CN107880525A - A kind of keyboard protective film - Google Patents

A kind of keyboard protective film Download PDF

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Publication number
CN107880525A
CN107880525A CN201711113628.2A CN201711113628A CN107880525A CN 107880525 A CN107880525 A CN 107880525A CN 201711113628 A CN201711113628 A CN 201711113628A CN 107880525 A CN107880525 A CN 107880525A
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parts
protective film
tpu
ammonium sulfate
mixed
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吕兰秀
徐颜峰
张琳
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Changzhou Kai Heng Textile Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02Homopolymers or copolymers of hydrocarbons
    • C08J2425/04Homopolymers or copolymers of styrene
    • C08J2425/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • C08K2003/3054Ammonium sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/12Adsorbed ingredients, e.g. ingredients on carriers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of keyboard protective film, belong to technical field of polymer materials.Count in parts by weight, 35~45 parts of TPU are weighed successively, 3~5 parts of plasticizer, 2~4 parts of age resistor, 8~12 parts of mixed extracts, 5~10 parts of mixed essential oils, 4~6 parts of modified glass-fibers, 15~20 parts of polystyrene, 2~5 parts of ammonium sulfate, 5~8 parts of nano-silver powders and 1~3 part of dispersant, ammonium sulfate is crushed, sieving, obtain ammonium sulfate powder, by TPU, plasticizer, age resistor, mixed extract, mixed essential oil, modified glass-fiber, polystyrene, ammonium sulfate powder, nano-silver powder and dispersant are added in mixer, and the water of 0.5~0.8 times of TPU mass is added into mixer, after being stirred, obtain mixture, mixture is extruded in double screw extruder, obtain blank, by blank casting film-forming, obtain keyboard protective film.Keyboard protective film prepared by the present invention has excellent anti-microbial property, while has preferable mechanical property.

Description

A kind of keyboard protective film
Technical field
The invention discloses a kind of keyboard protective film, belong to technical field of polymer materials.
Background technology
Keyboard membrane is made using TPU elastomeric materials by fashion IT.The bottom absorption of TPU smooth feel silica gel Power integrates the high-grade keyboard membrane of two big material advantages.The material that TPU is used as keyboard membrane is being proper in early days, but it Also there is the shortcomings that unconquerable such as:It is more crisp be easily pulled off, compactness difference is not fixed easily.
Increasingly perfect with information system, medical institutions carry out with no paper at all just in wider array of field, the covering of computer Face expands day by day, and the computor-keyboard and the microbiological pollution of mouse to accompany with this, also increasingly attracts attention.There is scholar's tune Look into and find that each button contaminating microorganisms of keyboard averagely may be up to 20.1CFU.
ICU patient causes its hospital infection high due to factors such as underlying diseases are serious, store period is more, hypoimmunities Hair, especially Multidrug resistant bacteria such as MRSA and Acinetobacter baumannii.It is many in the hospital infection of ICU patient to intersect biography between patient Broadcast, the hand of medical worker has played very crucial instrumentality between hospital environment and patient, and it is sudden and violent to even result in hospital infection Hair.Substantial amounts of contaminating microorganisms, norovirus, clostridium difficile, Acinetobacter baumannii etc. in hospital environment and body surface be present, It can for a long time be survived in all kinds of body surfaces of hospital, turn into the important hidden danger of hospital infection and dangerous link.It is each at present The increasingly popularization of hospital information system, computer progressively instead of the position of case record, but equally also bring new problem: The serious pollution problem of the microorganism of computer keyboard and mouse.Research finds that the germ contamination of surface of keyboard may be up to(153± 369)CFU/ is per key, and it can be used as intermediary by the hand of medical worker and be broadcast to the patient of hypoimmunity and causes to infect. Research finds that its microorganism pollution degree can effectively be reduced by periodically sterilizing computor-keyboard using special ultraviolet, and regular ultraviolet shines The keyboard penetrated can keep no bacteria pollution state for a long time.Also studies have found that, can be with the computor-keyboard film with antibacterial action Effectively reduce the microbial contamination of surface of keyboard.But the problem of anti-microbial property is bad also be present in traditional computor-keyboard film, Therefore also need to study it.
