CN101857704A - Luminous energy-saving polyvinyl chloride plastics and preparation method thereof - Google Patents

Luminous energy-saving polyvinyl chloride plastics and preparation method thereof Download PDF

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Publication number
CN101857704A
CN101857704A CN 201010191986 CN201010191986A CN101857704A CN 101857704 A CN101857704 A CN 101857704A CN 201010191986 CN201010191986 CN 201010191986 CN 201010191986 A CN201010191986 A CN 201010191986A CN 101857704 A CN101857704 A CN 101857704A
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China
Prior art keywords
polyvinyl chloride
weight parts
luminous energy
stirring
saving
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CN 201010191986
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Chinese (zh)
Inventor
谢宏杰
王安鹏
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HENAN XIEREN SAFETY SCREENS CO Ltd
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HENAN XIEREN SAFETY SCREENS CO Ltd
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Priority to CN 201010191986 priority Critical patent/CN101857704A/en
Publication of CN101857704A publication Critical patent/CN101857704A/en
Pending legal-status Critical Current

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Abstract

The invention relates to luminous energy-saving polyvinyl chloride plastics and a preparation method thereof. The luminous energy-saving polyvinyl chloride plastics comprise 100 weight parts of polyvinyl chloride resin, 50 to 60 weight parts of plasticizing agents, 3 to 5 weight parts of stabilizing agents, 20 to 30 weight parts of luminous powder, 1 to 1.5 weight parts of lubricating agents, 10 to 20 weight parts of tougheners and 3 to 5 weight parts of ageing resistant agents. The invention has the manufacture method comprising the following steps: placing the polyvinyl chloride, the plasticizing agents, the stabilizing agents, the ageing resistant agents and the tougheners prepared according to the respective weight proportion into a high-speed and low-speed mixing machine; starting high-speed stirring after 10 seconds of low-speed stirring; placing the luminous powder and the lubricating agents into the mixture for continuous stirring after the high-speed stirring to 90 DEG C; stopping the stirring when the temperature is raised to 110 DEG C; placing the stirred materials into a cooling stirring machine to be cooled to 50 to 80 DEG C; and carrying out forming and extrusion by a single-screw extruding machine. The invention has the advantage of luminous effect under the condition of dark light rays, can be widely used in various public places, does not need electric energy, and reduces the energy consumption.

