CN106118011A - A kind of use for electronic products plastic master batch - Google Patents

A kind of use for electronic products plastic master batch Download PDF

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Publication number
CN106118011A
CN106118011A CN201610717729.XA CN201610717729A CN106118011A CN 106118011 A CN106118011 A CN 106118011A CN 201610717729 A CN201610717729 A CN 201610717729A CN 106118011 A CN106118011 A CN 106118011A
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CN
China
Prior art keywords
parts
dispersant
master batch
electronic products
plastic master
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610717729.XA
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Chinese (zh)
Inventor
黄雄关
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Wuhu City Tian Xiong New Material Science And Technology Ltd
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Wuhu City Tian Xiong New Material Science And Technology Ltd
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Priority to CN201610717729.XA priority Critical patent/CN106118011A/en
Publication of CN106118011A publication Critical patent/CN106118011A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

Abstract

The invention discloses a kind of use for electronic products plastic master batch, component including following mass fraction: PC resin 65 85 parts, nano titanium oxide 10 15 parts, polycarbodiimide 0.5 1 parts, fire retardant 0.5 2 parts, toughener 15 parts, ultraviolet light screener 18 parts, ethylene methyl acrylate copolymer 16 18 parts, linear polyethylene 12 14 parts, high density polyethylene (HDPE) 8 10 parts, Low Density Polyethylene 25 parts, lubricant 25 parts, coupling agent 0.1 5 parts, plasticizer 1 10 parts, dispersant 0.1 5 parts, filler 15 40 parts, 0.5 2 parts of antioxidant, dispersant 0.5 5 parts.The plastic master batch wearability of the present invention, hydrolytic resistance are good, and have anti-ultraviolet property, can be widely applied to field of electronic devices.

