CN103804757A - Flame-retardant ultraviolet-proof polyethylene plastic - Google Patents

Flame-retardant ultraviolet-proof polyethylene plastic Download PDF

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Publication number
CN103804757A
CN103804757A CN201410024578.0A CN201410024578A CN103804757A CN 103804757 A CN103804757 A CN 103804757A CN 201410024578 A CN201410024578 A CN 201410024578A CN 103804757 A CN103804757 A CN 103804757A
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CN
China
Prior art keywords
retardant
fire
vinyon
good
antiultraviolet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410024578.0A
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Chinese (zh)
Inventor
徐春华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Huashida Engineering Plastic Co Ltd
Original Assignee
Suzhou New District Huashida Engineering Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Huashida Engineering Plastic Co Ltd filed Critical Suzhou New District Huashida Engineering Plastic Co Ltd
Priority to CN201410024578.0A priority Critical patent/CN103804757A/en
Publication of CN103804757A publication Critical patent/CN103804757A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses flame-retardant ultraviolet-proof polyethylene plastic, comprising a polyethylene base material, a flame retardant, a stabilizer, a silane coupling agent, a filler and a lubricant, wherein the flame retardant is a halogen-free flame retardant; the stabilizer is a light stabilizer-ultraviolet light absorber-benzotriazole-26; the filler is a glass fiber and carbon black; the lubricant is stearic acid or mineral oil. Therefore, the flame-retardant ultraviolet-proof polyethylene plastic provided by the invention has good flame retardant efficiency, as well as good ultraviolet irradiation resistance, good impact resistance, good ageing resistance and good heat resistance, and is especially applicable to automobile door and window, an agricultural film, a packaging film, an electric wire, a pipe, a coating product and the like, and related industries.

Description

A kind of fire-retardant antiultraviolet vinyon
Technical field
The present invention relates to a kind of plastic formula, particularly relate to a kind of fire-retardant antiultraviolet vinyon.
Background technology
Polyethylene odorless, nontoxic, feel ceraceous, has good resistance to low temperature, and chemical stability is good, the erosion of the most of soda acids of ability.Under normal temperature, be insoluble to common solvent, water-absorbent is little, and electrical insulation capability is good.
Polyethylene mainly should be in water supply and sewerage pipeline, sanitary ware, glass door and window etc., therefore has higher requirement for the fire-retardant and antiultraviolet of vinyon functional, and common vinyon is containing above function.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of good fire-retardant antiultraviolet vinyons such as better shock resistance, ageing-resistant, flame retardant resistance, antiultraviolet that have.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of fire-retardant antiultraviolet vinyon is provided, comprise: polyethylene base-material, fire retardant, stablizer, silane coupling agent, weighting agent and lubricant, described fire retardant is halogen-free flame retardants, described stablizer is photostabilizer---UV light absorber---benzotriazole-26, described weighting agent is glass fibre, carbon black, described lubricant stearic acid or mineral oil.
In a preferred embodiment of the present invention, described described weighting agent is glass fibre.
In a preferred embodiment of the present invention, described described lubricant is mineral oil.
In a preferred embodiment of the present invention, the described each composition weight of fire-retardant antiultraviolet vinyon accounts for per-cent and is: polyethylene base-material 70.2%-80.8%, photostabilizer---UV light absorber---benzotriazole-26 3.5%-4.2%, silane coupling agent 2.8%-3.6%, halogen-free flame retardants 3.3%-4.1%, glass fibre 10%-15%, mineral oil 3.3%-4.2%.
In a preferred embodiment of the present invention, the described each composition weight of fire-retardant antiultraviolet vinyon accounts for per-cent and is: polyethylene base-material 75.5%, photostabilizer---UV light absorber---benzotriazole-26 3.6%, silane coupling agent 3.2%, halogen-free flame retardants 3.4%, glass fibre 11%, mineral oil 3.3%.
The invention has the beneficial effects as follows: the invention provides a kind of fire-retardant antiultraviolet vinyon, by adding corresponding properties-correcting agent, thoroughly change common polythene performance, there is good flame retardant effect, resisting ultraviolet radiation, shock resistance, ageing-resistant, resistance toheat is good, architectural the answering such as suitable especially automobile door and window, plastic sheeting for farm use, packing film, electric wire, tubing, coated products, the scope of application further expands.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
The invention provides a kind of fire-retardant antiultraviolet vinyon, comprise: polyethylene base-material, fire retardant, stablizer, silane coupling agent, weighting agent and lubricant, described fire retardant is halogen-free flame retardants, described stablizer is photostabilizer---UV light absorber---benzotriazole-26, described weighting agent is glass fibre, carbon black, described lubricant stearic acid or mineral oil.
The fire-retardant antiultraviolet vinyon of one provided by the invention, described described described weighting agent is glass fibre, described described lubricant is mineral oil.
The fire-retardant antiultraviolet vinyon of one provided by the invention, the described each composition weight of fire-retardant antiultraviolet vinyon accounts for per-cent and is: polyethylene base-material 70.2%-80.8%, photostabilizer---UV light absorber---benzotriazole-26 3.5%-4.2%, silane coupling agent 2.8%-3.6%, halogen-free flame retardants 3.3%-4.1%, glass fibre 10%-15%, mineral oil 3.3%-4.2%.
The fire-retardant antiultraviolet vinyon of one provided by the invention, the described each composition weight of fire-retardant antiultraviolet vinyon accounts for per-cent and is: polyethylene base-material 75.5%, photostabilizer---UV light absorber---benzotriazole-26 3.6%, silane coupling agent 3.2%, halogen-free flame retardants 3.4%, glass fibre 11%, mineral oil 3.3%.
The invention provides a kind of fire-retardant antiultraviolet vinyon, by adding corresponding properties-correcting agent, thoroughly change common polythene performance, there is good flame retardant effect, resisting ultraviolet radiation, shock resistance, ageing-resistant, resistance toheat is good, architectural the answering such as suitable especially automobile door and window, plastic sheeting for farm use, packing film, electric wire, tubing, coated products, the scope of application further expands.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (5)