The content of the invention
The present invention solves the technical problem of:For conventional keyboard film anti-microbial property it is bad the problem of, there is provided one Kind keyboard protective film.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of keyboard protective film, it is made up of the raw material of following parts by weight:
35~45 parts of TPU
3~5 parts of plasticizer
2~4 parts of age resistor
8~12 parts of mixed extract
5~10 parts of mixed essential oil
4~6 parts of modified glass-fiber
15~20 parts of polystyrene
2~5 parts of ammonium sulfate
1~3 part of dispersant
5~8 parts of nano-silver powder
The TPU is:TPUE rubber;
The preparation method of the mixed extract:
By tealeaves and granatum in mass ratio 3:1~3:2 mixing, and add argy wormwood and the tealeaves matter of 0.5~0.6 times of tea quality 2~4h is boiled in the water of 4~5 times of amount, heating, filters, and concentration, obtains mixed extract;
The preparation method of the mixed essential oil is:
By ginger oil and sage oil in mass ratio 1:2~1:5 mixing, and add the black pepper of 0.3~0.4 times of sage oil quality Oil, after being stirred, obtain mixed essential oil;
The preparation method of the modified glass-fiber is:
By glass fibre and water in mass ratio 1:8~1:12 mixing, and the silane for adding 0.4~0.6 times of glass fiber quality is even Join agent, after being stirred, add the nano titanium oxide of 0.2~0.4 times of glass fiber quality, sonic oscillation, filter, dry, Obtain modified glass-fiber;
The preparation method of the keyboard protective film is:
(1)Formed by raw material and weigh each component;
(2)Ammonium sulfate is crushed, sieves, obtains ammonium sulfate powder, by TPU, plasticizer, age resistor, mixed extract, mixing essence Oil, modified glass-fiber, polystyrene, ammonium sulfate powder, nano-silver powder and dispersant are added in mixer, and into mixer The water of 0.5~0.8 times of TPU mass is added, after being stirred, mixture is obtained, mixture is extruded in double screw extruder, obtained Blank, by blank casting film-forming, obtain keyboard protective film.
The plasticizer is dioctyl phthalate, in di-n-octyl phthalate or dicyclohexyl phthalate Any one.
The age resistor is antioxidant 4010NA, any one or a few mixing in antioxidant 264 or antioxidant 4010 Thing.
The dispersant is dispersant NNO, any one in dispersant 5040 or Dispersant MF.
The silane coupler is silane resin acceptor kh-550, in silane coupler KH-560 or Silane coupling reagent KH-570 Any one.
The beneficial effects of the invention are as follows:
(1)The present invention adds modified glass-fiber when preparing keyboard protective film, and first, the addition of glass fibre can strengthen keyboard Each intermolecular active force in film system is protected, so that the mechanical property of product is improved, secondly fiberglass surfacing is inhaled Attached nano titanium oxide, after being added in protection film system, it can be sterilized under illumination effect, so that the antibiotic property of product It can get a promotion, and nano titanium oxide can change smooth fiberglass surfacing structure after fiberglass surfacing absorption For coarse structure, it is affiliated to so as to be advantageous to the winding of the strand of the macromolecular organic matter such as TPU, avoids product from being sent out in loading process Raw sliding, makes product mechanical property be further enhanced;
(2)The present invention adds polystyrene and ammonium sulfate when preparing keyboard protective film, on the one hand, polystyrene is adding keyboard After protecting in film system, the hydrophobic performance of diaphragm can be improved, while can also be densified protection membrane superficial tissue, avoids micro- life Thing adheres to, so that the anti-microbial property of product is improved, on the other hand, the ammonium sulfate of addition can be in extrusion and forming process Gas is produced, so that long-living many equally distributed micro-bubbles in protection film system, nano-silver powder can enter micro-bubble In, and then be evenly distributed in protection film system, and nano-emulsion lug structure is formed on film surface, this nano-emulsion lug structure can change The contact angle on film surface, product hydrophobic performance is improved, avoids microorganism from adhering to, so that the anti-microbial property of product further carries It is high;
(3)The present invention adds mixed essential oil when preparing keyboard protective film, on the one hand, the addition of mixed essential oil can be to surface of keyboard Bacterium play inhibitory action, so as to improve the anti-microbial property of product, on the other hand, due to mixed essential oil portion in use Divide volatilization, inhibitory action can be played to the bacterium in environment, so that the anti-microbial property of product further improves.
