CN106189144A - A kind of environmental-friendpacking packing material - Google Patents
A kind of environmental-friendpacking packing material Download PDFInfo
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- CN106189144A CN106189144A CN201610669375.6A CN201610669375A CN106189144A CN 106189144 A CN106189144 A CN 106189144A CN 201610669375 A CN201610669375 A CN 201610669375A CN 106189144 A CN106189144 A CN 106189144A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Packaging Frangible Articles (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of environmental-friendpacking packing material, be prepared by the raw materials in: degradable plastic masterbatch 40 50 parts, straw 10 20 parts, modified starch 10 15 parts, polyamide 8 12 parts, glycerol 24 parts, white carbon black 35 parts, conductive fiber 25 parts, glycerol 5 10 parts, Borax 35 parts, lubricant 48 parts, chitin fiber 14 parts, garlicin 13 parts, nano antimony tin oxide 36 parts, coupling agent 12 parts, stabilizer 13 parts.The present invention uses degradable plastic masterbatch, straw and modified starch to be that the plastic package material that raw material prepares has degradability, maintain the shock resistance of existing packaging material, non-oxidizability and corrosion resistance, it is finished and can be dissolved by environment after heap corruption, significantly alleviate the pollution to environment, straw and starch are with low cost, its recyclable again with, simultaneously can meet water decomposition, return earth, have a extensive future.There is good electric conductivity, weatherability, stability, uvioresistant, ageing resistance simultaneously.
Description
Technical field
The present invention relates to packaging material field, specifically a kind of environmental-friendpacking packing material.
Background technology
Packaging material refer to for manufacture packing container, packing and decorating, packages printing, packed and transported etc. meet product packaging
Requiring the material used, it had both included metal, plastics, glass, pottery, paper, bamboo basis, wild mushroom class, natural fiber, chemistry fibre
The main packaging material such as dimension, composite, include again the auxiliary materials such as coating, binding agent, strapping tape, decoration, printing material.
But, along with social industrialized development, all trades and professions need the packaging material related to multifarious, and kind is numerous
Many, the demand of corresponding packaging material is steeply risen simultaneously.But embody its value in industrial society at packaging material
While, many drawbacks occur in that the most simultaneously, use frequency and durability the highest, and the most degradable, the gas that volatilized is to ring
Border is harmful to, reclaim mechanism shortage or non-recovery value etc..Therefore, a kind of bag with better performance and environmental sound is developed
Package material just seems particularly necessary.
Summary of the invention
Present invention aim to solve above-mentioned deficiency and a kind of environmental-friendpacking packing material be provided, not only color and
Operability all with containing benzene packaging material indistinction, and due to without toluene, thus to ambient air pollution-free all have the brightest
Aobvious effect, the health fanout free region to execute-in-place employee.
For achieving the above object, the present invention provides following technical scheme:
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 40-50 part, straw 10-20 part, modified starch 10-15 part, polyamide 8-12
Part, glycerol 2-4 part, white carbon black 3-5 part, conductive fiber 2-5 part, glycerol 5-10 part, Borax 3-5 part, lubricant 4-8 part, carapace
Cellulose fiber 1-4 part, garlicin 1-3 part, nano antimony tin oxide 3-6 part, coupling agent 1-2 part, stabilizer 1-3 part.
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 40 parts, straw 10 parts, modified starch 10 parts, polyamide 8 parts, glycerol 2 parts, charcoal
Black 3 parts, conductive fiber 2 parts, glycerol 5 parts, Borax 3 parts, lubricant 4 parts, chitin fiber 1 part, garlicin 1 part, nano oxygen
Change 3 parts of stannum antimony, coupling agent 1 part, stabilizer 1 part.
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 50 parts, straw 20 parts, modified starch 15 parts, polyamide 12 parts, glycerol 4 parts,
White carbon black 5 parts, conductive fiber 5 parts, glycerol 10 parts, Borax 5 parts, lubricant 8 parts, chitin fiber 4 parts, garlicin 3 parts, nanometer
Tin-antiomony oxide 6 parts, coupling agent 2 parts, stabilizer 3 parts.
