CN105315554A - Flame-retardant antistatic tearproof film material - Google Patents
Flame-retardant antistatic tearproof film material Download PDFInfo
- Publication number
- CN105315554A CN105315554A CN201510752052.9A CN201510752052A CN105315554A CN 105315554 A CN105315554 A CN 105315554A CN 201510752052 A CN201510752052 A CN 201510752052A CN 105315554 A CN105315554 A CN 105315554A
- Authority
- CN
- China
- Prior art keywords
- parts
- retardant
- agent
- flame
- film material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a flame-retardant antistatic tearproof film material which is prepared from the following raw materials in parts by weight: 40-50 parts of polypropylene, 10-20 parts of polyethylene, 10-15 parts of polyester, 2-5 parts of polyurethane, 1-3 parts of 2,2-dimethylol propionic acid, 5-8 parts of 1,2-dimethylcyclohexane, 4-8 parts of dioctyl adipate, 0.5-3 parts of a flame retardant, 1.5-2.5 parts of a concentrated anti-blocking agent, 0.5-1.5 parts of an antifogging agent, 1-3 parts of an anti-sticking agent, 2.5-4 parts of a slipping agent, 1-5 parts of an antistatic agent, 3-5 parts of zinc oxide whisker and 1-5 parts of conductive fiber. The film material disclosed by the invention has the advantages of being firm and durable, economic and environment-friendly, antistatic, tearproof, antifogging, wide in application range, flame-retardant, fireproof, safe and reliable. The adding amount of the conductive fiber is small, so that the processability is good, the comprehensive performance is excellent, and the film material is particularly suitable for scale production. The added antistatic agent has better conductivity and meanwhile, the zinc oxide whisker with four feet and a three-dimensional structure is added and cooperates with the antistatic agent, so that the material is endowed with an antistatic property efficiently.
Description
Technical field
The present invention relates to field of packaging material, specifically a kind of flame-retardant and anti-static anti tear thin-film material.
Background technology
Polypropylene film is that it has, and physical strength is high, good toughness to replace a kind of Novel packaging film grown up for the purpose of glassine paper, transparency and the feature such as glossiness is better.Its cost ratio glassine paper is low by about 20%.So replaced in the packagings such as food, medicine, cigarette, textiles or partly instead of glassine paper.But its rebound resilience is large, the kink packaging of candy can not be used for, and do not possess flame retardant resistance and static resistance, existing fire retardant material mainly comprises inorganic anti-flaming material and organic fire-resisting material, wherein organic fire-resisting has good avidity, adds use in the plastic, and bromide fire retardant occupies absolute predominance in organic fire-resisting system, but in environmental issue, blame is many, easily to environment and harm.
Summary of the invention
The object of the present invention is to provide a kind of flame-retardant and anti-static anti tear thin-film material, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of flame-retardant and anti-static anti tear thin-film material, is made up of the raw material of following weight parts: polypropylene 40 ~ 50, polyethylene 10 ~ 20, polyester 10 ~ 15, urethane 2 ~ 5,2,2-dimethylol propionic acid 1 ~ 3,1,2-dimethyl cyclohexane 5 ~ 8, Octyl adipate 4 ~ 8, fire retardant 0.5 ~ 3, concentrated anti blocking agent 1.5 ~ 2.5, antifogging agent 0.5 ~ 1.5, release agent 1 ~ 3, slipping agent 2.5 ~ 4, static inhibitor 1 ~ 5, ZnOw 3 ~ 5, electro-conductive fiber 1 ~ 5.
Preferably, described fire retardant is one or more in ammonium phosphate, thionamic acid, thionamic acid ammonia, phosphoguanidine, Guanidine Sulfamate 99.
Preferably, described concentrated anti blocking agent and antifogging agent all add with master batch form.
Preferably, described static inhibitor is one or more combinations in stearic acid-base trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, hard ester acyl dimethyl-penten ammonium chloride, Trimethyllaurylammonium bromide, Tetradecyl Trimethyl Ammonium Bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or fatty alcohol-polyoxyethylene ether phosphoric acid salt.
Preferably, described electro-conductive fiber is the composition of conductive yam, natural plant fibre mixture, carbon fiber, and wherein the mass ratio of the composition of conductive yam, natural plant fibre mixture, carbon fiber is 1:3:4.
Preferably, described carbon fiber is continuity carbon fiber or staple fibre.