Description

A kind of use for electronic products plastic master batch
Technical field
The invention belongs to technical field of polymer materials, particularly relate to a kind of use for electronic products plastic master batch.
Background technology
Electronic device has become a part indispensable in our life, and a lot of parts of electronic device all need Plastics to be used.Electronic device plastics must have the function such as light weight, intensity is big, wearability good, uvioresistant as required.
PC i.e. Merlon, is the amorphous polymer of almost colourless glassy state, has the highest toughness, and higher is anti- Impact strength and higher heat distortion temperature, by the mechanical performance of its excellence, PC has become in five large-engineering plastics and has increased Fastest general engineering plastic.But because its stability to hydrolysis resistance is inadequate, wearability is poor and poor the lacking of ultraviolet resistance Point so that it is range of application receives a definite limitation, still can not meet specific occasion and be used for demand.
Therefore, a kind of modified PC compositions to be studied so that it is performance meets electronic device plastics.
Summary of the invention
Goal of the invention: the present invention is directed to deficiency of the prior art, proposes a kind of plastic master batch, wearability, hydrolytic resistance Good, and there is anti-ultraviolet property, can be widely applied to field of electronic devices.
Technical scheme: a kind of use for electronic products plastic master batch of the present invention, including the component of following mass fraction:
PC resin 65-85 part, nano titanium oxide 10-15 part, polycarbodiimide 0.5-1 part, fire retardant 0.5-2 Part, toughener 1-5 part, ultraviolet light screener 1-8 part, ethylene-methyl acrylate copolymer 16-18 part, linear polyethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 2-5 part, lubricant 2-5 part, coupling agent 0.1-5 part, increase Mould agent 1-10 part, dispersant 0.1-5 part, filler 15-40 part, antioxidant 0.5-2 part, dispersant 0.5-5 part.
Further, including the component of following mass fraction:
PC resin 70-85 part, nano titanium oxide 12-15 part, polycarbodiimide 0.6-1 part, fire retardant 1-2 Part, toughener 3-5 part, ultraviolet light screener 2-8 part, ethylene-methyl acrylate copolymer 16-18 part, linear polyethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 3-5 part, lubricant 3-5 part, coupling agent 3-5 part, plasticising Agent 2-10 part, dispersant 3-5 part, filler 20-40 part, antioxidant 1-2 part, dispersant 2-5 part.
Further, including the component of following mass fraction:
PC resin 75 parts, nano titanium oxide 13 parts, polycarbodiimide 0.8 part, fire retardant 1.5 parts, toughener 4 parts, ultraviolet light screener 6 parts, ethylene-methyl acrylate copolymer 17 parts, linear polyethylene 13 parts, high density polyethylene (HDPE) 9 parts, Low Density Polyethylene 4 parts, lubricant 4 parts, coupling agent 4 parts, plasticizer 6 parts, dispersant 4 parts, filler 30 parts, antioxygen Agent 1.5 parts, dispersant 3 parts.
Further, described coupling agent is silane coupler or aluminate coupling agent.
Further, described dispersant is grafting EBA dispersant.
Further, described lubricant is E wax, OP wax or Tissuemat E.
Further, the one or more combination thing during described plasticizer is ethylene glycol, glycerol, carbamide.
Further, described ultraviolet light screener is nano-ZnO.
Beneficial effect: the plastic master batch wearability of the present invention, hydrolytic resistance are good, and have anti-ultraviolet property, can be extensive It is applied to field of electronic devices.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
A kind of use for electronic products plastic master batch, including the component of following mass fraction:
PC resin 65 parts, nano titanium oxide 10 parts, polycarbodiimide 0.5 part, fire retardant 0.5 part, toughener 1 part, ultraviolet light screener 1 part, ethylene-methyl acrylate copolymer 16 parts, linear polyethylene 12 parts, high density polyethylene (HDPE) 8 parts, Low Density Polyethylene 2 parts, lubricant 2 parts, coupling agent 0.1 part, plasticizer 1 part, dispersant 0.1 part, filler 15 Part, 0.5 part of antioxidant, dispersant 0.5 part.
Described coupling agent is silane coupler or aluminate coupling agent.
Described dispersant is grafting EBA dispersant.
Described lubricant is E wax, OP wax or Tissuemat E.
Described plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
Described ultraviolet light screener is nano-ZnO.
Embodiment 2
A kind of use for electronic products plastic master batch, including the component of following mass fraction:
PC resin 85 parts, nano titanium oxide 15 parts, polycarbodiimide 1 part, fire retardant 2 parts, toughener 5 Part, ultraviolet light screener 8 parts, ethylene-methyl acrylate copolymer 18 parts, linear polyethylene 14 parts, high density polyethylene (HDPE) 10 parts, Low Density Polyethylene 5 parts, lubricant 5 parts, coupling agent 5 parts, plasticizer 10 parts, dispersant 5 parts, filler 40 parts, 2 parts of antioxidant, dispersant 5 parts.
Described coupling agent is silane coupler or aluminate coupling agent.
Described dispersant is grafting EBA dispersant.
Described lubricant is E wax, OP wax or Tissuemat E.
Described plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
Described ultraviolet light screener is nano-ZnO.
Embodiment 3
A kind of use for electronic products plastic master batch, including the component of following mass fraction:
PC resin 75 parts, nano titanium oxide 13 parts, polycarbodiimide 0.8 part, fire retardant 1.5 parts, toughener 4 parts, ultraviolet light screener 6 parts, ethylene-methyl acrylate copolymer 17 parts, linear polyethylene 13 parts, high density polyethylene (HDPE) 9 parts, Low Density Polyethylene 4 parts, lubricant 4 parts, coupling agent 4 parts, plasticizer 6 parts, dispersant 4 parts, filler 30 parts, antioxygen Agent 1.5 parts, dispersant 3 parts.
Described coupling agent is silane coupler or aluminate coupling agent.
Described dispersant is grafting EBA dispersant.
Described lubricant is E wax, OP wax or Tissuemat E.
Described plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
Described ultraviolet light screener is nano-ZnO.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification being made above example, all still falls within the range of technical solution of the present invention.

