CN103012990A - Raw material for manufacturing flexible soft lamp tubes - Google Patents

Raw material for manufacturing flexible soft lamp tubes Download PDF

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Publication number
CN103012990A
CN103012990A CN2012104980476A CN201210498047A CN103012990A CN 103012990 A CN103012990 A CN 103012990A CN 2012104980476 A CN2012104980476 A CN 2012104980476A CN 201210498047 A CN201210498047 A CN 201210498047A CN 103012990 A CN103012990 A CN 103012990A
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CN
China
Prior art keywords
mass parts
raw material
additive
fluorescent tube
flexible software
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Pending
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CN2012104980476A
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Chinese (zh)
Inventor
樊邦扬
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Heshan Lide Electronic Enterprise Co Ltd
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Heshan Lide Electronic Enterprise Co Ltd
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Priority to CN2012104980476A priority Critical patent/CN103012990A/en
Publication of CN103012990A publication Critical patent/CN103012990A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the field of chemical materials, and concretely discloses a raw material for manufacturing flexible soft lamp tubes. The raw material comprises the following components in parts by mass: 100 parts of polrvinyl chloride (PVC) powder, 28-50 parts of tri(2-ethylhex-yl) trirnellitate, 16-30 parts of phthalic acid, 12-25 parts of dioctyl adipate, 6-20 parts of phosphate flame-retardant, 4-5 parts of epoxidized soybean oil, 2-3 parts of organic tin stabilizer or calcium-zinc stabilizer, 0.6-1 part of stearic acid or butyl stearate, 0.2-0.4 part of complex antioxidant, and 1.5-3 parts of modified polystyrene. The various flexible soft lamp tubes manufactured by the raw material disclosed by the invention is resistant to four-level UV (ultra violet) as well as a high temperature up to 80 DEG C and a low temperature up to -40 DEG C, and the flame retardant property of the tubes can achieve V1 or V0 level, therefore, the raw material can be widely applied to the various flexible soft lamp tubes in the field of decorative lamps.

Description

A kind of raw material of making flexible software fluorescent tube
[technical field]
The present invention relates to a kind of raw material of fluorescent tube, refer in particular to a kind of raw material of making flexible software fluorescent tube.
[background technology]
Along with electronics and lamp decoration industry are more and more higher for the requirement of unfailing performance, safety performance, some ornament lamp needs transparent and fire-retardant, and softness is good, have in addition require the fire-retardant V0 of reaching level.The material of existing fluorescent tube is generally the PVC sizing material, and it is good that the PVC sizing material has softness, and transparency is high, good stability, therefore the characteristic such as insulating property etc. are good is widely used in the every field of national economy, but they can burn, to just inapplicable in the higher environment of fire-retardant requirement.
[summary of the invention]
In view of the defective that exists in the prior art, the object of the present invention is to provide a kind of raw material of making flexible software fluorescent tube, this raw material printing opacity, opaque, anti-UV and possess good flame retardant properties.
In order to reach above-mentioned technical purpose, the invention discloses a kind of raw material of making flexible software fluorescent tube, it constitutes: mass parts is 100 polyvinylchloride powder, mass parts is 8~50 trimellitic acid three different monooctyl esters, mass parts is 16~30 neck phthalic acid, mass parts is 12~25 Octyl adipate, mass parts is 6~20 fire retardant, mass parts is 4~5 epoxy soybean oil, mass parts is 2~3 organotin stabilizer or calcium zinc stabilizer, mass parts is 0.6~1 stearic acid or butyl stearate, and mass parts is 0.2~0.4 composite antioxidant, and mass parts is 1.5~3 modified polystyrene.
