CN111594561A - Environment-friendly composite brake shoe material and brake shoe manufacturing method - Google Patents

Environment-friendly composite brake shoe material and brake shoe manufacturing method Download PDF

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Publication number
CN111594561A
CN111594561A CN202010326238.9A CN202010326238A CN111594561A CN 111594561 A CN111594561 A CN 111594561A CN 202010326238 A CN202010326238 A CN 202010326238A CN 111594561 A CN111594561 A CN 111594561A
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China
Prior art keywords
parts
brake shoe
raw materials
banburying
fiber
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Pending
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CN202010326238.9A
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Chinese (zh)
Inventor
曾涔
丁雷
史敬文
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Jiangsu Tieke New Material Co ltd
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Jiangsu Tieke New Material Co ltd
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Priority to CN202010326238.9A priority Critical patent/CN111594561A/en
Publication of CN111594561A publication Critical patent/CN111594561A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • F16D69/023Composite materials containing carbon and carbon fibres or fibres made of carbonizable material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C08L61/14Modified phenol-aldehyde condensates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/006Materials; Production methods therefor containing fibres or particles
    • F16D2200/0065Inorganic, e.g. non-asbestos mineral fibres
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0082Production methods therefor
    • F16D2200/0086Moulding materials together by application of heat and pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2250/00Manufacturing; Assembly
    • F16D2250/003Chip removing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Braking Arrangements (AREA)

Abstract

The invention discloses an environment-friendly composite brake shoe material and a brake shoe manufacturing method. It comprises the following steps: A. accurately weighing various raw materials according to the formula requirements; B. putting the raw materials into an internal mixer, kneading and internally mixing at room temperature, discharging and cooling; c, drying the raw materials obtained by banburying, and then crushing for later use; D. after sand blasting and dirt removing are carried out on the tile back adhesive surface, brushing the tile back adhesive, and drying at room temperature for later use; E. hot-pressing, curing and forming to obtain a product; F. and (5) secondary curing, trimming and deburring to obtain a brake shoe finished product. The advantages are that: the material degradation caused by temperature rise is effectively reduced, the material friction heat generation rate is reduced, the shearing strength in the material is higher, the strength reduction speed is slowed down, the phenomenon that the friction layer falls slag and blocks is effectively prevented, the strength reduction problem caused by heat generation to material aging is reduced, the integral strength of the friction layer is greatly improved, the friction layer abrasion rate is reduced, the service life is effectively prolonged, and the current loading application effect is good.

