CN106234405A - A kind of Pesticidal combination containing fluorine chlorine ether chrysanthemum ester and ethofenprox and application thereof - Google Patents
A kind of Pesticidal combination containing fluorine chlorine ether chrysanthemum ester and ethofenprox and application thereof Download PDFInfo
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- CN106234405A CN106234405A CN201610612608.9A CN201610612608A CN106234405A CN 106234405 A CN106234405 A CN 106234405A CN 201610612608 A CN201610612608 A CN 201610612608A CN 106234405 A CN106234405 A CN 106234405A
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- biocide composition
- hygienic biocide
- ethofenprox
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- agriculture breast
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
Abstract
The present invention relates to a kind of hygienic biocide composition containing fluorine chlorine ether chrysanthemum ester Yu ethofenprox.Described compositions compares single dose significant potentiation, improves insecticidal effect, and coefficient of synergism is all more than 130；In addition, after this hygienic biocide composition is configured to specific aqueous emulsion, suspension emulsion and microemulsion, for relatively conventional dosage forms, the dispersibility of active component improves a lot, after preparing especially with the specific auxiliary agent of each dosage form, in addition to dispersibility improves, the transport of preparation, storage stability are also greatly improved.
Description
Technical field
The present invention relates to a kind of hygienic insecticide field, a kind of group containing fluorine chlorine ether chrysanthemum ester Yu ethofenprox
Compound.
Background technology
Fluorine chlorine ether chrysanthemum ester, No. CAS: 352271-52-4, chemical name: 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl bases-
(1R, 3S)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester, English name Meperfluthrin, chemistry
Structural formula is as follows:
。
This compound is a kind of pyrethroid compound with new construction, be suck and contact insecticide, to mosquito,
The sanitary insect pests such as fly have brilliance knock down and kill activity, be currently mainly applied to domestic hygiene preparation.
Ethofenprox, No. CAS: 80844-07-1, chemical name: 2-(4-ethoxyl phenenyl)-2-methyl-propyl-3-phenoxy group
Benzylic ether, English name Ethofenprox, chemical structural formula:
。
This compound has tags and stomach poison function, and insecticidal activity is high, it is fast, to Lepidoptera, Semiptera, elytrum to knock down speed
The various pests such as mesh, Diptera has efficiently.
On market, conventional chrysanthemum esters medicament carries out the preventing and treating of sanitary insect pest, and life-time service causes sanitary insect pest such as Blatta seu periplaneta, defends
Raw mosquito, health fly etc. produce great Drug resistance to this type of medicament, make prevention effect generally reduce.
At present, there are not fluorine chlorine ether chrysanthemum ester and ethofenprox mixture for the research of health pest control and report.
We are by the complementation of two kinds of composite reagent mechanism, the low toxicity of ethofenprox, low irritant, to environmental organism safety,
Advantage safe to the human body, it is thus achieved that the Pesticidal combination of a kind of high-efficiency environment friendly, improves the effect of the preventing and treating to sanitary insect pest to greatest extent
Really, drug-fast generation speed is reduced；And in terms of dosage form, develop aqueous emulsion, propellant, cream, wettable powder further
Agent, water dispersible granules, suspending agent novel dosage forms etc., compared to being traditionally used for the aerosol of mosquito control, solvent is few, no
Containing the flammable explosive gas such as the third butane, safer environmental protection, it is more suitable for indoor and outdoor health pest control.
Summary of the invention
An object of the present invention is to provide a kind of good disinsection effect, and compounding rear potentiation is notable, and can delay
Sanitary insect pest develop immunity to drugs containing fluorine chlorine ether chrysanthemum ester and the Pesticidal combination of ethofenprox.
Another object of the present invention is to the preparation method and application that above-mentioned Pesticidal combination is provided in preventing and treating multiple health
The purposes of insect.
The present invention provides a kind of hygienic biocide composition, it is characterised in that: described Pesticidal combination contains following activity group
Point: fluorine chlorine ether chrysanthemum ester and ethofenprox, wherein the weight ratio of fluorine chlorine ether chrysanthemum ester and ethofenprox is 1:99～99:1.
