CN112239958A - Low-foam penetrant and preparation method and application method thereof - Google Patents
Low-foam penetrant and preparation method and application method thereof Download PDFInfo
- Publication number
- CN112239958A CN112239958A CN202011088107.8A CN202011088107A CN112239958A CN 112239958 A CN112239958 A CN 112239958A CN 202011088107 A CN202011088107 A CN 202011088107A CN 112239958 A CN112239958 A CN 112239958A
- Authority
- CN
- China
- Prior art keywords
- low
- foam
- reaction solution
- penetrant
- sodium hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000006260 foam Substances 0.000 title claims abstract description 91
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 147
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 32
- 229920000570 polyether Polymers 0.000 claims abstract description 32
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 32
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 20
- 239000011734 sodium Substances 0.000 claims abstract description 20
- -1 sodium alkyl sulfonate Chemical group 0.000 claims abstract description 18
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- 239000010452 phosphate Substances 0.000 claims abstract description 16
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims abstract description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims description 72
- 238000005187 foaming Methods 0.000 claims description 35
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 23
- 239000002357 osmotic agent Substances 0.000 claims description 20
- 230000000149 penetrating effect Effects 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 11
- 239000004753 textile Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000004043 dyeing Methods 0.000 claims description 10
- 239000012295 chemical reaction liquid Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 238000007730 finishing process Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims 4
- 230000000694 effects Effects 0.000 abstract description 15
- 230000035515 penetration Effects 0.000 abstract description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 78
- 235000011121 sodium hydroxide Nutrition 0.000 description 43
- 229920001451 polypropylene glycol Polymers 0.000 description 28
- 239000000376 reactant Substances 0.000 description 24
- 239000002904 solvent Substances 0.000 description 19
- 239000002518 antifoaming agent Substances 0.000 description 14
- 238000007599 discharging Methods 0.000 description 13
- 239000004094 surface-active agent Substances 0.000 description 13
- 239000002699 waste material Substances 0.000 description 10
- 239000003513 alkali Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 8
- 238000009736 wetting Methods 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 230000035699 permeability Effects 0.000 description 6
- 239000012224 working solution Substances 0.000 description 6
- 238000006065 biodegradation reaction Methods 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 239000012670 alkaline solution Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000005574 cross-species transmission Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000004313 potentiometry Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/667—Organo-phosphorus compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The invention discloses a low-foam penetrant, a preparation method and an application method thereof, wherein the low-foam penetrant comprises the following components in percentage by mass: 12.0 to 20.0 percent of isomeric dodecyl polyoxyethylene ether; 5.0% -10.0% of block polyether; 10.0 to 18.0 percent of isooctanol polyoxyethylene ether phosphate; 2.0 to 6.0 percent of tributyl phosphate; 8.0% -15.0% of secondary sodium alkyl sulfonate; 11.0% -15.0% sodium hydroxide solution; and 16.0% -52.0% of water. The invention has the technical effects that the low-foam penetrant is prepared, so that the processing cost is reduced and the environment is protected while the penetration effect is ensured.
Description
Technical Field
The invention relates to the field of textile dyeing and finishing, and particularly relates to a low-foam penetrant, and a preparation method and an application method thereof.
Background
Penetrants are known by their name to act as penetrants, which are surfactants in the textile industry that allow liquids to penetrate rapidly and uniformly into the fibers, promoting rapid wetting of the fiber or fabric surface by water, and penetration into the fiber or fabric. The penetrant is applied to dyeing and finishing processes and has wide application. The pretreatment of cotton textiles is mostly wet processing, and a penetrant is an essential assistant for enabling a treatment solution to be uniformly and rapidly distributed or act on the inside of the textile.
The penetrant applied to the printing and dyeing process at present is mainly compounded by various surfactants, the surfactants, water and other additives are prepared into working liquid when the penetrant is used, in order to make the working liquid uniform, intensive stirring is carried out in the preparation process, however, in the stirring process, air is involved into the working liquid along with stirring, and in addition, air is also brought when the fabric enters a working liquid mangle, and some processes inevitably generate gas. In this in-process, produce a large amount of foams, can cause the operator to see the actual liquid level of unclear treatment fluid to lead to the working solution to spill over, it is inhomogeneous to change the material, remains a large amount of foams during final blowing, and the blowing is not clean. Excessive foam can float the fabric, block a spray head for circulating the working solution, aggravate the accumulation of dirt of the working solution and prevent the dirt from being stained on the surface of fabrics or equipment, and aggravate the foaming of the surfactant and cause more serious foaming sometimes after hydrogen peroxide and caustic soda are added into the working solution.
