CN103289380A - Flame-retardant heat-resistant nylon formula - Google Patents
Flame-retardant heat-resistant nylon formula Download PDFInfo
- Publication number
- CN103289380A CN103289380A CN2013102325963A CN201310232596A CN103289380A CN 103289380 A CN103289380 A CN 103289380A CN 2013102325963 A CN2013102325963 A CN 2013102325963A CN 201310232596 A CN201310232596 A CN 201310232596A CN 103289380 A CN103289380 A CN 103289380A
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- CN
- China
- Prior art keywords
- flame
- nylon
- accounts
- resistant nylon
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004677 Nylon Substances 0.000 title claims abstract description 18
- 229920001778 nylon Polymers 0.000 title claims abstract description 18
- 239000003063 flame retardant Substances 0.000 title claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 3
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003365 glass fiber Substances 0.000 claims abstract description 13
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 10
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 9
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims description 3
- 150000008065 acid anhydrides Chemical class 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000005062 Polybutadiene Substances 0.000 abstract 2
- 229920002857 polybutadiene Polymers 0.000 abstract 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 1
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a flame-retardant heat-resistant nylon formula which comprises the following components in percentage by weight: 70-78% of nylon 6, 15% of hydrogenated styrene-butadiene rubber, 14-15% of glass fiber, 1.0% of hydrogenated polybutadiene, 10% of decabromodiphenyl ether and 6% of antimony trioxide; and the hydrogenated polybutadiene uses chlorinated triphenylhexa-acid anhydride as the terminal group. The invention can reasonably integrate the wear-resistant nylon 6 formula by adding components; and the nylon 6 has the advantages of flame retardancy and heat resistance, and thus, can be better put into industrial application.
Description
Technical field
The present invention relates to a kind of nylon formula, particularly relate to a kind of flame-proof heat-resistant nylon formula.
Background technology
Nylon is a kind of range of application engineering plastics comparatively widely, along with it is increasingly extensive in the application in fields such as automobile, machinery and electrical industry, people are more and more higher to the requirement of its safety performance, so a kind of flame retardant resistance and stable on heating engineering prescription of can effectively improving of exigence produced the practicality that product improves product.
Summary of the invention
The technical problem that the present invention mainly solves provides a kind of flame-proof heat-resistant nylon formula, wear resistant nylon 6 prescription reasonable integrations can be added component, and nylon 6 has fire-retardant, heat-resisting action effect, makes nylon better drop into industrial application.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of flame-proof heat-resistant nylon formula is provided, count by weight percentage, the raw material nylon-6 accounts for 50 ~ 70% in the described prescription, heat-resistant agent is HSBR, HSBR accounts for 15%, anti-wear agent is glass fibre, and glass fibre accounts for 14 ~ 15%, hydrogenated butadiene polymer 1.0%, fire retardant account for 16%.
In a preferred embodiment of the present invention, described hydrogenated butadiene polymer is auxiliary agent, and wherein hydrogenated butadiene polymer is end group with chlorinated triphenyl six acid anhydrides.
In a preferred embodiment of the present invention, described glass fibre is that length is the alkali-free short glass fiber of 2 ~ 3mm.
In a preferred embodiment of the present invention, described fire retardant is decabromodiphenyl oxide and antimonous oxide mixture, and decabromodiphenyl oxide accounts for 10%, antimonous oxide accounts for 6%.
The invention has the beneficial effects as follows: the present invention can add component with wear resistant nylon 6 prescription reasonable integrations, and nylon 6 has fire-retardant, heat-resisting action effect.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
The embodiment of the invention provides following technical scheme.
In one embodiment, a kind of flame-proof heat-resistant nylon formula, comprise: count by weight percentage, the raw material nylon-6 accounts for 50 ~ 70% in the described prescription, heat-resistant agent is HSBR, HSBR accounts for 15%, anti-wear agent is glass fibre, and glass fibre accounts for 14 ~ 15%, hydrogenated butadiene polymer 1.0%, fire retardant account for 16%.