Description

Luminous energy-saving polyvinyl chloride plastics and preparation method thereof
Technical field:
The present invention relates to the production of igelite, particularly a kind of luminous energy-saving polyvinyl chloride plastics.
Background technology:
Present igelite product application is in a lot of fields and industry, but general igelite product does not have lighting function, like this in the employed a lot of occasions of igelite product, for example, the market, school, hospital, places such as large-scale theater, in case take place under power failure or other the ad hoc situation, carry out emergency lighting with regard to needing above-mentioned unit to install special emergent light and means of illumination, promoted the use and the installation cost of these units, be unfavorable for the trend of present All Around The World, increased the waste of the energy for energy-saving and emission-reduction.
Summary of the invention:
The purpose of this invention is to provide a kind of luminous energy-saving polyvinyl chloride plastics that illumination, marked effect can be provided under the bad situation of light condition.Technical scheme of the present invention is, luminous energy-saving polyvinyl chloride plastics, it is characterized in that: it comprises polyvinyl chloride (PVC) RESINS: 100 weight parts, softening agent: 50~60 weight parts, stablizer: 3~5 weight parts, luminescent powder: 20~30 weight parts, lubricant: 1~1.5 weight part, toughner: 10~20 weight parts, antiaging agent: 3~5 weight parts.Described softening agent is: diisononyl phthalate or diisobutyl phthalate or o-phthalic acid dibutyl ester.Described stablizer is organotin stabilizer or calcium-zinc composite stabilizing agent.Described luminescent powder is: YH8813 or GL-3A.Described lubricant is: amine hydroxybenzene or erucamid erucyl amide.Described toughner is: MBS or SBS or EVA or CPE.Described antiaging agent is: 1010 or 1076 or uv-absorbing agent UV531 or uv-absorbing agent UV9 or uv-absorbing agent UV327.Making method of the present invention is, it is characterized in that: will put into high low speed mixer according to the ready polyvinyl chloride of each part by weight, softening agent, stablizer, antiaging agent, toughner, utilize stirring at low speed to start after 10 seconds at a high speed, high-speed stirring to 90 ℃ is put into luminescent powder, lubricant continues to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 50~80 ℃, can utilize single screw extrusion machine to finalize the design and extrude.The present invention has advantage luminous under darker light condition, can be widely used in multiple public place, and does not need electric energy, has reduced energy consumption.
Embodiment:
Describe the embodiment of the invention in detail,
Embodiment 1,
With polyvinyl chloride (PVC) RESINS (three types): 100kg, diisononyl phthalate: 50kg, calcium-zinc composite stabilizing agent: 4kg, antiaging agent 10103kg, toughner MBS 20kg puts into high low speed mixer, utilize stirring at low speed to start after 10 seconds at a high speed earlier, high-speed stirring to 90 ℃ is put into luminescent powder YH8813 25kg, amine hydroxybenzene 1.5kg and is continued to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 50 ℃, can utilize single screw extrusion machine to finalize the design and extrude, promptly obtain product of the present invention.
Embodiment 2,
With polyvinyl chloride (PVC) RESINS (three types): 100kg, diisononyl phthalate: 60kg, calcium-zinc composite stabilizing agent: 4kg, antiaging agent 1076 4kg, toughner SBS 20kg puts into high low speed mixer, utilize stirring at low speed to start after 10 seconds at a high speed earlier, high-speed stirring to 90 ℃ is put into luminescent powder GL-3A 30kg, erucamid erucyl amide 1.5kg and is continued to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 60 ℃, can utilize single screw extrusion machine to finalize the design and extrude, promptly obtain product of the present invention.
Embodiment 3,
With polyvinyl chloride (PVC) RESINS (five types): 100kg, o-phthalic acid dibutyl ester: 50kg, organotin stabilizer: 3kg, uv-absorbing agent UV531 3kg, toughening agent C PE 15kg puts into high low speed mixer, utilize stirring at low speed to start after 10 seconds at a high speed earlier, high-speed stirring to 90 ℃ is put into luminescent powder YH8813 25kg, amine hydroxybenzene 1.5kg and is continued to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 70 ℃, can utilize single screw extrusion machine to finalize the design and extrude, promptly obtain product of the present invention.
Embodiment 4,
With polyvinyl chloride (PVC) RESINS (five types): 100kg, dibutyl phthalate (DBP): 55kg, organotin stabilizer: 5kg, ultraviolet absorbent uv-9 5kg, toughner ENA 10kg puts into high low speed mixer, utilize stirring at low speed to start after 10 seconds at a high speed earlier, high-speed stirring to 90 ℃ is put into luminescent powder YH8813 20kg, amine hydroxybenzene 1kg and is continued to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 75 ℃, can utilize single screw extrusion machine to finalize the design and extrude, promptly obtain product of the present invention.
Embodiment 5,
With polyvinyl chloride (PVC) RESINS (five types): 100kg, dibutyl phthalate (DBP): 55kg, organotin stabilizer: 5kg, uv-absorbing agent UV-327 5kg, toughner ENA 10kg puts into high low speed mixer, utilize stirring at low speed to start after 10 seconds at a high speed earlier, high-speed stirring to 90 ℃ is put into luminescent powder YH8813 20kg, amine hydroxybenzene 1kg and is continued to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 80 ℃, can utilize single screw extrusion machine to finalize the design and extrude, promptly obtain product of the present invention.
The present invention can send certain light under darker light condition, can be widely used in multiple public place, and not need electricity consumption, has reduced energy consumption, meets the national strategy of energy-saving and emission-reduction.

Claims (8)