Description

Environment-friendly composite brake shoe material and brake shoe manufacturing method
Technical Field
The invention relates to a fitting for train brake, in particular to an environment-friendly composite brake shoe material and a brake shoe manufacturing method.
Background
The brake shoe is an accessory used for braking a train, the structure of the brake shoe is equivalent to a section of circular arc, the front part and the rear part of the wheel are respectively provided with one piece, when the train brakes, the two pieces are compressed by air to hold the tread of the wheel tightly, and the braking function is realized through friction; the existing brake shoe which is commonly used at home and abroad on the market is generally short in service life because the brake shoe is limited in material formula and the manufacturing method is not scientific, so that the friction heat generation is fast when the product is used, the strength is reduced fast, and the abrasion is high, and in addition, the repair and maintenance cost is very high in the use process, the operation cost is increased accordingly, and the brake shoe which is slightly good in performance can be used for 6-8 months, and is worse, and is normal for 3-4 months by taking the domestic Daqin line as an example; through the service life analysis of all the systems of the whole vehicle, the parts with the service life lower than 1 year only have one brake shoe, so the maintenance cost and the operation cost of the vehicle are limited by the condition, and the service life of the brake shoe is improved to be the first task under the current 'state repair' requirement.
Disclosure of Invention
The invention aims to provide an environment-friendly composite brake shoe and a brake shoe manufacturing method, wherein the friction heat generation rate is reduced, and the strength loss rate is slowed down, so that the abrasion rate is reduced, the service life is prolonged, and the repair and maintenance cost is reduced.
In order to solve the technical problems, the environment-friendly composite brake shoe material adopts the following formula and weight ratio: 15-30 parts of modified phenolic resin; 10-20 parts of nitrile rubber; 5-10 parts of carbon fiber; 3-6 parts of graphene; 5-15 parts of steel fiber; 5-15 parts of vermiculite; 5-15 parts of ceramic fiber and 1-10 parts of precipitated barium sulfate; 2-6 parts of molybdenum disulfide, 1-3 parts of carbon black, 1-3 parts of sulfur, 0.1-1 part of accelerator and 0.1-1 part of zinc oxide.
The fiber lengths of the carbon fibers, the steel fibers and the ceramic fibers are all 1-5 mm.
The formula and the weight ratio are as follows: 23 parts of modified phenolic resin; 15 parts of nitrile rubber; 7 parts of carbon fiber; 5 parts of graphene; 10 parts of steel fiber; 10 parts of vermiculite; 10 parts of ceramic fiber and 7 parts of precipitated barium sulfate; 4 parts of molybdenum disulfide, 2 parts of carbon black, 2 parts of sulfur, 0.7 part of accelerator and 0.6 part of zinc oxide.
A method for manufacturing an environment-friendly composite brake shoe comprises the following steps:
A. preparing materials: accurately weighing various raw materials according to the formula requirements;
B. banburying: putting the raw materials into an internal mixer, kneading and internally mixing for 10-15min at room temperature until the temperature reaches 120-;
C. drying and crushing: drying the raw materials obtained by banburying at 90-120 ℃ for 3-8h, and then crushing for later use;
D. tile back treatment: after sand blasting and dirt removing are carried out on the tile back adhesive surface, brushing the tile back adhesive, and drying at room temperature for later use;
E. hot-pressing, curing and molding: placing the tile back into a mold, weighing the mixed raw materials for standby application, paving the mixed raw materials into the mold, and carrying out heat preservation and demolding under the set temperature and pressure condition after exhausting to obtain a product;
F. secondary curing: and (3) putting the cooled product into an oven, heating the product from the room temperature to 155-.
In the step B, the banburying rotating speed is 15-30 r/min.
In the step E, after exhausting, the mold is released after heat preservation is carried out for 15-30min at the temperature of 130-180 ℃ and the pressure of 15-30 mpa.
In the step C, the raw materials obtained by banburying are dried for 4 hours at 100 ℃, and then are crushed to a size capable of being screened by a five-mesh sieve.
The invention has the advantages that:
after reasonable formula and proportion collocation, a special manufacturing process is added, so that the friction material has a microporous structure, heat is easy to dissipate, the temperature of the wheel tread is far less than 400 ℃, the degradation of the material caused by temperature rise is effectively reduced, the heat generation rate of the material due to friction is reduced, the internal shear strength of the material is higher, the strength reduction speed is slowed down, the phenomenon that the friction layer falls off slag and blocks due to external force factors is effectively prevented, the strength reduction problem caused by heat generation to material aging is reduced, in addition, the integral strength of the friction layer is greatly improved, the wear rate of the friction layer is reduced, the service life is effectively prolonged, and the application effect of the existing loading is good.
Detailed Description
The environment-friendly composite brake shoe and the method for manufacturing the brake shoe according to the present invention will be described in detail with reference to the following embodiments.
The first embodiment is as follows:
the method for manufacturing an eco-friendly composite brake shoe of the present embodiment comprises the steps of:
A. preparing materials: accurately weighing various raw materials by using an electronic scale, wherein the raw materials comprise the following components in percentage by weight: 15 parts of modified phenolic resin; 10 parts of nitrile rubber; 5 parts of carbon fiber; 3 parts of graphene; 5 parts of steel fiber; 5 parts of vermiculite; 5 parts of ceramic fiber and 1 part of precipitated barium sulfate; 2 parts of molybdenum disulfide, 1 part of carbon black, 1 part of sulfur, 0.1 part of accelerator and 0.1 part of zinc oxide, wherein the fiber lengths of carbon fibers, steel fibers and ceramic fibers are all 1 mm;
B. banburying: putting the raw materials into an internal mixer, kneading and banburying at room temperature, banburying at the rotating speed of 15r/min for 10min until the temperature reaches above 120 ℃, discharging and cooling;
