CN103289164B - A polymer flame retardant antistatic plastic - Google Patents

A polymer flame retardant antistatic plastic Download PDF

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CN103289164B
CN103289164B CN201310190617.XA CN201310190617A CN103289164B CN 103289164 B CN103289164 B CN 103289164B CN 201310190617 A CN201310190617 A CN 201310190617A CN 103289164 B CN103289164 B CN 103289164B
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parts
flame
retardant
polymer
plastic
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CN201310190617.XA
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CN103289164A (en
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肖伟荣
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南通玖伍捌科技企业孵化器有限公司
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Abstract

本发明公开一种高分子阻燃抗静电塑料,其特征在于它由以下重量份的组分组成:热塑性塑料100份、环氧大豆油2-3份、抗氧剂DLTP? Disclosed is a flame-retardant anti-static plastic polymer, characterized in that it consists of the following parts by weight of components: 100 parts of thermoplastic, 2-3 parts of epoxidized soybean oil, antioxidant DLTP? 0-4份、硅烷偶联剂0.02-2.5份、炭黑5-10份、纳米氢氧化镁2-15份、硼酸锌5-10份、玻璃纤维3-5份、聚乙烯蜡1-5份。 0-4 parts, 0.02 to 2.5 parts of a silane coupling agent, 5-10 parts of carbon black, 15 parts of magnesium hydroxide nanoparticles, 5-10 parts of zinc borate, 3-5 parts of glass fiber, polyethylene wax 1-5 copies. 本发明利用聚酰胺与玻璃纤维的亲和性十分良好的优点,添加适量的玻璃纤维,不仅能提高塑料的抗静电性,同时也满足与基材相容性好,对基材的性能没有影响;本发明使用纳米氢氧化镁和硼酸锌作为阻燃剂,阻燃性能好。 The present invention takes advantage of the affinity of polyamide and glass fiber very good advantage, adding an appropriate amount of glass fibers not only improve the antistatic plastics, but also to meet good compatibility with the substrate, no effect on the properties of the substrate ; the present invention is the use of nano-zinc borate and magnesium hydroxide as a flame retardant, flame-retardant properties. 本发明制备得到的高分子阻燃抗静电塑料可用于汽车部件、化学建材等塑料制品中。 Polymer prepared by the invention can be used for flame retardant antistatic plastic automobile parts, building materials, chemical products and other plastic.

Description

一种高分子阻燃抗静电塑料 A polymer flame retardant antistatic plastic

技术领域 FIELD

[0001] 本发明涉及一种塑料材料,尤其涉及一种高分子阻燃抗静电塑料。 [0001] The present invention relates to a plastic material, particularly to a flame-retardant anti-static plastic polymer.

背景技术 Background technique

[0002] 超高分子量聚乙烯是一种线型结构的具有优异综合性能的热塑性工程塑料,它的平均分子量约35万-800万,因分子量高而具有其它塑料无可比拟的优异的耐冲击性、耐磨损、自润滑性、耐化学腐蚀等性能。 [0002] The ultrahigh molecular weight polyethylene is excellent in overall performance engineering thermoplastics having a linear structure, which is an average molecular weight of about 35 to 8,000,000, because of the high molecular weight have excellent impact resistance and other plastic unparalleled resistance, wear resistance, self-lubricating, corrosion-resistant chemical properties.

[0003] 聚酰胺俗称尼龙,为韧性角状半透明或乳白色结晶,作为工程塑料的尼龙分子量 [0003] commonly known as nylon polyamide, ductile angular translucent or white crystalline, as the molecular weight of nylon engineering plastics

1.5-3万,具有很好的机械强度,软化点高、耐热,摩擦系数低、耐磨损,自润滑性,电绝缘性好,无毒,无臭,耐候性好,与玻璃纤维的亲和性十分良好。 1.5-3 million and having good mechanical strength, high softening point, heat resistance, low coefficient of friction, wear resistance, self-lubricating, electrically insulating, non-toxic, odorless, good weather resistance, and glass fibers affinity is very good.

[0004] 塑料应用于各个领域,同时也对其性能提出了更高的要求,在高温下使用就要求具有阻燃性、耐高温性,抗静电性也是不可或缺的。 [0004] The plastics used in various fields, but also a higher requirements on their performance, at a high temperature requires flame retardancy, heat resistance, antistatic properties is indispensable.

