CN105315553A - Antibacterial and antistatic tear-resistant thin-film material - Google Patents
Antibacterial and antistatic tear-resistant thin-film material Download PDFInfo
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- CN105315553A CN105315553A CN201510751975.2A CN201510751975A CN105315553A CN 105315553 A CN105315553 A CN 105315553A CN 201510751975 A CN201510751975 A CN 201510751975A CN 105315553 A CN105315553 A CN 105315553A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an antibacterial and antistatic tear-resistant thin-film material. The antibacterial and antistatic tear-resistant thin-film material is prepared from the following raw materials in parts by weight: 40-50 parts of polypropylene, 10-20 parts of polyethylene, 10-15 parts of polyester, 2-5 parts of polyurethane, 1-3 parts of 2,2-dimethylol propionic acid, 5-8 parts of 1,2-dimethylcyclohexane, 4-8 parts of dioctyl adipate, 2-6 parts of 2-methyl-1,3-propylene glycol, 0.5-3 parts of a natural antibacterial agent, 1.5-2.5 parts of a concentrated anti-blocking agent, 0.5-1.5 parts of an anti-fog agent, 1-3 parts of an anti-sticking agent, 2.5-4 parts of a slipping agent, 1-5 parts of an antistatic agent, 3-5 parts of zinc oxide whiskers and 1-5 parts of electro-conductive fibers. The antibacterial and antistatic tear-resistant thin-film material has the advantages of being economical, environment-friendly, antistatic, antibacterial, stretch-proof, tear-resistant, anti-fog, wide in application, safe, reliable and the like.
Description
Technical field
The present invention relates to field of packaging material, specifically a kind of antibacterial antistatic anti tear thin-film material.
Background technology
Polypropylene film is that it has, and physical strength is high, good toughness to replace a kind of Novel packaging film grown up for the purpose of glassine paper, transparency and the feature such as glossiness is better.Its cost ratio glassine paper is low by about 20%.So replaced in the packagings such as food, medicine, cigarette, textiles or partly instead of glassine paper.But its rebound resilience is large, the kink packaging of candy can not be used for, and do not possess germ resistance and static resistance, wherein, its antimicrobial efficiency of existing antiseptic-germicide is on the low side, because antimicrobial efficiency is on the low side, needs to improve antiseptic-germicide consumption, cause the toxic side effect of antiseptic-germicide to increase, have a strong impact on the normal usage function of antibacterial film.
Summary of the invention
The object of the present invention is to provide a kind of antibacterial antistatic anti tear thin-film material, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of antibacterial antistatic anti tear thin-film material, be made up of the raw material of following weight parts: polypropylene 40 ~ 50, polyethylene 10 ~ 20, polyester 10 ~ 15, urethane 2 ~ 5,2,2-dimethylol propionic acid 1 ~ 3,1,2-dimethyl cyclohexane 5 ~ 8, Octyl adipate 4 ~ 8,2-methyl isophthalic acid, ammediol 2 ~ 6, natural antibacterial agent 0.5 ~ 3, concentrated anti blocking agent 1.5 ~ 2.5, antifogging agent 0.5 ~ 1.5, release agent 1 ~ 3, slipping agent 2.5 ~ 4, static inhibitor 1 ~ 5, ZnOw 3 ~ 5, electro-conductive fiber 1 ~ 5.
Preferably, described natural antibacterial agent is the composition of mustard essential oil, Bulbus Allii quintessence oil, Herba Houttuyniae extract, blue stone, realgar, and wherein the mass ratio of the composition of mustard essential oil, Bulbus Allii quintessence oil, Herba Houttuyniae extract, blue stone, realgar is 4:2:1:3:2.
Preferably, described concentrated anti blocking agent and antifogging agent all add with master batch form.
Preferably, described static inhibitor is one or more combinations in stearic acid-base trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, hard ester acyl dimethyl-penten ammonium chloride, Trimethyllaurylammonium bromide, Tetradecyl Trimethyl Ammonium Bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or fatty alcohol-polyoxyethylene ether phosphoric acid salt.
Preferably, described electro-conductive fiber is the composition of conductive yam, natural plant fibre mixture, carbon fiber, and wherein the mass ratio of the composition of conductive yam, natural plant fibre mixture, carbon fiber is 1:3:4.
