CN105820477A - Composite anti-corrosive and anti-static plastic - Google Patents

Composite anti-corrosive and anti-static plastic Download PDF

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Publication number
CN105820477A
CN105820477A CN201610345325.2A CN201610345325A CN105820477A CN 105820477 A CN105820477 A CN 105820477A CN 201610345325 A CN201610345325 A CN 201610345325A CN 105820477 A CN105820477 A CN 105820477A
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China
Prior art keywords
accounts
parts
agent
corrosive
antistatic
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201610345325.2A
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Chinese (zh)
Inventor
陆华平
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Suzhou New District Teflon Plastic Products Factory
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Suzhou New District Teflon Plastic Products Factory
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Priority to CN201610345325.2A priority Critical patent/CN105820477A/en
Publication of CN105820477A publication Critical patent/CN105820477A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552—Fatigue strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses composite anti-corrosive and anti-static plastic which comprises an anti-corrosive layer as a surface layer and an anti-static layer as an inner layer .The anti-corrosive layer is made from polyvinyl chloride, an antioxidant, an anti-corrosive agent, a filling agent and a toughening agent .The anti-static layer is made from polyethylene, an antistatic agent, a plasticizer, a dispersing agent and a reinforcing agent .The antioxidant is 2-hydroxy-4-n-octyloxybenzophenone .The anti-corrosive agent is sorbitan monooleate .The filling agent is kaolin .The toughening agent is polyvinyl butyral .The antistatic agent is alkyl sodium sulfonate .The plasticizer is triethyl citrate .The dispersing agent is triethylhexyl phosphoric acid .The reinforcing agent is talcum powder .By arranging a double-layer composite structure, the anti-corrosive and anti-aging effects can be effectively achieved, the internal structure is safe and resistant to static electricity, wrapping is complete, and the use effect is good.

