CN106221050A - A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable - Google Patents

A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable Download PDF

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Publication number
CN106221050A
CN106221050A CN201610668162.1A CN201610668162A CN106221050A CN 106221050 A CN106221050 A CN 106221050A CN 201610668162 A CN201610668162 A CN 201610668162A CN 106221050 A CN106221050 A CN 106221050A
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parts
rubber
antioxidant
temperature resistant
resin
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CN201610668162.1A
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吴显峰
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
    • C08L23/34—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

nullThe invention discloses a kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable，Including cable core and restrictive coating，Wherein restrictive coating raw material includes by weight: natural rubber 5 15，CSM 30 60，Butyl rubber 10 18，Chlorohydrin rubber 12 22，Silicone rubber 5 12，Accelerator TTEE 0.5 1.5，Accelerant N a 22 12，Sulfur 12，Vulcanizing agent HTDM 12，Tributyl citrate 0.5 1.6，Epoxy soybean oil 1 1.8，Disproportionated rosin 13，Coumarone indene resin 12，Antioxidant MB Z 0.2 1.2，Antioxidant A W 12，Antioxidant D NP 12，Hexamethoxymethyl melamine resin 0.5 1.2，Zirconium oxide 12，Blanc fixe 0.2 0.8，Graphene nanometer sheet 10 20，Silicon carbide micro-powder 5 15，Glass microballoon 10 20，RF 90 resin 12.