Preferably, in this hygienic biocide composition, the weight ratio of fluorine chlorine ether chrysanthemum ester and ethofenprox is 1:50～50:1；More
Preferably, the weight ratio of the two is 1:20～20:1；Being more highly preferred to, the weight ratio of the two is 1:20～1:5.
Further, described hygienic biocide composition can also comprise acceptable auxiliary agent, Qi Zhongyou in health medication
Effect composition accounts for 1-70 weight % of Pesticidal combination；It is preferably 5-40 weight %, more preferably 10-30 weight %, most preferably 15-25
Weight %.
Further, described hygienic biocide composition is configured to water dispersible granules, suspending agent, wettable powder, microemulsion
Or aqueous emulsion；It is preferably suspending agent, microemulsion or aqueous emulsion.
When being configured to aqueous emulsion, it is characterised in that described hygienic biocide composition contains following component by weight:
Active component: 10-30%；
Solvent: selected from one or more 8-20% of N,N-dimethylformamide, Ketohexamethylene, dimethyl sulfoxide and solvent naphtha；
Emulsifying agent: selected from sodium ascorbyl phosphate, thermally coupled distillation columns, phenethyl phenol polyoxyethylene ether, three phenethyls
Phenol polyoxyethylene phosphonate, alkyl benzene calcium sulfonate, Nongru-700 #, agriculture breast 2201#, Span-60#, emulsifying agent T-60, TX-
10, one or more in agriculture breast 1601#, agriculture breast 600# and agriculture breast 400#, 4-10%；Antifreezing agent: 3-8%；
Defoamer: 0.3-2%；
Water supplies surplus.
Described antifreezing agent and defoamer can be conventional antifreezing agent and defoamer.
Preferably, described emulsifying agent is thermally coupled distillation columns and triphenoethyl benzene phenol polyethenoxy ether phosphoric acid
The compound emulsifying agent of ester, the weight ratio of the two is 5:1-1:5, preferably 3:1.
When being configured to suspension emulsion, it is characterised in that described hygienic biocide composition contains following component by weight:
Active component: 10-30%；
Dispersant: one or more in polycarboxylate, lignosulfonates and alkylnaphthalene sulfonate, 8-15%；
Emulsifying agent: the one or many in Nongru-700 #, agriculture breast 2201, this dish-60#, emulsifying agent T-60 and agriculture breast 1601#
Kind；3-10%；
Wetting agent: selected from alkylphenol-polyethenoxy poly-base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy base ether phosphate,
One or more in phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate or naphthalene sulfonate, 5-
8%；
Thickening agent: one or more in xanthan gum, aluminium-magnesium silicate or bentonite, 0.5-1.5%；
Water supplies surplus.
Preferably, described dispersant is the composite dispersing agent of lignosulfonates and alkylnaphthalene sulfonate, the two compound ratio
Example is 3:1-1:4.Emulsifying agent is more preferably Nongru-700 #.
When being configured to microemulsion, it is characterised in that described hygienic biocide composition contains following component by weight:
Active component: 10-30%；
Emulsifying agent: selected from calcium dodecyl benzene sulfonate, Nongru-700 #, agriculture breast 2201#, this dish-60#, tween 80, TX-10, agriculture
One or more in breast 1601, agriculture breast 600# and agriculture breast 400#；8-15%；
Solvent: one or more in Ketohexamethylene, N-Methyl pyrrolidone, dimethylbenzene, toluene and solvent naphtha, 15-30%；
Cosolvent: one or more in methanol, isopropanol, n-butyl alcohol, ethanol, 4-10%；
Stabilizer: selected from triphenyl phosphite or epoxychloropropane, 2-6%；
Water supplies surplus.
Preferably, described emulsifying agent is calcium dodecyl benzene sulfonate or Nongru-700 #；Solvent is N-Methyl pyrrolidone.
