CN105860157A - Abrasion-resistant rubber for vehicles - Google Patents

Abrasion-resistant rubber for vehicles Download PDF

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Publication number
CN105860157A
CN105860157A CN201610270698.8A CN201610270698A CN105860157A CN 105860157 A CN105860157 A CN 105860157A CN 201610270698 A CN201610270698 A CN 201610270698A CN 105860157 A CN105860157 A CN 105860157A
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China
Prior art keywords
rubber
parts
agent
stearic acid
powder
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CN201610270698.8A
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Chinese (zh)
Inventor
秦磊
刘建国
张铭
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Anhui Runkang Plastic Rubber Technology Co Ltd
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Anhui Runkang Plastic Rubber Technology Co Ltd
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Priority to CN201610270698.8A priority Critical patent/CN105860157A/en
Publication of CN105860157A publication Critical patent/CN105860157A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to an abrasion-resistant rubber for vehicles. The abrasion-resistant rubber for vehicles is composed of the following components in parts by weight: 60-90 parts of natural rubber, 20-30 parts of styrene-butadiene rubber, 20-30 parts of cis-1,4-polybutadiene rubber, 40-140 parts of epichlorohydrin rubber, 20-60 parts of silicon rubber, 30-70 parts of polyurethane rubber, 10-40 parts of ethylene-propylene rubber, 3-5 parts of aromatic oil, 1-3 parts of stearic acid, 1-2 parts of coupling agent, 2-8 parts of calcium carbonate, 10-30 parts of fluororubber powder, 1-4 parts of zinc oxide, 3-4 parts of stearic acid, 6-7 parts of rubber protective agent, 5-10 parts of abrasion-resistance reinforcing agent, 5-10 parts of magnetic powder, 1-4 parts of softening agent, 0.5-1 part of accelerator and 4-6 parts of sulfur. The abrasion-resistant rubber can obtain excellent abrasion resistance effects, and has favorable wear resistance and heat resistance.