发明内容 SUMMARY

[0005] 本发明的目的在于提供一种高分子阻燃抗静电塑料。 [0005] The object of the present invention is to provide a flame-retardant anti-static plastic polymer.

[0006] 本发明的目的可以通过以下技术方案实现: [0006] The object of the present invention can be achieved by the following technical solution:

[0007] 一种高分子阻燃抗静电塑料,其特征在于它由以下重量份的组分组成:热塑性塑料100份、环氧大豆油2-3份、抗氧剂DLTP 0-4份、硅烷偶联剂0.02-2.5份、炭黑5_10份、纳米氢氧化镁2-15份、硼酸锌5-10份、玻璃纤维3-5份、聚乙烯蜡1-5份。 [0007] A polymer flame-retardant anti-static plastic, characterized in that it consists of the following parts by weight of components: 100 parts of thermoplastic, 2-3 parts of epoxidized soybean oil, antioxidant DLTP 0-4 parts silane 0.02 to 2.5 parts coupling agent, 5_10 parts of carbon black, 15 parts of magnesium hydroxide nanoparticles, 5-10 parts of zinc borate, 3-5 parts of glass fiber, polyethylene wax 1-5 parts.

[0008] 所述热塑性塑料为超高分子量聚乙烯和聚酰胺的混合物,且超高分子量聚乙烯和聚酰胺的重量比为5-10:1。 [0008] The ultrahigh molecular weight polyethylene is a thermoplastic polyamide and mixtures thereof, and the weight ratio of high molecular weight polyethylene and the polyamide is 5-10: 1.

[0009] 它由以下重量份的组分组成:超高分子量聚乙烯90份、聚酰胺10份、环氧大豆油2份、抗氧剂DLTP 3份、硅烷偶联剂1.5份、炭黑7份、纳米氢氧化镁10份、硼酸锌6份、玻璃纤维4份、聚乙烯蜡2份。 [0009] It consists of the following parts by weight of components: 90 parts of ultrahigh molecular weight polyethylene, polyamide 10 parts, 2 parts of epoxidized soybean oil, antioxidant DLTP 3 parts, 1.5 parts of a silane coupling agent, carbon black 7 parts of magnesium hydroxide nanoparticles 10 parts, 6 parts of zinc borate, 4 parts of glass fibers, 2 parts of polyethylene wax.

[0010] 如权利要求1或2所述的高分子阻燃抗静电塑料的制备方法:按配方称取各组分,混合均匀后,熔融混炼、挤出造粒,即获得所述高分子阻燃抗静电剂。 [0010] The method of preparing a polymer as claimed in flame-retardant anti-static plastic of claim 1 or 2, wherein: Weigh the components according to the formulation, after mixing, melt-kneading, extrusion granulation, i.e., the polymer is obtained retardant antistatic agent.

[0011] 本发明的有益效果:本发明利用聚酰胺与玻璃纤维的亲和性十分良好的优点,添加适量的玻璃纤维,不仅能提高塑料的抗静电性,同时也满足与基材相容性好,对基材的性能没有影响;本发明使用纳米氢氧化镁和硼酸锌作为阻燃剂,阻燃性能好。 [0011] Advantageous Effects of Invention: The present invention takes advantage of the affinity of polyamide and glass fiber a very good advantage, adding an appropriate amount of glass fibers not only improve the antistatic plastics, but also to meet the compatibility with the substrate good, no effect on the properties of the substrate; the present invention is the use of nano-zinc borate and magnesium hydroxide as good flame retardant properties.

具体实施方式 Detailed ways

[0012] 下面结合具体实施例对本发明作进一步描述。 [0012] The following embodiments in conjunction with specific embodiments of the present invention will be further described.

[0013] 实施例1 [0013] Example 1

[0014] 按照重量份取超高分子量聚乙烯90份、聚酰胺10份、环氧大豆油2份、抗氧剂DLTP 3份、硅烷偶联剂1.5份、炭黑7份、纳米氢氧化镁10份、硼酸锌6份、玻璃纤维4份、聚乙烯蜡2份。 [0014] parts by weight taken in accordance with 90 parts of ultrahigh molecular weight polyethylene, polyamide 10 parts, 2 parts of epoxidized soybean oil, antioxidant DLTP 3 parts, 1.5 parts of a silane coupling agent, 7 parts of carbon black, magnesium hydroxide nanoparticles 10 parts, 6 parts of zinc borate, 4 parts of glass fibers, 2 parts of polyethylene wax. 将各组分加入到高速混合机中,温下控制转速在800转/分钟,混合10分钟,取出后转入螺杆挤出机中,在200°C温度下挤出造粒,即获得所述高分子阻燃抗静电剂。 The components are added to the high-speed mixer, at a temperature controlling the rotational speed of 800 revolutions / minute, for 10 minutes, taken out into a screw extruder, extrusion granulation at 200 ° C for temperature, i.e., to obtain the retardant polymer antistatic agent.

