CN108034222A - A kind of polyurethane clad on forklift hub surface - Google Patents

A kind of polyurethane clad on forklift hub surface Download PDF

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Publication number
CN108034222A
CN108034222A CN201711374923.3A CN201711374923A CN108034222A CN 108034222 A CN108034222 A CN 108034222A CN 201711374923 A CN201711374923 A CN 201711374923A CN 108034222 A CN108034222 A CN 108034222A
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CN
China
Prior art keywords
parts
rubber
polyurethane
hub surface
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711374923.3A
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Chinese (zh)
Inventor
龚文祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chuzhou Huanqiu Polyurethane Technology Co Ltd
Original Assignee
Chuzhou Huanqiu Polyurethane Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chuzhou Huanqiu Polyurethane Technology Co Ltd filed Critical Chuzhou Huanqiu Polyurethane Technology Co Ltd
Priority to CN201711374923.3A priority Critical patent/CN108034222A/en
Publication of CN108034222A publication Critical patent/CN108034222A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Forklifts And Lifting Vehicles (AREA)

Abstract

The invention discloses a kind of polyurethane clad on forklift hub surface, its raw material includes by weight:100 140 parts of polyurethane rubber, 30 40 parts of butadiene-styrene rubber, 10 20 parts of natural rubber, 10 18 parts of nitrile rubber, 5 11 parts of vulcanizing agent, 25 45 parts of powdered whiting, 10 20 parts of graphene, 10 18 parts of nano-bentonite, 48 parts of vulcanization accelerator, 24 parts of pine tar, 24 parts of antiscorching agent, 24 parts of antioxidant, 24 parts of plasticizer, 24 parts of softening agent.The present invention has an excellent wear-resisting property, and suitable for persistently being used under high abrasive conditions, and the adhesive strength between core wheel is high, is not likely to produce sliding friction, while tensile strength height, fire resisting, corrosion-resistant.