C. drying and crushing: drying the raw materials obtained by banburying at 90 ℃ for 3h, and then crushing to a size capable of being screened by a five-mesh sieve for later use;
D. tile back treatment: after sand blasting and dirt removing are carried out on the tile back adhesive surface, brushing the tile back adhesive, and drying at room temperature for later use;
E. hot-pressing, curing and molding: placing the tile back into a mold, weighing the mixed raw materials for standby application, paving the mixed raw materials into the mold, exhausting air, keeping the temperature at 130 ℃ and the pressure at 15mpa for 15min, and demolding to obtain a product;
F. secondary curing: and (3) putting the cooled product into an oven, heating the product to 155 ℃ from the room temperature, keeping the temperature for 1h, then heating the product to 175 ℃, keeping the temperature for 1h, finally heating the product to 190 ℃, keeping the temperature for 1h, and finally cooling the product, and trimming and deburring the product to obtain a finished product of the brake shoe.
Example two:
the method for manufacturing an eco-friendly composite brake shoe of the present embodiment comprises the steps of:
A. preparing materials: accurately weighing various raw materials by using an electronic scale according to the formula requirements, wherein the raw materials comprise the following components in percentage by weight: 29 parts of modified phenolic resin; 8 parts of nitrile rubber; 9 parts of carbon fiber. 6 parts of graphene; 8 parts of steel fiber; 15 parts of vermiculite; 12 parts of ceramic fiber and 6 parts of precipitated barium sulfate; 3 parts of molybdenum disulfide, 2 parts of carbon black, 1 part of sulfur, 0.5 part of accelerator and 0.5 part of zinc oxide, wherein the fiber lengths of carbon fiber, steel fiber and ceramic fiber are all 5 mm;
B. banburying: putting the raw materials into an internal mixer, kneading and internally mixing for 15min at the rotating speed of 30r/min and room temperature until the temperature reaches below 140 ℃, discharging and cooling;
C. drying and crushing: drying the raw materials obtained by banburying at 120 ℃ for 8 hours, and then crushing to a size of five meshes for later use;
D. tile back treatment: after sand blasting and dirt removing are carried out on the tile back adhesive surface, the tile back adhesive is coated, and the tile back adhesive is dried at room temperature for standby
E. Hot-pressing, curing and molding: placing the tile back into a mold, weighing a quantitative mixture, paving the mixture into the mold, automatically exhausting, keeping the temperature at 180 ℃ and the pressure at 30mpa for 30min, and demolding to obtain a product;
F. secondary curing: and (3) putting the cooled product into an oven, heating the product to 165 ℃ from room temperature, keeping the temperature for 3h, then heating the product to 185 ℃, keeping the temperature for 3h, finally heating the product to 210 ℃, keeping the temperature for 3h, and finally cooling the product, and trimming and deburring the product to obtain the finished product of the brake shoe.
Example three:
the method for manufacturing an eco-friendly composite brake shoe of the present embodiment comprises the steps of:
A. preparing materials: accurately weighing various raw materials according to the formula requirements, wherein the raw materials comprise the following components in percentage by weight: 22 parts of modified phenolic resin; 15 parts of nitrile rubber; and 7 parts of carbon fiber. 3 parts of graphene; 12 parts of steel fiber; 12 parts of vermiculite; 7. 10 parts and 8 parts of ceramic fiber, and 10 parts of precipitated barium sulfate; 4 parts of molybdenum disulfide, 10 parts of carbon black, 2 parts of sulfur, 12 parts of accelerator, 0.5 part of 13 part of accelerator and 0.5 part of zinc oxide, wherein the fiber lengths of carbon fiber, steel fiber and ceramic fiber are all 3mm, the material strength is effectively improved by adopting carbon fiber and graphene in proper proportion, the heat generation rate of the material is reduced by adopting the steel fiber, vermiculite and carbon fiber in special proportion for heat dissipation, and the used materials do not contain forbidden substances and have the function of environmental protection;
B. banburying: putting the raw materials into an internal mixer, kneading and banburying at room temperature, banburying at the rotating speed of 20r/min for 12min until the temperature reaches about 130 ℃, discharging and cooling;
C. drying and crushing: drying the raw materials obtained by banburying at 100 ℃ for 4 hours, and then crushing to a size capable of being screened by a five-mesh sieve for later use;
D. tile back treatment: after sand blasting and dirt removing are carried out on the tile back adhesive surface, brushing the tile back adhesive, and drying at room temperature for later use;
E. hot-pressing, curing and molding: placing the tile back into a mold, weighing the mixed raw materials for standby application, paving the mixed raw materials into the mold, performing compression molding at the temperature of 150 ℃ (the compression molding is performed at the temperature, the bonding reliability is greatly improved in the molding process), and the mold is removed after heat preservation is performed for 20min under the pressure of 20mpa after exhausting, so that a product is obtained, and various materials are mixed through the process, so that the overall strength is very high;
F. secondary curing: and (3) putting the cooled product into an oven, heating the product to 160 ℃ from room temperature, keeping the temperature for 2h, then heating the product to 180 ℃ for 2h, finally heating the product to 200 ℃ for 2h, and finally cooling the product, and trimming and deburring the product to obtain a finished product of the brake shoe.
The test results of the second and third examples are shown in the following table:
example two EXAMPLE III
Compressive Strength (MPa) 43.2 67.7
Modulus of compression (GPa) 0.94 1.12
Internal shear Strength (KJ/m)2) 14.4 18.13
Flexural Strength (MPa) 30.88 38.21
Temperature of wheel tread (. degree. C.) 174 183
Wear Rate (mm/month) 2.52 1.81
Life (moon) 13 19
The tread temperature, the wear rate and the service life are detected according to the TB/T2403 standard, other parameters accord with the TB/T2403 standard, and the data of the test results show that the compression strength, the compression modulus, the internal shear strength and the bending strength are high, and the wear rate is reduced.