[0015] 实施例2 [0015] Example 2

[0016] 按照重量份取超高分子量聚乙烯90份、聚酰胺10份、环氧大豆油3份、硅烷偶联剂0.02份、炭黑10份、纳米氢氧化镁2份、硼酸锌10份、玻璃纤维5份、聚乙烯蜡5份。 [0016] parts by weight taken in accordance with 90 parts of ultrahigh molecular weight polyethylene, polyamide 10 parts, 3 parts of epoxidized soybean oil, 0.02 parts of a silane coupling agent, 10 parts of carbon black, 2 parts of magnesium hydroxide nanoparticles, 10 parts of zinc borate , 5 parts of glass fiber, 5 parts of polyethylene wax. 将各组分加入到高速混合机中,温下控制转速在800转/分钟,混合10分钟,取出后转入螺杆挤出机中,在200°C温度下挤出造粒,即获得所述高分子阻燃抗静电剂。 The components are added to the high-speed mixer, at a temperature controlling the rotational speed of 800 revolutions / minute, for 10 minutes, taken out into a screw extruder, extrusion granulation at 200 ° C for temperature, i.e., to obtain the retardant polymer antistatic agent.

Claims (2)

1.一种高分子阻燃抗静电塑料,其特征在于:它由以下重量份的组分组成:超高分子量聚乙烯90份、聚酰胺10份、环氧大豆油2份、抗氧剂DLTP 3份、硅烷偶联剂1.5份、炭黑7份、纳米氢氧化镁10份、硼酸锌6份、玻璃纤维4份、聚乙烯蜡2份。 A flame-retardant anti-static plastic polymer, characterized in that: it consists of the following parts by weight of components: 90 parts of ultrahigh molecular weight polyethylene, polyamide 10 parts, 2 parts of epoxidized soybean oil, antioxidant DLTP 3 parts, 1.5 parts of a silane coupling agent, 7 parts of carbon black, 10 parts of magnesium hydroxide nanoparticles, 6 parts of zinc borate, 4 parts of glass fibers, 2 parts of polyethylene wax.
2.如权利要求1所述的高分子阻燃抗静电塑料的制备方法:按配方称取各组分,混合均匀后,熔融混炼、挤出造粒,即获得所述高分子阻燃抗静电塑料。 2. The method of preparing a polymer flame-retardant anti-static plastic according to claim 1: Weigh the components according to the formulation, after mixing, melt-kneading, extrusion granulation, i.e., to obtain the anti-retardant polymer static plastic.
CN201310190617.XA 2013-05-22 2013-05-22 A polymer flame retardant antistatic plastic CN103289164B (en)

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CN106479022A (en) * 2016-10-21 2017-03-08 安徽江淮汽车集团股份有限公司 Antistatic PE composite material and preparation method thereof
WO2018119817A1 (en) * 2016-12-29 2018-07-05 黄卫建 Antistatic high-strength thermoplastic composite material
CN108239410A (en) * 2017-08-26 2018-07-03 南通成山高分子材料有限公司 Environment-friendly corrosion-resistant high-polymer plastic
CN107739524A (en) * 2017-08-26 2018-02-27 南通成山高分子材料有限公司 Wear-resistant high-polymer plastic
CN107383923A (en) * 2017-08-27 2017-11-24 南通成山高分子材料有限公司 Novel corrosion-resistant high-molecular plastic
CN107383922A (en) * 2017-08-27 2017-11-24 南通成山高分子材料有限公司 Preparation method of novel corrosion-resistant high-molecular plastic
CN107400349A (en) * 2017-08-28 2017-11-28 南通成山高分子材料有限公司 High-molecular plastic
CN107556733A (en) * 2017-08-28 2018-01-09 南通成山高分子材料有限公司 High polymer flame-retardant plastic
CN107759136A (en) * 2017-10-24 2018-03-06 蚌埠隆华压铸机有限公司 Wear-resistant antistatic material preparation method

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