Preferably, described a kind of antibacterial antistatic anti tear thin-film material, be made up of the raw material of following weight parts:
Polypropylene 40, polyethylene 10, polyester 10, urethane 2,2,2-dimethylol propionic acid 1,1,2-dimethyl cyclohexane 5, Octyl adipate 4,2-methyl isophthalic acid, ammediol 2, natural antibacterial agent 0.5, concentrated anti blocking agent 1.5, antifogging agent 0.5, release agent 1, slipping agent 2.5, static inhibitor 1, ZnOw 3, electro-conductive fiber 1.
Preferably, described carbon fiber is continuity carbon fiber or staple fibre.
Compared with prior art, the invention has the beneficial effects as follows:
Thin-film material of the present invention has economic environmental protection, antistatic, stretch-proof, anti tear, the advantage such as anti-fog, of many uses, safe and reliable.2-methyl isophthalic acid, ammediol composition, has larger effect for the tensile strength and elongation at break improving thin-film material; Natural antibacterial agent, safety non-toxic, antimicrobial efficiency are higher; The addition of electro-conductive fiber is little, good processability, and excellent combination property is specially adapted to large-scale production.The static inhibitor added in the present invention has good electroconductibility, effectively can reduce volume resistance or the surface resistivity of raw material, accelerate electrostatic leakage, the present invention simultaneously adds the ZnOw of four feet three-dimensional structures, adjoin each needle-like position when it disperses in the base and mutually overlap formation conductive path, play synergy with permanent antistatic agent, thus give material antistatic property efficiently.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
A kind of antibacterial antistatic anti tear of the present invention thin-film material, be made up of the raw material of following weight parts:
Polypropylene 40, polyethylene 10, polyester 10, urethane 2,2,2-dimethylol propionic acid 1,1,2-dimethyl cyclohexane 5, Octyl adipate 4,2-methyl isophthalic acid, ammediol 2, natural antibacterial agent 0.5, concentrated anti blocking agent 1.5, antifogging agent 0.5, release agent 1, slipping agent 2.5, static inhibitor 1, ZnOw 3, electro-conductive fiber 1.
Described natural antibacterial agent is the composition of mustard essential oil, Bulbus Allii quintessence oil, Herba Houttuyniae extract, blue stone, realgar, and wherein the mass ratio of the composition of mustard essential oil, Bulbus Allii quintessence oil, Herba Houttuyniae extract, blue stone, realgar is 4:2:1:3:2.
Described concentrated anti blocking agent and antifogging agent all add with master batch form.Adding concentrated anti blocking agent master batch can make film volume there is air between layers, prevents adhesion, easy to use.Add antifogging agent master batch, antifogging agent can precipitate into film surface, plays anti-fog effect.
Described static inhibitor is one or more combinations in stearic acid-base trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, hard ester acyl dimethyl-penten ammonium chloride, Trimethyllaurylammonium bromide, Tetradecyl Trimethyl Ammonium Bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or fatty alcohol-polyoxyethylene ether phosphoric acid salt.
Described electro-conductive fiber is the composition of conductive yam, natural plant fibre mixture, carbon fiber, wherein the mass ratio of the composition of conductive yam, natural plant fibre mixture, carbon fiber is 1:3:4, carbon fiber has the performances such as good electroconductibility, erosion resistance, is good anti static additive.Described carbon fiber is continuity carbon fiber or staple fibre.
Only be with the difference of next embodiment and embodiment 1,
Embodiment 2
A kind of antibacterial antistatic anti tear thin-film material, be made up of the raw material of following weight parts:
Polypropylene 45, polyethylene 15, polyester 13, urethane 3.5,2,2-dimethylol propionic acid 2,1,2-dimethyl cyclohexane 7, Octyl adipate 6,2-methyl isophthalic acid, ammediol 4, natural antibacterial agent 2, concentrated anti blocking agent 2, antifogging agent 1, release agent 2, slipping agent 3, static inhibitor 3, ZnOw 4, electro-conductive fiber 3.5.