In order to ensure the rinsing effect, a large amount of water is needed for cleaning for many times, water resources are wasted in transition, and meanwhile, a large amount of alkaline waste liquid is generated to pollute the environment. In the actual printing and dyeing operation, the phenomena of too much foam, vehicle winding, cylinder blockage or no cloth walking are often caused, the problem can be solved only by adding a defoaming agent, most of the defoaming agents are silicone defoaming agents, the defoaming agent is not resistant to high temperature, high alkali and high shear, and meanwhile, if the water quality is hard, Ca (calcium) is hard2+、Mg2+、Fe3+When the defoaming agent is demulsified, the result is that floating oil is generated, which is floated in the dye liquor and combined with scum and dirt generated by metal ions or fibers, auxiliaries and impurities in dye to generate irregular color spots, color blocks and oil stains to be adhered to the fabric and the inner wall of equipment.
Disclosure of Invention
The invention aims to solve the technical problems of incomplete discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam in the preparation process of the existing penetrant.
In order to achieve the above object, the present invention provides a low-foaming osmotic agent, comprising, by mass:
further, the block polyether is an EO/PO block polyether.
Further, the concentration of sodium hydroxide in the sodium hydroxide solution was 30%.
In order to achieve the above object, the present invention also provides a method for preparing a low-foaming osmotic agent, comprising the steps of: adding 16.0-52.0% of water and 8.0-15.0% of secondary sodium alkyl sulfonate into a reaction kettle, and stirring to dissolve the secondary sodium alkyl sulfonate into the water to form a first reaction liquid; adding 12.0-20.0% of isomeric dodecyl alcohol polyoxyethylene ether, 5.0-10.0% of EO/PO block polyether, 10.0-18.0% of isooctanol polyoxyethylene ether phosphate and 2.0-6.0% of tributyl phosphate into the reaction kettle, and stirring to form a second reaction solution; adding 11.0-15.0% of sodium hydroxide solution into the reaction kettle to form a third reaction solution; and filtering the third reaction solution to form the low-foam penetrant.
Further, in the step of forming the first reaction solution, the water is added into the reaction kettle, the stirrer is started, the secondary sodium alkylsulfonate is added while stirring at the temperature of 50-60 ℃, and the secondary sodium alkylsulfonate is fully stirred for 30-50 minutes, so that the secondary sodium alkylsulfonate is completely dissolved.
Further, in the step of forming the second reaction solution, stirring for 1-2 hours at a temperature of 50-60 ℃ to completely dissolve the isomeric decyl alcohol polyoxyethylene ether, the EO/PO block polyether, the isooctyl alcohol polyoxyethylene ether phosphate and the tributyl phosphate to form the second reaction solution.
Further, in the step of forming the second reaction liquid, the temperature of the second reaction liquid is reduced to 40 ℃ or lower.
Further, in the step of forming the third reaction solution, the concentration of sodium hydroxide in the sodium hydroxide solution is 30%, the pH value of the second reaction solution is adjusted to be 6.8-7.2, and the third reaction solution is obtained by uniformly stirring.
Further, in the step of filtering the third reaction solution, the temperature is reduced to 30-40 ℃, and the third reaction solution is filtered.
In order to realize the purpose, the invention also provides an application method of the low-foam penetrant, which is applied to a textile dyeing and finishing process.
The invention has the technical effects that the EO/PO block polyether has good low-foaming property, the low-foaming penetrating agent prepared from the EO/PO block polyether also has good low-foaming property, excessive foam is not generated in the using process of the low-foaming penetrating agent, the defoaming treatment can be carried out without additionally adding a defoaming agent, and various problems of incomplete discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are greatly solved. The prepared low-foam penetrant has the characteristics of good wetting, penetrating and low-foam effects, easy biodegradation and the like, and has good compatibility with other surfactants and auxiliaries.
Detailed Description
All raw materials used in the present invention are conventionally used and commercially available. In the present invention, all amounts, percentages and parts are by weight, unless otherwise specified.
