CN105860157A - Abrasion-resistant rubber for vehicles - Google Patents
Abrasion-resistant rubber for vehicles Download PDFInfo
- Publication number
- CN105860157A CN105860157A CN201610270698.8A CN201610270698A CN105860157A CN 105860157 A CN105860157 A CN 105860157A CN 201610270698 A CN201610270698 A CN 201610270698A CN 105860157 A CN105860157 A CN 105860157A
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- rubber
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- agent
- stearic acid
- powder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an abrasion-resistant rubber for vehicles. The abrasion-resistant rubber for vehicles is composed of the following components in parts by weight: 60-90 parts of natural rubber, 20-30 parts of styrene-butadiene rubber, 20-30 parts of cis-1,4-polybutadiene rubber, 40-140 parts of epichlorohydrin rubber, 20-60 parts of silicon rubber, 30-70 parts of polyurethane rubber, 10-40 parts of ethylene-propylene rubber, 3-5 parts of aromatic oil, 1-3 parts of stearic acid, 1-2 parts of coupling agent, 2-8 parts of calcium carbonate, 10-30 parts of fluororubber powder, 1-4 parts of zinc oxide, 3-4 parts of stearic acid, 6-7 parts of rubber protective agent, 5-10 parts of abrasion-resistance reinforcing agent, 5-10 parts of magnetic powder, 1-4 parts of softening agent, 0.5-1 part of accelerator and 4-6 parts of sulfur. The abrasion-resistant rubber can obtain excellent abrasion resistance effects, and has favorable wear resistance and heat resistance.
Description
Technical field
The present invention relates to abrasive rubber production field, a kind of new and effective automobile-used wear-resisting
Rubber and production method.
Background technology
Rubber industry is one of important foundation industry of national economy.It not only provides day for people
The light industry rubber product such as daily, medical that often life is indispensable, and to digging, traffic,
The heavy industry such as building, machinery, electronics and new industry provide various rubber systems to produce equipment or rubber
Glue component.Visible, the product category of rubber industry is various, and backward industry is the most wide.
In prior art, it is used for manufacturing automobile rubber, generally selects natural rubber, due to sky
So reason of rubber self chemical constitution, its resistance to oxidation anti-wear performance is poor, thus have impact on vapour
Car rubber physical and mechanical properties and service life.Accordingly, it would be desirable on the basis of prior art
On existing elastomeric material is made improvements, improve its oxidation resistent susceptibility, thus improve automobile rubber
The service life of glue goods.The rubber one that wearability is good, the anti-ageing property of excellent heat resistance, oxytolerant is good
Directly being devoted to the pursuit to rubber, the production method of current rubber is a lot, makes rubber production reduce
Cost, raising performance, simplification operation, will continue the focus being to study.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of automobile-used abrasive rubber and system thereof
Preparation Method.
The present invention solves that the technical scheme that above-mentioned technical problem uses is:
A kind of automobile-used abrasive rubber, described abrasive rubber component by weight is: natural rubber
60-90 part, butadiene-styrene rubber 20-30 part, butadiene rubber 20-30 part, chlorohydrin rubber 40-140
Part, silicone rubber 20-60 part, polyurethane rubber 30-70 part, EP rubbers 10-40 part,
Polyacrylamide 15-25 part, vinyl polysiloxane 25-35 part, aromatic naphtha 3-5 part is stearic
Acid 1-3 part, coupling agent 1-2 part, calcium carbonate 2-8 part, fluorubber powder 10-30 part,
Zinc oxide 1-4 part, stearic acid 3-4 part, rubber protecting agent 6-7 part, wear-resisting reinforcing agent 5-10
Part, Magnaglo 5-10 part, softening agent 1-4 part, accelerator 0.5-1 part, sulfur 4-6
Part, age resistor 1-5 part, potter's clay 2-12 part, white carbon 1-5 part, antiscorching agent 2-3 part,
Lactoprene powder 2-4 part, 2-mercapto imidazoline 1-2 part, plasticizer 1-10
Part, softening agent 3-10 part.
Further, the preparation method step of described abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia
Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C,
Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard
Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C
Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented
Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal
Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften
Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h,
To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give
Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is
145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min,
In calorstat, place 30-40h after sulfuration, to obtain final product.