1. luminous energy-saving polyvinyl chloride plastics, it is characterized in that: it comprises polyvinyl chloride (PVC) RESINS: 100 weight parts, softening agent: 50~60 weight parts, stablizer: 3~5 weight parts, luminescent powder: 20~30 weight parts, lubricant: 1~1.5 weight part, toughner: 10~20 weight parts, antiaging agent: 3~5 weight parts.
2. luminous energy-saving polyvinyl chloride plastics as claimed in claim 1 is characterized in that: described softening agent is: diisononyl phthalate or diisobutyl phthalate or o-phthalic acid dibutyl ester.
3. luminous energy-saving polyvinyl chloride plastics as claimed in claim 1 is characterized in that: described stablizer is organotin stabilizer or calcium-zinc composite stabilizing agent.
4. luminous energy-saving polyvinyl chloride plastics as claimed in claim 1 is characterized in that: described luminescent powder is: YH8813 or GL-3A.
5. luminous energy-saving polyvinyl chloride plastics as claimed in claim 1 is characterized in that: described lubricant is: amine hydroxybenzene or erucamid erucyl amide.
6. luminous energy-saving polyvinyl chloride plastics as claimed in claim 1 is characterized in that: described toughner is: MBS or SBS or EVA or CPE.
7. luminous energy-saving polyvinyl chloride plastics as claimed in claim 1 is characterized in that: described antiaging agent is: 1010 or 1076 or uv-absorbing agent UV531 or uv-absorbing agent UV9 or uv-absorbing agent UV327.
8. the preparation method of luminous energy-saving polyvinyl chloride plastics, it is characterized in that: will put into high low speed mixer according to the ready polyvinyl chloride of each part by weight, softening agent, stablizer, antiaging agent, toughner, utilize stirring at low speed to start after 10 seconds at a high speed, high-speed stirring to 90 ℃ is put into luminescent powder, lubricant continues to stir, when rising to 110 ℃, temperature stops to stir, the material that stirs is put into the cooling and stirring machine be cooled to 50~80 ℃, can utilize single screw extrusion machine to finalize the design and extrude.
CN 201010191986 2010-05-28 2010-05-28 Luminous energy-saving polyvinyl chloride plastics and preparation method thereof Pending CN101857704A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103012990A (en) * 2012-11-29 2013-04-03 鹤山丽得电子实业有限公司 Raw material for manufacturing flexible soft lamp tubes
CN104231467A (en) * 2014-01-03 2014-12-24 江苏金材科技有限公司 Anti-counterfeit polyvinyl chloride sheet and preparation method thereof
CN106609018A (en) * 2016-12-28 2017-05-03 滁州品之达电器科技有限公司 Plastic special for fluorescent switch buttons
CN106751262A (en) * 2016-12-20 2017-05-31 佛山市高明区塑料行业协会 A kind of chliorinated polyvinyl chloride is modified fluorescent material
CN106751204A (en) * 2016-12-20 2017-05-31 佛山市高明区塑料行业协会 A kind of modified fluorescent polyvinyl chloride new material
CN116478437A (en) * 2023-04-28 2023-07-25 苏州华苏塑料有限公司 Self-repairing light high-brightness PVC luminous film, preparation method thereof and night water life-saving equipment

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000027908A2 (en) * 1998-11-10 2000-05-18 M.A. Hannacolor A Division Of M.A. Hanna Company Daylight/nightglow colored phosphorescent plastic compositions and articles
CN1367073A (en) * 2002-03-12 2002-09-04 美喆国际企业股份有限公司 Production method of plastic floor brick
CN1680477A (en) * 2004-04-05 2005-10-12 王敏 Fluorescent plastic tiles and production thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000027908A2 (en) * 1998-11-10 2000-05-18 M.A. Hannacolor A Division Of M.A. Hanna Company Daylight/nightglow colored phosphorescent plastic compositions and articles
CN1367073A (en) * 2002-03-12 2002-09-04 美喆国际企业股份有限公司 Production method of plastic floor brick
CN1680477A (en) * 2004-04-05 2005-10-12 王敏 Fluorescent plastic tiles and production thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《中国塑料》 20060228 孙家跃,项爱民,杜海燕,李继忠,许文才,马二军 储能型自发光PVC板材的性能研究 第70页至71页 1-7 第20卷, 第2期 2 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103012990A (en) * 2012-11-29 2013-04-03 鹤山丽得电子实业有限公司 Raw material for manufacturing flexible soft lamp tubes
CN104231467A (en) * 2014-01-03 2014-12-24 江苏金材科技有限公司 Anti-counterfeit polyvinyl chloride sheet and preparation method thereof
CN106751262A (en) * 2016-12-20 2017-05-31 佛山市高明区塑料行业协会 A kind of chliorinated polyvinyl chloride is modified fluorescent material
CN106751204A (en) * 2016-12-20 2017-05-31 佛山市高明区塑料行业协会 A kind of modified fluorescent polyvinyl chloride new material
CN106609018A (en) * 2016-12-28 2017-05-03 滁州品之达电器科技有限公司 Plastic special for fluorescent switch buttons
CN116478437A (en) * 2023-04-28 2023-07-25 苏州华苏塑料有限公司 Self-repairing light high-brightness PVC luminous film, preparation method thereof and night water life-saving equipment
CN116478437B (en) * 2023-04-28 2024-04-02 苏州华苏塑料有限公司 Self-repairing light high-brightness PVC luminous film, preparation method thereof and night water life-saving equipment

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Open date: 20101013