Example 1
The embodiment of the invention provides a low-foam penetrant, which comprises the following components in percentage by mass:
the main components of the isomeric decyl alcohol polyoxyethylene ether are isomeric decyl alcohol and ethylene oxide, and the chemical structure of the isomeric decyl alcohol polyoxyethylene ether is iso-C10H21O-(CH2CH2O) -H, the isomeric fatty dodecyl alcohol polyoxyethylene ether belongs to isomeric alcohol ether, is a high-efficiency dispersing agent, wetting agent and emulsifying agent, does not contain benzene ring structure, and is an excellent substitute of alkylphenol polyoxyethylene ether in textile auxiliaries and detergents.
The block polyether is preferably an EO/PO block polyether in the embodiment, the EO/PO block polyether is composed of polyoxyethylene (EO) and Polyoxypropylene (PO), is generally formed by randomly copolymerizing EO and PO, and has good low-foaming performance, so that the penetrant prepared from the EO/PO block polyether has good low-foaming performance, the technical problem that foam is generated in the penetration process to influence the preparation process is effectively solved, and a large amount of foam is prevented from remaining in the discharging process to block a spray head.
The working solution for the pretreatment of cotton textiles is mostly carried out in strong alkali bath, which requires that the used penetrating agent can still keep good wetting permeability in the strong alkali bath, and can still keep high-efficiency permeability even if the working solution can resist 200g/L of strong alkali, the ordinary penetrating agent JFC can not meet the requirement, and an additional strong alkali-resistant penetrating agent must be searched, and the phosphate ester has better permeability and alkali resistance and can be used as the strong alkali-resistant penetrating agent exactly, and meanwhile, when the monoester content in the synthesized phosphate ester product is higher, the alkali-resistant permeability of the product is the best.
The tributyl phosphate is mainly used as a solvent, and is also commonly used as a plasticizer of nitrocellulose, cellulose acetate, chlorinated rubber and polyvinyl chloride, an extractant of rare metals and the like, and a heat exchange medium. The tributyl phosphate has low surface tension and physical property of being difficult to dissolve in water, so the tributyl phosphate can be used as a defoaming agent in the embodiment, so that a film with foam is in an unstable state, and the technical effect of effectively and rapidly defoaming is achieved.
The sodium secondary alkyl sulfonate has good detergency and emulsifying power, good hard water resistance and foaming power and excellent biodegradability, belongs to a green surfactant, can be used as an anionic surfactant in the penetrant, has strong penetrating power under the conditions of strong alkali, high temperature and the like, and simultaneously has the functions of emulsification, deoiling, washing and the like.
The concentration of sodium hydroxide in the sodium hydroxide solution is 25% -35%, preferably 30% in this embodiment, and the sodium hydroxide solution is an alkaline solution, and in this embodiment, the sodium hydroxide solution is used to adjust the ph of the low-foaming penetrant so that the ph is 6.8-7.2, and the ph is preferably 7.0, that is, the prepared low-foaming penetrant is a neutral solution.
In this embodiment, the mass fractions of the above components are preferably as follows:
the EO/PO block polyether has good low-foaming property, the low-foaming penetrating agent prepared from the EO/PO block polyether also has good low-foaming property, and defoaming treatment is carried out without additionally adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are greatly solved. The penetrating agent has the characteristics of good wetting, penetrating and low foaming effects, easy biodegradation and the like, and has good compatibility with other surfactants and auxiliaries.
The technical effect of the penetrant of the embodiment is that the main component of the low-foam penetrant is a compound of surfactants with various special structures, and the low-foam penetrant is prepared by adding a low-foam component according to the influence of the molecular structure of the surfactant on foam, so that the comprehensive performance of the penetrant can be ensured, the processing cost of the low-foam penetrant can be reduced, and the use safety under severe working conditions can be ensured.
The embodiment also provides a preparation method of the low-foam penetrant, which comprises the following steps S1-S4.
S1 the components required to prepare the low-foaming osmotic agent described in this example were prepared and the amounts of each component were calculated and prepared for use. Adding a first solvent and a first reactant into a reaction kettle to form a first reaction solution. The first solvent is water, the first reactant is secondary sodium alkyl sulfonate, the mass fraction of the first solvent is 16.0% -52.0%, and the mass fraction of the secondary sodium alkyl sulfonate is 8.0% -15.0%.