Embodiment
By tealeaves and granatum in mass ratio 3:1~3:2 are mixed in beaker, and tea quality 0.5 is added into beaker ~0.6 times of argy wormwood and the water of 4~5 times of tea quality, beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 95 ~100 DEG C, under conditions of rotating speed is 280~350r/min, after heating stirring boils 2~4h, filtering, mixed liquor is obtained, will be mixed Liquid moves into Rotary Evaporators, is 55~65 DEG C in temperature, and rotating speed is 120~180r/min, gives as security the bar that pressure is 600~800kPa Under part, 60~80min of spin concentration, mixed extract is obtained;By ginger oil and sage oil in mass ratio 1:2~1:5 are mixed in burning In bottle, and the black pepper oil of 0.3~0.4 times of sage oil quality is added into flask, flask immigration digital display is tested the speed constant temperature magnetic Power agitator, it is 75~85 DEG C in temperature, under conditions of rotating speed is 300~350r/min, is stirred 35~50min, obtains mixed Close essential oil;By glass fibre and water in mass ratio 1:8~1:12 mixing, and add the silane of 0.4~0.6 times of glass fiber quality Coupling agent, under conditions of temperature is 75~90 DEG C, after 6~8h of mixing immersion, add 0.2~0.4 times of glass fiber quality Nano titanium oxide, in frequency be 45~50kHz under conditions of 15~25min of sonic oscillation, filtering, filter cake is obtained, by filter cake Drying box is moved into, under conditions of temperature is 85~95 DEG C, 60~90min is dried, obtains modified glass-fiber;In parts by weight Meter, 35~45 parts of TPU is weighed successively, 3~5 parts of plasticizer, 2~4 parts of age resistor, 8~12 parts of mixed extracts, 5~10 parts mixed Close essential oil, 4~6 parts of modified glass-fibers, 15~20 parts of polystyrene, 2~5 parts of ammonium sulfate, 5~8 parts of nano-silver powders and 1~3 Part dispersant, ammonium sulfate is added in pulverizer, is crushed, and is crossed 120~160 mesh sieves, is obtained ammonium sulfate powder;By TPU, plasticizer, Age resistor, mixed extract, mixed essential oil, modified glass-fiber, polystyrene, ammonium sulfate powder, nano-silver powder and dispersant Add in mixer, and the water of 0.5~0.8 times of TPU mass is added into mixer, in the bar that rotating speed is 400~480r/min Be stirred 45~60min under part, obtain mixture, by mixture move into double screw extruder in, in temperature be 180~220 DEG C Under conditions of extrude, obtain blank, by blank casting film-forming, obtain keyboard protective film.The TPU is:TPUE Rubber.The plasticizer is dioctyl phthalate, is appointed in di-n-octyl phthalate or dicyclohexyl phthalate Meaning is a kind of.The age resistor is antioxidant 4010NA, any one or a few mixing in antioxidant 264 or antioxidant 4010 Thing.The dispersant is dispersant NNO, any one in dispersant 5040 or Dispersant MF.The silane coupler is silane Any one in coupling agent KH-550, silane coupler KH-560 or Silane coupling reagent KH-570.