For water dispersible granules, it is possible to use following main auxiliary agent, employing conventional method are prepared: dispersant selects
With from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate；Wetting agent is selected from polyoxyethylene alcohol, alkyl sulfate, alkyl sulphur
Hydrochlorate, naphthalene sulfonate；Disintegrating agent is selected from ammonium sulfate, carbamide, sucrose, glucose, citric acid, succinic acid, sodium bicarbonate；Binding agent
Selected from kieselguhr, corn starch, PVA, carboxymethyl (ethyl) cellulose and microcrystalline Cellulose class；Filler is selected from kieselguhr, kaolinite
Soil, white carbon, fine particle calcium carbonate, meerschaum, Pulvis Talci, attapulgite, potter's clay etc..
For wettable powder, those skilled in the art use following main auxiliary agent, use conventional method to join
System: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate；Wetting agent is selected from alkyl sulfate, alkyl sulfonic acid
Salt, naphthalene sulfonate；Filler is selected from kieselguhr, Kaolin, white carbon, fine particle calcium carbonate, Pulvis Talci, attapulgite, potter's clay etc..Described dosage form
Employing well known to a person skilled in the art that method is processed, prepares.
Further, the present invention furthermore provides the application of above-mentioned hygienic biocide composition preventing and treating sanitary insect pest, and it is special
Levying and be, described sanitary insect pest is cockroach, flea, Formica fusca, Cimex bedbug, mosquito and fly；It is preferably health mosquito and health fly.
Compared with prior art, the invention have the benefit that
(1) compared with single dose, Pesticidal combination of the present invention has significant potentiation to insect, improves insecticidal effect,
Coefficient of synergism is all more than 130.
(2) reduce times for spraying, reduce drug cost, reduce environmental pollution and pesticide residues.
(3) compositions is made up of the effective ingredient that insecticidal mechanism is complementary, and action site increases, and is conducive to overcoming and delay to resist
The generation of the property of medicine.
(4) being that domestic hygienic biocide field adds a new complex composition, drug effect is notable, it is possible to obtain widely
Popularization and application.
(5) after being configured to aqueous emulsion, suspension emulsion and microemulsion with above-mentioned specific form formula in addition, relatively conventional dosage forms and
Speech, the dispersibility of active component improves a lot, after preparing especially with the specific auxiliary agent of each dosage form, except dispersibility improves
Outward, the transport of preparation, storage stability are also greatly improved, and this has great significance for follow-up sanitary insect pest of killing.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these tools
Body embodiment.One skilled in the art would recognize that present invention encompasses and potentially included in Claims scope
All alternatives, improvement project and equivalents.
One, preparation embodiment
" % " involved in following all formulations proportioning is all weight percentage.
Example of formulations 1～9:
According to fluorine chlorine ether chrysanthemum ester in table-1 and the compound proportion of ethofenprox and consumption, adjuvant is 150# solvent naphtha 15g, benzene sulfonamide
Acid calcium 3g, phenethyl phenol polyoxyethylene ether 3g, 601 phosphoric acid ester sodium 2g, ethylene glycol 5g, defoamer 0.5g, water is mended to 100g
Prepare aqueous emulsion example of formulations 1～9.
Table-1 example of formulations 1～9
Example of formulations 5A:
Additionally, for the effect contrasting aqueous emulsion, use thermally coupled distillation columns and triphenoethyl benzene phenol polyoxy second
Alkene ether phosphate replaces alkyl benzene calcium sulfonate, phenethyl phenol polyoxyethylene ether and 601 phosphoric acid ester sodiums as emulsifying agent, wherein
Thermally coupled distillation columns is 6g, and triphenoethyl benzene phenol polyethenoxy ether phosphate is 2g, and remaining is with embodiment 5, system
Obtain embodiment 5A.
Example of formulations 10:
By fluorine chlorine ether chrysanthemum ester 0.5g, ethofenprox 9.5g, white carbon 3g, calcium dodecyl benzene sulfonate 3g, sodium lignin sulfonate 7g, lemon
Lemon acid 0.3g, Kaolin benefit prepares wettable powder formulation embodiment 10 to 100g.
Example of formulations 11:
By fluorine chlorine ether chrysanthemum ester 1.5g, ethofenprox 8.5g, calcium dodecyl benzene sulfonate 4g, fatty alcohol-polyoxyethylene ether 6g, 150# are molten
Agent oil benefit prepares cream preparation embodiment 11 to 100g.