Fluorescent tube sizing material according to composition of raw materials of the present invention is made possesses good flame retardant properties, anti-UV, and printing opacity is still opaque.
Preferably, fire retardant is the phosphoric acid ester fire retardant.
Preferably, polyvinylchloride powder mass parts is 100, trimellitic acid three different monooctyl ester mass parts are 35, and neck phthalic acid mass parts is 20, and the Octyl adipate mass parts is 12, phosphoric acid ester fire retardant mass parts is 6, Quaity of Epoxidized Soybean Oil part is 4, and organotin stabilizer or calcium zinc stabilizer mass parts are 2, and stearic acid or butyl stearate mass parts are 0.6, the composite antioxidant mass parts is 0.3, and the mass parts of modified polystyrene is 2.
Preferably, the raw material of flexible software fluorescent tube comprises that also the mass parts of described fluorescent material additive is 0.007~0.01 for the fluorescent material additive of adjusting color.
Preferably, the phosphor powder additive adopts silicate series fluorescent material.
Preferably, the mass parts of silicate series fluorescent material is 0.008.
Preferably, the raw material of flexible software fluorescent tube also comprises the uvioresistant additive, and described uvioresistant additive mass parts is 0.6~1.
Preferably, described uvioresistant additive comprises hindered amine light stabilizer.
Preferably, the mass parts of described hindered amine light stabilizer is 0.75.
[embodiment]
The below is further described main points of the present invention.
Prescription one: polyvinylchloride powder mass parts is 100, trimellitic acid three different monooctyl ester mass parts are 35, neck phthalic acid mass parts is 20, the Octyl adipate mass parts is 12, and phosphoric acid ester fire retardant mass parts is 6, and Quaity of Epoxidized Soybean Oil part is 4, organotin stabilizer or calcium zinc stabilizer mass parts are 2, stearic acid or butyl stearate mass parts are 0.6, and the composite antioxidant mass parts is 0.3, and the modified polystyrene mass parts is 2.The mass parts of silicate series fluorescent material is 0.008, and the mass parts of hindered amine light stabilizer is 0.75
Prescription two: polyvinylchloride powder mass parts is 100, trimellitic acid three different monooctyl ester mass parts are 35, neck phthalic acid mass parts is 20, the Octyl adipate mass parts is 12, and phosphoric acid ester fire retardant mass parts is 6, and Quaity of Epoxidized Soybean Oil part is 4, organotin stabilizer or calcium zinc stabilizer mass parts are 2, stearic acid or butyl stearate mass parts are 0.6, and the composite antioxidant mass parts is 0.3, and the modified polystyrene mass parts is 2.The mass parts of silicate series fluorescent material is 0.008.
Prescription three: polyvinylchloride powder mass parts is 100, trimellitic acid three different monooctyl ester mass parts are 35, neck phthalic acid mass parts is 20, the Octyl adipate mass parts is 12, and phosphoric acid ester fire retardant mass parts is 6, and Quaity of Epoxidized Soybean Oil part is 4, organotin stabilizer or calcium zinc stabilizer mass parts are 2, stearic acid or butyl stearate mass parts are 0.6, and the composite antioxidant mass parts is 0.3, and the modified polystyrene mass parts is 2.The mass parts of hindered amine light stabilizer is 0.75.
Prescription four: polyvinylchloride powder mass parts is 100, trimellitic acid three different monooctyl ester mass parts are 35, neck phthalic acid mass parts is 20, the Octyl adipate mass parts is 12, and phosphoric acid ester fire retardant mass parts is 6, and Quaity of Epoxidized Soybean Oil part is 4, organotin stabilizer or calcium zinc stabilizer mass parts are 2, stearic acid or butyl stearate mass parts are 0.6, and the composite antioxidant mass parts is 0.3, and the modified polystyrene mass parts is 2.
Above only the act take convenient explanation the present invention as purpose, in the category that does not break away from initiative spirit of the present invention, that knows that the technician of this technology does various simple in a disguised form still belongs to protection scope of the present invention with modifying.