Description

A kind of composite anti-corrosive antistatic plastic
Technical field
The present invention relates to a kind of plastic applications, be specifically related to a kind of composite anti-corrosive antistatic plastic.
Background technology
Cable cover(ing) is the outermost layer of cable, if VV is polyvinyl chloride insulation, and pvc sheath.Outside wear to cry protection manage.The sheath used in prior art is mostly single layer structure, uses function the most single, it is impossible to fully effective plays protected effect.
Summary of the invention
It is an object of the invention to provide and a kind of arrange by two-layer composite, not only can effectively play the age inhibiting effect of anticorrosion, and the safe antistatic of internal structure, cladding is complete, the composite anti-corrosive antistatic plastic that using effect is good.
nullThe technical scheme is that，A kind of composite anti-corrosive antistatic plastic，Corrosion-resistant coating and the antistatic backing of internal layer including top layer，Described corrosion-resistant coating is by polrvinyl chloride、Antioxidant、Corrosion-resistant agent、Filler and toughener composition，Described antioxidant is Octabenzone，Described corrosion-resistant agent is sorbitan monooleate，Described filler is Kaolin，Described toughener is polyvinyl butyral resin，Parts by weight shared by each composition of described corrosion-resistant coating are respectively as follows: described polrvinyl chloride and account for 57-63 part，Described Octabenzone accounts for 10-15 part，Described sorbitan monooleate accounts for 14-18 part，Described Kaolin accounts for 42-46 part，Described polyvinyl butyral resin accounts for 23-27 part，Described antistatic backing is by polyethylene、Antistatic additive、Plasticiser、Dispersant and reinforcing agent composition，Described antistatic additive is sodium alkyl sulfonate，Described plasticiser is triethyl citrate，Described dispersant is triethyl group hexyl phosphoric acid，Described reinforcing agent is Pulvis Talci，Parts by weight shared by each composition of described antistatic backing are respectively as follows: described polyethylene and account for 48-52 part，Described sodium alkyl sulfonate accounts for 9-14 part，Described triethyl citrate accounts for 5-10 part，Described triethyl group hexyl phosphoric acid accounts for 7-11 part，Described Pulvis Talci accounts for 31-36 part.
In a preferred embodiment of the present invention, parts by weight shared by each composition of described corrosion-resistant coating are particularly as follows: described polrvinyl chloride accounts for 58 parts, described Octabenzone accounts for 11 parts, and described sorbitan monooleate accounts for 15 parts, and described Kaolin accounts for 43 parts；Described polyvinyl butyral resin accounts for 24 parts.
In a preferred embodiment of the present invention, parts by weight shared by each composition of described antistatic backing are particularly as follows: described polyethylene accounts for 49 parts, and described sodium alkyl sulfonate accounts for 10 parts, and described triethyl citrate accounts for 6 parts, described triethyl group hexyl phosphoric acid accounts for 8 parts, and described Pulvis Talci accounts for 32 parts.
Of the present invention is a kind of composite anti-corrosive antistatic plastic, is arranged by two-layer composite, not only can effectively play the age inhibiting effect of anticorrosion, and the safe antistatic of internal structure, completely, using effect is good for cladding.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
nullOf the present invention is a kind of composite anti-corrosive antistatic plastic，Corrosion-resistant coating and the antistatic backing of internal layer including top layer，Described corrosion-resistant coating is by polrvinyl chloride、Antioxidant、Corrosion-resistant agent、Filler and toughener composition，Described antioxidant is Octabenzone，Described corrosion-resistant agent is sorbitan monooleate，Described filler is Kaolin，Described toughener is polyvinyl butyral resin，Parts by weight shared by each composition of described corrosion-resistant coating are respectively as follows: described polrvinyl chloride and account for 57-63 part，Described Octabenzone accounts for 10-15 part，Described sorbitan monooleate accounts for 14-18 part，Described Kaolin accounts for 42-46 part，Described polyvinyl butyral resin accounts for 23-27 part，Described antistatic backing is by polyethylene、Antistatic additive、Plasticiser、Dispersant and reinforcing agent composition，Described antistatic additive is sodium alkyl sulfonate，Described plasticiser is triethyl citrate，Described dispersant is triethyl group hexyl phosphoric acid，Described reinforcing agent is Pulvis Talci，Parts by weight shared by each composition of described antistatic backing are respectively as follows: described polyethylene and account for 48-52 part，Described sodium alkyl sulfonate accounts for 9-14 part，Described triethyl citrate accounts for 5-10 part，Described triethyl group hexyl phosphoric acid accounts for 7-11 part，Described Pulvis Talci accounts for 31-36 part.
Further, parts by weight shared by each composition of described corrosion-resistant coating are particularly as follows: described polrvinyl chloride accounts for 58 parts, and described Octabenzone accounts for 11 parts, and described sorbitan monooleate accounts for 15 parts, and described Kaolin accounts for 43 parts；Described polyvinyl butyral resin accounts for 24 parts.
Further, parts by weight shared by each composition of described antistatic backing are particularly as follows: described polyethylene accounts for 49 parts, and described sodium alkyl sulfonate accounts for 10 parts, and described triethyl citrate accounts for 6 parts, and described triethyl group hexyl phosphoric acid accounts for 8 parts, and described Pulvis Talci accounts for 32 parts.
Further, parts by weight shared by each composition of described corrosion-resistant coating are respectively as follows: described polrvinyl chloride and account for 62 parts, and described Octabenzone accounts for 14 parts, and described sorbitan monooleate accounts for 17 parts, and described Kaolin accounts for 45 parts；Described polyvinyl butyral resin accounts for 26 parts.
Further, parts by weight shared by each composition of described antistatic backing are respectively as follows: described polyethylene and account for 48-52 part, and described sodium alkyl sulfonate accounts for 13 parts, and described triethyl citrate accounts for 9 parts, and described triethyl group hexyl phosphoric acid accounts for 10 parts, and described Pulvis Talci accounts for 35 parts.
It addition, can be by regulating the Different Weight number of each composition of product so that the properties of product height obtained differs.
Of the present invention is a kind of composite anti-corrosive antistatic plastic, is arranged by two-layer composite, not only can effectively play the age inhibiting effect of anticorrosion, and the safe antistatic of internal structure, completely, using effect is good for cladding.
The foregoing is only the detailed description of the invention of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope that disclosed herein; the change can expected without creative work or replacement, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims are limited.