The invention have the benefit that
By by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, gathering
Urethane rubber, EP rubbers, polyacrylamide, the mixed smelting of vinyl polysiloxane, passes through
Characteristic between each rubber is complementary, can avoid the natural defect of each rubber with high degree,
Comprehensive and give full play to good characteristics and the performance that each rubber has, each rubber itself is also
Possess extraordinary wearability, especially natural rubber and polypropylene rubber, vinyl silicon tree
The collocation of fat, makes premixing glue have excellent wearability, oil resistivity, oxidative resistance, anti-aging
Property.
By adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid, rubber protecting agent,
Wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, white carbon, anti-
Burnt agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, softening agent, can
The wearability of premixing glue is further enhanced in the performance excellent to ensure premixing glue.
By rubber protecting agent, sulfur, potter's clay, white carbon, antiscorching agent, polyacrylate rubber
Rubber powder end, 2-mercapto imidazoline, the addition of plasticizer, the non-oxidizability of rubber can be promoted
And intensity, coordinate calcium carbonate, fluorubber powder etc., can further promote rubber itself
Wearability and high temperature resistant, corrosion resistance.
The abrasive rubber prepared by the present invention, not only cost is relatively low, and fabrication cycle is short, and
The abrasive rubber yields obtained is high, service life is long.
The abrasive rubber prepared by the present invention, can obtain extraordinary abrasion resistant effect, simultaneously
The wearability of rubber, thermostability also have the best performance.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the invention will be further described.
Embodiment 1:
Component by weight takes: natural rubber 60 parts, 20 parts of butadiene-styrene rubber, butadiene rubber 20
Part, chlorohydrin rubber 40 parts, 20 parts of silicone rubber, polyurethane rubber 30 parts, EP rubbers 10
Part, aromatic naphtha 3 parts, stearic acid 1 part, coupling agent 1 part, calcium carbonate 2 parts, fluorubber
10 parts of powder, zinc oxide 1 part, stearic acid 3 parts, rubber protecting agent 6 parts, wear-resisting benefit
Strong agent 5 parts, Magnaglo 5 parts, softening agent 1 part, accelerator 0.5 part, sulfur 4
Part, 1 part of age resistor, 2 parts of potter's clay, white carbon 1 part, antiscorching agent 2 parts, polyacrylic acid
Ester rubber powder 2 parts, 2-mercapto imidazoline 1 part, plasticizer 1 part, softening agent 3 parts.
The step preparing abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia
Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C,
Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard
Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C
Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented
Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal
Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften
Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h,
To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give
Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is
145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min,
In calorstat, place 30-40h after sulfuration, to obtain final product.
Embodiment 2:
Component by weight takes: natural rubber 90 parts, 30 parts of butadiene-styrene rubber, butadiene rubber 30
Part, chlorohydrin rubber 140 parts, 60 parts of silicone rubber, polyurethane rubber 70 parts, EP rubbers
40 parts, aromatic naphtha 5 parts, stearic acid 3 parts, coupling agent 2 parts, calcium carbonate 8 parts, fluorine
Rubber powder 30 parts, zinc oxide 4 parts, stearic acid 4 parts, rubber protecting agent 7 parts, resistance to
Mill reinforcing agent 10 parts, Magnaglo 10 parts, softening agent 4 parts, accelerator 1 part, sulfur
4-6 part, 5 parts of age resistor, 12 parts of potter's clay, white carbon 5 parts, antiscorching agent 3 parts, poly-third
Olefin(e) acid ester rubber powder 4 parts, 2-mercapto imidazoline 2 parts, plasticizer 10 parts, soften
Agent 10 parts.
The step preparing abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia
Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C,
Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard
Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C
Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented
Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal
Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften
Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h,
To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give
Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is
145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min,
In calorstat, place 30-40h after sulfuration, to obtain final product.