Claims (7)

1. An environment-friendly composite brake shoe material adopts the following formula and weight ratio: 15-30 parts of modified phenolic resin; 10-20 parts of nitrile rubber; 5-10 parts of carbon fiber; 3-6 parts of graphene; 5-15 parts of steel fiber; 5-15 parts of vermiculite; 5-15 parts of ceramic fiber and 1-10 parts of precipitated barium sulfate; 2-6 parts of molybdenum disulfide, 1-3 parts of carbon black, 1-3 parts of sulfur, 0.1-1 part of accelerator and 0.1-1 part of zinc oxide.
2. An environmentally friendly composite brake shoe material according to claim 1, wherein: the fiber lengths of the carbon fibers, the steel fibers and the ceramic fibers are all 1-5 mm.
3. An environment-friendly composite brake shoe material according to claim 1 or 2, which is prepared from the following components in percentage by weight: 23 parts of modified phenolic resin; 15 parts of nitrile rubber; 7 parts of carbon fiber; 5 parts of graphene; 10 parts of steel fiber; 10 parts of vermiculite; 10 parts of ceramic fiber and 7 parts of precipitated barium sulfate; 4 parts of molybdenum disulfide, 2 parts of carbon black, 2 parts of sulfur, 0.7 part of accelerator and 0.6 part of zinc oxide.
4. A method for manufacturing an environment-friendly composite brake shoe, comprising the steps of:
A. preparing materials: accurately weighing various raw materials according to the formula requirements;
B. banburying: putting the raw materials into an internal mixer, kneading and internally mixing for 10-15min at room temperature until the temperature reaches 120-;
C. drying and crushing: drying the raw materials obtained by banburying at 90-120 ℃ for 3-8h, and then crushing for later use;
D. tile back treatment: after sand blasting and dirt removing are carried out on the tile back adhesive surface, brushing the tile back adhesive, and drying at room temperature for later use;
E. hot-pressing, curing and molding: placing the tile back into a mold, weighing the mixed raw materials for standby application, paving the mixed raw materials into the mold, and carrying out heat preservation and demolding under the set temperature and pressure condition after exhausting to obtain a product;
F. secondary curing: and (3) putting the cooled product into an oven, heating the product from the room temperature to 155-.
5. The method of manufacturing a brake shoe according to claim 4, wherein: in the step B, the banburying rotating speed is 15-30 r/min.
6. The method for manufacturing brake shoe according to claim 4 or 5, wherein: in the step E, after exhausting, the mold is released after heat preservation is carried out for 15-30min at the temperature of 130-180 ℃ and the pressure of 15-30 mpa.
7. The method of manufacturing a brake shoe according to claim 6, wherein: in the step C, the raw materials obtained by banburying are dried for 4 hours at 100 ℃, and then are crushed to a size capable of being screened by a five-mesh sieve.
CN202010326238.9A 2020-04-23 2020-04-23 Environment-friendly composite brake shoe material and brake shoe manufacturing method Pending CN111594561A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010326238.9A CN111594561A (en) 2020-04-23 2020-04-23 Environment-friendly composite brake shoe material and brake shoe manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010326238.9A CN111594561A (en) 2020-04-23 2020-04-23 Environment-friendly composite brake shoe material and brake shoe manufacturing method