1. a fire-retardant antiultraviolet vinyon, it is characterized in that, comprise: polyethylene base-material, fire retardant, stablizer, silane coupling agent, weighting agent and lubricant, described fire retardant is halogen-free flame retardants, described stablizer is photostabilizer---UV light absorber---benzotriazole-26, described weighting agent is glass fibre, carbon black, described lubricant stearic acid or mineral oil.
2. the fire-retardant antiultraviolet vinyon of one according to claim 1, is characterized in that, described weighting agent is glass fibre.
3. the outer vinyon of the fire-retardant anti-purple line of one according to claim 1, is characterized in that, described lubricant is mineral oil.
4. the fire-retardant antiultraviolet vinyon of one according to claim 1, it is characterized in that, the described each composition weight of fire-retardant antiultraviolet vinyon accounts for per-cent and is: polyethylene base-material 70.2%-80.8%, photostabilizer---UV light absorber---benzotriazole-26 3.5%-4.2%, silane coupling agent 2.8%-3.6%, halogen-free flame retardants 3.3%-4.1%, glass fibre 10%-15%, mineral oil 3.3%-4.2%.
5. the fire-retardant antiultraviolet vinyon of one according to claim 4, it is characterized in that, the described each composition weight of fire-retardant antiultraviolet vinyon accounts for per-cent and is: polyethylene base-material 75.5%, photostabilizer---UV light absorber---benzotriazole-26 3.6%, silane coupling agent 3.2%, halogen-free flame retardants 3.4%, glass fibre 11%, mineral oil 3.3%.
CN201410024578.0A 2014-01-20 2014-01-20 Flame-retardant ultraviolet-proof polyethylene plastic Pending CN103804757A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410024578.0A CN103804757A (en) 2014-01-20 2014-01-20 Flame-retardant ultraviolet-proof polyethylene plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410024578.0A CN103804757A (en) 2014-01-20 2014-01-20 Flame-retardant ultraviolet-proof polyethylene plastic

Publications (1)

Publication Number Publication Date
CN103804757A true CN103804757A (en) 2014-05-21