Description

A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable
Technical field
The present invention relates to field of cable technology, particularly relate to a kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable.
Background technology
Coal mine moving cable is that the MT818 issued according to State Administration of Quality and Technical Supervision carries out producing, main The power supply of ore deposit to be used for underground moving coal excavation apparatus connects, and the occasion that coal mine moving cable uses now gets more and more, more Come the widest.But coal mine moving cable is mainly common cable at present, can not use, the most also must in hot environment Must meet cable and have fire-resistant, the wear-resisting and requirement of tension, current common cable also cannot meet its demand.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of combined wear-resistant tensile of fireproof high-temperature resistant and moves Galvanic electricity cable, has high temperature resistant, wear-resisting, the tensile property of excellence, and fire resistance and good mechanical properties is good, and it is right to can be applicable to Fireproof high-temperature resistant requires more harsh occasion, halogen-free environmental simultaneously.
A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable that the present invention proposes, including cable core and restrictive coating, its Middle restrictive coating raw material includes by weight: natural rubber 5-15 part, CSM 30-60 part, butyl rubber 10-18 Part, chlorohydrin rubber 12-22 part, silicone rubber 5-12 part, accelerator TTEE 0.5-1.5 part, accelerant N a-22 1-2 part, sulfur 1- 2 parts, vulcanizing agent HTDM 1-2 part, tributyl citrate 0.5-1.6 part, epoxy soybean oil 1-1.8 part, disproportionated rosin 1-3 part is ancient Horse grand resin 1-2 part, antioxidant MB Z 0.2-1.2 part, antioxidant A W 1-2 part, antioxidant D NP 1-2 part, hexakis-methoxy methyl three Cymel 0.5-1.2 part, zirconium oxide 1-2 part, blanc fixe 0.2-0.8 part, graphene nanometer sheet 10-20 part, carborundum Micropowder 5-15 part, glass microballoon 10-20 part, RF-90 resin 1-2 part.
Preferably, in restrictive coating raw material, natural rubber, CSM, butyl rubber, chlorohydrin rubber, silicon rubber The weight ratio of glue is 8-12:40-50:12-16:14-20:6-10.
Preferably, in restrictive coating raw material, accelerator TTEE, accelerant N a-22, sulfur, the weight ratio of vulcanizing agent HTDM are 0.8-1.2:1.3-1.7:1.5-1.8:1.2-1.4.
Preferably, in restrictive coating raw material, tributyl citrate, epoxy soybean oil, disproportionated rosin, the weight of coumarone indene resin Ratio is 0.7-1.4:1.2-1.6:1.5-2.5:1.5-1.7.
Preferably, in restrictive coating raw material, zirconium oxide, blanc fixe, graphene nanometer sheet, silicon carbide micro-powder, glass microballoon Weight ratio be 1.4-1.6:0.4-0.6:14-18:3-10:17-19.
Preferably, restrictive coating raw material includes by weight: natural rubber 8-12 part, CSM 40-50 part, Butyl rubber 12-16 part, chlorohydrin rubber 14-20 part, silicone rubber 6-10 part, accelerator TTEE0.8-1.2 part, accelerant N a-22 1.3-1.7 part, sulfur 1.5-1.8 part, vulcanizing agent HTDM 1.2-1.4 part, tributyl citrate 0.7-1.4 part, epoxy soybean oil 1.2-1.6 part, disproportionated rosin 1.5-2.5 part, coumarone indene resin 1.5-1.7 part, antioxidant MB Z 0.4-1 part, antioxidant A W 1.3-1.6 part, antioxidant D NP 1.4-1.8 part, hexamethoxymethyl melamine resin 0.7-1 part, zirconium oxide 1.4-1.6 part, Blanc fixe 0.4-0.6 part, graphene nanometer sheet 14-18 part, silicon carbide micro-powder 3-10 part, glass microballoon 17-19 part, RF-90 Resin 1.1-1.3 part.
The present invention uses natural rubber, CSM, butyl rubber, chlorohydrin rubber and silicone rubber to be base material, Using sulfur, vulcanizing agent HTDM as vulcanizing agent, coordinate interpolation accelerator TTEE and accelerant N a-22 to carry out helping sulfuration, make this Bright high temperature resistant, wear-resisting, tension, and there is the most fire-resistant and mechanical property；Add tributyl citrate, epoxy soybean oil, Disproportionated rosin and coumarone indene resin carry out mating reaction, and not only storeroom compatibility is good, good processability, simultaneously fireproof high-temperature resistant And tensile property is the most excellent；Add silicon carbide micro-powder, graphene nanometer sheet, blanc fixe and glass microballoon further to assist Same-action, makes the present invention the most cheap, and wearability is good, and can be applicable to the field more harsh to fireproof high-temperature resistant requirement Closing, halogen-free environmental simultaneously, overall mix homogeneously, organic with other high with the combination degree of inorganic material, pull resistance is good, and it is fire-resistant And mechanical property further enhances.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable that the present invention proposes, including cable core and restrictive coating, its Middle restrictive coating raw material includes by weight: natural rubber 5 parts, CSM 60 parts, butyl rubber 10 parts, chloropharin rubber 22 parts of glue, 5 parts of silicone rubber, accelerator TTEE 1.5 parts, accelerant N a-221 part, 2 parts of sulfur, vulcanizing agent HTDM 1 part, Fructus Citri Limoniae Acid tributyl 1.6 parts, epoxy soybean oil 1 part, disproportionated rosin 3 parts, coumarone indene resin 1 part, antioxidant MB Z 1.2 parts, age resistor AW 1 part, antioxidant D NP 2 parts, hexamethoxymethyl melamine resin 0.5 part, zirconium oxide 2 parts, blanc fixe 0.2 part, graphite Alkene nanometer sheet 20 parts, silicon carbide micro-powder 5 parts, glass microballoon 20 parts, RF-90 resin 1 part.
Embodiment 2
A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable that the present invention proposes, including cable core and restrictive coating, its Middle restrictive coating raw material includes by weight: natural rubber 15 parts, CSM 30 parts, butyl rubber 18 parts, chloropharin Rubber 12 parts, 12 parts of silicone rubber, accelerator TTEE 0.5 part, accelerant N a-22 2 parts, 1 part of sulfur, vulcanizing agent HTDM 2 parts, Tributyl citrate 0.5 part, epoxy soybean oil 1.8 parts, disproportionated rosin 1 part, coumarone indene resin 2 parts, antioxidant MB Z 0.2 part, Antioxidant A W 2 parts, antioxidant D NP 1 part, hexamethoxymethyl melamine resin 1.2 parts, zirconium oxide 1 part, blanc fixe 0.8 Part, graphene nanometer sheet 10 parts, silicon carbide micro-powder 15 parts, glass microballoon 10 parts, RF-90 resin 2 parts.
Embodiment 3
A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable that the present invention proposes, including cable core and restrictive coating, its Middle restrictive coating raw material includes by weight: natural rubber 8 parts, CSM 50 parts, butyl rubber 12 parts, chloropharin rubber 20 parts of glue, 6 parts of silicone rubber, accelerator TTEE 1.2 parts, accelerant N a-221.3 part, 1.8 parts of sulfur, vulcanizing agent HTDM 1.2 Part, tributyl citrate 1.4 parts, epoxy soybean oil 1.2 parts, disproportionated rosin 2.5 parts, coumarone indene resin 1.5 parts, antioxidant MB Z 1 part, antioxidant A W 1.3 parts, antioxidant D NP 1.8 parts, hexamethoxymethyl melamine resin 0.7 part, zirconium oxide 1.6 parts, weight 0.4 part of spar powder, graphene nanometer sheet 18 parts, silicon carbide micro-powder 3 parts, glass microballoon 19 parts, RF-90 resin 1.1 parts.
Embodiment 4
A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable that the present invention proposes, including cable core and restrictive coating, its Middle restrictive coating raw material includes by weight: natural rubber 12 parts, CSM 40 parts, butyl rubber 16 parts, chloropharin Rubber 14 parts, 10 parts of silicone rubber, accelerator TTEE 0.8 part, accelerant N a-22 1.7 parts, 1.5 parts of sulfur, vulcanizing agent HTDM 1.4 parts, tributyl citrate 0.7 part, epoxy soybean oil 1.6 parts, disproportionated rosin 1.5 parts, coumarone indene resin 1.7 parts, age resistor MBZ 0.4 part, antioxidant A W 1.6 parts, antioxidant D NP 1.4 parts, hexamethoxymethyl melamine resin 1 part, zirconium oxide 1.4 Part, blanc fixe 0.6 part, graphene nanometer sheet 14 parts, silicon carbide micro-powder 10 parts, glass microballoon 17 parts, RF-90 resin 1.3 parts.
Embodiment 5
A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable that the present invention proposes, including cable core and restrictive coating, its Middle restrictive coating raw material includes by weight: natural rubber 10 parts, CSM 45 parts, butyl rubber 14 parts, chloropharin Rubber 17 parts, 8 parts of silicone rubber, accelerator TTEE 1 part, accelerant N a-221.5 part, 1.6 parts of sulfur, vulcanizing agent HTDM 1.3 Part, tributyl citrate 1 part, epoxy soybean oil 1.4 parts, disproportionated rosin 2 parts, coumarone indene resin 1.6 parts, antioxidant MB Z 0.7 Part, antioxidant A W 1.5 parts, antioxidant D NP 1.6 parts, hexamethoxymethyl melamine resin 0.8 part, zirconium oxide 1.5 parts, weight 0.5 part of spar powder, graphene nanometer sheet 16 parts, silicon carbide micro-powder 7 parts, glass microballoon 18 parts, RF-90 resin 1.2 parts.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (6)