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 44 parts, straw 15 parts, modified starch 12 parts, polyamide 10 parts, glycerol 3 parts,
White carbon black 4 parts, conductive fiber 3 parts, glycerol 7 parts, Borax 4 parts, lubricant 6 parts, chitin fiber 2 parts, garlicin 2 parts, nanometer
Tin-antiomony oxide 4 parts, coupling agent 1.4 parts, stabilizer 2 parts.
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 47 parts, straw 18 parts, modified starch 14 parts, polyamide 11 parts, glycerol 3.5
Part, white carbon black 4.2 parts, conductive fiber 4 parts, glycerol 8 parts, Borax 4.5 parts, lubricant 7 parts, chitin fiber 3.3 parts, garlicin
2.4 parts, nano antimony tin oxide 5 parts, coupling agent 1.8 parts, stabilizer 1.5 parts.
Described conductive fiber is carbon fiber.Preferably, described carbon fiber is seriality carbon fiber or chopped fiber.
Described degradable plastic masterbatch is that PLA and PHB forms according to the mixing crosslinking of mol ratio 1:2.
Described stabilizer includes salicylate type ultraviolet light stabilizer and organo-tin compound type thermal stabilizing agent.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention uses degradable plastic masterbatch, straw and modified starch to be the plastic package material tool that raw material prepares
Having degradability, maintain the shock resistance of existing packaging material, non-oxidizability and corrosion resistance, being finished after heap corruption can quilt
Environment is dissolved, and significantly alleviates the pollution to environment, straw and starch with low cost, its recyclable again with, simultaneously can
Meet water decomposition, return earth, have a extensive future.Add chitin fiber, garlicin, thin in can effectively suppressing packaged food
Growing and anticorrosion of bacterium, is effectively ensured freshness and the usage safety performance of packaged food.Have simultaneously good electric conductivity,
Weatherability, stability, uvioresistant, ageing resistance.
Detailed description of the invention
Embodiment 1
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 40 parts, straw 10 parts, modified starch 10 parts, polyamide 8 parts, glycerol 2 parts, charcoal
Black 3 parts, conductive fiber 2 parts, glycerol 5 parts, Borax 3 parts, lubricant 4 parts, chitin fiber 1 part, garlicin 1 part, nano oxygen
Change 3 parts of stannum antimony, coupling agent 1 part, stabilizer 1 part.
Described conductive fiber is carbon fiber.Preferably, described carbon fiber is seriality carbon fiber or chopped fiber.
Described degradable plastic masterbatch is that PLA and PHB forms according to the mixing crosslinking of mol ratio 1:2.
Described stabilizer includes salicylate type ultraviolet light stabilizer and organo-tin compound type thermal stabilizing agent.
Nano antimony tin oxide powder body is the super-fine material that particle size is less than 100nm, is a kind of N-type semiconductor material, with
Traditional anti-static material is compared, and nano antimony tin oxide powder body has obvious advantage, is mainly manifested in good electric conductivity, resistance to
The aspects such as Hou Xing, stability, light-coloured transparent and low infrared emittance, are the most potential Multifunctions of one
Conductive material and heat-barrier material；
Embodiment 2
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 50 parts, straw 20 parts, modified starch 15 parts, polyamide 12 parts, glycerol 4 parts,
White carbon black 5 parts, conductive fiber 5 parts, glycerol 10 parts, Borax 5 parts, lubricant 8 parts, chitin fiber 4 parts, garlicin 3 parts, nanometer
Tin-antiomony oxide 6 parts, coupling agent 2 parts, stabilizer 3 parts.
Described conductive fiber is carbon fiber.Preferably, described carbon fiber is seriality carbon fiber or chopped fiber.
Described degradable plastic masterbatch is that PLA and PHB forms according to the mixing crosslinking of mol ratio 1:2.
Described stabilizer includes salicylate type ultraviolet light stabilizer and organo-tin compound type thermal stabilizing agent.