Example of formulations 12:
By fluorine chlorine ether chrysanthemum ester 3.0g, ethofenprox 7.0g, white carbon 5g, pull open powder 3g, naphthalenesulfonate formaldehyde condensation compound 7g, carboxymethyl
Sodium cellulosate 0.2g, oxalic acid 0.4g, bentonite benefit prepares water dispersible granules example of formulations 12 to 100g.
Example of formulations 13:
By fluorine chlorine ether chrysanthemum ester 10g, ethofenprox 10g, lignosulfonates 11.5g, emulsifying agent T-60 be 6%, alkylsulfonate 6%,
Xanthan gum 1%, water benefit prepares aqueous suspension formulations embodiment 13 to 100g.
Example of formulations 13A:
In addition to dispersant is alkylnaphthalene sulfonate, remaining is with embodiment 13.
Example of formulations 13B:
Except dispersant be weight ratio be in addition to the lignosulfonates of 1:1 and the composite dispersing agent of alkylnaphthalene sulfonate, remaining is with real
Execute example 13.
Example of formulations 13C:
In addition to emulsifying agent is Nongru-700 #, remaining is with embodiment 13.
Example of formulations 14:
By fluorine chlorine ether chrysanthemum ester 0.02g, ethofenprox 0.08g, tributyl citrate 2.0g, calcium dodecyl benzene sulfonate 1.5g, Semen Ricini
Oil polyoxyethylene ether 4.5g, dehydrated alcohol 5g, propylene glycol 10g, water benefit prepares propellant example of formulations 14 to 100g.
Example of formulations 15:
By fluorine chlorine ether chrysanthemum ester 10g, ethofenprox 10g, calcium dodecyl benzene sulfonate 12g, Ketohexamethylene be 20%, n-butyl alcohol 6%, phosphorous acid
Triphenylmethyl methacrylate 3%, water benefit prepares aqueous suspension formulations embodiment 15 to 100g.
Example of formulations 15A:
Except emulsifying agent is that in addition to Nongru-700 # replaces calcium dodecyl benzene sulfonate, remaining is with embodiment 15.
Example of formulations 15B:
In addition to solvent is N-Methyl pyrrolidone, remaining is with embodiment 15.
Comparing embodiment 1:
By fluorine chlorine ether chrysanthemum ester 20g, adjuvant is 150# solvent naphtha 15g, alkyl benzene calcium sulfonate 3g, phenethyl phenol polyoxyethylene ether
3g, 601 phosphoric acid ester sodium 2g, ethylene glycol 5g, defoamer 0.5g, water benefit prepares 10% fluorine chlorine ether chrysanthemum ester aqueous emulsion to 100g and compares
Embodiment 1.
Comparing embodiment 2:
By ethofenprox 20g, adjuvant is 150# solvent naphtha 15g, alkyl benzene calcium sulfonate 3g, phenethyl phenol polyoxyethylene ether 3g, 601
Phosphoric acid ester sodium 2g, ethylene glycol 5g, defoamer 0.5g, water benefit prepares 10% ethofenprox aqueous emulsion comparing embodiment 2 to 100g.
Application Example 1: culex pipiens pallens indoor biological active determination test
With reference to farm-chemical indoor determination test rule insecticide part 1: contact toxicity testing site dripping method NY/T
1154.1-2006 carries out active determination test to culex pipiens pallens, and ratio, according to example of formulations 1～9, calculates LD50.Measurement result
As follows (table-2).
Table-2 Application Example measurement result
By compounding embodiment LD each in Application Example 150 With single dose LD50 Computational methods are referred to by virulence with reference to Sun Yunpei's
Number calculates the method for mixture co-toxicity, calculates co-toxicity coefficient, and result of calculation is following (table-3).
Table-3 present invention compounds co-toxicity coefficient measurement result:
Test result shows, when fluorine chlorine ether chrysanthemum ester and ethofenprox compound proportion are at 1:99～99:1, and the equal ＞ of co-toxicity coefficient 130,
There is notable synergistic effect.Particularly, when the ratio of fluorine chlorine ether chrysanthemum ester Yu ethofenprox is 1:20～1:5, potentiation is more
Substantially, all more than 200.