Claims (22)

1. raw material of making flexible software fluorescent tube, comprise that mass parts is 100 polyvinylchloride powder, mass parts is 28 ~ 50 trimellitic acid three different monooctyl esters, mass parts is 16 ~ 30 neck phthalic acid, mass parts is 12 ~ 25 adipic acid dioctyl ester, mass parts is 6 ~ 20 fire retardant, mass parts is 4 ~ 5 epoxy soybean oil, mass parts is 2 ~ 5 organotin stabilizer or calcium zinc stabilizer, mass parts is 0.6 ~ 1 stearic acid or butyl stearate, mass parts is 0.2 ~ 0.4 composite antioxidant, and mass parts is 1.5 ~ 3 modified polystyrene.
2. the raw material of the flexible software fluorescent tube of making according to claim 1, it is characterized in that: described fire retardant is the phosphoric acid ester fire retardant.
3. the raw material of the flexible software fluorescent tube of making according to claim 1 is characterized in that, comprises that also mass parts is 0.007 ~ 0.01 fluorescent material additive.
4. the raw material of the flexible software fluorescent tube of making according to claim 1 is characterized in that, comprises that also mass parts is 0.6 ~ 1 uvioresistant additive.
5. the raw material of the flexible software fluorescent tube of making according to claim 3 is characterized in that, described fluorescent material additive is silicate series fluorescent material.
6. the raw material of the flexible software fluorescent tube of making according to claim 4 is characterized in that, described uvioresistant additive comprises hindered amine light stabilizer.
7. the raw material of the flexible software fluorescent tube of making according to claim 3 is characterized in that, the mass parts of described fluorescent material additive is 0.008.
8. the raw material of the flexible software fluorescent tube of making according to claim 4 is characterized in that, the mass parts of described uvioresistant additive is 0.75.
9. the raw material of the flexible software fluorescent tube of making according to claim 1 is characterized in that, comprises that also mass parts is that 0.007 ~ 0.01 fluorescent material additive and mass parts are 0.6 ~ 1 uvioresistant additive.
10. the raw material of the flexible software fluorescent tube of making according to claim 9 is characterized in that, described fluorescent material additive is silicate series fluorescent material, and described uvioresistant additive comprises hindered amine light stabilizer.
11. the raw material of the flexible software fluorescent tube of making according to claim 9 is characterized in that, the mass parts of described fluorescent material additive is 0.008, and the mass parts of described uvioresistant additive is 0.75.
12. the raw material of the flexible software fluorescent tube of making according to claim 1, it is characterized in that: comprise that mass parts is 100 polyvinylchloride powder, mass parts is 35 trimellitic acid three different monooctyl esters, mass parts is 20 neck phthalic acid, mass parts is 12 adipic acid dioctyl ester, mass parts be 6 the phosphoric acid ester fire retardant, mass parts is 4 epoxy soybean oil, mass parts is 2 organotin stabilizer or calcium zinc stabilizer, mass parts is 0.6 stearic acid or butyl stearate, mass parts is 0.3 composite antioxidant, and mass parts is 2 modified polystyrene.
13. the raw material of the flexible software fluorescent tube of making according to claim 12 is characterized in that: also comprise the phosphor powder additive, described phosphor powder additive mass parts is 0.007 ~ 0.01.
14. the raw material according to the flexible software fluorescent tube of right 13 described making is characterized in that: described phosphor powder additive adopts silicate series fluorescent material.
15. the raw material of the flexible software fluorescent tube of each described making according to claim 13-14, it is characterized in that: the mass parts of described fluorescent material additive is 0.008.
16. the raw material according to the flexible software fluorescent tube of right 12 described making is characterized in that: also comprise the uvioresistant additive, described uvioresistant additive mass parts is 0.6 ~ 1.
17. the raw material according to the flexible software fluorescent tube of right 16 described making is characterized in that: described uvioresistant additive comprises hindered amine light stabilizer.
18. the raw material of the flexible software fluorescent tube of making according to claim 16 is characterized in that: the mass parts of described uvioresistant additive is 0.75.
19. the raw material of the flexible software fluorescent tube of making according to claim 17 is characterized in that: the mass parts of described hindered amine light stabilizer is 0.75.
20. the raw material of the flexible software fluorescent tube of making according to claim 12 is characterized in that, comprise that also mass parts is 0.007 ~ 0.01 phosphor powder additive, and mass parts is 0.6 ~ 1 uvioresistant additive.
21. the raw material of the flexible software fluorescent tube of making according to claim 20 is characterized in that, described fluorescent material additive is silicate series fluorescent material, and described uvioresistant additive comprises hindered amine light stabilizer.
22. the raw material of the flexible software fluorescent tube of each described making is characterized in that according to claim 20-21, the mass fraction of described fluorescent material additive is 0.008, and the mass fraction of described uvioresistant additive is 0.75.
CN2012104980476A 2012-11-29 2012-11-29 Raw material for manufacturing flexible soft lamp tubes Pending CN103012990A (en)

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CN103012990A true CN103012990A (en) 2013-04-03

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819843A (en) * 2014-01-28 2014-05-28 徐松炎 LED lamp forming material and manufacturing method
CN105837975A (en) * 2016-04-22 2016-08-10 刘志宏 PVC (polyvinyl chloride) light-transmitting material
CN106609018A (en) * 2016-12-28 2017-05-03 滁州品之达电器科技有限公司 Plastic special for fluorescent switch buttons
CN107245199A (en) * 2017-05-23 2017-10-13 江阴华东装饰材料有限公司 The preparation method of imitative curtain wall stained glass PVC hard sheets
CN108559202A (en) * 2018-04-25 2018-09-21 东阳市特意新材料科技有限公司 A kind of polyvinyl chloride neon light tube preparation method for material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86106991A (en) * 1986-10-31 1988-05-11 天津市和平霓虹灯厂 Material applied to plastic advertisement decorating lamp
CN101857704A (en) * 2010-05-28 2010-10-13 河南谢人安防门帘有限公司 Luminous energy-saving polyvinyl chloride plastics and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86106991A (en) * 1986-10-31 1988-05-11 天津市和平霓虹灯厂 Material applied to plastic advertisement decorating lamp
CN101857704A (en) * 2010-05-28 2010-10-13 河南谢人安防门帘有限公司 Luminous energy-saving polyvinyl chloride plastics and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
顾文华等: "软虹灯用透明聚氯乙烯材料的研制", 《现代塑料加工应用》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819843A (en) * 2014-01-28 2014-05-28 徐松炎 LED lamp forming material and manufacturing method
CN105837975A (en) * 2016-04-22 2016-08-10 刘志宏 PVC (polyvinyl chloride) light-transmitting material
CN106609018A (en) * 2016-12-28 2017-05-03 滁州品之达电器科技有限公司 Plastic special for fluorescent switch buttons
CN107245199A (en) * 2017-05-23 2017-10-13 江阴华东装饰材料有限公司 The preparation method of imitative curtain wall stained glass PVC hard sheets
CN108559202A (en) * 2018-04-25 2018-09-21 东阳市特意新材料科技有限公司 A kind of polyvinyl chloride neon light tube preparation method for material

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Application publication date: 20130403