CN101953369A - Composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof - Google Patents
Composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof Download PDFInfo
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- CN101953369A CN101953369A CN2010102006080A CN201010200608A CN101953369A CN 101953369 A CN101953369 A CN 101953369A CN 2010102006080 A CN2010102006080 A CN 2010102006080A CN 201010200608 A CN201010200608 A CN 201010200608A CN 101953369 A CN101953369 A CN 101953369A
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Abstract
The invention relates to a composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof. The mass ratio of the chlorine fluorine ethofenprox to the deltamethrin is 1:99-99:1. When the two pesticides are compounded, the mutual synergy is obvious, and the prevention and control effect on sanitary pests can be remarkably improved; and the pesticide composition for preparing products such as disc insecticidal mosquito incense, insecticidal aerosol and the like has the advantages of quick pest knockdown and durable pesticide effect, and can ideally prevent and control the sanitary pests against dimethrin agents.
Description
Technical field
The present invention relates to Pesticidal combination, particularly a kind of health that is used to prevent and treat sanitary insect pest, environmental protection, Pesticidal combination efficiently.Be specially the Pesticidal combination that contains chlorine fluorine ether chrysanthemum ester and decis.
Background technology
For a long time, the employed medicament of control sanitary insect pest is the agent of chrysanthemum ester class medicament list, the long-term use of chrysanthemum ester class medicament list agent makes sanitary insect pest such as cockroach, health mosquito and health fly etc. improve greatly the pesticide resistance of chrysanthemum ester class medicament, has occurred the phenomenon that preventive effect generally reduces in recent years.Therefore need a kind of new varieties of pesticides of environment-friendly high-efficiency or the drug-fast generation that the agriculture chemical compounding kind delays sanitary insect pest, because the price of novel pesticide is more expensive than conventional pesticide, use can make the control cost improve greatly separately, and the drug effect that conventional pesticide uses does not separately reach requirement, therefore pass through the composite of two kinds of pesticidal chemicals, can not only improve the control efficiency of control sanitary insect pest so to greatest extent, and economical convenient, greatly reduce the drug-fast generation speed of sanitary insect pest.
Summary of the invention
The technical problem to be solved in the present invention is, defective at the prior art existence, the Pesticidal combination of a kind of chlorine fluorine ether chrysanthemum ester and decis is proposed, kind performance obvious synergistic effect after the combination, reduce the drug-fast generation of sanitary insect pest greatly, have the characteristics of low toxicity, safety, efficient, economy, environmental protection.
One of technical solution of the present invention is, the Pesticidal combination of described control sanitary insect pest is prepared as mosquito-repellent incense, and its mass percent consists of:
Pesticidal combination 0.01%-5%
Conventional auxiliary agent 1%-10%
Inflammable substance polishing 100%
The concrete production stage of this mosquito-repellent incense is: on the one hand, the cream preparation or the vegetable oil solution of preparation Pesticidal combination are mediated inflammable substance and auxiliary agent and water on the other hand routinely, and moulding is also dried, and sprays above-mentioned Pesticidal combination solution.Oven dry promptly gets product again.
Two of technical solution of the present invention is, the Pesticidal combination of described control sanitary insect pest is prepared as aerosol, and its mass percent consists of:
Pesticidal combination 0.01%-5%
Conventional solvent 10%-30%
Conventional propellant 20%-60%
The concrete production stage of this aerosol is: Pesticidal combination, solvent are mixed routinely, add in the jar that valve is housed, and add propellant by this valve under pressure in jar and make.
Below the present invention is described further.
Described Pesticidal combination contains chlorine fluorine ether chrysanthemum ester and the decis mass ratio is 1: 99~99: 1.
Described chlorine fluorine ether chrysanthemum ester, chemical name is 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl (1R, 3S)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.Have and tag and fumigation action, poisonous to silkworm, should not use in silkworm room and cocoonery, sanitary insect pests such as mosquitos and flies, cockroach all there is the higher activity of knocking down.
Described decis (deltamethrin), chemical name dextrorotation-cis-2,2-dimethyl-3-(2, the 2-dibromo vinyl) cyclopropane-carboxylic acid-(S)-alpha-cyano-3-phenoxy group benzyl ester, based on tag, stomach toxicity, insect is had certain repellent action.Insecticidal spectrum is wide, and the speed of knocking down is fast, and is especially big to sanitary insect pest lethality such as mosquitos and flies, and site of action is never poison in nervous system, makes insect be overexcited, benumb and dead.
Described conventional auxiliary agent is any one or the two or more mixed aid that mixes with arbitrary proportion in surfactant, binding agent, aromatic, the colouring agent.
Described inflammable substance is any one or the two or more mixing powder that mixes with arbitrary proportion in wood powder, wooden carbon dust, tangerine orange peel powder, corn starch, coconut shell powder, the walnut parting.