Application Example 2: preventing and treating mosquitos and flies indoor pharmacodynamic test
Test method: with reference to GB/T13919.1-2009 agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and evaluation, spraying
Test.
Experiment processes: by equal to example of formulations and comparing embodiment dilute with water 100 times use.
Result of the test is following (table-4):
Table-4 mosquito, fly test of pesticide effectiveness result (nebulization)
Above-mentioned indoor pharmacodynamic test result shows, fluorine chlorine ether ethofenprox compounds with ethofenprox, can significantly improve complex preparation pair
Mosquitos and flies knock down speed, the most identical with the result of Application Example 1.When fluorine chlorine ether chrysanthemum ester: ethofenprox=1:99, i.e. with a small amount of
When fluorine chlorine ether chrysanthemum ester and ethofenprox compound, can significantly improve and knock down speed；When fluorine chlorine ether chrysanthemum ester: during ethofenprox ＞ 1:20, i.e.
Can reach A level activity.
Application Example 3: preventing and treating Groton bug indoor pharmacodynamic test
Test method: with reference to GB/T13919.1-2009 agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and evaluation, spraying
Test.
Experiment processes: by equal to example of formulations and comparing embodiment dilute with water 20 times use.
Result of the test is following (table-5):
Table-5 Groton bug test of pesticide effectiveness result (nebulization)
Above-mentioned indoor pharmacodynamic test result shows, when fluorine chlorine ether chrysanthemum ester and ethofenprox compound, can significantly improve complex preparation pair
Groton bug knock down speed, the most identical with the result of Application Example 1.
Stability test
Test preparation embodiment 5,5A, preparation embodiment 13,13A, 13B, 13C, 15, the storage stability of 15A, 15B sample,
Store 1 month at-10 DEG C and 50 DEG C, observe with or without precipitation, as follows about precipitation fractionation:
0 grade without precipitation
1 grade has a small amount of precipitation
2 grades have more precipitation
3 grades have a large amount of precipitation
Result of the test is shown in Table 6.
The storage stability of table 6 invention formulation
As can be seen from the above table, when using currently preferred pharmaceutical formulation to prepare corresponding preparation, obtained preparation
Stability more excellent.
The a kind of of the present invention has passed through concrete containing fluorine chlorine ether chrysanthemum ester with the Pesticidal combination of ethofenprox and application thereof
Example is described, and those skilled in the art can use for reference present invention, and the link such as suitable feed change, process conditions is come real
Now other purpose corresponding, its relevant change is all without departing from present disclosure, and all similar replacements and change are for this
It is apparent from for skilled person, is considered as being included within the scope of the present invention.
Claims (10)
1. a hygienic biocide composition, it is characterised in that: described Pesticidal combination contains following active component: fluorine chlorine ether chrysanthemum ester
And ethofenprox, wherein the weight ratio of fluorine chlorine ether chrysanthemum ester and ethofenprox is 1:99～99:1.
Hygienic biocide composition the most according to claim 1, it is characterised in that: the weight ratio of the two is 1:20～20:1.
Hygienic biocide composition the most according to claim 1, it is characterised in that: the weight ratio of the two is 1:20～1:5.
Hygienic biocide composition the most according to claim 1, it is characterised in that: described hygienic biocide composition comprises and defends
Acceptable auxiliary agent in raw medication, wherein effective ingredient accounts for 1-70 weight % of Pesticidal combination.
Hygienic biocide composition the most according to claim 4, it is characterised in that: described hygienic biocide composition is configured to following water
Emulsion:
Active component: 10-30%；
Solvent: selected from one or more 8-20% of N,N-dimethylformamide, Ketohexamethylene, dimethyl sulfoxide and solvent naphtha；
Emulsifying agent: selected from sodium ascorbyl phosphate, thermally coupled distillation columns, phenethyl phenol polyoxyethylene ether, three phenethyls
Phenol polyoxyethylene phosphonate, alkyl benzene calcium sulfonate, Nongru-700 #, agriculture breast 2201#, Span-60#, emulsifying agent T-60, TX-
10, one or more in agriculture breast 1601#, agriculture breast 600# and agriculture breast 400#, 4-10%；
Antifreezing agent: 3-8%；
Defoamer: 0.3-2%；
Water supplies surplus.
