CN106245345A - 一种耐高温防老化帆布帐篷面料及其制备方法 - Google Patents

一种耐高温防老化帆布帐篷面料及其制备方法 Download PDF

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CN106245345A
CN106245345A CN201610681528.9A CN201610681528A CN106245345A CN 106245345 A CN106245345 A CN 106245345A CN 201610681528 A CN201610681528 A CN 201610681528A CN 106245345 A CN106245345 A CN 106245345A
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龙小伟
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Yingshang County Yida Tent Co Ltd
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Abstract

本发明公开了一种耐高温防老化帆布帐篷面料，其是由下述重量份的原料制得：涤纶纤维20‑30，聚酰亚胺纤维20‑30，碳纤维10‑15，陶瓷纤维10‑15，钛白粉3‑5，纳米氧化铈3‑5，苯丙乳液5‑10，2‑羟基‑4‑甲氧基二苯甲酮0.5‑1，单硬脂酸甘油酯0.3‑0.5，改性淀粉溶胶5‑10。本发明的帆布帐篷面料既符合基本的使用要求，又具有良好的透湿透气性，涂层稳定性和均匀度高，不易脱落、开裂，防水效果和外观品质好，并且具有良好的耐高温防老化性能，适用于高温场所使用。

Description

一种耐高温防老化帆布帐篷面料及其制备方法
技术领域
本发明涉及帐篷面料技术领域，尤其涉及一种耐高温防老化帆布帐篷面料及其制备方法。
背景技术
帐篷是一种具有建筑材料功能的纺织品，用于在野外环境中隔离出一个独立安全的空间。帐篷具有简便、轻巧的特点，需要具有防风、防雨、防雪、防寒、防蚊虫的基本功能。近年来随着旅游业的发展，帐篷的销量得到大幅度增长，市场进一步扩大，人们对帐篷外观、性能的需求也进一步提高。帐篷面料由基布经表面整理制成，它的性能很大程度上影响了帐篷的使用性能。目前应用最广泛的帐篷面料是涤纶帆布，其透气透湿性能差，使用性能和附加价值不高，无法满足市场对中高档产品的潜在需求。而且普通帐篷面料在高温使用时会发生热老化、热氧化，使机械性能下降，影响帐篷的使用性能。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种耐高温防老化帆布帐篷面料及其制备方法。
本发明是通过以下技术方案实现的：
一种耐高温防老化帆布帐篷面料，其是由下述重量份的原料制得：
涤纶纤维20-30，聚酰亚胺纤维20-30，碳纤维10-15，陶瓷纤维10-15，钛白粉3-5，纳米氧化铈3-5，苯丙乳液5-10，2-羟基-4-甲氧基二苯甲酮0.5-1，单硬脂酸甘油酯0.3-0.5，改性淀粉溶胶5-10；
其中改性淀粉溶胶由下列重量份的原料制成：玉米淀粉30-40，石墨粉10-15，硝酸钠1-2，高锰酸钾2-4，丙烯酸3-5，甲基丙烯酸甲酯6-8，15-20％浓度双氧水水溶液10-15，过硫酸铵0.5-1，十二烷基硫酸钠0.5-1，水200-300；改性淀粉溶胶的制备方法是将石墨粉按固液重量比1：1.5-1：2与质量分数为98％的浓硫酸混合后加入硝酸钠、高锰酸钾，40-50℃反应0.5-1h后依次加入水、玉米淀粉和15-20％浓度双氧水水溶液60-80℃搅拌3-4h，将pH调至中性后加入其余原料70-80℃反应1-2h，冷却后即得。
一种耐高温防老化帆布帐篷面料的制备方法，包括以下步骤：
(1)将涤纶纤维、聚酰亚胺纤维、碳纤维和陶瓷纤维按比例混纺编织，得帆布基布；
(2)将苯丙乳液、改性淀粉溶胶与单硬脂酸甘油酯混合后40-50℃搅拌1-2h，冷却后加入其余原料共同研磨至细度≤50μm，得涂覆剂；
(3)将(2)中的涂覆剂均匀涂覆于(1)中的帆布基布表面，先于80-90℃干燥4-6h，再于120-140℃热处理10-20min，冷却后即得耐高温防老化帆布帐篷面料。
本发明的优点是：
本发明通过改性淀粉溶胶与苯丙乳液等原料复配，合成的涂覆剂与帐篷帆布基布具有良好的结合性，在基布上生成具有良好粘着牢度、透湿透气性和力学性能的涂膜，使最终得到的帆布帐篷面料既符合基本的使用要求，又具有良好的透湿透气性，涂层稳定性和均匀度高，不易脱落、开裂，防水效果和外观品质好，并且具有良好的耐高温防老化性能，适用于高温场所使用。
具体实施方式
一种耐高温防老化帆布帐篷面料，其是由下述重量份的原料制得：
涤纶纤维20，聚酰亚胺纤维20，碳纤维10，陶瓷纤维10，钛白粉3，纳米氧化铈3，苯丙乳液5，2-羟基-4-甲氧基二苯甲酮0.5，单硬脂酸甘油酯0.3，改性淀粉溶胶5；
其中改性淀粉溶胶由下列重量份的原料制成：玉米淀粉30，石墨粉10，硝酸钠1，高锰酸钾2，丙烯酸3，甲基丙烯酸甲酯6，15％浓度双氧水水溶液10，过硫酸铵0.5，十二烷基硫酸钠0.5，水200；改性淀粉溶胶的制备方法是将石墨粉按固液重量比1：1.5与质量分数为98％的浓硫酸混合后加入硝酸钠、高锰酸钾，40℃反应0.5h后依次加入水、玉米淀粉和15％浓度双氧水水溶液60℃搅拌3h，将pH调至中性后加入其余原料70℃反应1h，冷却后即得。
一种耐高温防老化帆布帐篷面料的制备方法，包括以下步骤：
(1)将涤纶纤维、聚酰亚胺纤维、碳纤维和陶瓷纤维按比例混纺编织，得帆布基布；
(2)将苯丙乳液、改性淀粉溶胶与单硬脂酸甘油酯混合后40℃搅拌1h，冷却后加入其余原料共同研磨至细度≤50μm，得涂覆剂；
(3)将(2)中的涂覆剂均匀涂覆于(1)中的帆布基布表面，先于80℃干燥4h，再于120℃热处理10min，冷却后即得耐高温防老化帆布帐篷面料。
上述制得的帆布帐篷面料性能指标测试结果如下：