Nano antimony tin oxide powder body is the super-fine material that particle size is less than 100nm, is a kind of N-type semiconductor material, with
Traditional anti-static material is compared, and nano antimony tin oxide powder body has obvious advantage, is mainly manifested in good electric conductivity, resistance to
The aspects such as Hou Xing, stability, light-coloured transparent and low infrared emittance, are the most potential Multifunctions of one
Conductive material and heat-barrier material；
Embodiment 3
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 44 parts, straw 15 parts, modified starch 12 parts, polyamide 10 parts, glycerol 3 parts,
White carbon black 4 parts, conductive fiber 3 parts, glycerol 7 parts, Borax 4 parts, lubricant 6 parts, chitin fiber 2 parts, garlicin 2 parts, nanometer
Tin-antiomony oxide 4 parts, coupling agent 1.4 parts, stabilizer 2 parts.
Embodiment 4
A kind of environmental-friendpacking packing material, is prepared by the raw materials in:
Degradable plastic masterbatch 47 parts, straw 18 parts, modified starch 14 parts, polyamide 11 parts, glycerol 3.5
Part, white carbon black 4.2 parts, conductive fiber 4 parts, glycerol 8 parts, Borax 4.5 parts, lubricant 7 parts, chitin fiber 3.3 parts, garlicin
2.4 parts, nano antimony tin oxide 5 parts, coupling agent 1.8 parts, stabilizer 1.5 parts.
Described conductive fiber is carbon fiber.Preferably, described carbon fiber is seriality carbon fiber or chopped fiber.
Described degradable plastic masterbatch is that PLA and PHB forms according to the mixing crosslinking of mol ratio 1:2.
Described stabilizer includes salicylate type ultraviolet light stabilizer and organo-tin compound type thermal stabilizing agent.
Nano antimony tin oxide powder body is the super-fine material that particle size is less than 100nm, is a kind of N-type semiconductor material, with
Traditional anti-static material is compared, and nano antimony tin oxide powder body has obvious advantage, is mainly manifested in good electric conductivity, resistance to
The aspects such as Hou Xing, stability, light-coloured transparent and low infrared emittance, are the most potential Multifunctions of one
Conductive material and heat-barrier material.
Claims (9)
1. an environmental-friendpacking packing material, it is characterised in that be prepared by the raw materials in:
Degradable plastic masterbatch 40-50 part, straw 10-20 part, modified starch 10-15 part, polyamide 8-12 part, sweet
Oil 2-4 part, white carbon black 3-5 part, conductive fiber 2-5 part, glycerol 5-10 part, Borax 3-5 part, lubricant 4-8 part, chitin fiber
1-4 part, garlicin 1-3 part, nano antimony tin oxide 3-6 part, coupling agent 1-2 part, stabilizer 1-3 part.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that be prepared by the raw materials in:
Degradable plastic masterbatch 40 parts, straw 10 parts, modified starch 10 parts, polyamide 8 parts, glycerol 2 parts, white carbon black 3
Part, conductive fiber 2 parts, glycerol 5 parts, Borax 3 parts, lubricant 4 parts, chitin fiber 1 part, garlicin 1 part, nano tin dioxide
3 parts of antimony, coupling agent 1 part, stabilizer 1 part.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that be prepared by the raw materials in:
Degradable plastic masterbatch 50 parts, straw 20 parts, modified starch 15 parts, polyamide 12 parts, glycerol 4 parts, white carbon black 5
Part, conductive fiber 5 parts, glycerol 10 parts, Borax 5 parts, lubricant 8 parts, chitin fiber 4 parts, garlicin 3 parts, nano oxidized
6 parts of stannum antimony, coupling agent 2 parts, stabilizer 3 parts.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that be prepared by the raw materials in:
Degradable plastic masterbatch 44 parts, straw 15 parts, modified starch 12 parts, polyamide 10 parts, glycerol 3 parts, white carbon black 4
Part, conductive fiber 3 parts, glycerol 7 parts, Borax 4 parts, lubricant 6 parts, chitin fiber 2 parts, garlicin 2 parts, nano tin dioxide
4 parts of antimony, coupling agent 1.4 parts, stabilizer 2 parts.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that be prepared by the raw materials in:
Degradable plastic masterbatch 47 parts, straw 18 parts, modified starch 14 parts, polyamide 11 parts, glycerol 3.5 parts, charcoal
Black 4.2 parts, conductive fiber 4 parts, glycerol 8 parts, Borax 4.5 parts, lubricant 7 parts, chitin fiber 3.3 parts, garlicin 2.4
Part, nano antimony tin oxide 5 parts, coupling agent 1.8 parts, stabilizer 1.5 parts.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that described conductive fiber is carbon fiber.