Claims (8)

1. a use for electronic products plastic master batch, it is characterised in that: include the component of following mass fraction:
PC resin 65-85 part, nano titanium oxide 10-15 part, polycarbodiimide 0.5-1 part, fire retardant 0.5-2 Part, toughener 1-5 part, ultraviolet light screener 1-8 part, ethylene-methyl acrylate copolymer 16-18 part, linear polyethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 2-5 part, lubricant 2-5 part, coupling agent 0.1-5 part, increase Mould agent 1-10 part, dispersant 0.1-5 part, filler 15-40 part, antioxidant 0.5-2 part, dispersant 0.5-5 part.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: include following mass fraction Component:
PC resin 70-85 part, nano titanium oxide 12-15 part, polycarbodiimide 0.6-1 part, fire retardant 1-2 Part, toughener 3-5 part, ultraviolet light screener 2-8 part, ethylene-methyl acrylate copolymer 16-18 part, linear polyethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 3-5 part, lubricant 3-5 part, coupling agent 3-5 part, plasticising Agent 2-10 part, dispersant 3-5 part, filler 20-40 part, antioxidant 1-2 part, dispersant 2-5 part.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: include following mass fraction Component:
PC resin 75 parts, nano titanium oxide 13 parts, polycarbodiimide 0.8 part, fire retardant 1.5 parts, toughener 4 parts, ultraviolet light screener 6 parts, ethylene-methyl acrylate copolymer 17 parts, linear polyethylene 13 parts, high density polyethylene (HDPE) 9 parts, Low Density Polyethylene 4 parts, lubricant 4 parts, coupling agent 4 parts, plasticizer 6 parts, dispersant 4 parts, filler 30 parts, antioxygen Agent 1.5 parts, dispersant 3 parts.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: described coupling agent is that silane is even Connection agent or aluminate coupling agent.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: described dispersant is grafting EBA dispersant.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: described lubricant be E wax, OP wax or Tissuemat E.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: described plasticizer is second two One or more combination thing in alcohol, glycerol, carbamide.
A kind of use for electronic products plastic master batch the most according to claim 1, it is characterised in that: described ultraviolet light screener is Nano-ZnO.
CN201610717729.XA 2016-08-25 2016-08-25 A kind of use for electronic products plastic master batch Pending CN106118011A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113174128A (en) * 2021-06-17 2021-07-27 惠州市适合颜料塑胶制品有限公司 Ultraviolet-resistant anti-aging master batch and ultraviolet-resistant anti-aging plastic

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1160414A (en) * 1994-09-09 1997-09-24 陶氏化学公司 Blends of polycarbonate and ethylene polymers
CN101724238A (en) * 2008-10-24 2010-06-09 比亚迪股份有限公司 Makrolon/polyethylene alloy material and preparation method thereof
CN104945877A (en) * 2015-06-25 2015-09-30 苏州洋杰电子有限公司 Plastic masterbatch for electronic device and preparation method thereof
CN105802183A (en) * 2016-05-25 2016-07-27 奉化市旭日鸿宇有限公司 Polyethylene-modified polycarbonate composite material composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1160414A (en) * 1994-09-09 1997-09-24 陶氏化学公司 Blends of polycarbonate and ethylene polymers
CN101724238A (en) * 2008-10-24 2010-06-09 比亚迪股份有限公司 Makrolon/polyethylene alloy material and preparation method thereof
CN104945877A (en) * 2015-06-25 2015-09-30 苏州洋杰电子有限公司 Plastic masterbatch for electronic device and preparation method thereof
CN105802183A (en) * 2016-05-25 2016-07-27 奉化市旭日鸿宇有限公司 Polyethylene-modified polycarbonate composite material composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113174128A (en) * 2021-06-17 2021-07-27 惠州市适合颜料塑胶制品有限公司 Ultraviolet-resistant anti-aging master batch and ultraviolet-resistant anti-aging plastic

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Application publication date: 20161116

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