1. a fireproof high-temperature resistant combined wear-resistant tensile removal cable, it is characterised in that include cable core and restrictive coating, Qi Zhonghu Jacket layer raw material includes by weight: natural rubber 5-15 part, CSM 30-60 part, butyl rubber 10-18 part, Chlorohydrin rubber 12-22 part, silicone rubber 5-12 part, accelerator TTEE 0.5-1.5 part, accelerant N a-22 1-2 part, sulfur 1-2 Part, vulcanizing agent HTDM 1-2 part, tributyl citrate 0.5-1.6 part, epoxy soybean oil 1-1.8 part, disproportionated rosin 1-3 part is ancient Horse grand resin 1-2 part, antioxidant MB Z 0.2-1.2 part, antioxidant A W 1-2 part, antioxidant D NP 1-2 part, hexakis-methoxy methyl three Cymel 0.5-1.2 part, zirconium oxide 1-2 part, blanc fixe 0.2-0.8 part, graphene nanometer sheet 10-20 part, carborundum Micropowder 5-15 part, glass microballoon 10-20 part, RF-90 resin 1-2 part.
Fireproof high-temperature resistant combined wear-resistant tensile removal cable the most according to claim 1, it is characterised in that restrictive coating raw material In, natural rubber, CSM, butyl rubber, chlorohydrin rubber, the weight ratio of silicone rubber are 8-12:40-50:12- 16:14-20:6-10.
Fireproof high-temperature resistant the most according to claim 1 or claim 2 combined wear-resistant tensile removal cable, it is characterised in that restrictive coating In raw material, accelerator TTEE, accelerant N a-22, sulfur, the weight ratio of vulcanizing agent HTDM are 0.8-1.2:1.3-1.7:1.5- 1.8:1.2-1.4.
4. according to fireproof high-temperature resistant combined wear-resistant tensile removal cable described in any one of claim 1-3, it is characterised in that protect In jacket layer raw material, tributyl citrate, epoxy soybean oil, disproportionated rosin, the weight ratio of coumarone indene resin are 0.7-1.4:1.2- 1.6:1.5-2.5:1.5-1.7.
5. according to fireproof high-temperature resistant combined wear-resistant tensile removal cable described in any one of claim 1-4, it is characterised in that protect In jacket layer raw material, zirconium oxide, blanc fixe, graphene nanometer sheet, silicon carbide micro-powder, the weight ratio of glass microballoon are 1.4-1.6: 0.4-0.6:14-18:3-10:17-19.
6. according to fireproof high-temperature resistant combined wear-resistant tensile removal cable described in any one of claim 1-5, it is characterised in that protect Jacket layer raw material includes by weight: natural rubber 8-12 part, CSM 40-50 part, butyl rubber 12-16 part, Chlorohydrin rubber 14-20 part, silicone rubber 6-10 part, accelerator TTEE 0.8-1.2 part, accelerant N a-22 1.3-1.7 part, sulfur 1.5-1.8 part, vulcanizing agent HTDM 1.2-1.4 part, tributyl citrate 0.7-1.4 part, epoxy soybean oil 1.2-1.6 part, disproportionation Colophonium 1.5-2.5 part, coumarone indene resin 1.5-1.7 part, antioxidant MB Z 0.4-1 part, antioxidant A W 1.3-1.6 part, age resistor DNP 1.4-1.8 part, hexamethoxymethyl melamine resin 0.7-1 part, zirconium oxide 1.4-1.6 part, blanc fixe 0.4-0.6 Part, graphene nanometer sheet 14-18 part, silicon carbide micro-powder 3-10 part, glass microballoon 17-19 part, RF-90 resin 1.1-1.3 part.
CN201610668162.1A 2016-08-15 2016-08-15 A kind of fireproof high-temperature resistant combined wear-resistant tensile removal cable Pending CN106221050A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107778873A (en) * 2017-10-31 2018-03-09 定远县保尔工贸有限公司 A kind of good charger baby rubber sheath preparation method of thermal conductivity
CN108192317A (en) * 2017-11-28 2018-06-22 安徽华源电缆集团有限公司 A kind of waterproof corrosion type cable material
CN111403094A (en) * 2020-04-29 2020-07-10 国网河南省电力公司内乡县供电公司 Enhanced cable
CN111524654A (en) * 2020-04-29 2020-08-11 国网河南省电力公司内乡县供电公司 Preparation method of enhanced cable