Description

A kind of polyurethane clad on forklift hub surface
Technical field
The present invention relates to polyurethanes technology field, more particularly to a kind of polyurethane clad on forklift hub surface.
Background technology
Fork truck needs crotch stretching to tray bottom in use, is moved integrally under the drive of fork truck wheel, This bearing capacity to fork truck wheel requires high, and fork truck wheel includes wheel hub and is coated on the polyurethane clad of hub surface, mesh The preceding wheel hub weight due to 5-10t fork trucks reach more than 40kg, after loading cargo, is manually transported to mounting plate and subsequently 90 ° of turn work of process, its labor intensity is big, and since workpiece quality is big, to the polyurethane clad wear resistance on top layer It is required that high, there are serious security risk.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of polyurethane cladding on forklift hub surface Layer, has excellent wear-resisting property, and suitable for persistently being used under high abrasive conditions, and the adhesive strength between core wheel Height, is not likely to produce sliding friction, while tensile strength is high, fire resisting, corrosion-resistant.
A kind of polyurethane clad on forklift hub surface proposed by the present invention, its raw material include by weight:Polyurethane 100-140 parts of rubber, 30-40 parts of butadiene-styrene rubber, 10-20 parts of natural rubber, 10-18 parts of nitrile rubber, 5-11 parts of vulcanizing agent, weight 25-45 parts of matter calcium carbonate, 10-20 parts of graphene, 10-18 parts of nano-bentonite, 4-8 parts of vulcanization accelerator, 2-4 parts of pine tar, 2-4 parts of antiscorching agent, 2-4 parts of antioxidant, 2-4 parts of plasticizer, 2-4 parts of softening agent.
Preferably, vulcanizing agent includes by weight:4-8 parts of cumyl peroxide, 1-3 parts of tert-butyl hydroperoxide.
Preferably, vulcanization accelerator includes by weight:2-4 parts of 2- mercapto imidazolines, tetramethylthiuram disulfide 2-4 parts.
With common rubber phase ratio, the present invention has excellent wear-resisting property, and suitable for continuing under high abrasive conditions Use, and tensile strength is high, it is fire resisting, corrosion-resistant.
The present invention is compounded using polyurethane rubber and butadiene-styrene rubber, natural rubber, nitrile rubber, and synergistic effect, can improve Adhesive strength between the present invention and core wheel, bond strength is high, is not likely to produce sliding friction, service life is grown, and peroxidating two Isopropylbenzene, tert-butyl hydroperoxide can promote to form cross-linked network between polyurethane rubber, butadiene-styrene rubber, natural rubber, nitrile rubber Shape structure, bond strength is high, and wear-resisting property is excellent, and good toughness, and powdered whiting, graphene, nano-bentonite can be abundant It is dispersed in system, on the basis of polyurethane rubber additive amount is reduced, reduce cost, hardness is high, and wearability is outstanding, makes The present invention is uniformly and intimately fitted in core surfaces, and composite performance is good, and gained fork truck wheel is corrosion-resistant, wear-resistant, and cost is low It is honest and clean.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of polyurethane clad on forklift hub surface, its raw material include:Polyurethane rubber 100kg, butadiene-styrene rubber 40kg, natural rubber 10kg, nitrile rubber 18kg, vulcanizing agent 5kg, powdered whiting 45kg, graphene 10kg, nano-bentonite 18kg, vulcanization accelerator 4kg, pine tar 4kg, antiscorching agent 2kg, antioxidant 4kg, plasticizer 2kg, softening agent 4kg.
Vulcanizing agent includes:Cumyl peroxide 4kg, tert-butyl hydroperoxide 3kg.Vulcanization accelerator includes:2- mercaptan Base imidazoline 2kg, tetramethylthiuram disulfide 4kg.
Embodiment 2
A kind of polyurethane clad on forklift hub surface, its raw material include:Polyurethane rubber 140kg, butadiene-styrene rubber 30- Kg, natural rubber 20kg, nitrile rubber 10kg, vulcanizing agent 11kg, powdered whiting 25kg, graphene 20kg, nano-bentonite 10kg, vulcanization accelerator 8kg, pine tar 2kg, antiscorching agent 4kg, antioxidant 2kg, plasticizer 4kg, softening agent 2kg.
Vulcanizing agent includes:Cumyl peroxide 8kg, tert-butyl hydroperoxide 1kg.Vulcanization accelerator includes:2- mercaptan Base imidazoline 4kg, tetramethylthiuram disulfide 2kg.
Embodiment 3
A kind of polyurethane clad on forklift hub surface, its raw material include:Polyurethane rubber 110kg, butadiene-styrene rubber 37kg, natural rubber 12kg, nitrile rubber 16kg, vulcanizing agent 6kg, powdered whiting 40kg, graphene 12kg, nano-bentonite 16kg, vulcanization accelerator 5kg, pine tar 3.5kg, antiscorching agent 2.5kg, antioxidant 3.5kg, plasticizer 2.5kg, softening agent 3.5kg。
Vulcanizing agent includes:Cumyl peroxide 5kg, tert-butyl hydroperoxide 2.5kg.Vulcanization accelerator includes:2- sulphur Alcohol radical imidazoline 2.5kg, tetramethylthiuram disulfide 3.5kg.
Embodiment 4
A kind of polyurethane clad on forklift hub surface, its raw material include:Polyurethane rubber 130kg, butadiene-styrene rubber 33kg, natural rubber 18kg, nitrile rubber 12kg, vulcanizing agent 8kg, powdered whiting 30kg, graphene 18kg, nano-bentonite 12kg, vulcanization accelerator 7kg, pine tar 2.5kg, antiscorching agent 3.5kg, antioxidant 2.5kg, plasticizer 3.5kg, softening agent 2.5kg。
Vulcanizing agent includes:Cumyl peroxide 7kg, tert-butyl hydroperoxide 1.5kg.Vulcanization accelerator includes:2- sulphur Alcohol radical imidazoline 3.5kg, tetramethylthiuram disulfide 2.5kg.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (3)