Claims (3)

  1. null1. a composite anti-corrosive antistatic plastic，Corrosion-resistant coating and the antistatic backing of internal layer including top layer，It is characterized in that: described corrosion-resistant coating is by polrvinyl chloride、Antioxidant、Corrosion-resistant agent、Filler and toughener composition，Described antioxidant is Octabenzone，Described corrosion-resistant agent is sorbitan monooleate，Described filler is Kaolin，Described toughener is polyvinyl butyral resin，Parts by weight shared by each composition of described corrosion-resistant coating are respectively as follows: described polrvinyl chloride and account for 57-63 part，Described Octabenzone accounts for 10-15 part，Described sorbitan monooleate accounts for 14-18 part，Described Kaolin accounts for 42-46 part，Described polyvinyl butyral resin accounts for 23-27 part，Described antistatic backing is by polyethylene、Antistatic additive、Plasticiser、Dispersant and reinforcing agent composition，Described antistatic additive is sodium alkyl sulfonate，Described plasticiser is triethyl citrate，Described dispersant is triethyl group hexyl phosphoric acid，Described reinforcing agent is Pulvis Talci，Parts by weight shared by each composition of described antistatic backing are respectively as follows: described polyethylene and account for 48-52 part，Described sodium alkyl sulfonate accounts for 9-14 part，Described triethyl citrate accounts for 5-10 part，Described triethyl group hexyl phosphoric acid accounts for 7-11 part，Described Pulvis Talci accounts for 31-36 part.
  2. Composite anti-corrosive antistatic plastic the most according to claim 1, it is characterized in that: parts by weight shared by each composition of described corrosion-resistant coating are particularly as follows: described polrvinyl chloride accounts for 58 parts, described Octabenzone accounts for 11 parts, described sorbitan monooleate accounts for 15 parts, and described Kaolin accounts for 43 parts；Described polyvinyl butyral resin accounts for 24 parts.
  3. Composite anti-corrosive antistatic plastic the most according to claim 1, it is characterized in that: parts by weight shared by each composition of described antistatic backing are particularly as follows: described polyethylene accounts for 49 parts, described sodium alkyl sulfonate accounts for 10 parts, described triethyl citrate accounts for 6 parts, described triethyl group hexyl phosphoric acid accounts for 8 parts, and described Pulvis Talci accounts for 32 parts.
CN201610345325.2A 2016-05-24 2016-05-24 Composite anti-corrosive and anti-static plastic Pending CN105820477A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108003424A (en) * 2017-04-20 2018-05-08 安徽助成信息科技有限公司 A kind of waterproof and anticorrosion composite material
CN108192243A (en) * 2018-01-26 2018-06-22 福建宏翔塑胶有限公司 A kind of PVC shield card basement membranes and its preparation process

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423641A (en) * 2007-11-02 2009-05-06 上海国成塑料有限公司 Rigid PVC co-extrusion wood-like outdoor furniture section steel and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101423641A (en) * 2007-11-02 2009-05-06 上海国成塑料有限公司 Rigid PVC co-extrusion wood-like outdoor furniture section steel and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108003424A (en) * 2017-04-20 2018-05-08 安徽助成信息科技有限公司 A kind of waterproof and anticorrosion composite material
CN108192243A (en) * 2018-01-26 2018-06-22 福建宏翔塑胶有限公司 A kind of PVC shield card basement membranes and its preparation process

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Application publication date: 20160803