CN103709698A - Formula of modified unsaturated polyester resin - Google Patents

Formula of modified unsaturated polyester resin Download PDF

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Publication number
CN103709698A
CN103709698A CN201310728232.4A CN201310728232A CN103709698A CN 103709698 A CN103709698 A CN 103709698A CN 201310728232 A CN201310728232 A CN 201310728232A CN 103709698 A CN103709698 A CN 103709698A
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CN
China
Prior art keywords
accounts
polyester resin
unsaturated polyester
formula
modified unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310728232.4A
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Chinese (zh)
Inventor
刘荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU HANXIN PLASTIC Co Ltd
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SUZHOU HANXIN PLASTIC Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by SUZHOU HANXIN PLASTIC Co Ltd filed Critical SUZHOU HANXIN PLASTIC Co Ltd
Priority to CN201310728232.4A priority Critical patent/CN103709698A/en
Publication of CN103709698A publication Critical patent/CN103709698A/en
Pending legal-status Critical Current

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  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention discloses a formula of a modified unsaturated polyester resin, which comprises an unsaturated polyester resin and additives, wherein the additives comprise a filler, an antioxidant, a compatilizer, a photostabilizer and a toughener; and the filler is glass fibers, the antioxidant is butylated hydroxytoluene, the compatilizer is meta-isopropenyl-2,2-dimethylmesitoylisocyanate, the photostabilizer is phenyl salicylate, and the toughener is polyvinyl butyral. The modified unsaturated polyester resin has the advantages of high mechanical strength, small shrinkage, aging resistance, ultraviolet resistance, favorable compatibility and the like.

Description

A kind of formula of modified unsaturated polyester resin
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of formula of modified unsaturated polyester resin.
Background technology
Unsaturated polyester resin can at room temperature solidify, normal pressure compacted under, and processing performance is flexible, but the intensity of unsaturated polyester resin own is not high, and while solidifying, shrinking percentage is larger, and the shelf-life is short, the poor performance of organic solvent-resistant, mechanical performance index is lower slightly.
Summary of the invention
The object of the present invention is to provide that a kind of physical strength is large, shrinking percentage is little, the formula of ageing-resistant, antiultraviolet and the good modified unsaturated polyester resin of consistency.
Technical scheme of the present invention is, a kind of formula of modified unsaturated polyester resin, comprise unsaturated polyester resin and additive, described additive comprises weighting agent, antioxidant, compatilizer, photostabilizer and toughner, described weighting agent is glass fibre, described antioxidant is butylated hydroxytoluene, described compatilizer is m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester, described photostabilizer is salicylic acid phenyl ester, and described toughner is polyvinyl butyral acetal.
In a preferred embodiment of the present invention, each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 65%-73%, glass fibre accounts for 13.4%-16.7%, butylated hydroxytoluene accounts for 3.4%-5.2%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.8%-3.7%, and salicylic acid phenyl ester accounts for 2.9%-4.1%, and polyvinyl butyral acetal accounts for 4.5%-5.3%.
In a preferred embodiment of the present invention, each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 71.3%, glass fibre accounts for 13.9%, butylated hydroxytoluene accounts for 3.8%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 3.1%, and salicylic acid phenyl ester accounts for 3.2%, and polyvinyl butyral acetal accounts for 4.7%.
Of the present invention is a kind of formula of modified unsaturated polyester resin, and the modified unsaturated polyester resin that makes to make has that physical strength is large, shrinking percentage is little, ageing-resistant, antiultraviolet and the effect such as consistency is good.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Of the present invention is a kind of formula of modified unsaturated polyester resin, comprise unsaturated polyester resin and additive, described additive comprises weighting agent, antioxidant, compatilizer, photostabilizer and toughner, described weighting agent is glass fibre, described antioxidant is butylated hydroxytoluene, and described compatilizer is m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester, described photostabilizer is salicylic acid phenyl ester, and described toughner is polyvinyl butyral acetal.
Further, each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 65%-73%, glass fibre accounts for 13.4%-16.7%, butylated hydroxytoluene accounts for 3.4%-5.2%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.8%-3.7%, and salicylic acid phenyl ester accounts for 2.9%-4.1%, and polyvinyl butyral acetal accounts for 4.5%-5.3%.
Further, each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 71.3%, glass fibre accounts for 13.9%, butylated hydroxytoluene accounts for 3.8%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 3.1%, and salicylic acid phenyl ester accounts for 3.2%, and polyvinyl butyral acetal accounts for 4.7%.
Further, each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 66.8%, glass fibre accounts for 16.1%, butylated hydroxytoluene accounts for 4.8%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 3.4%, and salicylic acid phenyl ester accounts for 3.8%, and polyvinyl butyral acetal accounts for 5.1%.
Of the present invention is a kind of formula of modified unsaturated polyester resin, and the modified unsaturated polyester resin that makes to make has that physical strength is large, shrinking percentage is little, ageing-resistant, antiultraviolet and the effect such as consistency is good.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; the variation that can expect without creative work or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (3)