Example 1
By tealeaves and granatum in mass ratio 3:2 are mixed in beaker, and into beaker add 0.6 times of tea quality argy wormwood and The water that 5 times of tea quality, beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 100 DEG C, rotating speed 350r/min Under conditions of, after heating stirring boils 4h, filtering, obtain mixed liquor, mixed liquor moved into Rotary Evaporators, in temperature be 65 DEG C, Rotating speed is 180r/min, gives as security pressure under conditions of 800kPa, spin concentration 80min, to obtain mixed extract;By ginger oil and rat-tail Careless oil in mass ratio 1:5 are mixed in flask, and the black pepper oil of 0.4 times of sage oil quality is added into flask, by flask Move into digital display to test the speed constant temperature blender with magnetic force, be 85 DEG C in temperature, under conditions of rotating speed is 350r/min, be stirred 50min, Obtain mixed essential oil;By glass fibre and water in mass ratio 1:12 mixing, and add the silane coupled of 0.6 times of glass fiber quality Agent, under conditions of temperature is 90 DEG C, after mixing immersion 8h, the nano titanium oxide of 0.4 times of glass fiber quality is added, in Frequency is sonic oscillation 25min under conditions of 50kHz, filtering, obtains filter cake, filter cake is moved into drying box, in temperature be 95 DEG C Under the conditions of, 90min is dried, obtains modified glass-fiber;Count in parts by weight, weigh 45 parts of TPU successively, 5 parts of plasticizer, 4 parts anti- Old agent, 12 parts of mixed extracts, 10 parts of mixed essential oils, 6 parts of modified glass-fibers, 20 parts of polystyrene, 5 parts of ammonium sulfate, 8 parts are received Rice silver powder and 3 parts of dispersants, ammonium sulfate is added in pulverizer, crushed, crossed 160 mesh sieves, obtain ammonium sulfate powder;By TPU, plasticising Agent, age resistor, mixed extract, mixed essential oil, modified glass-fiber, polystyrene, ammonium sulfate powder, nano-silver powder and scattered Agent is added in mixer, and the water of 0.8 times of TPU mass is added into mixer, is stirred under conditions of rotating speed is 480r/min 60min is mixed, obtains mixture, mixture is moved into double screw extruder, is extruded under conditions of being 220 DEG C in temperature, obtains base Material, by blank casting film-forming, obtains keyboard protective film.The TPU is:TPUE rubber.The plasticizer is Dioctyl phthalate.The age resistor is antioxidant 4010NA.The dispersant is dispersant NNO.It is described silane coupled Agent is silane resin acceptor kh-550.
Example 2
By tealeaves and granatum in mass ratio 3:2 are mixed in beaker, and into beaker add 0.6 times of tea quality argy wormwood and The water that 5 times of tea quality, beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 100 DEG C, rotating speed 350r/min Under conditions of, after heating stirring boils 4h, filtering, obtain mixed liquor, mixed liquor moved into Rotary Evaporators, in temperature be 65 DEG C, Rotating speed is 180r/min, gives as security pressure under conditions of 800kPa, spin concentration 80min, to obtain mixed extract;By ginger oil and rat-tail Careless oil in mass ratio 1:5 are mixed in flask, and the black pepper oil of 0.4 times of sage oil quality is added into flask, by flask Move into digital display to test the speed constant temperature blender with magnetic force, be 85 DEG C in temperature, under conditions of rotating speed is 350r/min, be stirred 50min, Obtain mixed essential oil;Number meter by weight, weighs 45 parts of TPU successively, 5 parts of plasticizer, 4 parts of age resistor, 12 parts of mixed extracts, 10 parts Mixed essential oil, 6 parts of glass fibres, 20 parts of polystyrene, 5 parts of ammonium sulfate, 8 parts of nano-silver powders and 3 parts of dispersants, by ammonium sulfate plus Enter in pulverizer, crush, cross 160 mesh sieves, obtain ammonium sulfate powder;By TPU, plasticizer, age resistor, mixed extract, mixing essence Oil, glass fibre, polystyrene, ammonium sulfate powder, nano-silver powder and dispersant are added in mixer, and are added into mixer The water that 0.8 times of TPU mass, 60min is stirred under conditions of rotating speed is 480r/min, mixture is obtained, mixture is moved into In double screw extruder, extruded under conditions of being 220 DEG C in temperature, obtain blank, by blank casting film-forming, obtain keyboard protective film. The TPU is:TPUE rubber.The plasticizer is dioctyl phthalate.The age resistor is anti- Old agent 4010NA.The dispersant is dispersant NNO.The silane coupler is silane resin acceptor kh-550.