Description

A kind of automobile-used abrasive rubber
Technical field
The present invention relates to abrasive rubber production field, a kind of new and effective automobile-used wear-resisting Rubber and production method.
Background technology
Rubber industry is one of important foundation industry of national economy.It not only provides day for people The light industry rubber product such as daily, medical that often life is indispensable, and to digging, traffic, The heavy industry such as building, machinery, electronics and new industry provide various rubber systems to produce equipment or rubber Glue component.Visible, the product category of rubber industry is various, and backward industry is the most wide.
In prior art, it is used for manufacturing automobile rubber, generally selects natural rubber, due to sky So reason of rubber self chemical constitution, its resistance to oxidation anti-wear performance is poor, thus have impact on vapour Car rubber physical and mechanical properties and service life.Accordingly, it would be desirable on the basis of prior art On existing elastomeric material is made improvements, improve its oxidation resistent susceptibility, thus improve automobile rubber The service life of glue goods.The rubber one that wearability is good, the anti-ageing property of excellent heat resistance, oxytolerant is good Directly being devoted to the pursuit to rubber, the production method of current rubber is a lot, makes rubber production reduce Cost, raising performance, simplification operation, will continue the focus being to study.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of automobile-used abrasive rubber and system thereof Preparation Method.
The present invention solves that the technical scheme that above-mentioned technical problem uses is:
A kind of automobile-used abrasive rubber, described abrasive rubber component by weight is: natural rubber 60-90 part, butadiene-styrene rubber 20-30 part, butadiene rubber 20-30 part, chlorohydrin rubber 40-140 Part, silicone rubber 20-60 part, polyurethane rubber 30-70 part, EP rubbers 10-40 part, Polyacrylamide 15-25 part, vinyl polysiloxane 25-35 part, aromatic naphtha 3-5 part is stearic Acid 1-3 part, coupling agent 1-2 part, calcium carbonate 2-8 part, fluorubber powder 10-30 part, Zinc oxide 1-4 part, stearic acid 3-4 part, rubber protecting agent 6-7 part, wear-resisting reinforcing agent 5-10 Part, Magnaglo 5-10 part, softening agent 1-4 part, accelerator 0.5-1 part, sulfur 4-6 Part, age resistor 1-5 part, potter's clay 2-12 part, white carbon 1-5 part, antiscorching agent 2-3 part, Lactoprene powder 2-4 part, 2-mercapto imidazoline 1-2 part, plasticizer 1-10 Part, softening agent 3-10 part.
Further, the preparation method step of described abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C, Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h, To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is 145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min, In calorstat, place 30-40h after sulfuration, to obtain final product.
The invention have the benefit that
By by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, gathering Urethane rubber, EP rubbers, polyacrylamide, the mixed smelting of vinyl polysiloxane, passes through Characteristic between each rubber is complementary, can avoid the natural defect of each rubber with high degree, Comprehensive and give full play to good characteristics and the performance that each rubber has, each rubber itself is also Possess extraordinary wearability, especially natural rubber and polypropylene rubber, vinyl silicon tree The collocation of fat, makes premixing glue have excellent wearability, oil resistivity, oxidative resistance, anti-aging Property.
By adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid, rubber protecting agent, Wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, white carbon, anti- Burnt agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, softening agent, can The wearability of premixing glue is further enhanced in the performance excellent to ensure premixing glue.
By rubber protecting agent, sulfur, potter's clay, white carbon, antiscorching agent, polyacrylate rubber Rubber powder end, 2-mercapto imidazoline, the addition of plasticizer, the non-oxidizability of rubber can be promoted And intensity, coordinate calcium carbonate, fluorubber powder etc., can further promote rubber itself Wearability and high temperature resistant, corrosion resistance.
The abrasive rubber prepared by the present invention, not only cost is relatively low, and fabrication cycle is short, and The abrasive rubber yields obtained is high, service life is long.
The abrasive rubber prepared by the present invention, can obtain extraordinary abrasion resistant effect, simultaneously The wearability of rubber, thermostability also have the best performance.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the invention will be further described.
Embodiment 1:
Component by weight takes: natural rubber 60 parts, 20 parts of butadiene-styrene rubber, butadiene rubber 20 Part, chlorohydrin rubber 40 parts, 20 parts of silicone rubber, polyurethane rubber 30 parts, EP rubbers 10 Part, aromatic naphtha 3 parts, stearic acid 1 part, coupling agent 1 part, calcium carbonate 2 parts, fluorubber 10 parts of powder, zinc oxide 1 part, stearic acid 3 parts, rubber protecting agent 6 parts, wear-resisting benefit Strong agent 5 parts, Magnaglo 5 parts, softening agent 1 part, accelerator 0.5 part, sulfur 4 Part, 1 part of age resistor, 2 parts of potter's clay, white carbon 1 part, antiscorching agent 2 parts, polyacrylic acid Ester rubber powder 2 parts, 2-mercapto imidazoline 1 part, plasticizer 1 part, softening agent 3 parts.
The step preparing abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C, Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h, To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is 145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min, In calorstat, place 30-40h after sulfuration, to obtain final product.
Embodiment 2:
Component by weight takes: natural rubber 90 parts, 30 parts of butadiene-styrene rubber, butadiene rubber 30 Part, chlorohydrin rubber 140 parts, 60 parts of silicone rubber, polyurethane rubber 70 parts, EP rubbers 40 parts, aromatic naphtha 5 parts, stearic acid 3 parts, coupling agent 2 parts, calcium carbonate 8 parts, fluorine Rubber powder 30 parts, zinc oxide 4 parts, stearic acid 4 parts, rubber protecting agent 7 parts, resistance to Mill reinforcing agent 10 parts, Magnaglo 10 parts, softening agent 4 parts, accelerator 1 part, sulfur 4-6 part, 5 parts of age resistor, 12 parts of potter's clay, white carbon 5 parts, antiscorching agent 3 parts, poly-third Olefin(e) acid ester rubber powder 4 parts, 2-mercapto imidazoline 2 parts, plasticizer 10 parts, soften Agent 10 parts.
The step preparing abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C, Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h, To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is 145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min, In calorstat, place 30-40h after sulfuration, to obtain final product.
Embodiment 3:
Natural rubber 90 parts, 30 parts of butadiene-styrene rubber, butadiene rubber 20 parts, chlorohydrin rubber 40 Part, 60 parts of silicone rubber, polyurethane rubber 70 parts, 10 parts of EP rubbers, aromatic naphtha 5 Part, stearic acid 3 parts, coupling agent 1 part, calcium carbonate 8 parts, 10 parts of fluorubber powder, Zinc oxide 4 parts, stearic acid 3 parts, rubber protecting agent 7 parts, wear-resisting reinforcing agent 5 parts, magnetic 10 parts of powder of property, softening agent 1 part, accelerator 1 part, 4 parts of sulfur, 5 parts of age resistor, 12 parts of potter's clay, white carbon 1 part, antiscorching agent 3 parts, 2 parts of lactoprene powder, 2-mercapto imidazoline 2 parts, plasticizer 1 part, softening agent 10 parts.
The step preparing abrasive rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C, Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h, To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give Enter double screw extruder hopper, carry out extruding pelletization;
D. putting in vulcanizing press by the rubber grain obtained, controlling curing temperature is 145-155 DEG C, control sulfide stress is 10-14MPa, and control cure time is 20-30min, In calorstat, place 30-40h after sulfuration, to obtain final product.
The abrasive rubber prepared by the present invention, not only cost is relatively low, and fabrication cycle is short, and The abrasive rubber yields obtained is high, service life is long.
The abrasive rubber prepared by the present invention, can obtain extraordinary abrasion resistant effect, simultaneously The wearability of rubber, thermostability also have the best performance.