Preferably, described a kind of flame-retardant and anti-static anti tear thin-film material, be made up of the raw material of following weight parts:
Polypropylene 45, polyethylene 15, polyester 13, urethane 3.5,2,2-dimethylol propionic acid 2,1,2-dimethyl cyclohexane 7, Octyl adipate 6, fire retardant 2, concentrated anti blocking agent 2, antifogging agent 1, release agent 2, slipping agent 3, static inhibitor 3, ZnOw 4, electro-conductive fiber 3.5.
Compared with prior art, the invention has the beneficial effects as follows:
Thin-film material of the present invention has sturdy and durable, economic environmental protection, antistatic, anti tear, anti-fog, of many uses, fire-retardant fireproof, the advantage such as safe and reliable.The addition of electro-conductive fiber is little, good processability, and excellent combination property is specially adapted to large-scale production.The static inhibitor added in the present invention has good electroconductibility, effectively can reduce volume resistance or the surface resistivity of raw material, accelerate electrostatic leakage, the present invention simultaneously adds the ZnOw of four feet three-dimensional structures, adjoin each needle-like position when it disperses in the base and mutually overlap formation conductive path, play synergy with permanent antistatic agent, thus give material antistatic property efficiently.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
A kind of flame-retardant and anti-static anti tear of the present invention thin-film material, be made up of the raw material of following weight parts:
Polypropylene 40, polyethylene 10, polyester 10, urethane 2,2,2-dimethylol propionic acid 1,1,2-dimethyl cyclohexane 5, Octyl adipate 4, fire retardant 0.5, concentrated anti blocking agent 1.5, antifogging agent 0.5, release agent 1, slipping agent 2.5, static inhibitor 1, ZnOw 3, electro-conductive fiber 1.
Described fire retardant is one or more in ammonium phosphate, thionamic acid, thionamic acid ammonia, phosphoguanidine, Guanidine Sulfamate 99.
Described concentrated anti blocking agent and antifogging agent all add with master batch form.Adding concentrated anti blocking agent master batch can make film volume there is air between layers, prevents adhesion, easy to use.Add antifogging agent master batch, antifogging agent can precipitate into film surface, plays anti-fog effect.
Described static inhibitor is one or more combinations in stearic acid-base trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, hard ester acyl dimethyl-penten ammonium chloride, Trimethyllaurylammonium bromide, Tetradecyl Trimethyl Ammonium Bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or fatty alcohol-polyoxyethylene ether phosphoric acid salt.
Described electro-conductive fiber is the composition of conductive yam, natural plant fibre mixture, carbon fiber, wherein the mass ratio of the composition of conductive yam, natural plant fibre mixture, carbon fiber is 1:3:4, carbon fiber has the performances such as good electroconductibility, erosion resistance, is good anti static additive.Described carbon fiber is continuity carbon fiber or staple fibre.
Only be with the difference of next embodiment and embodiment 1,
Embodiment 2
A kind of flame-retardant and anti-static anti tear thin-film material, be made up of the raw material of following weight parts:
Polypropylene 45, polyethylene 15, polyester 13, urethane 3.5,2,2-dimethylol propionic acid 2,1,2-dimethyl cyclohexane 7, Octyl adipate 6, fire retardant 2, concentrated anti blocking agent 2, antifogging agent 1, release agent 2, slipping agent 3, static inhibitor 3, ZnOw 4, electro-conductive fiber 3.5.
Embodiment 3
A kind of flame-retardant and anti-static anti tear thin-film material, be made up of the raw material of following weight parts:
Polypropylene 50, polyethylene 20, polyester 15, urethane 5,2,2-dimethylol propionic acid 3,1,2-dimethyl cyclohexane 8, Octyl adipate 8, fire retardant 3, concentrated anti blocking agent 2.5, antifogging agent 1.5, release agent 3, slipping agent 4, static inhibitor 5, ZnOw 5, electro-conductive fiber 5.
Claims (7)
1. a flame-retardant and anti-static anti tear thin-film material, is characterized in that, is made up of the raw material of following weight parts: polypropylene 40 ~ 50, polyethylene 10 ~ 20, polyester 10 ~ 15, urethane 2 ~ 5,2,2-dimethylol propionic acid 1 ~ 3,1,2-dimethyl cyclohexane 5 ~ 8, Octyl adipate 4 ~ 8, fire retardant 0.5 ~ 3, concentrated anti blocking agent 1.5 ~ 2.5, antifogging agent 0.5 ~ 1.5, release agent 1 ~ 3, slipping agent 2.5 ~ 4, static inhibitor 1 ~ 5, ZnOw 3 ~ 5, electro-conductive fiber 1 ~ 5.