1. the formula of a modified unsaturated polyester resin, it is characterized in that: comprise unsaturated polyester resin and additive, described additive comprises weighting agent, antioxidant, compatilizer, photostabilizer and toughner, described weighting agent is glass fibre, described antioxidant is butylated hydroxytoluene, and described compatilizer is m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester, described photostabilizer is salicylic acid phenyl ester, and described toughner is polyvinyl butyral acetal.
2. the formula of modified unsaturated polyester resin according to claim 1, it is characterized in that: each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 65%-73%, glass fibre accounts for 13.4%-16.7%, butylated hydroxytoluene accounts for 3.4%-5.2%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.8%-3.7%, and salicylic acid phenyl ester accounts for 2.9%-4.1%, and polyvinyl butyral acetal accounts for 4.5%-5.3%.
3. the formula of modified unsaturated polyester resin according to claim 2, it is characterized in that: each composition weight percent of the formula of described modified unsaturated polyester resin is that unsaturated polyester resin accounts for 71.3%, glass fibre accounts for 13.9%, butylated hydroxytoluene accounts for 3.8%, m-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 3.1%, and salicylic acid phenyl ester accounts for 3.2%, and polyvinyl butyral acetal accounts for 4.7%.
CN201310728232.4A 2013-12-26 2013-12-26 Formula of modified unsaturated polyester resin Pending CN103709698A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310728232.4A CN103709698A (en) 2013-12-26 2013-12-26 Formula of modified unsaturated polyester resin

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Application Number Priority Date Filing Date Title
CN201310728232.4A CN103709698A (en) 2013-12-26 2013-12-26 Formula of modified unsaturated polyester resin

Publications (1)

Publication Number Publication Date
CN103709698A true CN103709698A (en) 2014-04-09

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107012742A (en) * 2017-04-27 2017-08-04 舒尔环保科技(合肥)有限公司 A kind of breakage-proof air purification filter paper and preparation method
CN110128987A (en) * 2019-05-30 2019-08-16 山西工程技术学院 A kind of Anchor Agent high temperature resistant high tenacity resin and preparation method thereof
CN110283439A (en) * 2019-04-17 2019-09-27 深圳市深捷通管业发展有限公司 A kind of production technology of glass modified PE pipe

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1184828A (en) * 1996-12-09 1998-06-17 杨正海 Flame-retardant unsaturated polyester resin compositions, and decoration plate made therefrom
CN1376738A (en) * 2001-03-27 2002-10-30 上海合科科技有限公司 Composite high-molecular section for road surface and its preparing process
CN101050295A (en) * 2007-04-20 2007-10-10 常熟佳发化学有限责任公司 Composition of unsaturated resin, preparation method, and method of application

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1184828A (en) * 1996-12-09 1998-06-17 杨正海 Flame-retardant unsaturated polyester resin compositions, and decoration plate made therefrom
CN1376738A (en) * 2001-03-27 2002-10-30 上海合科科技有限公司 Composite high-molecular section for road surface and its preparing process
CN101050295A (en) * 2007-04-20 2007-10-10 常熟佳发化学有限责任公司 Composition of unsaturated resin, preparation method, and method of application

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107012742A (en) * 2017-04-27 2017-08-04 舒尔环保科技(合肥)有限公司 A kind of breakage-proof air purification filter paper and preparation method
CN110283439A (en) * 2019-04-17 2019-09-27 深圳市深捷通管业发展有限公司 A kind of production technology of glass modified PE pipe
CN110283439B (en) * 2019-04-17 2023-01-20 深圳市深捷通管业发展有限公司 Production process of glass fiber modified PE pipe
CN110128987A (en) * 2019-05-30 2019-08-16 山西工程技术学院 A kind of Anchor Agent high temperature resistant high tenacity resin and preparation method thereof

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Application publication date: 20140409