Claims (2)

1. an automobile-used abrasive rubber, it is characterised in that described abrasive rubber component by weight For: natural rubber 60-90 part, butadiene-styrene rubber 20-30 part, butadiene rubber 20-30 part, Chlorohydrin rubber 40-140 part, silicone rubber 20-60 part, polyurethane rubber 30-70 part, second Third rubber 10-40 part, polyacrylamide 15-25 part, vinyl polysiloxane 25-35 part, Aromatic naphtha 3-5 part, stearic acid 1-3 part, coupling agent 1-2 part, calcium carbonate 2-8 part, fluorine Rubber powder 10-30 part, zinc oxide 1-4 part, stearic acid 3-4 part, rubber protecting agent 6-7 Part, wear-resisting reinforcing agent 5-10 part, Magnaglo 5-10 part, accelerator 0.5-1 part, sulfur Sulphur 4-6 part, age resistor 1-5 part, potter's clay 2-12 part, white carbon 1-5 part, antiscorching agent 2-3 Part, lactoprene powder 2-4 part, 2-mercapto imidazoline 1-2 part, plasticizer 1-10 part, softening agent 3-10 part.
Automobile-used abrasive rubber the most according to claim 1, it is characterised in that described wear-resisting The preparation method step of rubber is as follows:
A. by natural rubber, butadiene-styrene rubber, butadiene rubber, chlorohydrin rubber, silicone rubber, poly-ammonia Ester rubber, EP rubbers put into the 5-8min that plasticates in banbury, make temperature reach 90-100 DEG C, Continuously adding aromatic naphtha, stearic acid, coupling agent, carry out mixing, mixing 20-25min is laggard Row cooling, obtains premixing glue;
B. the premixing glue obtained in step a is added in mill, at a temperature of 60-80 DEG C Adding calcium carbonate, fluorubber powder, zinc oxide, stearic acid after mill 8-10min, rubber is prevented Protect agent, wear-resisting reinforcing agent, Magnaglo, softening agent, accelerator, sulfur, potter's clay, Linesless charcoal Black, antiscorching agent, lactoprene powder, 2-mercapto imidazoline, plasticizer, soften Agent, continues mill, binder removal when temperature is raised to 140-160 DEG C, and room temperature places 10-12h, To colloid mixture;
C. by colloid mixture in two-roll mill mixing, and add sulfur, mixing uniformly after give Enter double screw extruder hopper, carry out extruding pelletization;
D. the rubber grain obtained is put in vulcanizing press, controls curing temperature and be 145-155 DEG C, Control sulfide stress is 10-14MPa, and control cure time is 20-30min, in perseverance after sulfuration Incubator is placed 30-40h, to obtain final product.
CN201610270698.8A 2016-04-26 2016-04-26 Abrasion-resistant rubber for vehicles Pending CN105860157A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106397853A (en) * 2016-08-30 2017-02-15 安徽省宁国市宁康密封件有限公司 Novel wear resistant rubber and preparation method thereof
CN106519526A (en) * 2016-11-25 2017-03-22 安徽美翔塑业有限公司 Rubber material for hydraulic oil tank and preparation method of rubber material
CN106854332A (en) * 2016-12-19 2017-06-16 钦州市科学技术开发中心 A kind of yielding rubber and preparation method thereof
CN107033466A (en) * 2016-11-24 2017-08-11 安徽美腾特种电缆材料有限公司 A kind of high-strength abrasion-proof rubber composite and preparation method thereof
CN107030184A (en) * 2017-03-17 2017-08-11 宁国昕远金属制品有限公司 A kind of high-precision punching die
CN107057327A (en) * 2017-05-24 2017-08-18 黄山全晟密封科技有限公司 A kind of elastomeric material and production method for being exclusively used in motor shock absorption pad
CN108003404A (en) * 2017-12-22 2018-05-08 谢涛 A kind of rubber new material and manufacturing process
CN108034222A (en) * 2017-12-19 2018-05-15 滁州环球聚氨酯科技有限公司 A kind of polyurethane clad on forklift hub surface
CN108148227A (en) * 2017-12-26 2018-06-12 太仓冠联高分子材料有限公司 A kind of tracked carrier sizing material
CN108384242A (en) * 2018-02-11 2018-08-10 山东星火科学技术研究院 A kind of military refractory seals rubber cushion
CN109553832A (en) * 2017-09-26 2019-04-02 宜兴市聚金信化工有限公司 Improved abrasive rubber
CN109666192A (en) * 2018-11-22 2019-04-23 三力士股份有限公司 A kind of wrapped V-belt formed protective sleeve and preparation method thereof
CN109777082A (en) * 2017-11-13 2019-05-21 丹阳市日晟工业设备有限公司 A kind of sound absorbent rubber pad
CN110861234A (en) * 2019-11-28 2020-03-06 湖州双凤橡塑有限公司 Rubber sole main rubber mixing process