2. a kind of flame-retardant and anti-static anti tear thin-film material according to claim 1, is characterized in that, described fire retardant is one or more in ammonium phosphate, thionamic acid, thionamic acid ammonia, phosphoguanidine, Guanidine Sulfamate 99.
3. a kind of flame-retardant and anti-static anti tear thin-film material according to claim 1, it is characterized in that, described concentrated anti blocking agent and antifogging agent all add with master batch form.
4. a kind of flame-retardant and anti-static anti tear thin-film material according to claim 1, it is characterized in that, described static inhibitor is one or more combinations in stearic acid-base trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, hard ester acyl dimethyl-penten ammonium chloride, Trimethyllaurylammonium bromide, Tetradecyl Trimethyl Ammonium Bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or fatty alcohol-polyoxyethylene ether phosphoric acid salt.
5. a kind of flame-retardant and anti-static anti tear thin-film material according to claim 1, it is characterized in that, described electro-conductive fiber is the composition of conductive yam, natural plant fibre mixture, carbon fiber, and wherein the mass ratio of the composition of conductive yam, natural plant fibre mixture, carbon fiber is 1:3:4.
6. a kind of flame-retardant and anti-static anti tear thin-film material according to claim 1, it is characterized in that, described carbon fiber is continuity carbon fiber or staple fibre.
7. a kind of flame-retardant and anti-static anti tear thin-film material according to claim 1, is characterized in that, be made up of the raw material of following weight parts:
Polypropylene 45, polyethylene 15, polyester 13, urethane 3.5,2,2-dimethylol propionic acid 2,1,2-dimethyl cyclohexane 7, Octyl adipate 6, fire retardant 2, concentrated anti blocking agent 2, antifogging agent 1, release agent 2, slipping agent 3, static inhibitor 3, ZnOw 4, electro-conductive fiber 3.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510752052.9A CN105315554A (en) | 2015-11-04 | 2015-11-04 | Flame-retardant antistatic tearproof film material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510752052.9A CN105315554A (en) | 2015-11-04 | 2015-11-04 | Flame-retardant antistatic tearproof film material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105315554A true CN105315554A (en) | 2016-02-10 |
Family
ID=55243924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510752052.9A Pending CN105315554A (en) | 2015-11-04 | 2015-11-04 | Flame-retardant antistatic tearproof film material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105315554A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105801977A (en) * | 2016-04-26 | 2016-07-27 | 界首市锦丰塑业有限公司 | Anti-aging plastic cloth |
| CN106243498A (en) * | 2016-08-15 | 2016-12-21 | 桐城市人和包装有限公司 | A kind of antistatic polypropylene film packing material |
| CN106279987A (en) * | 2016-08-15 | 2017-01-04 | 桐城市人和包装有限公司 | A kind of antibacterial nano plastic packaging material |
| CN106279885A (en) * | 2016-08-15 | 2017-01-04 | 桐城市人和包装有限公司 | A kind of flame retardant type plastic package material |
| CN107573589A (en) * | 2017-09-06 | 2018-01-12 | 桐城市华猫软膜有限公司 | A kind of tear-proof antibacterial agricultural mulching |
| CN108794887A (en) * | 2018-06-29 | 2018-11-13 | 怀宁县日升塑业有限公司 | A kind of tear-resistant plastic garbage bag preparation method |
| CN109385009A (en) * | 2018-10-30 | 2019-02-26 | 合肥市丽红塑胶材料有限公司 | A kind of Anti-static PP modified material |
| PL423837A1 (en) * | 2017-12-11 | 2019-06-17 | Borowski Jacek Przedsiębiorstwo Produkcyjno Handlowo Usługowe Fol-Pol | Method for modification of polymer film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101759921A (en) * | 2008-12-26 | 2010-06-30 | 上海普利特复合材料股份有限公司 | Novel antistatic polypropylene material and preparation method thereof |
| CN103304898A (en) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | Antistatic flame retardant PP (polypropylene) material |
