CN102807699A - Formula of flame-retardant polyethylene plastic - Google Patents
Formula of flame-retardant polyethylene plastic Download PDFInfo
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- CN102807699A CN102807699A CN2012102615158A CN201210261515A CN102807699A CN 102807699 A CN102807699 A CN 102807699A CN 2012102615158 A CN2012102615158 A CN 2012102615158A CN 201210261515 A CN201210261515 A CN 201210261515A CN 102807699 A CN102807699 A CN 102807699A
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- flame
- polyethylene plastic
- retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 37
- 229920003023 plastic Polymers 0.000 title claims abstract description 37
- 239000004033 plastic Substances 0.000 title claims abstract description 37
- -1 polyethylene Polymers 0.000 title claims abstract description 26
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 25
- 239000000654 additive Substances 0.000 claims abstract description 14
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 11
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims description 18
- 239000003112 inhibitor Substances 0.000 claims description 18
- 229920001617 Vinyon Polymers 0.000 claims description 13
- 230000003068 static effect Effects 0.000 claims description 11
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical group [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000004519 grease Substances 0.000 claims description 9
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical group C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 abstract description 4
- 230000003078 antioxidant effect Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002216 antistatic agent Substances 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 2
- 239000004611 light stabiliser Substances 0.000 abstract 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a formula of flame-retardant polyethylene plastic. The flame-retardant polyethylene plastic comprises polyethylene plastic and additives, wherein the additives comprise antimony oxide serving as a flame retardant, dilauryl thiodipropionate serving as an antioxidant, benzophenone serving as a light stabilizer, polyoxyethylene stearate serving as an antistatic agent, acrylate copolymer serving as an impact modifier and dimethylaminopropylamine serving as a cross-linking agent. After the auxiliary additives such as the flame retardant, the antioxidant, the light stabilizer, the antistatic agent and the impact modifier are added during production and processing, the flame-retardant polyethylene plastic has flame retardance, oxidation resistance, ultraviolet absorption property, high mechanical properties and the like; and by the cross-linking agent, the stability of the additives and the polyethylene plastic can be adjusted, and the properties of the polyethylene plastic product are balanced.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of flame-retardant polyethylene plastic.
Background technology
Plastics replace metal to obtain promoting in a lot of fields.According to the requirement of five ministries and commissions, the CIP pipeline will progressively be eliminated after 2000, is replaced by plastics tubing; Plastic pipe has that good corrosion resistance, cost are low, in light weight, the life-span long, easy for installation a bit, still, plastics tubing has shortcomings such as very easily producing static, inflammable, withstand voltage low and poor impact resistance, making prescription are complicated, operation inconvenience simultaneously; Therefore, polythene material is awaited an into adjustment, improve, improve its performance; Especially for the mining plastics in down-hole; Need to adapt to harsh environmental conditions, more need improve its static resistance, flame retardant resistance, improve intensity, toughness etc.
Summary of the invention
The object of the present invention is to provide a kind of fire-retardant, antistatic, anti-oxidation, prescription of absorbing the flame-retardant polyethylene plastic of ultraviolet ray, good mechanical property.
Technical scheme of the present invention is that a kind of prescription of flame-retardant polyethylene plastic comprises vinyon and additive; Described additive comprises fire retardant, inhibitor, photostabilizer, static inhibitor, anti-impact modifier and linking agent, and described fire retardant is a weisspiessglanz, and inhibitor is a thio-2 acid silicone grease in February; Photostabilizer is a UVNUL MS-40; Static inhibitor is a T 46155 hard acid esters, and anti-impact modifier is a Yodo Sol GH 28, and linking agent is a dimethylaminopropylamine.
In preferred embodiment of the present invention; The weight proportion scope of each composition is that vinyon accounts for 78.3%-84.6% in the prescription of said flame-retardant polyethylene plastic, and weisspiessglanz accounts for 5.2%-6.7%, and thio-2 acid silicone grease in February accounts for 1.3%-2.5%; UVNUL MS-40 accounts for 1.6%-2.1%; T 46155 hard acid esters accounts for 1.8%-2.4%, and Yodo Sol GH 28 accounts for 3.3%-4.9%, and dimethylaminopropylamine accounts for 2.2%-3.1%.