Example 3
By tealeaves and granatum in mass ratio 3:2 are mixed in beaker, and into beaker add 0.6 times of tea quality argy wormwood and The water that 5 times of tea quality, beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 100 DEG C, rotating speed 350r/min Under conditions of, after heating stirring boils 4h, filtering, obtain mixed liquor, mixed liquor moved into Rotary Evaporators, in temperature be 65 DEG C, Rotating speed is 180r/min, gives as security pressure under conditions of 800kPa, spin concentration 80min, to obtain mixed extract;By ginger oil and rat-tail Careless oil in mass ratio 1:5 are mixed in flask, and the black pepper oil of 0.4 times of sage oil quality is added into flask, by flask Move into digital display to test the speed constant temperature blender with magnetic force, be 85 DEG C in temperature, under conditions of rotating speed is 350r/min, be stirred 50min, Obtain mixed essential oil;By glass fibre and water in mass ratio 1:12 mixing, and add the silane coupled of 0.6 times of glass fiber quality Agent, under conditions of temperature is 90 DEG C, after mixing immersion 8h, the nano titanium oxide of 0.4 times of glass fiber quality is added, in Frequency is sonic oscillation 25min under conditions of 50kHz, filtering, obtains filter cake, filter cake is moved into drying box, in temperature be 95 DEG C Under the conditions of, 90min is dried, obtains modified glass-fiber;Count in parts by weight, weigh 45 parts of TPU successively, 5 parts of plasticizer, 4 parts anti- Old agent, 12 parts of mixed extracts, 10 parts of mixed essential oils, 6 parts of modified glass-fibers, 8 parts of nano-silver powders and 3 parts of dispersants, will TPU, plasticizer, age resistor, mixed extract, mixed essential oil, modified glass-fiber, nano-silver powder and dispersant add mixer In, and the water of 0.8 times of TPU mass is added into mixer, 60min is stirred under conditions of rotating speed is 480r/min, is obtained Mixture, mixture is moved into double screw extruder, extruded under conditions of being 220 DEG C in temperature, obtain blank, blank is cast Film forming, obtain keyboard protective film.The TPU is:TPUE rubber.The plasticizer is that phthalic acid two is pungent Ester.The age resistor is antioxidant 4010NA.The dispersant is dispersant NNO.The silane coupler is silane coupler KH-550。
Example 4
By tealeaves and granatum in mass ratio 3:2 are mixed in beaker, and into beaker add 0.6 times of tea quality argy wormwood and The water that 5 times of tea quality, beaker immigration digital display is tested the speed constant temperature blender with magnetic force, in temperature be 100 DEG C, rotating speed 350r/min Under conditions of, after heating stirring boils 4h, filtering, obtain mixed liquor, mixed liquor moved into Rotary Evaporators, in temperature be 65 DEG C, Rotating speed is 180r/min, gives as security pressure under conditions of 800kPa, spin concentration 80min, to obtain mixed extract;By glass fibre with Water in mass ratio 1:12 mixing, and the silane coupler of 0.6 times of glass fiber quality is added, under conditions of temperature is 90 DEG C, After mixing immersion 8h, the nano titanium oxide of 0.4 times of glass fiber quality is added, the ultrasound under conditions of frequency is 50kHz 25min is vibrated, filtering, filter cake is obtained, filter cake is moved into drying box, under conditions of temperature is 95 DEG C, 90min is dried, obtains modification Glass fibre;Count in parts by weight, weigh 45 parts of TPU successively, 5 parts of plasticizer, 4 parts of age resistor, 12 parts of mixed extracts, 6 parts Modified glass-fiber, 20 parts of polystyrene, 5 parts of ammonium sulfate, 8 parts of nano-silver powders and 3 parts of dispersants, pulverizer is added by ammonium sulfate In, crush, cross 160 mesh sieves, obtain ammonium sulfate powder;By TPU, plasticizer, age resistor, mixed extract, modified glass-fiber, gather Styrene, ammonium sulfate powder, nano-silver powder and dispersant are added in mixer, and 0.8 times of TPU mass is added into mixer Water, 60min is stirred under conditions of rotating speed is 480r/min, mixture is obtained, mixture is moved into double screw extruder, Extruded under conditions of being 220 DEG C in temperature, obtain blank, by blank casting film-forming, obtain keyboard protective film.The TPU is:Thermoplasticity Elastic polyurethane body rubber.The plasticizer is dioctyl phthalate.The age resistor is antioxidant 4010NA.Described point Powder is dispersant NNO.The silane coupler is silane resin acceptor kh-550.
