CN106245336A - A kind of fabric scouring penetrating agent based on alcohol ether glucoside - Google Patents

A kind of fabric scouring penetrating agent based on alcohol ether glucoside Download PDF

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Publication number
CN106245336A
CN106245336A CN201610716969.8A CN201610716969A CN106245336A CN 106245336 A CN106245336 A CN 106245336A CN 201610716969 A CN201610716969 A CN 201610716969A CN 106245336 A CN106245336 A CN 106245336A
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CN
China
Prior art keywords
ether
fabric
alcohol
penetrating agent
aeg
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Pending
Application number
CN201610716969.8A
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Chinese (zh)
Inventor
荆丰伟
金瑞
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Wan Qi Bio Tech Ltd Jiangsu
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Wan Qi Bio Tech Ltd Jiangsu
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Priority to CN201610716969.8A priority Critical patent/CN106245336A/en
Publication of CN106245336A publication Critical patent/CN106245336A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • D06M13/17Polyoxyalkyleneglycol ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to fabric treating auxiliary agent field, be a kind of fabric scouring penetrating agent based on alcohol ether glucoside, be made up of following component by mass percentage: fatty alcohol-polyoxyethylene ether AEO 9 1% 5%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 5% 20%;Isooctanol ether glucosides AEG 1,511 15% 30%;Disodium EDTA 0.1% 2%;Carbamide 0.5% 5%;Ethylene glycol monobutyl ether 0.5% 5%;Defoamer S 1850.1% 0.8%;Water 35% 50%.Penetrating agent of the present invention highly basic acidproof, resistance to, there is good stability, remain under the high temperature conditions play good osmosis, there is the functions such as emulsifying, infiltration, solubilising, washing, scrubbing, can make to scouring and bleaching uniform, thorough, fabric strength loss after kiering is few, without APEO, NPEO and derivant thereof, biodegradable.