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CN104059253A (en) * 2014-01-21 2014-09-24 四川远星橡胶有限责任公司 Wear-resistant rubber material combination of tire tread and preparation method thereof
CN105418994A (en) * 2015-12-17 2016-03-23 山东永泰集团有限公司 Wear resistance tire tread rubber and production method thereof
CN105418991A (en) * 2015-12-15 2016-03-23 宁国天运橡塑制品有限公司 Damping rubber for mounting bushing of automobile steering device

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CN102030926A (en) * 2010-11-30 2011-04-27 江苏通用科技股份有限公司 High abrasion-resistant tread rubber for middle and long distance highway transportation type radial tire and producing method thereof
CN103421217A (en) * 2013-08-20 2013-12-04 双星东风轮胎有限公司 Rubber composite for wear-resistant tire treads
CN104059253A (en) * 2014-01-21 2014-09-24 四川远星橡胶有限责任公司 Wear-resistant rubber material combination of tire tread and preparation method thereof
CN105418991A (en) * 2015-12-15 2016-03-23 宁国天运橡塑制品有限公司 Damping rubber for mounting bushing of automobile steering device
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106397853A (en) * 2016-08-30 2017-02-15 安徽省宁国市宁康密封件有限公司 Novel wear resistant rubber and preparation method thereof
CN107033466A (en) * 2016-11-24 2017-08-11 安徽美腾特种电缆材料有限公司 A kind of high-strength abrasion-proof rubber composite and preparation method thereof
CN106519526A (en) * 2016-11-25 2017-03-22 安徽美翔塑业有限公司 Rubber material for hydraulic oil tank and preparation method of rubber material
CN106854332A (en) * 2016-12-19 2017-06-16 钦州市科学技术开发中心 A kind of yielding rubber and preparation method thereof
CN107030184A (en) * 2017-03-17 2017-08-11 宁国昕远金属制品有限公司 A kind of high-precision punching die
CN107057327A (en) * 2017-05-24 2017-08-18 黄山全晟密封科技有限公司 A kind of elastomeric material and production method for being exclusively used in motor shock absorption pad
CN109553832A (en) * 2017-09-26 2019-04-02 宜兴市聚金信化工有限公司 Improved abrasive rubber
CN109777082A (en) * 2017-11-13 2019-05-21 丹阳市日晟工业设备有限公司 A kind of sound absorbent rubber pad
CN108034222A (en) * 2017-12-19 2018-05-15 滁州环球聚氨酯科技有限公司 A kind of polyurethane clad on forklift hub surface
CN108003404A (en) * 2017-12-22 2018-05-08 谢涛 A kind of rubber new material and manufacturing process
CN108148227A (en) * 2017-12-26 2018-06-12 太仓冠联高分子材料有限公司 A kind of tracked carrier sizing material
CN108384242A (en) * 2018-02-11 2018-08-10 山东星火科学技术研究院 A kind of military refractory seals rubber cushion
CN109666192A (en) * 2018-11-22 2019-04-23 三力士股份有限公司 A kind of wrapped V-belt formed protective sleeve and preparation method thereof
CN110861234A (en) * 2019-11-28 2020-03-06 湖州双凤橡塑有限公司 Rubber sole main rubber mixing process

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Application publication date: 20160817