Comparative example:The keyboard protective film in certain digital shop.
The gained of example 1 to 4 keyboard protective film and comparative example product are subjected to performance detection, specific detection method is as follows:
The method of sampling:20 buttons commonly used using the aseptic cotton carrier for being soaked with nertralizer to keyboard are sampled, and are inoculated with blood agar Flat board, MRSA ID and MDRAB ID flat boards, observe cultivation results after being incubated 48h in 37 DEG C of incubators and carry out bacterium colony counting, record Whether MRSA and MDRAB are detected.
Detection is divided into 3 stages, and before the 1st stage is cleaning, two all computor-keyboards of ICU are sampled;2nd stage To intervene the stage, keyboard protective film is equipped with for all computor-keyboards, and formulates the standard practice instructions of diaphragm cleaning and sterilizing, All keyboard protective films are asked to change and clean daily;3rd stage for cleaning after, replacing keyboard protective film using 3h after carry out Sampling.
Specific testing result is as shown in table 1:
Table 1
From the testing result of table 1, present invention gained keyboard protective film has good antibiotic property.

Claims (5)

  1. A kind of 1. keyboard protective film, it is characterised in that:It is made up of the raw material of following parts by weight:
    35~45 parts of TPU
    3~5 parts of plasticizer
    2~4 parts of age resistor
    8~12 parts of mixed extract
    5~10 parts of mixed essential oil
    4~6 parts of modified glass-fiber
    15~20 parts of polystyrene
    2~5 parts of ammonium sulfate
    1~3 part of dispersant
    5~8 parts of nano-silver powder
    The TPU is:TPUE rubber;
    The preparation method of the mixed extract:
    By tealeaves and granatum in mass ratio 3:1~3:2 mixing, and add argy wormwood and the tealeaves matter of 0.5~0.6 times of tea quality 2~4h is boiled in the water of 4~5 times of amount, heating, filters, and concentration, obtains mixed extract;
    The preparation method of the mixed essential oil is:
    By ginger oil and sage oil in mass ratio 1:2~1:5 mixing, and add the black pepper of 0.3~0.4 times of sage oil quality Oil, after being stirred, obtain mixed essential oil;
    The preparation method of the modified glass-fiber is:
    By glass fibre and water in mass ratio 1:8~1:12 mixing, and the silane for adding 0.4~0.6 times of glass fiber quality is even Join agent, after being stirred, add the nano titanium oxide of 0.2~0.4 times of glass fiber quality, sonic oscillation, filter, dry, Obtain modified glass-fiber;
    The preparation method of the keyboard protective film is:
    (1)Formed by raw material and weigh each component;
    (2)Ammonium sulfate is crushed, sieves, obtains ammonium sulfate powder, by TPU, plasticizer, age resistor, mixed extract, mixing essence Oil, modified glass-fiber, polystyrene, ammonium sulfate powder, nano-silver powder and dispersant are added in mixer, and into mixer The water of 0.5~0.8 times of TPU mass is added, after being stirred, mixture is obtained, mixture is extruded in double screw extruder, obtained Blank, by blank casting film-forming, obtain keyboard protective film.
  2. A kind of 2. keyboard protective film according to claim 1, it is characterised in that:The plasticizer is that phthalic acid two is pungent Any one in ester, di-n-octyl phthalate or dicyclohexyl phthalate.
  3. A kind of 3. keyboard protective film according to claim 1, it is characterised in that:The age resistor is antioxidant 4010NA, The mixture of any one or a few in antioxidant 264 or antioxidant 4010.