Embodiment 3
A kind of antibacterial antistatic anti tear thin-film material, be made up of the raw material of following weight parts:
Polypropylene 50, polyethylene 20, polyester 15, urethane 5,2,2-dimethylol propionic acid 3,1,2-dimethyl cyclohexane 8, Octyl adipate 8,2-methyl isophthalic acid, ammediol 6, natural antibacterial agent 3, concentrated anti blocking agent 2.5, antifogging agent 1.5, release agent 3, slipping agent 4, static inhibitor 5, ZnOw 5, electro-conductive fiber 5.
Claims (7)
1. an antibacterial antistatic anti tear thin-film material, is characterized in that, is made up of the raw material of following weight parts: polypropylene 40 ~ 50, polyethylene 10 ~ 20, polyester 10 ~ 15, urethane 2 ~ 5,2,2-dimethylol propionic acid 1 ~ 3,1,2-dimethyl cyclohexane 5 ~ 8, Octyl adipate 4 ~ 8,2-methyl isophthalic acid, ammediol 2 ~ 6, natural antibacterial agent 0.5 ~ 3, concentrated anti blocking agent 1.5 ~ 2.5, antifogging agent 0.5 ~ 1.5, release agent 1 ~ 3, slipping agent 2.5 ~ 4, static inhibitor 1 ~ 5, ZnOw 3 ~ 5, electro-conductive fiber 1 ~ 5.
2. a kind of antibacterial antistatic anti tear thin-film material according to claim 1, it is characterized in that, described natural antibacterial agent is the composition of mustard essential oil, Bulbus Allii quintessence oil, Herba Houttuyniae extract, blue stone, realgar, and wherein the mass ratio of the composition of mustard essential oil, Bulbus Allii quintessence oil, Herba Houttuyniae extract, blue stone, realgar is 4:2:1:3:2.
3. a kind of antibacterial antistatic anti tear thin-film material according to claim 1, it is characterized in that, described concentrated anti blocking agent and antifogging agent all add with master batch form.
4. a kind of antibacterial antistatic anti tear thin-film material according to claim 1, it is characterized in that, described static inhibitor is one or more combinations in stearic acid-base trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, hard ester acyl dimethyl-penten ammonium chloride, Trimethyllaurylammonium bromide, Tetradecyl Trimethyl Ammonium Bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or fatty alcohol-polyoxyethylene ether phosphoric acid salt.
5. a kind of antibacterial antistatic anti tear thin-film material according to claim 1, it is characterized in that, described electro-conductive fiber is the composition of conductive yam, natural plant fibre mixture, carbon fiber, and wherein the mass ratio of the composition of conductive yam, natural plant fibre mixture, carbon fiber is 1:3:4.
6. a kind of antibacterial antistatic anti tear thin-film material according to claim 1, it is characterized in that, described carbon fiber is continuity carbon fiber or staple fibre.
7. a kind of antibacterial antistatic anti tear thin-film material according to claim 1, is characterized in that, be made up of the raw material of following weight parts:
Polypropylene 40, polyethylene 10, polyester 10, urethane 2,2,2-dimethylol propionic acid 1,1,2-dimethyl cyclohexane 5, Octyl adipate 4,2-methyl isophthalic acid, ammediol 2, natural antibacterial agent 0.5, concentrated anti blocking agent 1.5, antifogging agent 0.5, release agent 1, slipping agent 2.5, static inhibitor 1, ZnOw 3, electro-conductive fiber 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510751975.2A CN105315553A (en) | 2015-11-04 | 2015-11-04 | Antibacterial and antistatic tear-resistant thin-film material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510751975.2A CN105315553A (en) | 2015-11-04 | 2015-11-04 | Antibacterial and antistatic tear-resistant thin-film material |
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| CN105315553A true CN105315553A (en) | 2016-02-10 |