| CN104893100A (en) * | 2015-05-29 | 2015-09-09 | 安徽顺彤包装材料有限公司 | Anti-explosion and anti-electrostatic material and preparation method thereof |
-
2015
- 2015-11-04 CN CN201510752052.9A patent/CN105315554A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101759921A (en) * | 2008-12-26 | 2010-06-30 | 上海普利特复合材料股份有限公司 | Novel antistatic polypropylene material and preparation method thereof |
| CN103304898A (en) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | Antistatic flame retardant PP (polypropylene) material |
| CN104893100A (en) * | 2015-05-29 | 2015-09-09 | 安徽顺彤包装材料有限公司 | Anti-explosion and anti-electrostatic material and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105801977A (en) * | 2016-04-26 | 2016-07-27 | 界首市锦丰塑业有限公司 | Anti-aging plastic cloth |
| CN106243498A (en) * | 2016-08-15 | 2016-12-21 | 桐城市人和包装有限公司 | A kind of antistatic polypropylene film packing material |
| CN106279987A (en) * | 2016-08-15 | 2017-01-04 | 桐城市人和包装有限公司 | A kind of antibacterial nano plastic packaging material |
| CN106279885A (en) * | 2016-08-15 | 2017-01-04 | 桐城市人和包装有限公司 | A kind of flame retardant type plastic package material |
| CN107573589A (en) * | 2017-09-06 | 2018-01-12 | 桐城市华猫软膜有限公司 | A kind of tear-proof antibacterial agricultural mulching |
| PL423837A1 (en) * | 2017-12-11 | 2019-06-17 | Borowski Jacek Przedsiębiorstwo Produkcyjno Handlowo Usługowe Fol-Pol | Method for modification of polymer film |
| CN108794887A (en) * | 2018-06-29 | 2018-11-13 | 怀宁县日升塑业有限公司 | A kind of tear-resistant plastic garbage bag preparation method |
| CN109385009A (en) * | 2018-10-30 | 2019-02-26 | 合肥市丽红塑胶材料有限公司 | A kind of Anti-static PP modified material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105315554A (en) | Flame-retardant antistatic tearproof film material | |
| CN105315553A (en) | Antibacterial and antistatic tear-resistant thin-film material | |
| Hörold | Phosphorus-based and intumescent flame retardants | |
| US20100267853A1 (en) | Polymer-based fire-retarding formulations | |
| CN103333392A (en) | Natural antibacterial pearl wool | |
| WO2013175445A3 (en) | Flame retardant polycarbonate compositions, methods of manufacture thereof and articles comprising the same | |
| EP2404968A4 (en) | Aromatic polycarbonate resin composition and molded article thereof | |
| CN102850646A (en) | Flame-retardant antistatic high-strength thermoplastic composite material and its preparation method | |
| IN2014CN04681A (en) | ||
| WO2010091007A3 (en) | Polyurethane foam composition containing flame-retardant, and process for making same, flame retardant composition and polyurethane foam made therefrom | |
| CN102807699A (en) | Formula of flame-retardant polyethylene plastic | |
| WO2011113795A3 (en) | Flame-resistant composite foam | |
| CN102807729A (en) | Formula of flame-retardant modified polyformaldehyde (POM) | |
| CN105255037A (en) | Permanent antistatic ABS (acrylonitrile butadiene styrene) flame-retardant material | |
| CN105255070A (en) | Transparent air cushion film | |
| CN101845168A (en) | Environment-friendly, antiflaming and antistatic foaming material and preparation method thereof | |
| CN105037938A (en) | Halogen-free flame retardant plastic material | |
| CN105820477A (en) | Composite anti-corrosive and anti-static plastic | |
| KR102121865B1 (en) | Thermoplastic resin composition and molded article comprising the same | |
| CN103740088A (en) | Formula for modifying polyether-ether-ketone plastics | |
| CN103937171A (en) | Glass fiber reinforced plastic explosion-proof material for mine and preparation method thereof | |
| CN104592799A (en) | Novel flame-retardant antistatic safe paint | |
| KR20170058533A (en) | A flame retardant tile for a ship comprising a biodegradable polymer resin | |
| CN104962012A (en) | Antistatic PVC (polyvinyl chloride) modified plastic and preparation method thereof | |
| CN107556616A (en) | A kind of good plastic grain of anti-wear performance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160210 |