  4. A kind of 4. keyboard protective film according to claim 1, it is characterised in that:The dispersant is dispersant NNO, is disperseed Any one in agent 5040 or Dispersant MF.
  5. A kind of 5. keyboard protective film according to claim 1, it is characterised in that:The silane coupler is silane coupler Any one in KH-550, silane coupler KH-560 or Silane coupling reagent KH-570.
CN201711113628.2A 2017-11-13 2017-11-13 A kind of keyboard protective film Pending CN107880525A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109082101A (en) * 2018-07-03 2018-12-25 阜南县创发工艺品有限公司 A kind of high-intensitive Artificial board for braiding
CN109825061A (en) * 2019-01-08 2019-05-31 苏州市奥贝膜业有限公司 A kind of Mobile phone film and preparation method thereof with antistatic effect

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201824604U (en) * 2010-09-17 2011-05-11 杨玉兵 Novel protective membrane for notebook computers
CN103838382A (en) * 2012-11-22 2014-06-04 刘逸婷 Novel computer keyboard film
CN105238020A (en) * 2015-09-18 2016-01-13 滁州市莎朗新材料科技有限公司 Antibiotic and flame-retardant plant type soft polyurethane foam for seamless wallpaper, and preparation method thereof
CN105315553A (en) * 2015-11-04 2016-02-10 桐城市人和包装有限公司 Antibacterial and antistatic tear-resistant thin-film material
CN106046477A (en) * 2016-06-03 2016-10-26 苏州市奎克力电子科技有限公司 Antibacterial protection film for electronic product and preparing method of antibacterial protection film
CN106221538A (en) * 2016-08-24 2016-12-14 江苏大学 A kind of preparation method and application of modified aqueous polyurethane antibacterial film
CN107033376A (en) * 2016-11-23 2017-08-11 广东聚航新材料研究院有限公司 A kind of antimicrobial form TPU is cast membrane preparation method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201824604U (en) * 2010-09-17 2011-05-11 杨玉兵 Novel protective membrane for notebook computers
CN103838382A (en) * 2012-11-22 2014-06-04 刘逸婷 Novel computer keyboard film
CN105238020A (en) * 2015-09-18 2016-01-13 滁州市莎朗新材料科技有限公司 Antibiotic and flame-retardant plant type soft polyurethane foam for seamless wallpaper, and preparation method thereof
CN105315553A (en) * 2015-11-04 2016-02-10 桐城市人和包装有限公司 Antibacterial and antistatic tear-resistant thin-film material
CN106046477A (en) * 2016-06-03 2016-10-26 苏州市奎克力电子科技有限公司 Antibacterial protection film for electronic product and preparing method of antibacterial protection film
CN106221538A (en) * 2016-08-24 2016-12-14 江苏大学 A kind of preparation method and application of modified aqueous polyurethane antibacterial film
CN107033376A (en) * 2016-11-23 2017-08-11 广东聚航新材料研究院有限公司 A kind of antimicrobial form TPU is cast membrane preparation method

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
何公霖: "《建筑装饰工程材料与构造》", 28 February 2017, 重庆大学出版社 *
吴人洁: "《复合材料》", 31 December 2000, 天津大学出版社 *
屈华昌: "《塑料成型工艺与模具设计》", 31 October 1995, 机械工业出版社 *
张东兴: "《聚合物基复合材料科学与工程》", 31 July 2017, 化学工业出版社 *
张袁松: "《新型纤维材料概论》", 31 March 2012, 西南师范大学出版社 *
胡正海: "《药用植物的结构、发育与药用成分的关系》", 31 October 2014, 上海科学技术出版社 *
骆光林: "《包装材料学》", 31 August 2011, 印刷工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109082101A (en) * 2018-07-03 2018-12-25 阜南县创发工艺品有限公司 A kind of high-intensitive Artificial board for braiding
CN109082101B (en) * 2018-07-03 2020-11-27 阜南县创发工艺品有限公司 High-strength artificial wood board for weaving and preparation method thereof
CN109825061A (en) * 2019-01-08 2019-05-31 苏州市奥贝膜业有限公司 A kind of Mobile phone film and preparation method thereof with antistatic effect

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