In preferred embodiment of the present invention; The weight proportion of each composition is that vinyon accounts for 79.8% in the prescription of said flame-retardant polyethylene plastic, and weisspiessglanz accounts for 6.3%, and thio-2 acid silicone grease in February accounts for 2.4%; UVNUL MS-40 accounts for 1.9%; T 46155 hard acid esters accounts for 2.3%, and Yodo Sol GH 28 accounts for 4.5%, and dimethylaminopropylamine accounts for 2.8%.
According to the invention is a kind of prescription of flame-retardant polyethylene plastic; After in process of manufacture, having added supplementary additives such as fire retardant, inhibitor, photostabilizer, static inhibitor and anti-impact modifier; Make flame-retardant polyethylene plastic had fire-retardant, anti-oxidant, absorb effects such as ultraviolet ray, good mechanical property; Linking agent can be regulated the stable of additive and vinyon, balance vinyon performance of products.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription of flame-retardant polyethylene plastic, comprises vinyon and additive, and described additive comprises fire retardant, inhibitor, photostabilizer, static inhibitor, anti-impact modifier and linking agent; Described fire retardant is a weisspiessglanz; Inhibitor is a thio-2 acid silicone grease in February, and photostabilizer is a UVNUL MS-40, and static inhibitor is a T 46155 hard acid esters; Anti-impact modifier is a Yodo Sol GH 28, and linking agent is a dimethylaminopropylamine.
Further; The weight proportion scope of each composition is that vinyon accounts for 78.3%-84.6% in the prescription of said flame-retardant polyethylene plastic, and weisspiessglanz accounts for 5.2%-6.7%, and thio-2 acid silicone grease in February accounts for 1.3%-2.5%; UVNUL MS-40 accounts for 1.6%-2.1%; T 46155 hard acid esters accounts for 1.8%-2.4%, and Yodo Sol GH 28 accounts for 3.3%-4.9%, and dimethylaminopropylamine accounts for 2.2%-3.1%.
Further; The weight proportion of each composition is that vinyon accounts for 79.8% in the prescription of said flame-retardant polyethylene plastic, and weisspiessglanz accounts for 6.3%, and thio-2 acid silicone grease in February accounts for 2.4%; UVNUL MS-40 accounts for 1.9%; T 46155 hard acid esters accounts for 2.3%, and Yodo Sol GH 28 accounts for 4.5%, and dimethylaminopropylamine accounts for 2.8%.
Fire retardant can play the auxiliary agent that stops or suppress its incendiary effect in plastics.
Inhibitor can delay or block plastics and accelerate the aged material because of oxygenizement, thereby reaches the effect in the work-ing life that prolongs plastics.
Photostabilizer is meant the material that can suppress and delay plastics aged deterioration process in the Working environment under the solar radiation.
Static inhibitor is the electroconductibility that increases product surface, prevents that electrostatic from gathering, thereby plays the electrostatic effect that prevents.
Anti-impact modifier can improve the physical strength of plastics, thus the performance of each side such as the elasticity of increase plastics, toughness, anti tear.
Linking agent can significantly improve thermotolerance, resistance to chemical corrosion, dimensional stability, weathering resistance and mechanical property etc.
According to the invention is a kind of prescription of flame-retardant polyethylene plastic; After in process of manufacture, having added supplementary additives such as fire retardant, inhibitor, photostabilizer, static inhibitor and anti-impact modifier; Make flame-retardant polyethylene plastic had fire-retardant, anti-oxidant, absorb effects such as ultraviolet ray, good mechanical property; Linking agent can be regulated the stable of additive and vinyon, balance vinyon performance of products.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of a flame-retardant polyethylene plastic, it is characterized in that: comprise vinyon and additive, described additive comprises fire retardant, inhibitor, photostabilizer, static inhibitor, anti-impact modifier and linking agent; Described fire retardant is a weisspiessglanz; Inhibitor is a thio-2 acid silicone grease in February, and photostabilizer is a UVNUL MS-40, and static inhibitor is a T 46155 hard acid esters; Anti-impact modifier is a Yodo Sol GH 28, and linking agent is a dimethylaminopropylamine.