In this embodiment, specifically, 30% of a first solvent is added into a reaction kettle, a stirrer is started, the first reactant is slowly added while stirring at a temperature of 50 to 60 ℃, 12.0% of secondary alkyl sodium sulfonate is added, and sufficient stirring is continued for 30 to 50 minutes, so that the first reactant is completely dissolved to form a first reaction solution.
S2, adding a second reactant into the reaction kettle, and stirring to form a second reaction solution, wherein the second reactant is isomeric dodecyl alcohol polyoxyethylene ether, EO/PO block polyether, isooctyl alcohol polyoxyethylene ether phosphate and tributyl phosphate, the mass fractions of the second reactant are respectively 12.0-20.0% of isomeric dodecyl alcohol polyoxyethylene ether, 5.0-10.0% of EO/PO block polyether, 10.0-18.0% of isooctyl alcohol polyoxyethylene ether phosphate and 2.0-6.0% of tributyl phosphate.
In this embodiment, specifically, 18.0% of the isomeric dodecyl alcohol polyoxyethylene ether, 7.0% of the EO/PO block polyether, 16.0% of the isooctyl alcohol polyoxyethylene ether phosphate, and 4.0% of the tributyl phosphate are sequentially added into the reaction kettle, and the addition is completed within 30 to 60 minutes, and the mixture is stirred for 1 to 2 hours at a temperature of 50 to 60 ℃ to completely dissolve the second reactant. And opening cooling water for cooling treatment, and cooling the generated second reaction liquid to below 40 ℃.
S3, adding a second solvent into the reaction kettle to form a third reaction solution, wherein the second solvent is a sodium hydroxide solution, the sodium hydroxide solution is a sodium hydroxide solution with the sodium hydroxide content of 30% and is an alkaline solution, and the mass fraction of the sodium hydroxide solution is 11.0% -15.0%.
Specifically, the mass fraction of the sodium hydroxide solution in this embodiment is preferably 13.0%, the sodium hydroxide solution is used to adjust the ph of the second reaction solution, the sodium hydroxide solution is added while the ph of the reaction solution is tested, so that the ph is 6.0-8.0, in this embodiment, the sodium hydroxide solution is preferably 6.9, the addition is stopped after the sodium hydroxide solution reaches the standard, and the sodium hydroxide solution is uniformly stirred to obtain a third reaction solution.
S4, filtering the third reaction solution to form a penetrant, specifically, reducing the temperature to 30-40 ℃, filtering the third reaction solution, and discharging to obtain the low-foam penetrant.
The preparation method of the low-foam penetrant has the technical effects that the EO/PO block polyether has good low-foam property, the low-foam penetrant prepared from the EO/PO block polyether also has good low-foam property, excessive foam is not generated in the use process of the low-foam penetrant, and defoaming treatment can be performed without additionally adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are greatly solved. The prepared low-foam penetrant has the characteristics of good wetting, penetrating and low-foam effects, easy biodegradation and the like, and has good compatibility with other surfactants and auxiliaries.
The embodiment also provides an application method of the low-foam penetrant, and the low-foam penetrant can be applied to a textile dyeing and finishing process to realize low-foam penetration of dyes without adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are solved greatly.
The low foam osmotic agent prepared has a variety of applications and test methods, some of which are listed in this example:
1) the solid content of the low-foam penetrant, namely the content of nonvolatile components in the penetrant, can be detected by adopting ZB G73010-90. After detection, the solid content of the low-foaming penetrant is 55% to 57%, and in this embodiment, the solid content of the low-foaming penetrant is preferably 56.3%.
2) The pH of the surfactant aqueous solution of the low-foam penetrant can be measured by a potentiometric method, and specifically GB/T6368-93 (ISO 4316-1977). After detection, the pH value of the low-foaming penetrant is 6.0-8.0, and in this embodiment, the pH value of the low-foaming penetrant is preferably 6.9.
3) The testing method of the foamability of the low-foam penetrant can adopt a measuring cylinder method with a plug for testing, and the method is as follows: any one of GB/T13173.6-91, GB/T7462-94 and dyeing and finishing professional teaching materials. After testing, the low-foam osmotic agent produced less than 10.0 ml of foam in the measuring cylinder within 30 seconds, and in this example, the low-foam osmotic agent had a foam content of 3.0 ml.
4) The wetting permeability of the low-foam penetrant can be tested by adopting a standard canvas settlement method, and the method is from GB 5557-85. The low-foaming osmotic agent has a wet permeability of less than 5.0 seconds, and preferably 2.0 seconds in this embodiment.