Embodiment 3:
Natural rubber 90 parts, 30 parts of butadiene-styrene rubber, butadiene rubber 20 parts, chlorohydrin rubber 40
Part, 60 parts of silicone rubber, polyurethane rubber 70 parts, 10 parts of EP rubbers, aromatic naphtha 5
Part, stearic acid 3 parts, coupling agent 1 part, calcium carbonate 8 parts, 10 parts of fluorubber powder,
Zinc oxide 4 parts, stearic acid 3 parts, rubber protecting agent 7 parts, wear-resisting reinforcing agent 5 parts, magnetic
10 parts of powder of property, softening agent 1 part, accelerator 1 part, 4 parts of sulfur, 5 parts of age resistor,
12 parts of potter's clay, white carbon 1 part, antiscorching agent 3 parts, 2 parts of lactoprene powder,
2-mercapto imidazoline 2 parts, plasticizer 1 part, softening agent 10 parts.
The step preparing abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia
Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C,
Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard
Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C
Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented
Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal
Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften
Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h,
To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give
Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is
145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min,
In calorstat, place 30-40h after sulfuration, to obtain final product.
The abrasive rubber prepared by the present invention, not only cost is relatively low, and fabrication cycle is short, and
The abrasive rubber yields obtained is high, service life is long.
The abrasive rubber prepared by the present invention, can obtain extraordinary abrasion resistant effect, simultaneously
The wearability of rubber, thermostability also have the best performance.
Claims (2)
1. an automobile-used abrasive rubber, it is characterised in that described abrasive rubber component by weight
For: natural rubber 60-90 part, butadiene-styrene rubber 20-30 part, butadiene rubber 20-30 part,
Chlorohydrin rubber 40-140 part, silicone rubber 20-60 part, polyurethane rubber 30-70 part, second
Third rubber 10-40 part, polyacrylamide 15-25 part, vinyl polysiloxane 25-35 part,
Aromatic naphtha 3-5 part, stearic acid 1-3 part, coupling agent 1-2 part, calcium carbonate 2-8 part, fluorine
Rubber powder 10-30 part, zinc oxide 1-4 part, stearic acid 3-4 part, rubber protecting agent 6-7
Part, wear-resisting reinforcing agent 5-10 part, Magnaglo 5-10 part, accelerator 0.5-1 part, sulfur
Sulphur 4-6 part, age resistor 1-5 part, potter's clay 2-12 part, white carbon 1-5 part, antiscorching agent 2-3
Part, lactoprene powder 2-4 part, 2-mercapto imidazoline 1-2 part, plasticizer
1-10 part, softening agent 3-10 part.
Automobile-used abrasive rubber the most according to claim 1, it is characterised in that described wear-resisting
The preparation method step of rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia
Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C,
Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard
Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C
Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented
Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal
Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften
Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h,
To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give
Enter double screw extruder hopper, carry out extruding pelletization;
D. the rubber grain obtained is put in vulcanizing press, controls curing temperature and be 145-155 DEG C,
Control sulfide stress is 10-14MPa, and control cure time is 20-30min, in perseverance after sulfuration
Incubator is placed 30-40h, to obtain final product.
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CN201610270698.8A CN105860157A (en) | 2016-04-26 | 2016-04-26 | Abrasion-resistant rubber for vehicles |
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CN201610270698.8A CN105860157A (en) | 2016-04-26 | 2016-04-26 | Abrasion-resistant rubber for vehicles |