Claims (2)

1.一种耐高温防老化帆布帐篷面料，其特征在于，其是由下述重量份的原料制得：
涤纶纤维20-30，聚酰亚胺纤维20-30，碳纤维10-15，陶瓷纤维10-15，钛白粉3-5，纳米氧化铈3-5，苯丙乳液5-10，2-羟基-4-甲氧基二苯甲酮0.5-1，单硬脂酸甘油酯0.3-0.5，改性淀粉溶胶5-10；
所述的改性淀粉溶胶由下列重量份的原料制成：玉米淀粉30-40，石墨粉10-15，硝酸钠1-2，高锰酸钾2-4，丙烯酸3-5，甲基丙烯酸甲酯6-8，15-20%浓度双氧水水溶液10-15，过硫酸铵0.5-1，十二烷基硫酸钠0.5-1，水200-300；改性淀粉溶胶的制备方法是将石墨粉按固液重量比1：1.5-1：2与质量分数为98%的浓硫酸混合后加入硝酸钠、高锰酸钾，40-50℃反应0.5-1h后依次加入水、玉米淀粉和15-20%浓度双氧水水溶液60-80℃搅拌3-4h，将pH调至中性后加入其余原料70-80℃反应1-2h，冷却后即得。
2.根据权利要求1所述的一种耐高温防老化帆布帐篷面料的制备方法，其特征在于，包括以下步骤：
（1）将涤纶纤维、聚酰亚胺纤维、碳纤维和陶瓷纤维按比例混纺编织，得帆布基布；
（2）将苯丙乳液、改性淀粉溶胶与单硬脂酸甘油酯混合后40-50℃搅拌1-2h，冷却后加入其余原料共同研磨至细度≤50μm，得涂覆剂；
（3）将（2）中的涂覆剂均匀涂覆于（1）中的帆布基布表面，先于80-90℃干燥4-6h，再于120-140℃热处理10-20min，冷却后即得耐高温防老化帆布帐篷面料。
CN201610681528.9A 2016-08-17 2016-08-17 一种耐高温防老化帆布帐篷面料及其制备方法 Pending CN106245345A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103397535A (zh) * 2013-08-13 2013-11-20 苏州鑫汉纺纺织有限公司 一种新型耐高温面料
CN104178011A (zh) * 2014-08-27 2014-12-03 句容市石狮冲压件厂 一种户外帐篷用复合涂料及其制备方法
CN105129901A (zh) * 2015-09-22 2015-12-09 陕西科技大学 用于制革污水的接枝改性淀粉絮凝吸附剂及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103397535A (zh) * 2013-08-13 2013-11-20 苏州鑫汉纺纺织有限公司 一种新型耐高温面料
CN104178011A (zh) * 2014-08-27 2014-12-03 句容市石狮冲压件厂 一种户外帐篷用复合涂料及其制备方法
CN105129901A (zh) * 2015-09-22 2015-12-09 陕西科技大学 用于制革污水的接枝改性淀粉絮凝吸附剂及其制备方法

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Application publication date: 20161221