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417668A (en) * 2011-11-15 2012-04-18 中天科技装备电缆有限公司 Cable sheath material for wind power generation and production method thereof
CN103059425A (en) * 2011-10-24 2013-04-24 远东电缆有限公司 Protective jacket rubber for marine cable
CN104817843A (en) * 2015-04-26 2015-08-05 青岛康泰鑫环保科技有限公司 Ageing-resistant cable rubber
CN105175835A (en) * 2015-09-22 2015-12-23 晋源电气集团股份有限公司 High-performance fire-retardant computer cable

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103059425A (en) * 2011-10-24 2013-04-24 远东电缆有限公司 Protective jacket rubber for marine cable
CN102417668A (en) * 2011-11-15 2012-04-18 中天科技装备电缆有限公司 Cable sheath material for wind power generation and production method thereof
CN104817843A (en) * 2015-04-26 2015-08-05 青岛康泰鑫环保科技有限公司 Ageing-resistant cable rubber
CN105175835A (en) * 2015-09-22 2015-12-23 晋源电气集团股份有限公司 High-performance fire-retardant computer cable

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107778873A (en) * 2017-10-31 2018-03-09 定远县保尔工贸有限公司 A kind of good charger baby rubber sheath preparation method of thermal conductivity
CN108192317A (en) * 2017-11-28 2018-06-22 安徽华源电缆集团有限公司 A kind of waterproof corrosion type cable material
CN111403094A (en) * 2020-04-29 2020-07-10 国网河南省电力公司内乡县供电公司 Enhanced cable
CN111524654A (en) * 2020-04-29 2020-08-11 国网河南省电力公司内乡县供电公司 Preparation method of enhanced cable
CN111524654B (en) * 2020-04-29 2022-03-01 国网河南省电力公司内乡县供电公司 Preparation method of enhanced cable

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Application publication date: 20161214