Be different from prior art, in one embodiment, described hydrogenated butadiene polymer is auxiliary agent, and wherein hydrogenated butadiene polymer is end group with chlorinated triphenyl six acid anhydrides.
Preferably, described glass fibre is that length is the alkali-free short glass fiber of 2 ~ 3mm.
Preferably, described fire retardant is decabromodiphenyl oxide and antimonous oxide mixture, still guarantees to have good electrical properties in order to make in the nylon after introducing fire retardant, and wherein decabromodiphenyl oxide accounts for 10%, antimonous oxide accounts for 6%.
The present invention adds component by reasonable integration that wear resistant nylon is filled a prescription, and nylon has fire-retardant, heat-resisting action effect, makes nylon better drop into industrial application, when being convenient for people to live, brings better economic benefit.
The above only is embodiments of the invention; be not so limit claim of the present invention; every equivalent structure or equivalent flow process conversion that utilizes description of the present invention to do; or directly or indirectly be used in other relevant technical fields, all in like manner be included in the scope of patent protection of the present invention.
Claims (4)
1. flame-proof heat-resistant nylon formula, it is characterized in that, count by weight percentage, the raw material nylon-6 accounts for 50 ~ 70% in the described prescription, heat-resistant agent is HSBR, HSBR accounts for 15%, anti-wear agent is glass fibre, and glass fibre accounts for 14 ~ 15%, hydrogenated butadiene polymer 1.0%, fire retardant account for 16%.
2. flame-proof heat-resistant nylon formula according to claim 1 is characterized in that, described hydrogenated butadiene polymer is auxiliary agent, and wherein hydrogenated butadiene polymer is end group with chlorinated triphenyl six acid anhydrides.
3. flame-proof heat-resistant nylon formula according to claim 1 is characterized in that, described glass fibre is that length is the alkali-free short glass fiber of 2 ~ 3mm.
4. flame-proof heat-resistant nylon formula according to claim 1 is characterized in that, described fire retardant is decabromodiphenyl oxide and antimonous oxide mixture, and decabromodiphenyl oxide accounts for 10%, antimonous oxide accounts for 6%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102325963A CN103289380A (en) | 2013-06-13 | 2013-06-13 | Flame-retardant heat-resistant nylon formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102325963A CN103289380A (en) | 2013-06-13 | 2013-06-13 | Flame-retardant heat-resistant nylon formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103289380A true CN103289380A (en) | 2013-09-11 |
Family
ID=49090944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102325963A Pending CN103289380A (en) | 2013-06-13 | 2013-06-13 | Flame-retardant heat-resistant nylon formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103289380A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104489987A (en) * | 2014-10-22 | 2015-04-08 | 嘉兴职业技术学院 | Multifunctional safety helmet |
| CN105113044A (en) * | 2015-09-15 | 2015-12-02 | 苏州顺唐化纤有限公司 | Inflaming-retarding polyamide fiber preparing method |
| CN106675008A (en) * | 2017-01-19 | 2017-05-17 | 广东星联科技有限公司 | High-heat conducting nylon 6 composite material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0532889A (en) * | 1991-07-31 | 1993-02-09 | Asahi Chem Ind Co Ltd | Automobile underhood part |
-
2013
- 2013-06-13 CN CN2013102325963A patent/CN103289380A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0532889A (en) * | 1991-07-31 | 1993-02-09 | Asahi Chem Ind Co Ltd | Automobile underhood part |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104489987A (en) * | 2014-10-22 | 2015-04-08 | 嘉兴职业技术学院 | Multifunctional safety helmet |
| CN105113044A (en) * | 2015-09-15 | 2015-12-02 | 苏州顺唐化纤有限公司 | Inflaming-retarding polyamide fiber preparing method |
| CN106675008A (en) * | 2017-01-19 | 2017-05-17 | 广东星联科技有限公司 | High-heat conducting nylon 6 composite material and preparation method thereof |
| CN106675008B (en) * | 2017-01-19 | 2020-08-14 | 广东星联科技有限公司 | High-thermal-conductivity nylon 6 composite material and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130911 |