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CN111594561A true CN111594561A (en) 2020-08-28

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112694649A (en) * 2020-12-25 2021-04-23 湖北飞龙摩擦密封材料股份有限公司 Preparation method of novel disc type friction plate
CN115353675A (en) * 2022-10-21 2022-11-18 河北腾跃铁路装备股份有限公司 High-strength brake shoe material and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4344133A1 (en) * 1993-12-23 1995-06-29 Hoechst Ag Process for the preparation of thermostable moldings
JP2002234951A (en) * 2000-11-06 2002-08-23 Borgwarner Inc Friction material formed by depositing friction modifier on surface of high moisture energy carbonaceous friction material
CN101131189A (en) * 2007-08-20 2008-02-27 谭美田 Rubber multi-component composite brake shoe
CN103410893A (en) * 2013-04-26 2013-11-27 广西民族大学 Composition brake shoe for urban rail vehicle and manufacturing method thereof
CN105001471A (en) * 2015-05-29 2015-10-28 河北辛集腾跃实业有限公司 High-friction coefficient composition brake shoe and production method thereof
CN106065912A (en) * 2016-06-03 2016-11-02 上海国由复合材料科技有限公司 Composite brake shoe and preparation method thereof
CN106366366A (en) * 2016-08-31 2017-02-01 沈阳远程摩擦密封材料有限公司 Composite brake lining for braking high speed railway with speed of 300 km/h
CN109707773A (en) * 2018-12-27 2019-05-03 湖北飞龙摩擦密封材料股份有限公司 A kind of low noise high temperature resistant drum type friction piece and preparation method thereof by the production of three layered materials

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4344133A1 (en) * 1993-12-23 1995-06-29 Hoechst Ag Process for the preparation of thermostable moldings
JP2002234951A (en) * 2000-11-06 2002-08-23 Borgwarner Inc Friction material formed by depositing friction modifier on surface of high moisture energy carbonaceous friction material
CN101131189A (en) * 2007-08-20 2008-02-27 谭美田 Rubber multi-component composite brake shoe
CN103410893A (en) * 2013-04-26 2013-11-27 广西民族大学 Composition brake shoe for urban rail vehicle and manufacturing method thereof
CN105001471A (en) * 2015-05-29 2015-10-28 河北辛集腾跃实业有限公司 High-friction coefficient composition brake shoe and production method thereof
CN106065912A (en) * 2016-06-03 2016-11-02 上海国由复合材料科技有限公司 Composite brake shoe and preparation method thereof
CN106366366A (en) * 2016-08-31 2017-02-01 沈阳远程摩擦密封材料有限公司 Composite brake lining for braking high speed railway with speed of 300 km/h
CN109707773A (en) * 2018-12-27 2019-05-03 湖北飞龙摩擦密封材料股份有限公司 A kind of low noise high temperature resistant drum type friction piece and preparation method thereof by the production of three layered materials

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112694649A (en) * 2020-12-25 2021-04-23 湖北飞龙摩擦密封材料股份有限公司 Preparation method of novel disc type friction plate
CN115353675A (en) * 2022-10-21 2022-11-18 河北腾跃铁路装备股份有限公司 High-strength brake shoe material and preparation method thereof
CN115353675B (en) * 2022-10-21 2023-02-28 河北腾跃铁路装备股份有限公司 High-strength brake shoe material and preparation method thereof

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Application publication date: 20200828