the synergy between each component so that multi-functional polyamide compoiste material has excellent mechanics
Performance, heat resistance, anti-wear performance and antistatic property, and there is good UV resistant performance.The present invention's is multi-functional
It is a variety of added with silver nano-grain, kaolin, carborundum, tin-antiomony oxide, molybdenum trioxide, lithium fluoride in polyamide compoiste material
The mating reaction of inorganic particle, effectively increase the heat conductivility of multi-functional polyamide compoiste material, anti-microbial property and anti-quiet
Electrical property, and then prevent multi-functional polyamide compoiste material high temperature ageing.Add in the multi-functional polyamide compoiste material of the present invention
Added with glass fibre and carbon fiber, above-mentioned material is cross-linked with each other in multi-functional polyamide compoiste material, effectively increases more work(
The toughness and mechanical property of energy polyamide compoiste material, simultaneously added with the 3- hexyl thiophene polymer of characteristic of semiconductor, enter one
Step improves its antistatic property.A variety of auxiliary agents are added with the multi-functional polyamide compoiste material of the present invention, it is each by optimizing
Concrete content between component so that complemented each other between each component, the multi-functional polyamide compoiste material combination property of formation
It is excellent, it is suitable for multiple fields.
Finally it should be noted that above example is merely to illustrate technical scheme rather than the present invention is protected
The limitation of scope, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should manage
Solution, can modify or equivalent substitution to technical scheme, without departing from technical solution of the present invention essence and
Scope.
Claims (4)
1. a kind of multi-functional polyamide compoiste material, it is characterised in that the multi-functional polyamide compoiste material is by following components
Parts by weight composition：100 parts of polyamide；Polyethylene terephthalate 10-20 parts；Kynoar 5-15 parts；Polyethylene
Alcohol 10-15 parts；PEI 5-10 parts；Polystyrene 5-10 parts；Sodium phosphate 3-6 parts；Melamine 2-5 parts；BTA
1-3 parts；MBS 2-8 parts；Stearic acid sodium 1-4 parts；Silver nano-grain 2-6 parts；
Kayexalate 5-15 parts；It is double（3,5- three-level butyl -4- hydroxy phenyls）Thioether 1-5 parts；Dibenzoyl peroxide 0.1-
0.5 part；Kaolin 1-5 parts；Carborundum 2-6 parts；Tin-antiomony oxide 1-3 parts；Methyl phenyl silicone oil 1-5 parts；Molybdenum trioxide 1-3 parts；
Lithium fluoride 0.1-0.5 parts；Three（8-hydroxyquinoline）Aluminium 1-3 parts；Glyceryl tristearate 2-6 parts；Ethene 1-5 parts；Vinyl three
Ethoxysilane 1-2 parts；Dioctyl phthalate 1-4 parts；TBHQ 1-3 parts, glass fibre 2-6 parts；Carbon is fine
Tie up 1-5 parts；3- hexyl thiophene polymer 0.5-2 parts；Magnesium oxide particle 2-6 parts；Phosphite ester 1-6 parts；Ethyl acetate 1-3 parts.
2. multi-functional polyamide compoiste material according to claim 1, it is characterised in that the multi-functional polyamide is compound
Material is made up of the parts by weight of following components：100 parts of polyamide；15 parts of polyethylene terephthalate；Kynoar 10
Part；12 parts of polyvinyl alcohol；7 parts of PEI；8 parts of polystyrene；5 parts of sodium phosphate；4 parts of melamine；2 parts of BTA；
5 parts of MBS；3 parts of stearic acid sodium；4 parts of silver nano-grain；Polystyrolsulfon acid
10 parts of sodium；It is double（3,5- three-level butyl -4- hydroxy phenyls）3 parts of thioether；0.3 part of dibenzoyl peroxide；3 parts of kaolin；Carbonization
4 parts of silicon；2 parts of tin-antiomony oxide；3 parts of methyl phenyl silicone oil；2 parts of molybdenum trioxide；0.3 part of lithium fluoride；Three（8-hydroxyquinoline）Aluminium 2
Part；4 parts of glyceryl tristearate；3 parts of ethene；1 part of VTES；3 parts of dioctyl phthalate；The tert-butyl group
2 parts of hydroquinones, 4 parts of glass fibre；3 parts of carbon fiber；1 part of 3- hexyl thiophenes polymer；4 parts of magnesium oxide particle；Phosphite ester 4
Part；2 parts of ethyl acetate.