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CN105860157A true CN105860157A (en) | 2016-08-17 |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106397853A (en) * | 2016-08-30 | 2017-02-15 | 安徽省宁国市宁康密封件有限公司 | Novel wear resistant rubber and preparation method thereof |
CN106519526A (en) * | 2016-11-25 | 2017-03-22 | 安徽美翔塑业有限公司 | Rubber material for hydraulic oil tank and preparation method of rubber material |
CN106854332A (en) * | 2016-12-19 | 2017-06-16 | 钦州市科学技术开发中心 | A kind of yielding rubber and preparation method thereof |
CN107033466A (en) * | 2016-11-24 | 2017-08-11 | 安徽美腾特种电缆材料有限公司 | A kind of high-strength abrasion-proof rubber composite and preparation method thereof |
CN107030184A (en) * | 2017-03-17 | 2017-08-11 | 宁国昕远金属制品有限公司 | A kind of high-precision punching die |
CN107057327A (en) * | 2017-05-24 | 2017-08-18 | 黄山全晟密封科技有限公司 | A kind of elastomeric material and production method for being exclusively used in motor shock absorption pad |
CN108003404A (en) * | 2017-12-22 | 2018-05-08 | 谢涛 | A kind of rubber new material and manufacturing process |
CN108034222A (en) * | 2017-12-19 | 2018-05-15 | 滁州环球聚氨酯科技有限公司 | A kind of polyurethane clad on forklift hub surface |
CN108148227A (en) * | 2017-12-26 | 2018-06-12 | 太仓冠联高分子材料有限公司 | A kind of tracked carrier sizing material |
CN108384242A (en) * | 2018-02-11 | 2018-08-10 | 山东星火科学技术研究院 | A kind of military refractory seals rubber cushion |
CN109553832A (en) * | 2017-09-26 | 2019-04-02 | 宜兴市聚金信化工有限公司 | Improved abrasive rubber |
CN109666192A (en) * | 2018-11-22 | 2019-04-23 | 三力士股份有限公司 | A kind of wrapped V-belt formed protective sleeve and preparation method thereof |
CN109777082A (en) * | 2017-11-13 | 2019-05-21 | 丹阳市日晟工业设备有限公司 | A kind of sound absorbent rubber pad |
CN110861234A (en) * | 2019-11-28 | 2020-03-06 | 湖州双凤橡塑有限公司 | Rubber sole main rubber mixing process |
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CN105418994A (en) * | 2015-12-17 | 2016-03-23 | 山东永泰集团有限公司 | Wear resistance tire tread rubber and production method thereof |
CN105418991A (en) * | 2015-12-15 | 2016-03-23 | 宁国天运橡塑制品有限公司 | Damping rubber for mounting bushing of automobile steering device |
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CN103421217A (en) * | 2013-08-20 | 2013-12-04 | 双星东风轮胎有限公司 | Rubber composite for wear-resistant tire treads |
CN104059253A (en) * | 2014-01-21 | 2014-09-24 | 四川远星橡胶有限责任公司 | Wear-resistant rubber material combination of tire tread and preparation method thereof |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106397853A (en) * | 2016-08-30 | 2017-02-15 | 安徽省宁国市宁康密封件有限公司 | Novel wear resistant rubber and preparation method thereof |
CN107033466A (en) * | 2016-11-24 | 2017-08-11 | 安徽美腾特种电缆材料有限公司 | A kind of high-strength abrasion-proof rubber composite and preparation method thereof |
CN106519526A (en) * | 2016-11-25 | 2017-03-22 | 安徽美翔塑业有限公司 | Rubber material for hydraulic oil tank and preparation method of rubber material |
CN106854332A (en) * | 2016-12-19 | 2017-06-16 | 钦州市科学技术开发中心 | A kind of yielding rubber and preparation method thereof |
CN107030184A (en) * | 2017-03-17 | 2017-08-11 | 宁国昕远金属制品有限公司 | A kind of high-precision punching die |
CN107057327A (en) * | 2017-05-24 | 2017-08-18 | 黄山全晟密封科技有限公司 | A kind of elastomeric material and production method for being exclusively used in motor shock absorption pad |
CN109553832A (en) * | 2017-09-26 | 2019-04-02 | 宜兴市聚金信化工有限公司 | Improved abrasive rubber |
CN109777082A (en) * | 2017-11-13 | 2019-05-21 | 丹阳市日晟工业设备有限公司 | A kind of sound absorbent rubber pad |
CN108034222A (en) * | 2017-12-19 | 2018-05-15 | 滁州环球聚氨酯科技有限公司 | A kind of polyurethane clad on forklift hub surface |
CN108003404A (en) * | 2017-12-22 | 2018-05-08 | 谢涛 | A kind of rubber new material and manufacturing process |
CN108148227A (en) * | 2017-12-26 | 2018-06-12 | 太仓冠联高分子材料有限公司 | A kind of tracked carrier sizing material |
CN108384242A (en) * | 2018-02-11 | 2018-08-10 | 山东星火科学技术研究院 | A kind of military refractory seals rubber cushion |
CN109666192A (en) * | 2018-11-22 | 2019-04-23 | 三力士股份有限公司 | A kind of wrapped V-belt formed protective sleeve and preparation method thereof |
CN110861234A (en) * | 2019-11-28 | 2020-03-06 | 湖州双凤橡塑有限公司 | Rubber sole main rubber mixing process |
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Application publication date: 20160817 |