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| CN201510751975.2A Pending CN105315553A (en) | 2015-11-04 | 2015-11-04 | Antibacterial and antistatic tear-resistant thin-film material |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542439A (en) * | 2016-02-29 | 2016-05-04 | 江苏宏远新材料科技有限公司 | Medical antibacterial PU (polyurethane) film and preparation method thereof |
| CN105801977A (en) * | 2016-04-26 | 2016-07-27 | 界首市锦丰塑业有限公司 | Anti-aging plastic cloth |
| CN106113839A (en) * | 2016-07-15 | 2016-11-16 | 黄山永新股份有限公司 | A kind of fruit and vegerable salad packaging composite film and production technology thereof |
| CN106243498A (en) * | 2016-08-15 | 2016-12-21 | 桐城市人和包装有限公司 | A kind of antistatic polypropylene film packing material |
| CN106243499A (en) * | 2016-08-16 | 2016-12-21 | 金田集团（桐城）塑业有限公司 | A kind of antistatic antibiotic BOPP thin film |
| CN106273945A (en) * | 2016-08-03 | 2017-01-04 | 海宁长昆包装有限公司 | A kind of anti-electrostatic antibiotic Biaxially oriented polypropylene bag film and production technology thereof |
| CN106279987A (en) * | 2016-08-15 | 2017-01-04 | 桐城市人和包装有限公司 | A kind of antibacterial nano plastic packaging material |
| CN106800767A (en) * | 2016-06-17 | 2017-06-06 | 无锡英普林纳米科技有限公司 | A kind of high intensity anti-biotic material for nano-imprinting apparatus |
| CN107573589A (en) * | 2017-09-06 | 2018-01-12 | 桐城市华猫软膜有限公司 | A kind of tear-proof antibacterial agricultural mulching |
| CN107880525A (en) * | 2017-11-13 | 2018-04-06 | 常州凯恒纺织品有限公司 | A kind of keyboard protective film |
| CN112406145A (en) * | 2020-09-27 | 2021-02-26 | 江苏海美新材料有限公司 | High-uniformity preparation process of PVC (polyvinyl chloride) antibacterial film |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893100A (en) * | 2015-05-29 | 2015-09-09 | 安徽顺彤包装材料有限公司 | Anti-explosion and anti-electrostatic material and preparation method thereof |
-
2015
- 2015-11-04 CN CN201510751975.2A patent/CN105315553A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893100A (en) * | 2015-05-29 | 2015-09-09 | 安徽顺彤包装材料有限公司 | Anti-explosion and anti-electrostatic material and preparation method thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542439A (en) * | 2016-02-29 | 2016-05-04 | 江苏宏远新材料科技有限公司 | Medical antibacterial PU (polyurethane) film and preparation method thereof |
| CN105801977A (en) * | 2016-04-26 | 2016-07-27 | 界首市锦丰塑业有限公司 | Anti-aging plastic cloth |
| CN106800767A (en) * | 2016-06-17 | 2017-06-06 | 无锡英普林纳米科技有限公司 | A kind of high intensity anti-biotic material for nano-imprinting apparatus |
| CN106113839A (en) * | 2016-07-15 | 2016-11-16 | 黄山永新股份有限公司 | A kind of fruit and vegerable salad packaging composite film and production technology thereof |
| CN106273945A (en) * | 2016-08-03 | 2017-01-04 | 海宁长昆包装有限公司 | A kind of anti-electrostatic antibiotic Biaxially oriented polypropylene bag film and production technology thereof |
| CN106243498A (en) * | 2016-08-15 | 2016-12-21 | 桐城市人和包装有限公司 | A kind of antistatic polypropylene film packing material |
| CN106279987A (en) * | 2016-08-15 | 2017-01-04 | 桐城市人和包装有限公司 | A kind of antibacterial nano plastic packaging material |
| CN106243499A (en) * | 2016-08-16 | 2016-12-21 | 金田集团（桐城）塑业有限公司 | A kind of antistatic antibiotic BOPP thin film |
| CN107573589A (en) * | 2017-09-06 | 2018-01-12 | 桐城市华猫软膜有限公司 | A kind of tear-proof antibacterial agricultural mulching |
| CN107880525A (en) * | 2017-11-13 | 2018-04-06 | 常州凯恒纺织品有限公司 | A kind of keyboard protective film |
| CN112406145A (en) * | 2020-09-27 | 2021-02-26 | 江苏海美新材料有限公司 | High-uniformity preparation process of PVC (polyvinyl chloride) antibacterial film |
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Application publication date: 20160210 |