2. the prescription of flame-retardant polyethylene plastic according to claim 1; It is characterized in that: the weight proportion scope of each composition is that vinyon accounts for 78.3%-84.6% in the prescription of said flame-retardant polyethylene plastic, and weisspiessglanz accounts for 5.2%-6.7%, and thio-2 acid silicone grease in February accounts for 1.3%-2.5%; UVNUL MS-40 accounts for 1.6%-2.1%; T 46155 hard acid esters accounts for 1.8%-2.4%, and Yodo Sol GH 28 accounts for 3.3%-4.9%, and dimethylaminopropylamine accounts for 2.2%-3.1%.
3. the prescription of flame-retardant polyethylene plastic according to claim 2; It is characterized in that: the weight proportion of each composition is that vinyon accounts for 79.8% in the prescription of said flame-retardant polyethylene plastic, and weisspiessglanz accounts for 6.3%, and thio-2 acid silicone grease in February accounts for 2.4%; UVNUL MS-40 accounts for 1.9%; T 46155 hard acid esters accounts for 2.3%, and Yodo Sol GH 28 accounts for 4.5%, and dimethylaminopropylamine accounts for 2.8%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210261515.8A CN102807699B (en) | 2012-07-27 | 2012-07-27 | Formula of flame-retardant polyethylene plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210261515.8A CN102807699B (en) | 2012-07-27 | 2012-07-27 | Formula of flame-retardant polyethylene plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102807699A true CN102807699A (en) | 2012-12-05 |
| CN102807699B CN102807699B (en) | 2014-05-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210261515.8A Expired - Fee Related CN102807699B (en) | 2012-07-27 | 2012-07-27 | Formula of flame-retardant polyethylene plastic |
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| CN (1) | CN102807699B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232688A (en) * | 2013-05-10 | 2013-08-07 | 苏州工业园区方圆金属制品有限公司 | Polybutylene terephthalate plastic plate |
| CN105694200A (en) * | 2016-04-28 | 2016-06-22 | 苏州新区华士达工程塑胶有限公司 | Anti-corrosion plastic |
| CN105713331A (en) * | 2016-04-28 | 2016-06-29 | 苏州新区华士达工程塑胶有限公司 | High-temperature corrosion-resistant plastic |
| CN105860208A (en) * | 2016-04-28 | 2016-08-17 | 苏州新区华士达工程塑胶有限公司 | High-temperature resistant anticorrosion plastic |
| CN108440820A (en) * | 2018-03-15 | 2018-08-24 | 苏州新区特氟龙塑料制品厂 | A kind of novel antistatic environmentally-friendly plastic |
| CN112023307A (en) * | 2020-07-29 | 2020-12-04 | 北纬四五(深圳)技术有限公司 | Explosion-proof antistatic flame-retardant fire extinguisher box body with integrated arrangement |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018210217A1 (en) * | 2017-05-15 | 2018-11-22 | Rhodia Operations | Method for Scavenging Airborne Formaldehyde |
Citations (5)
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| CN1258692A (en) * | 1998-12-31 | 2000-07-05 | 中国科学院近代物理研究所 | Crosslinked halide-free fireproof composite polyolefine material and its preparation |
| CN101265344A (en) * | 2008-05-04 | 2008-09-17 | 江苏东南电缆有限公司 | Flame-proof crosslinked polyethylene and preparation method thereof |
| WO2009005249A1 (en) * | 2007-07-03 | 2009-01-08 | Ls Cable Ltd. | Flame retardant polymer composition |
| JP2009051918A (en) * | 2007-08-25 | 2009-03-12 | Furukawa Electric Co Ltd:The | Flame-retardant insulated wire |
| CN102250406A (en) * | 2011-05-05 | 2011-11-23 | 上海邦中新材料有限公司 | Polyethylene material with high flame resistance |
-
2012