The content and the like of each component in the prepared low-foaming penetrant can be detected by the detection methods, so that the low-foaming penetrant can have a good low-foaming effect, and the specific detection method is not described in detail.
Example 2
The present embodiment provides a low-foaming penetrant, which comprises the following components by mass:
the difference between this example and the above example 1 is that the components and mass fractions of the low-foam penetrant in this example are:
the embodiment also provides a preparation method of the low-foam penetrant, which comprises the following steps S1-S4.
S1 the components required to prepare the low-foaming osmotic agent described in this example were prepared and the amounts of each component were calculated and prepared for use. Adding a first solvent and a first reactant into a reaction kettle to form a first reaction solution. The first solvent is water, the first reactant is secondary sodium alkyl sulfonate, the mass fraction of the first solvent is 16.0% -52.0%, and the mass fraction of the secondary sodium alkyl sulfonate is 8.0% -15.0%.
In this embodiment, specifically, 32% of a first solvent is added into a reaction kettle, a stirrer is started, the first reactant is slowly added while stirring at a temperature of 50 to 60 ℃, 14.0% of secondary alkyl sodium sulfonate is added, and sufficient stirring is continued for 30 to 50 minutes, so that the first reactant is completely dissolved to form a first reaction solution.
S2, adding a second reactant into the reaction kettle, and stirring to form a second reaction solution, wherein the second reactant is isomeric dodecyl alcohol polyoxyethylene ether, EO/PO block polyether, isooctyl alcohol polyoxyethylene ether phosphate and tributyl phosphate, the mass fractions of the second reactant are respectively 12.0-20.0% of isomeric dodecyl alcohol polyoxyethylene ether, 5.0-10.0% of EO/PO block polyether, 10.0-18.0% of isooctyl alcohol polyoxyethylene ether phosphate and 2.0-6.0% of tributyl phosphate.
In this embodiment, specifically, 15.0% of the isomeric dodecyl alcohol polyoxyethylene ether, 8.0% of the EO/PO block polyether, 14.0% of the isooctyl alcohol polyoxyethylene ether phosphate, and 5.0% of the tributyl phosphate are sequentially added into the reaction kettle, and the addition is completed within 30 to 60 minutes, and the mixture is stirred for 1 to 2 hours at a temperature of 50 to 60 ℃ to completely dissolve the second reactant. And opening cooling water for cooling treatment, and cooling the generated second reaction liquid to below 40 ℃.
S3, adding a second solvent into the reaction kettle to form a third reaction solution, wherein the second solvent is a sodium hydroxide solution, the sodium hydroxide solution is a sodium hydroxide solution with the sodium hydroxide content of 30% and is an alkaline solution, and the mass fraction of the sodium hydroxide solution is 11.0% -15.0%.
Specifically, the mass fraction of the sodium hydroxide solution in this embodiment is preferably 12.0%, the sodium hydroxide solution is used to adjust the ph of the second reaction solution, the sodium hydroxide solution is added while the ph of the reaction solution is tested, so that the ph is 6.0 to 8.0, in this embodiment, the sodium hydroxide solution is preferably 7.5, the addition is stopped after the sodium hydroxide solution reaches the standard, and the sodium hydroxide solution is uniformly stirred to obtain a third reaction solution.
S4, filtering the third reaction solution to form a penetrant, specifically, reducing the temperature to 30-40 ℃, filtering the third reaction solution, and discharging to obtain the low-foam penetrant.
The preparation method of the low-foam penetrant has the technical effects that the EO/PO block polyether has good low-foam property, the low-foam penetrant prepared from the EO/PO block polyether also has good low-foam property, excessive foam is not generated in the use process of the low-foam penetrant, and defoaming treatment can be performed without additionally adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are greatly solved. The prepared low-foam penetrant has the characteristics of good wetting, penetrating and low-foam effects, easy biodegradation and the like, and has good compatibility with other surfactants and auxiliaries.
The embodiment also provides an application method of the low-foam penetrant, and the low-foam penetrant can be applied to a textile dyeing and finishing process to realize low-foam penetration of dyes without adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are solved greatly.
Example 3
The present embodiment provides a low-foaming penetrant, which comprises the following components by mass:
the difference between this embodiment and the above embodiment 2 is that the components and mass fractions of the low-foam osmotic agent in this embodiment are:
the embodiment also provides a preparation method of the low-foam penetrant, which comprises the following steps S1-S4.