Environmental-friendpacking packing material the most according to claim 6, it is characterised in that described carbon fiber is seriality carbon fiber
Or chopped fiber.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that described degradable plastic masterbatch is PLA
Form according to the mixing crosslinking of mol ratio 1:2 with PHB.
Environmental-friendpacking packing material the most according to claim 1, it is characterised in that described stabilizer includes that salicylic acid esters is purple
Outer light stabilizer and organo-tin compound type thermal stabilizing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669375.6A CN106189144A (en) | 2016-08-15 | 2016-08-15 | A kind of environmental-friendpacking packing material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669375.6A CN106189144A (en) | 2016-08-15 | 2016-08-15 | A kind of environmental-friendpacking packing material |
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| Publication Number | Publication Date |
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| CN106189144A true CN106189144A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610669375.6A Pending CN106189144A (en) | 2016-08-15 | 2016-08-15 | A kind of environmental-friendpacking packing material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722645A (en) * | 2017-10-20 | 2018-02-23 | 桂林市春晓环保科技有限公司 | A kind of fire resisting packaging material and preparation method thereof |
| CN111253732A (en) * | 2018-11-30 | 2020-06-09 | 中科纺织研究院（青岛）有限公司 | Plant-derived polyamide master batch and preparation method and application thereof |
| CN111393866A (en) * | 2020-04-08 | 2020-07-10 | 保定茂华塑料制品有限公司 | Biodegradable mulching film and preparation method thereof |
Citations (5)
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|---|---|---|---|---|
| CN1357509A (en) * | 2000-12-14 | 2002-07-10 | 成都亿安方博低维材料科技有限公司 | Transparent conductive nano Sb:SnO2 fine powder |
| CN104945714A (en) * | 2015-06-23 | 2015-09-30 | 江南大学 | Novel bi-component polyolefin composite anti-static packaging film filled with organic-inorganic doped composite material and manufacturing method thereof |
| CN105800063A (en) * | 2016-04-14 | 2016-07-27 | 太仓市源创包装材料厂 | Freshness retaining and bacterium inhibiting plastic packaging bag for foods |
| CN105802167A (en) * | 2016-05-10 | 2016-07-27 | 江苏道勤新材料科技有限公司 | Degradable environment-friendly plastic material |
| CN105837924A (en) * | 2016-04-21 | 2016-08-10 | 苏州市双虎科技有限公司 | Low-cost semiconductive shielding material for cables |
-
2016
- 2016-08-15 CN CN201610669375.6A patent/CN106189144A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1357509A (en) * | 2000-12-14 | 2002-07-10 | 成都亿安方博低维材料科技有限公司 | Transparent conductive nano Sb:SnO2 fine powder |
| CN104945714A (en) * | 2015-06-23 | 2015-09-30 | 江南大学 | Novel bi-component polyolefin composite anti-static packaging film filled with organic-inorganic doped composite material and manufacturing method thereof |
| CN105800063A (en) * | 2016-04-14 | 2016-07-27 | 太仓市源创包装材料厂 | Freshness retaining and bacterium inhibiting plastic packaging bag for foods |
| CN105837924A (en) * | 2016-04-21 | 2016-08-10 | 苏州市双虎科技有限公司 | Low-cost semiconductive shielding material for cables |
| CN105802167A (en) * | 2016-05-10 | 2016-07-27 | 江苏道勤新材料科技有限公司 | Degradable environment-friendly plastic material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722645A (en) * | 2017-10-20 | 2018-02-23 | 桂林市春晓环保科技有限公司 | A kind of fire resisting packaging material and preparation method thereof |
| CN111253732A (en) * | 2018-11-30 | 2020-06-09 | 中科纺织研究院（青岛）有限公司 | Plant-derived polyamide master batch and preparation method and application thereof |
| CN111393866A (en) * | 2020-04-08 | 2020-07-10 | 保定茂华塑料制品有限公司 | Biodegradable mulching film and preparation method thereof |
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Application publication date: 20161207 |