Description

A kind of fabric scouring penetrating agent based on alcohol ether glucoside
Technical field
The present invention relates to fabric treating auxiliary agent technical field, specifically, be a kind of novel fabric based on alcohol ether glucoside Concise penetrating agent.
Background technology
The concise of fabric refers to the operative employee such as cotton and the desizing of synthetic fibre mixed fabric, kiering, bleaching and mercerising Sequence.Concise purpose is to remove the various impurity on fiber.The big feature of the one of concise operation is to need to use the Caustic soda of high concentration Processing fiber, the alkali content of solution is the highest.In general, excellent scouring penetrant needs possess following characteristic: infiltration is rapidly; Emulsifying ability is strong;Detergency is good;High temperature resistant;Resistance to highly basic and oxidant;Low foam;Degradability is good;Non-toxic and safe.Generally, The surfactant of one-component is difficult to meet all of requirement, needs can be prepared by compound synergic to meet the concise of requirement Agent.
Owing to not eliminating containing in cotton wax, pectin, protein, cotton seed hulls, oils and fats and desizing operation on bafta when concise The impurity such as the oil stain being infected with on most slurry and fabric so that fabric is not easy by alkali liquor moistening and infiltration.It addition, it is traditional Fabric fabric strength loss often occurs after concise penetrant treating, be embodied in fabric and be susceptible to when weaving cotton cloth Broken hole, the situation such as broken end, causes fabric fastness to decline, affects fabric combination property.
Therefore, in order to overcome current problem encountered, it is necessary to provide a kind of effective concise penetrating agent, can be as quickly as possible Speed infiltration emulsifying, decontamination, increase substantially concise efficiency, reduce the time-consuming of refinery practice, the impact of fabric is down to by concentrated base Minimum.
Summary of the invention
It is an object of the invention to provide a kind of efficient and that there is certain fabric protective effect concise penetrating agent, can be significantly Shorten concise operation time-consuming, effectively reduce the infringement to fabric itself of the concise operation, improve the overall matter of fabric to a certain extent Amount.
Two kinds of main materials selected by the present invention are respectively FMES (fatty acid methyl ester sodium sulfonate of ethoxylated) and AEG (alcohol Ether glucoside compound).First FMES is the optimization and upgrading version of FMEE (fatty acid methyl ester ethoxylate), have concurrently nonionic and The characteristic of anion surfactant.Its prominent feature is good soil release performance, defat, dispersibility, at anionic product Middle washing power is the highest.This feature can help scouring agent to reach the purpose of rapid osmotic decontamination.It addition, AEG is alcohol ether glucoside class chemical combination Thing, can pass through osmosis, effectively containing glycosidic bond with the fiber in cotton fiber have preferable affinity in this compounds Absorption, on cotton fiber surface, plays the effect of protection cotton fiber.
To achieve these goals, a first aspect of the present invention, it is provided that a kind of fabric scouring based on alcohol ether glucoside permeates Agent, is made up of following component by mass percentage: fatty alcohol-polyoxyethylene ether AEO-9 1%-5%;Fatty acid methyl ester polyoxy second Alkene ether sulfonic acid sodium FMES 5%-20%;Isooctanol ether glucosides AEG-1511 15%-30%;Disodium EDTA (EDETATE DISODIUM) 0.1%-2%;Carbamide 0.5%-5%;Ethylene glycol monobutyl ether 0.5%-5%;Defoamer S-185 0.1%- 0.8%;Water 35%-50%.
Preferably, described fabric scouring penetrating agent based on alcohol ether glucoside, it is made up of following component by mass percentage: Fatty alcohol-polyoxyethylene ether AEO-9 4.5%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 17.8%;Isooctanol ether sugar Glycosides AEG-1511 26%;Disodium EDTA (EDETATE DISODIUM) 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 4.5%;Defoamer S-185 0.45%;Water 42.75%.
Preferably, described fabric scouring penetrating agent based on alcohol ether glucoside, it is made up of following component by mass percentage: Fatty alcohol-polyoxyethylene ether AEO-9 3%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 20%;Isooctanol ether glucosides AEG-1511 25%;Disodium EDTA (EDETATE DISODIUM) 1%;Carbamide 3%;Ethylene glycol monobutyl ether 3%;Froth breaking Agent S-185 0.5%;Water 44.5%.
Preferably, described fabric scouring penetrating agent based on alcohol ether glucoside, it is made up of following component by mass percentage: Fatty alcohol-polyoxyethylene ether AEO-9 1%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 10%;Isooctanol ether glucosides AEG-1511 30%;Disodium EDTA (EDETATE DISODIUM) 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 4.5%;Defoamer S-185 0.5%;Water 50%.
Preferably, described fabric scouring penetrating agent based on alcohol ether glucoside, it is made up of following component by mass percentage: Fatty alcohol-polyoxyethylene ether AEO-9 5%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 20%;Isooctanol ether glucosides AEG-1511 20%;Disodium EDTA (EDETATE DISODIUM) 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 0.5%;Defoamer S-185 0.5%;Water 50%.
It is an advantage of the current invention that:
1, the boiling before the concise penetrating agent that the present invention provides is applicable to textile dyeing, the concise penetrating agent of the present invention Energy highly basic acidproof, resistance to, has good stability, remains under the high temperature conditions play good osmosis.
2, inventive formulation has the functions such as emulsifying, infiltration, solubilising, washing, scrubbing, can make to scouring and bleaching uniform, thorough, it is ensured that Uniformly, capillary effect.
3, the fabric after kiering of the present invention, loss of strength is few, is difficult to broken hole when weaving cotton cloth, broken end.
4, the present invention does not contains APEO, NPEO and derivant thereof, biodegradable, belongs to environment-friendly products.
Detailed description of the invention
The detailed description of the invention provided the present invention below in conjunction with embodiment elaborates.
Embodiment 1:
Each component is formed by following mass percent: fatty alcohol-polyoxyethylene ether AEO-9 4.5%;Fatty acid methyl ester polyoxy Vinyl Ether sodium sulfonate FMES 17.8%;Isooctanol ether glucosides AEG-1511 26%;Disodium EDTA (EDETATE SODIUM Salt) 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 4.5%;Defoamer S-185 0.45%;Water 42.75%.
Preparation method: 427.5 kilograms of 70 DEG C of hot water of suction in still, stirring is lower adds 260Kg AEG-1511,15Kg second Edetate disodium salt, 4.5Kg S-185 defoamer, 45Kg ethylene glycol monobutyl ether, stirs 30 minutes, suction successively under stirring 178Kg FMES, 45Kg AEO-9, is sufficiently stirred for 1 hour, and product is yellow transparent liquid.It is cooled to room temperature, adds 25Kg urine Element stirring i.e. can get the scouring penetrant of the present invention for 10 minutes.
Embodiment 2:
Each component is formed by following mass percent: fatty alcohol-polyoxyethylene ether AEO-9 3%;Fatty acid methyl ester polyoxy second Alkene ether sulfonic acid sodium FMES 20%;Isooctanol ether glucosides AEG-1511 25%;Disodium EDTA (EDETATE DISODIUM) 1%;Carbamide 3%;Ethylene glycol monobutyl ether 3%;Defoamer S-185 0.5%;Water 44.5%.
The same embodiment of preparation method: 1.
Embodiment 3:
Each component is formed by following mass percent: fatty alcohol-polyoxyethylene ether AEO-9 1%;Fatty acid methyl ester polyoxy second Alkene ether sulfonic acid sodium FMES 10%;Isooctanol ether glucosides AEG-1511 30%;Disodium EDTA (EDETATE DISODIUM) 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 4.5%;Defoamer S-185 0.5%;Water 50%.
Preparation method is with embodiment 1.
Embodiment 4:
Each component is formed by following mass percent: fatty alcohol-polyoxyethylene ether AEO-9 5%;Fatty acid methyl ester polyoxy second Alkene ether sulfonic acid sodium FMES 20%;Isooctanol ether glucosides AEG-1511 20%;Disodium EDTA (EDETATE DISODIUM) 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 0.5%;Defoamer S-185 0.5%;Water 50%.
Preparation method is with embodiment 1.
Embodiment 5: performance measurement
Measure the performance data of penetrating agent that above-described embodiment prepares and all meet following index:
Outward appearance: weak yellow liquid
Solid content: 30%-35%
PH value: 6.5-7.5
Viscosity: less than 300
Ionic: the moon/nonionic
Dissolubility: can ratio phased soln any with water.
Joined concise penetrating agent product performance index according to this formula and all met or exceeded standard value.
The high-efficiency environment friendly penetrating agent prepared the present invention below carries out performance test.
1, permeability
Use canvas sedimentation.A diameter of 25mm circle canvas without kiering is put in equipped with 400mL 1% test solution (25 DEG C) beaker in, test time of sinking needed for bottom of canvas, be repeated 4 times and average, be the sedimentation time, the time is more Short, show that the permeability of this solution is the best.
2, alkali resistance
Taking 1% test solution 100mL in beaker, respectively reinforcing body NaOH 3g, 5g, 8g, 11g stir.Stand 24 hours Rear observation separates out or deposited phenomenon with or without muddy, upper strata.
3, temperature stability
High-effective low foam osmotic agent solution 1% respectively 20 DEG C, 30 DEG C, 40 DEG C, 50 DEG C, 60 DEG C, 70 DEG C, 80 DEG C, 90 DEG C time place 30min, if solution is substantially clarified or is completely dispersed, high-effective low foam penetrating agent stability at such a temperature is described Good.
For the ease of contrast, the comparative example that this experiment is used is replacing embodiment 1 isooctanol ether glucosides AEG-1511 It is changed to the dodecyl ether sulfate of equal volume.Meanwhile, we have also purchased presently commercially available main flow scouring agent commodity together Carry out contrast experiment.Gained contrast test result is as shown in table 1.
Table 1 concise penetrating agent performance measurement
Being shown by above test result, the effect of each embodiment of this formula is substantially better than commercial goods and comparative example, body Show the pungent alcohol ether glucoside AEG-1511 huge advantage as scouring agent.
Below preferred embodiment to the invention is illustrated, but the invention is not limited to described Embodiment, those of ordinary skill in the art it may also be made that all equivalents on the premise of the invention spirit Modification or replacement, modification or the replacement of these equivalents are all contained in the application claim limited range.