S1 the components required to prepare the low-foaming osmotic agent described in this example were prepared and the amounts of each component were calculated and prepared for use. Adding a first solvent and a first reactant into a reaction kettle to form a first reaction solution. The first solvent is water, the first reactant is secondary sodium alkyl sulfonate, the mass fraction of the first solvent is 16.0% -52.0%, and the mass fraction of the secondary sodium alkyl sulfonate is 8.0% -15.0%.
In this embodiment, specifically, 40.0% of a first solvent is added into a reaction kettle, a stirrer is started, the first reactant is slowly added while stirring at a temperature of 50 to 60 ℃, 9.0% of secondary alkyl sodium sulfonate is added, and sufficient stirring is continued for 40 minutes, so that the first reactant is completely dissolved, and a first reaction solution is formed.
S2, adding a second reactant into the reaction kettle, and stirring to form a second reaction solution, wherein the second reactant is isomeric dodecyl alcohol polyoxyethylene ether, EO/PO block polyether, isooctyl alcohol polyoxyethylene ether phosphate and tributyl phosphate, the mass fractions of the second reactant are respectively 12.0-20.0% of isomeric dodecyl alcohol polyoxyethylene ether, 5.0-10.0% of EO/PO block polyether, 10.0-18.0% of isooctyl alcohol polyoxyethylene ether phosphate and 2.0-6.0% of tributyl phosphate.
In this embodiment, specifically, 14.0% of the isomeric dodecyl alcohol polyoxyethylene ether, 6.0% of the EO/PO block polyether, 16.0% of the isooctyl alcohol polyoxyethylene ether phosphate, and 3.0% of the tributyl phosphate are sequentially added into the reaction kettle, and the addition is completed within 30 to 60 minutes, and the mixture is stirred for 1.5 hours at a temperature of 55 ℃ to completely dissolve the second reactant. And opening cooling water for cooling treatment, and cooling the generated second reaction liquid to below 40 ℃.
S3, adding a second solvent into the reaction kettle to form a third reaction solution, wherein the second solvent is a sodium hydroxide solution, the sodium hydroxide solution is a sodium hydroxide solution with the sodium hydroxide content of 30% and is an alkaline solution, and the mass fraction of the sodium hydroxide solution is 11.0% -15.0%.
Specifically, the mass fraction of the sodium hydroxide solution in this embodiment is preferably 12.0%, the sodium hydroxide solution is used to adjust the ph of the second reaction solution, the sodium hydroxide solution is added while the ph of the reaction solution is tested, so that the ph is 6.0 to 8.0, in this embodiment, the sodium hydroxide solution is preferably 6.5, the addition is stopped after the sodium hydroxide solution reaches the standard, and the sodium hydroxide solution is uniformly stirred to obtain a third reaction solution.
S4, filtering the third reaction solution to form a penetrant, specifically, reducing the temperature to 30-40 ℃, filtering the third reaction solution, and discharging to obtain the low-foam penetrant.
The preparation method of the low-foam penetrant has the technical effects that the EO/PO block polyether has good low-foam property, the low-foam penetrant prepared from the EO/PO block polyether also has good low-foam property, excessive foam is not generated in the use process of the low-foam penetrant, and defoaming treatment can be performed without additionally adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are greatly solved. The prepared low-foam penetrant has the characteristics of good wetting, penetrating and low-foam effects, easy biodegradation and the like, and has good compatibility with other surfactants and auxiliaries.
The embodiment also provides an application method of the low-foam penetrant, and the low-foam penetrant can be applied to a textile dyeing and finishing process to realize low-foam penetration of dyes without adding a defoaming agent, so that various problems of unclean discharging, nozzle blockage, water resource waste, environment pollution and the like caused by excessive foam are solved greatly.
In the foregoing embodiments, the descriptions of the respective embodiments have respective emphasis, and for parts that are not described in detail in a certain embodiment, reference may be made to related descriptions of other embodiments.
The low-foam osmotic agent provided by the embodiment of the invention, the preparation method and the application method thereof are described in detail, the principle and the implementation mode of the invention are explained by applying specific examples, and the description of the embodiment is only used for helping to understand the technical scheme and the core idea of the invention; those of ordinary skill in the art will understand that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (10)
2. the low-foam osmotic agent of claim 1,
the block polyether is EO/PO block polyether.