3. multi-functional polyamide compoiste material according to claim 1, it is characterised in that the multi-functional polyamide is compound
Material is made up of the parts by weight of following components：100 parts of polyamide；18 parts of polyethylene terephthalate；Kynoar 12
Part；14 parts of polyvinyl alcohol；9 parts of PEI；8 parts of polystyrene；5 parts of sodium phosphate；3 parts of melamine；3 parts of BTA；
7 parts of MBS；3 parts of stearic acid sodium；5 parts of silver nano-grain；Polystyrolsulfon acid
12 parts of sodium；It is double（3,5- three-level butyl -4- hydroxy phenyls）4 parts of thioether；0.4 part of dibenzoyl peroxide；4 parts of kaolin；Carbonization
5 parts of silicon；3 parts of tin-antiomony oxide；4 parts of methyl phenyl silicone oil；1 part of molybdenum trioxide；0. 5 parts of lithium fluoride；Three（8-hydroxyquinoline）Aluminium 3
Part；5 parts of glyceryl tristearate；1 part of ethene；2 parts of VTES；3 parts of dioctyl phthalate；The tert-butyl group
3 parts of hydroquinones, 5 parts of glass fibre；4 parts of carbon fiber；2 parts of 3- hexyl thiophenes polymer；5 parts of magnesium oxide particle；Phosphite ester 5
Part；1 part of ethyl acetate.
4. multi-functional polyamide compoiste material according to claim 1, it is characterised in that the multi-functional polyamide is compound
Material is made up of the parts by weight of following components：100 parts of polyamide；12 parts of polyethylene terephthalate；Kynoar 7
Part；11 parts of polyvinyl alcohol；6 parts of PEI；7 parts of polystyrene；3 parts of sodium phosphate；4 parts of melamine；1 part of BTA；
4 parts of MBS；2 parts of stearic acid sodium；3 parts of silver nano-grain；Polystyrolsulfon acid
7 parts of sodium；It is double（3,5- three-level butyl -4- hydroxy phenyls）2 parts of thioether；0.1 part of dibenzoyl peroxide；1 part of kaolin；Carborundum
4 parts；3 parts of tin-antiomony oxide；2 parts of methyl phenyl silicone oil；2 parts of molybdenum trioxide；0.5 part of lithium fluoride；Three（8-hydroxyquinoline）2 parts of aluminium；
3 parts of glyceryl tristearate；2 parts of ethene；1 part of VTES；4 parts of dioctyl phthalate；The tert-butyl group pair
2 parts of benzenediol, 3 parts of glass fibre；2 parts of carbon fiber；0.5 part of 3- hexyl thiophenes polymer；3 parts of magnesium oxide particle；Phosphite ester 2
Part；1 part of ethyl acetate.
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| CN201711172209.6A CN107778844A (en) | 2017-11-22 | 2017-11-22 | A kind of multi-functional polyamide compoiste material |
| PCT/CN2017/116557 WO2019100469A1 (en) | 2017-11-22 | 2017-12-15 | Multifunctional polyamide composite material |
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| CN201711172209.6A CN107778844A (en) | 2017-11-22 | 2017-11-22 | A kind of multi-functional polyamide compoiste material |
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| CN112431377A (en) * | 2020-11-27 | 2021-03-02 | 曾跃申 | Anti-static super-wear-resistant thin-layer material special for gas station and oil depot ground and construction method |
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| DE19720317A1 (en) * | 1997-05-15 | 1998-11-19 | Huels Chemische Werke Ag | Adhesion promoter for a multi-layer composite |
| CN101302337B (en) * | 2008-07-03 | 2010-08-11 | 杭州临安宏凯工程塑料有限公司 | High temperature resistant low water absorption polyamide 66 composite material and preparation thereof |
| CN103059556A (en) * | 2011-10-19 | 2013-04-24 | 合肥杰事杰新材料股份有限公司 | Polyamide composition and preparation method thereof |
| PL3006506T3 (en) * | 2014-10-08 | 2017-06-30 | Ems-Patent Ag | Flowable polyamides |
| CN106280408A (en) * | 2016-08-27 | 2017-01-04 | 朱燕华 | A kind of modified resin of plate type heat exchanger |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112431377A (en) * | 2020-11-27 | 2021-03-02 | 曾跃申 | Anti-static super-wear-resistant thin-layer material special for gas station and oil depot ground and construction method |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019100469A1 (en) | 2019-05-31 |
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Application publication date: 20180309 |