- 2012-07-27 CN CN201210261515.8A patent/CN102807699B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258692A (en) * | 1998-12-31 | 2000-07-05 | 中国科学院近代物理研究所 | Crosslinked halide-free fireproof composite polyolefine material and its preparation |
| WO2009005249A1 (en) * | 2007-07-03 | 2009-01-08 | Ls Cable Ltd. | Flame retardant polymer composition |
| JP2009051918A (en) * | 2007-08-25 | 2009-03-12 | Furukawa Electric Co Ltd:The | Flame-retardant insulated wire |
| CN101265344A (en) * | 2008-05-04 | 2008-09-17 | 江苏东南电缆有限公司 | Flame-proof crosslinked polyethylene and preparation method thereof |
| CN102250406A (en) * | 2011-05-05 | 2011-11-23 | 上海邦中新材料有限公司 | Polyethylene material with high flame resistance |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103232688A (en) * | 2013-05-10 | 2013-08-07 | 苏州工业园区方圆金属制品有限公司 | Polybutylene terephthalate plastic plate |
| CN105694200A (en) * | 2016-04-28 | 2016-06-22 | 苏州新区华士达工程塑胶有限公司 | Anti-corrosion plastic |
| CN105713331A (en) * | 2016-04-28 | 2016-06-29 | 苏州新区华士达工程塑胶有限公司 | High-temperature corrosion-resistant plastic |
| CN105860208A (en) * | 2016-04-28 | 2016-08-17 | 苏州新区华士达工程塑胶有限公司 | High-temperature resistant anticorrosion plastic |
| CN108440820A (en) * | 2018-03-15 | 2018-08-24 | 苏州新区特氟龙塑料制品厂 | A kind of novel antistatic environmentally-friendly plastic |
| CN112023307A (en) * | 2020-07-29 | 2020-12-04 | 北纬四五(深圳)技术有限公司 | Explosion-proof antistatic flame-retardant fire extinguisher box body with integrated arrangement |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102807699B (en) | 2014-05-14 |
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Effective date of registration: 20131022 Address after: 215427 Innovation Industrial Zone, Huang Jing Town, Taicang, Jiangsu Applicant after: Taicang Tiansili Plastics Co., Ltd. Address before: 215000 Jiangsu city of Suzhou province high tech Zone Jinfeng Road south of Hanshan substation Applicant before: Suzhou Xingwu Engineering Plastic Co., Ltd. |
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Owner name: LINYI SENNUOTE RECYCLED PLASTIC INDUSTRY CO., LTD. Free format text: FORMER OWNER: TAICANG TIANSILI PLASTICS CO., LTD. Effective date: 20141102 |
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Inventor after: Shi Liang Inventor before: Rong Qunshan |
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Free format text: CORRECT: ADDRESS; FROM: 215427 SUZHOU, JIANGSU PROVINCE TO: 276000 LINYI, SHANDONG PROVINCE Free format text: CORRECT: INVENTOR; FROM: RONG QUNSHAN TO: SHI LIANG |
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Effective date of registration: 20141102 Address after: 276000 Shandong Province Hedong District of Linyi City Messire Street Office of Linyi city of renewable resources, eco industrial park Patentee after: Linyi Sennuote Recycled Plastic Industry Co., Ltd. Address before: 215427 Innovation Industrial Zone, Huang Jing Town, Taicang, Jiangsu Patentee before: Taicang Tiansili Plastics Co., Ltd. |
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| C56 | Change in the name or address of the patentee | ||
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Address after: Wang Zhen 276000 Shandong Province Hedong District of Linyi City Zheng Ren Li Village Patentee after: Shandong Sennuote environmental energy Limited by Share Ltd Address before: Linyi Hedong District Messire Street Office of Linyi city of renewable resources, eco industrial park Patentee before: Linyi Sennuote Recycled Plastic Industry Co., Ltd. |
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