3. The low-foam osmotic agent of claim 1,
the concentration of the sodium hydroxide in the sodium hydroxide solution is 25-35%.
4. A preparation method of a low-foam osmotic agent is characterized by comprising the following steps:
adding 16.0-52.0% of water and 8.0-15.0% of secondary sodium alkyl sulfonate into a reaction kettle, and stirring to dissolve the secondary sodium alkyl sulfonate into the water to form a first reaction liquid;
adding 12.0-20.0% of isomeric dodecyl alcohol polyoxyethylene ether, 5.0-10.0% of EO/PO block polyether, 10.0-18.0% of isooctanol polyoxyethylene ether phosphate and 2.0-6.0% of tributyl phosphate into the reaction kettle, and stirring to form a second reaction solution;
adding 11.0-15.0% of sodium hydroxide solution into the reaction kettle to form a third reaction solution; and
and filtering the third reaction solution to form the low-foam penetrant.
5. The method of producing a low-foaming osmotic agent according to claim 4, wherein, in the step of forming the first reaction liquid,
adding the water into the reaction kettle, starting a stirrer, adding the secondary alkyl sodium sulfonate while stirring at the temperature of 50-60 ℃, and fully stirring for 30-50 minutes to completely dissolve the secondary alkyl sodium sulfonate.
6. The method for producing a low-foaming osmotic agent according to claim 5, wherein, in the step of forming the second reaction solution,
and stirring for 1-2 hours at the temperature of 50-60 ℃ to completely dissolve the isomeric dodecyl alcohol polyoxyethylene ether, the EO/PO block polyether, the isooctyl alcohol polyoxyethylene ether phosphate and the tributyl phosphate to form a second reaction solution.
7. The method for producing a low-foaming osmotic agent according to claim 6, wherein, in the step of forming the second reaction solution,
and cooling the second reaction solution to below 40 ℃.
8. The method for producing a low-foaming osmotic agent according to claim 6, wherein, in the step of forming the third reaction liquid,
the concentration of sodium hydroxide in the sodium hydroxide solution is 25% -35%, the pH value of the second reaction solution is adjusted to be 6.8-7.2, and the third reaction solution is obtained after uniform stirring.
9. The method for producing a low-foaming osmotic agent according to claim 8, wherein, in the step of subjecting the third reaction solution to filtration treatment,
and reducing the temperature to 30-40 ℃, and filtering the third reaction solution.
10. An application method of a low-foam penetrating agent is characterized in that the low-foam penetrating agent is applied to a textile dyeing and finishing process.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011088107.8A CN112239958A (en) | 2020-10-13 | 2020-10-13 | Low-foam penetrant and preparation method and application method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011088107.8A CN112239958A (en) | 2020-10-13 | 2020-10-13 | Low-foam penetrant and preparation method and application method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN112239958A true CN112239958A (en) | 2021-01-19 |
Family
ID=74168864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011088107.8A Pending CN112239958A (en) | 2020-10-13 | 2020-10-13 | Low-foam penetrant and preparation method and application method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112239958A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114000354A (en) * | 2021-11-09 | 2022-02-01 | 苏州联胜化学有限公司 | Low-foam scouring agent for long-distance vehicle made of cotton woven fabric and preparation method of low-foam scouring agent |
CN114481651A (en) * | 2021-12-31 | 2022-05-13 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
CN115323810A (en) * | 2022-08-26 | 2022-11-11 | 珠海天威新材料股份有限公司 | Fabric printing pretreatment liquid and fabric printing method |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104532560A (en) * | 2014-12-30 | 2015-04-22 | 成都德美精英化工有限公司 | Refining agent for continuous dyeing |
CN105155306A (en) * | 2015-07-23 | 2015-12-16 | 百宁纺织化工(中山)有限公司 | Formula for osmotic agent |
CN106368009A (en) * | 2016-08-31 | 2017-02-01 | 浙江皇马科技股份有限公司 | Rapid alkali-resistant penetration agent and compounding method thereof |
CN108070465A (en) * | 2017-11-14 | 2018-05-25 | 广州先盈生物科技有限公司 | Multi-functional Clean products and preparation method thereof |