Claims (7)

1. a fabric scouring penetrating agent based on alcohol ether glucoside, it is characterised in that be made up of following component by mass percentage: Fatty alcohol-polyoxyethylene ether AEO-9 1%-5%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 5%-20%;Isooctanol Ether glucosides AEG-1511 15%-30%;Disodium EDTA 0.1%-2%;Carbamide 0.5%-5%;Ethylene glycol only son Ether 0.5%-5%;Defoamer S-185 0.1%-0.8%;Water 35%-50%.
Fabric scouring penetrating agent based on alcohol ether glucoside the most according to claim 1, it is characterised in that by mass percentage It is made up of following component: fatty alcohol-polyoxyethylene ether AEO-9 4.5%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 17.8%;Isooctanol ether glucosides AEG-1511 26%;Disodium EDTA 1.5%;Carbamide 2.5%;Ethylene glycol only son Ether 4.5%;Defoamer S-185 0.45%;Water 42.75%.
Fabric scouring penetrating agent based on alcohol ether glucoside the most according to claim 1, it is characterised in that by mass percentage It is made up of following component: fatty alcohol-polyoxyethylene ether AEO-9 3%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 20%; Isooctanol ether glucosides AEG-1511 25%;Disodium EDTA 1%;Carbamide 3%;Ethylene glycol monobutyl ether 3%;Froth breaking Agent S-185 0.5%;Water 44.5%.
Fabric scouring penetrating agent based on alcohol ether glucoside the most according to claim 1, it is characterised in that by mass percentage It is made up of following component: fatty alcohol-polyoxyethylene ether AEO-9 1%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 10%; Isooctanol ether glucosides AEG-1511 30%;Disodium EDTA 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 4.5%;Defoamer S-185 0.5%;Water 50%.
Fabric scouring penetrating agent based on alcohol ether glucoside the most according to claim 1, it is characterised in that by mass percentage It is made up of following component: fatty alcohol-polyoxyethylene ether AEO-9 5%;Fatty acid methyl ester sodium sulfonate of ethoxylated FMES 20%; Isooctanol ether glucosides AEG-1511 20%;Disodium EDTA 1.5%;Carbamide 2.5%;Ethylene glycol monobutyl ether 0.5%;Defoamer S-185 0.5%;Water 50%.
6. a preparation method for the fabric scouring penetrating agent based on alcohol ether glucoside as described in claim 1-5 is arbitrary, it is special Levy and be, comprise the following steps: proportionally, 70 DEG C of hot water of suction in still, add AEG-1511, ethylenediamine tetrem under stirring Acid disodium salt, defoamer S-185, ethylene glycol monobutyl ether, stirs 30 minutes, suction FMES, AEO-9 successively under stirring, fully stirs Mix 1 hour, be cooled to room temperature, add carbamide and stir i.e. available described fabric refine based on alcohol ether glucoside infiltration in 10 minutes Agent.
7. the answering in fabric refine of the fabric scouring penetrating agent based on alcohol ether glucoside as described in claim 1-5 is arbitrary With.
CN201610716969.8A 2016-08-24 2016-08-24 A kind of fabric scouring penetrating agent based on alcohol ether glucoside Pending CN106245336A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3704228A (en) * 1969-06-07 1972-11-28 Henkel & Cie Gmbh Washing agents containing a textile softener
CN101545202A (en) * 2009-04-28 2009-09-30 上海市毛麻纺织科学技术研究所 Scouring agent formulation and scouring and dyeing process for high-efficiency scouring and dyeing of multi-component fiber mixed fabrics or interwoven fabric in same bath
CN105040423A (en) * 2015-08-25 2015-11-11 无锡市长安曙光手套厂 Alkali-resisting spinning refining agent and preparation method thereof
CN105155273A (en) * 2015-10-14 2015-12-16 吴江市七都镇庙港雅迪针织制衣厂 Environment-friendly scouring agent and preparation method thereof
CN105155249A (en) * 2015-10-14 2015-12-16 吴江市七都镇庙港雅迪针织制衣厂 Low-temperature scouring agent as well as preparation and application thereof
CN105525509A (en) * 2016-02-02 2016-04-27 山东黄河三角洲纺织科技研究院有限公司 Low-alkaline scouring agent for continuous rope scouring of cotton fabrics

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3704228A (en) * 1969-06-07 1972-11-28 Henkel & Cie Gmbh Washing agents containing a textile softener
CN101545202A (en) * 2009-04-28 2009-09-30 上海市毛麻纺织科学技术研究所 Scouring agent formulation and scouring and dyeing process for high-efficiency scouring and dyeing of multi-component fiber mixed fabrics or interwoven fabric in same bath
CN105040423A (en) * 2015-08-25 2015-11-11 无锡市长安曙光手套厂 Alkali-resisting spinning refining agent and preparation method thereof
CN105155273A (en) * 2015-10-14 2015-12-16 吴江市七都镇庙港雅迪针织制衣厂 Environment-friendly scouring agent and preparation method thereof
CN105155249A (en) * 2015-10-14 2015-12-16 吴江市七都镇庙港雅迪针织制衣厂 Low-temperature scouring agent as well as preparation and application thereof
CN105525509A (en) * 2016-02-02 2016-04-27 山东黄河三角洲纺织科技研究院有限公司 Low-alkaline scouring agent for continuous rope scouring of cotton fabrics

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