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104725700A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Impact-resistant and heat-resistant modified plastic and production method thereof
CN104725703A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Boron fiber modified plastic and preparation method thereof
CN104725702A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Boron-carbide-filled modified plastic and manufacturing method thereof
CN104725698A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Novel hollow glass microballoon filled modified plastic and manufacturing method thereof
CN104725699A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 High-strength corrosion-resistant modified plastic and manufacturing method thereof
CN104844900A (en) * 2015-04-28 2015-08-19 芜湖众力部件有限公司 Modified plastic with the anti-aging flame-retardant performance and production method thereof
CN104844898A (en) * 2015-04-28 2015-08-19 芜湖众力部件有限公司 Heat-resistant antioxidant modified plastic and manufacturing method thereof
CN104861262A (en) * 2015-04-28 2015-08-26 芜湖众力部件有限公司 UV-resistant anti-crack modified plastic and production method thereof
CN105328949A (en) * 2015-12-15 2016-02-17 常熟市众友包装材料有限公司 High-barrier liquid packaging material
CN105479881A (en) * 2015-12-15 2016-04-13 常熟市众友包装材料有限公司 Method for preparing high-barrier packing material
CN108070132A (en) * 2016-11-17 2018-05-25 印佳斌 A kind of advertising cloth

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1516721A (en) * 2001-06-08 2004-07-28 ��һë֯��ʽ���� Flame retardant thermoplastic resin composition
CN1657561A (en) * 2004-12-07 2005-08-24 青岛科技大学 Special material for antistatic impact fire resistant polyethylene pipe
CN101759900A (en) * 2010-01-14 2010-06-30 四川剑南春（集团）有限责任公司 Halogen-free flame-retardant and anti-static polyethylene material, pipe and preparing method thereof
CN102167861A (en) * 2011-04-29 2011-08-31 上海金发科技发展有限公司 Flame-retardant bimodal polyethylene composite material and preparation method thereof
CN102875947A (en) * 2012-09-20 2013-01-16 中国科学院上海应用物理研究所 Halogen-free flame retardant sheath material for nuclear cable, cable sheath, preparation method and application
CN103265752A (en) * 2013-06-04 2013-08-28 广东聚石化学股份有限公司 Halogen-free flame retardant thermoplastic polyolefin cable material
CN103275376A (en) * 2013-06-05 2013-09-04 广东聚石化学股份有限公司 No-precipitating non-halogen environmentally friendly flame-retardant polyethylene material and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1516721A (en) * 2001-06-08 2004-07-28 ��һë֯��ʽ���� Flame retardant thermoplastic resin composition
CN1657561A (en) * 2004-12-07 2005-08-24 青岛科技大学 Special material for antistatic impact fire resistant polyethylene pipe
CN101759900A (en) * 2010-01-14 2010-06-30 四川剑南春（集团）有限责任公司 Halogen-free flame-retardant and anti-static polyethylene material, pipe and preparing method thereof
CN102167861A (en) * 2011-04-29 2011-08-31 上海金发科技发展有限公司 Flame-retardant bimodal polyethylene composite material and preparation method thereof
CN102875947A (en) * 2012-09-20 2013-01-16 中国科学院上海应用物理研究所 Halogen-free flame retardant sheath material for nuclear cable, cable sheath, preparation method and application
CN103265752A (en) * 2013-06-04 2013-08-28 广东聚石化学股份有限公司 Halogen-free flame retardant thermoplastic polyolefin cable material
CN103275376A (en) * 2013-06-05 2013-09-04 广东聚石化学股份有限公司 No-precipitating non-halogen environmentally friendly flame-retardant polyethylene material and preparation method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104725700A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Impact-resistant and heat-resistant modified plastic and production method thereof
CN104725703A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Boron fiber modified plastic and preparation method thereof
CN104725702A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Boron-carbide-filled modified plastic and manufacturing method thereof
CN104725698A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Novel hollow glass microballoon filled modified plastic and manufacturing method thereof
CN104725699A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 High-strength corrosion-resistant modified plastic and manufacturing method thereof
CN104844900A (en) * 2015-04-28 2015-08-19 芜湖众力部件有限公司 Modified plastic with the anti-aging flame-retardant performance and production method thereof
CN104844898A (en) * 2015-04-28 2015-08-19 芜湖众力部件有限公司 Heat-resistant antioxidant modified plastic and manufacturing method thereof
CN104861262A (en) * 2015-04-28 2015-08-26 芜湖众力部件有限公司 UV-resistant anti-crack modified plastic and production method thereof
CN105328949A (en) * 2015-12-15 2016-02-17 常熟市众友包装材料有限公司 High-barrier liquid packaging material
CN105479881A (en) * 2015-12-15 2016-04-13 常熟市众友包装材料有限公司 Method for preparing high-barrier packing material
CN108070132A (en) * 2016-11-17 2018-05-25 印佳斌 A kind of advertising cloth

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Application publication date: 20140521