CN108611850A (en) * | 2018-06-22 | 2018-10-02 | 淄博鲁瑞精细化工有限公司 | The preparation method of the low bubble concise bleeding agent of phosphate |
CN111088711A (en) * | 2019-12-31 | 2020-05-01 | 中纺检测(福建)有限公司 | High-alkali-resistance easily-biodegradable textile penetrant and preparation method thereof |
-
2020
- 2020-10-13 CN CN202011088107.8A patent/CN112239958A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104532560A (en) * | 2014-12-30 | 2015-04-22 | 成都德美精英化工有限公司 | Refining agent for continuous dyeing |
CN105155306A (en) * | 2015-07-23 | 2015-12-16 | 百宁纺织化工(中山)有限公司 | Formula for osmotic agent |
CN106368009A (en) * | 2016-08-31 | 2017-02-01 | 浙江皇马科技股份有限公司 | Rapid alkali-resistant penetration agent and compounding method thereof |
CN108070465A (en) * | 2017-11-14 | 2018-05-25 | 广州先盈生物科技有限公司 | Multi-functional Clean products and preparation method thereof |
CN108611850A (en) * | 2018-06-22 | 2018-10-02 | 淄博鲁瑞精细化工有限公司 | The preparation method of the low bubble concise bleeding agent of phosphate |
CN111088711A (en) * | 2019-12-31 | 2020-05-01 | 中纺检测(福建)有限公司 | High-alkali-resistance easily-biodegradable textile penetrant and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
沈一丁主编: "《轻化工助剂》", 31 July 2004 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114000354A (en) * | 2021-11-09 | 2022-02-01 | 苏州联胜化学有限公司 | Low-foam scouring agent for long-distance vehicle made of cotton woven fabric and preparation method of low-foam scouring agent |
CN114481651A (en) * | 2021-12-31 | 2022-05-13 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
CN114481651B (en) * | 2021-12-31 | 2024-02-02 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
CN115323810A (en) * | 2022-08-26 | 2022-11-11 | 珠海天威新材料股份有限公司 | Fabric printing pretreatment liquid and fabric printing method |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN112239958A (en) | Low-foam penetrant and preparation method and application method thereof | |
CN108219987B (en) | Glass cleaning agent after screen printing of mirror silver and preparation method thereof | |
CA2692254C (en) | Paste-like detergent formulation comprising branched alkoxylated fatty alcohols as non-ionic surfactants | |
EP0436470B1 (en) | Process of photochemical stabilization of dyed polyamid-fibre materials | |
CN111996803B (en) | Novel environment-friendly low-foam low-temperature degreasing agent and preparation method thereof | |
CN106634163A (en) | Water-based cleaning agent, preparation method thereof and PCB ink cleaning method | |
MXPA02010528A (en) | Composition for pretreating fiber materials. | |
US4028280A (en) | Non-phosphate or reduced phosphate detergent compositions containing mixtures of alkyl ether sulfates | |
CN110564517A (en) | low-foam oil-removing scouring agent and preparation method and use method thereof | |
DE10162023A1 (en) | Mixtures of gemini surfactants and fatty alcohol alkoxylates in rinse aid | |
DE69729815T2 (en) | Pretreatment compositions in stick form | |
CN104818614A (en) | Novel penetrating agent for textile pretreatment | |
JP4579954B2 (en) | Fiber scouring agent composition | |
JP4087393B2 (en) | Fiber scouring agent composition | |
CN111749022A (en) | Low-foam high-concentration scouring agent and preparation method thereof | |
KR20110072087A (en) | Degreasing agent with excellent dispersion and wetting property | |
KR101905890B1 (en) | Manufacturing method of a multi-functional refining agent and multi-functional refining agent manufactured by same method | |
CN108560266A (en) | A kind of environmental protection oil removing refining agent and preparation method thereof | |
US20070000075A1 (en) | Multifunctional textile-pretreating agent | |
CN117285987A (en) | Wool detergent and preparation method thereof | |
CN114000354A (en) | Low-foam scouring agent for long-distance vehicle made of cotton woven fabric and preparation method of low-foam scouring agent | |
KR20200047184A (en) | A normal temperature defat agent applicable in normal temperature and a defat method using the same | |
CN113373712B (en) | Salt-resistant soaping agent for ultralow bath ratio and soaping process thereof | |
JPS62199697A (en) | Liquid detergent composition | |
CN114481651B (en) | Alkali-resistant penetrating agent and application thereof in sizing |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210119 |
|
RJ01 | Rejection of invention patent application after publication |