Hygienic biocide composition the most according to claim 5, it is characterised in that: described emulsifying agent is Nonyl pheno
Ether phosphate and the compound emulsifying agent of triphenoethyl benzene phenol polyethenoxy ether phosphate, the weight ratio of the two is 5:1-1:5.
Hygienic biocide composition the most according to claim 4, it is characterised in that: described hygienic biocide composition is configured to following outstanding
Emulsion:
Active component: 10-30%；
Dispersant: one or more in polycarboxylate, lignosulfonates and alkylnaphthalene sulfonate, 8-15%；
Emulsifying agent: the one or many in Nongru-700 #, agriculture breast 2201, this dish-60#, emulsifying agent T-60 and agriculture breast 1601#
Kind；3-10%；
Wetting agent: selected from alkylphenol-polyethenoxy poly-base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy base ether phosphate,
One or more in phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate or naphthalene sulfonate, 5-
8%；
Thickening agent: one or more in xanthan gum, aluminium-magnesium silicate or bentonite, 0.5-1.5%；
Water supplies surplus.
Hygienic biocide composition the most according to claim 7, it is characterised in that: described dispersant is lignosulfonates and alkyl
The composite dispersing agent of naphthalene sulfonate, the two ratio is 3:1-1:4.
Hygienic biocide composition the most according to claim 4, it is characterised in that: described hygienic biocide composition is configured to the most micro-
Emulsion:
Active component: 10-30%；
Emulsifying agent: selected from calcium dodecyl benzene sulfonate, Nongru-700 #, agriculture breast 2201#, this dish-60#, tween 80, TX-10, agriculture
One or more in breast 1601, agriculture breast 600# and agriculture breast 400#；8-15%；
Solvent: one or more in Ketohexamethylene, N-Methyl pyrrolidone, dimethylbenzene, toluene and solvent naphtha, 15-30%；
Cosolvent: one or more in methanol, isopropanol, n-butyl alcohol, ethanol, 4-10%；
Stabilizer: selected from triphenyl phosphite or epoxychloropropane, 2-6%；
Water supplies surplus.
10. the application of the arbitrary described hygienic biocide composition preventing and treating sanitary insect pest of claim 1 to 9, it is characterised in that described
Sanitary insect pest is cockroach, flea, Formica fusca, Cimex bedbug, mosquito and fly；It is preferably health mosquito and health fly.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107372578A (en) * | 2017-07-26 | 2017-11-24 | 南通功成精细化工有限公司 | A kind of hygienic biocide suspension emulsion and preparation method thereof |
| CN114271286A (en) * | 2022-01-05 | 2022-04-05 | 定远众邦生物工程有限公司 | Missible oil containing metamifop and oxaziclomefone |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101473842B (en) * | 2009-01-23 | 2012-06-06 | 江苏扬农化工股份有限公司 | Insecticidal composition |
| CN101953370A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composite containing chlorine fluorine ethofenprox and cypermethrin and application thereof |
| CN101953368A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing chlorine fluorine ethofenprox and beta-cypermethrin and application thereof |
| CN101953362A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing meperfluthrin and bifenthrin and application thereof |
| CN101953369A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof |
| CN103168795B (en) * | 2011-12-26 | 2015-01-07 | 江苏扬农化工股份有限公司 | Meperfluthrin-containing compound insecticidal composition and application thereof |
| JP2014159380A (en) * | 2013-02-19 | 2014-09-04 | Sumitomo Chemical Co Ltd | Pest control composition and controlling method of pest |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107372578A (en) * | 2017-07-26 | 2017-11-24 | 南通功成精细化工有限公司 | A kind of hygienic biocide suspension emulsion and preparation method thereof |
| CN107372578B (en) * | 2017-07-26 | 2020-10-02 | 江苏功成生物科技有限公司 | Sanitary insecticidal suspoemulsion and preparation method thereof |
| CN114271286A (en) * | 2022-01-05 | 2022-04-05 | 定远众邦生物工程有限公司 | Missible oil containing metamifop and oxaziclomefone |
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