1. a kind of polyurethane clad on forklift hub surface, it is characterised in that its raw material includes by weight:Polyurethane rubber 100-140 parts, 30-40 parts of butadiene-styrene rubber, 10-20 parts of natural rubber, 10-18 parts of nitrile rubber, 5-11 parts of vulcanizing agent, heavy carbon Sour calcium 25-45 parts, 10-20 parts of graphene, 10-18 parts of nano-bentonite, 4-8 parts of vulcanization accelerator, 2-4 parts of pine tar is anti-scorch 2-4 parts of agent, 2-4 parts of antioxidant, 2-4 parts of plasticizer, 2-4 parts of softening agent.
2. the polyurethane clad on forklift hub surface according to claim 1, it is characterised in that vulcanizing agent wraps by weight Include:4-8 parts of cumyl peroxide, 1-3 parts of tert-butyl hydroperoxide.
3. the polyurethane clad on forklift hub surface according to claim 1, it is characterised in that vulcanization accelerator is by weight Part includes:2-4 parts of 2- mercapto imidazolines, 2-4 parts of tetramethylthiuram disulfide.
CN201711374923.3A 2017-12-19 2017-12-19 A kind of polyurethane clad on forklift hub surface Withdrawn CN108034222A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711374923.3A CN108034222A (en) 2017-12-19 2017-12-19 A kind of polyurethane clad on forklift hub surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711374923.3A CN108034222A (en) 2017-12-19 2017-12-19 A kind of polyurethane clad on forklift hub surface

Publications (1)

Publication Number Publication Date
CN108034222A true CN108034222A (en) 2018-05-15

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110330781A (en) * 2019-06-04 2019-10-15 中电鼎康(天长)科技有限公司 A kind of ageing-resistant sensor outer housing material of damping and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1834140A (en) * 2005-03-18 2006-09-20 西北工业大学 Gross rubber for high wearable tyre and its prepn.
CN102108140A (en) * 2009-12-23 2011-06-29 韩国轮胎株式会社 Rubber composition for tire tread and tire manufactured using the same
CN102924760A (en) * 2012-10-25 2013-02-13 北京化工大学 High-performance tyre with ultra-wear resistant tyre surface and manufacturing method thereof
CN103467789A (en) * 2013-09-17 2013-12-25 山东永泰化工有限公司 Pneumatic tyre
CN103665821A (en) * 2013-11-29 2014-03-26 山东永泰化工有限公司 Cold-resistant rubber
CN103923360A (en) * 2014-05-10 2014-07-16 任新年 Abrasion-resistant rubber for tire and preparing method of abrasion-resistant rubber
CN105860157A (en) * 2016-04-26 2016-08-17 安徽润康橡塑科技有限公司 Abrasion-resistant rubber for vehicles

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1834140A (en) * 2005-03-18 2006-09-20 西北工业大学 Gross rubber for high wearable tyre and its prepn.
CN102108140A (en) * 2009-12-23 2011-06-29 韩国轮胎株式会社 Rubber composition for tire tread and tire manufactured using the same
CN102924760A (en) * 2012-10-25 2013-02-13 北京化工大学 High-performance tyre with ultra-wear resistant tyre surface and manufacturing method thereof
CN103467789A (en) * 2013-09-17 2013-12-25 山东永泰化工有限公司 Pneumatic tyre
CN103665821A (en) * 2013-11-29 2014-03-26 山东永泰化工有限公司 Cold-resistant rubber
CN103923360A (en) * 2014-05-10 2014-07-16 任新年 Abrasion-resistant rubber for tire and preparing method of abrasion-resistant rubber
CN105860157A (en) * 2016-04-26 2016-08-17 安徽润康橡塑科技有限公司 Abrasion-resistant rubber for vehicles

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110330781A (en) * 2019-06-04 2019-10-15 中电鼎康(天长)科技有限公司 A kind of ageing-resistant sensor outer housing material of damping and preparation method thereof

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Application publication date: 20180515

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