Described conventional solvent is a kind of for organic solvent, the alcohol that can be dissolved with effective constituent, water.
Described conventional propellant is a kind of in liquefied petroleum gas, third butane, dimethyl ether or the compressed air.
Embodiment:
The present invention is further described below in conjunction with specific embodiment, but the present invention is not limited to following examples.
Application Example 1
Add the water of 80 weight portions and mediate in the mixture of the wood powder of 100 weight portions, corn starch and English walnut nuclear powder (5: 1: 4) and be shaped, oven dry forms coiled mosquito-repellent incense desinsection base material (diameter 14cm, thick 4mm, a counterweight 34g) then.
On the other hand, the decis of the chlorine fluorine ether chrysanthemum ester of 0.05 weight portion, 0.32 weight portion is dissolved into obtains chloride fluorine ether chrysanthemum ester 0.05w/v%, the mixed solution of decis 0.32w/v% in the vegetable oil.
Draw above mixed solution 3.4ml with microsyringe and evenly be added drop-wise on the above coiled mosquito-repellent incense desinsection base material, at room temperature place then and obtained a cover in 5 hours and have a coiled mosquito-repellent incense I of 0.005w/w% chlorine fluorine ether chrysanthemum ester, 0.032w/w% decis.
Reference embodiment 1
Add the water of 100 weight portions and mediate in the mixture of the wood powder of 100 weight portions, corn starch and English walnut nuclear powder (5: 1: 4) and be shaped, oven dry forms line spices shape disc type desinsection base materials (diameter 14cm, thick 4mm, a counterweight 34g) then.
On the other hand, the chlorine fluorine ether chrysanthemum ester of 0.37 weight portion is dissolved into obtains chloride fluorine ether chrysanthemum ester 0.37w/v% solution in the vegetable oil.
Draw above mixed solution 3.4ml with microsyringe and evenly be added drop-wise on the above coiled mosquito-repellent incense desinsection base material, at room temperature place then and obtained a cover in 5 hours and have a coiled mosquito-repellent incense II of 0.037w/w% chlorine fluorine ether chrysanthemum ester.
Reference embodiment 2
Add the water of 100 weight portions and mediate in the mixture of the wood powder of 100 weight portions, corn starch and English walnut nuclear powder (5: 1: 4) and be shaped, oven dry forms line spices shape disc type desinsection base materials (diameter 14cm, thick 4mm, a counterweight 34g) then.
On the other hand, the decis of 0.37 weight portion is dissolved into obtains containing decis 0.37w/v% solution in the vegetable oil.
Draw above mixed solution 3.4ml with microsyringe and evenly be added drop-wise on the above coiled mosquito-repellent incense desinsection base material, at room temperature place then and obtained a cover in 5 hours and have a coiled mosquito-repellent incense III of 0.037w/w% decis.
Test implementation example 1
Application Example 1, reference embodiment 1 and reference embodiment 2 prepared coiled mosquito-repellent incenses are carried out the contrast of the kill mosquito test of pesticide effectiveness by GB/T 13917.4-2009, the examination worm is Culex quinquefasciatus (Culex pipiens quinque fasciatus), the female insect of not sucking blood in the back of sprouting wings in 3-5 days.Detailed process is: draw 30 of examination mosquitos with mosquito sucking tube; put into the described cylinder unit of GB/T 13917.4-2009 (3.1), after waiting to try worm and recovering normal activity, get one section of mosquito-repellent incense to be measured at random; horizontal on mosquito coil frame; after lighting 5min in advance elsewhere, move to fumigation 1min in the cylinder, immediately mosquito-repellent incense is removed; cylinder is sealed; and timing, respectively write down down and out examination borer population when 1min, 2min, 3min, 4min, 5min, be limited to 20min during observation.Four repetitions are established in test, and the used mosquito-repellent incense of repeated test is taked at random at difference dish mosquito-repellent incense.The retest data are pressed linear weighted function Return Law calculating K T50 value and virulence regression equation.
Experimental data and the results are shown in Table 1, table 2:
Table 1, Pesticidal combination of the present invention and control compounds kill mosquito master data
The average dead worm rate (%) of table 2 Pesticidal combination of the present invention and control compounds KT50 value and 20min
Mosquito-repellent incense | Virulence regression equation | KT50 | The average dead worm rate (%) of 20min |
The coiled mosquito-repellent incense I | y=2.3818x+4.0171 R 2=0.9924 | 2.59 | 100 |
The coiled mosquito-repellent incense II | y=3.2254x+3.2549 R 2=0.9987 | 3.48 | 96.7 |
The coiled mosquito-repellent incense III | y=3.0097x+3.2581 R 2=0.9933 | 3.79 | 70 |
Table 3 Pesticidal combination co-toxicity coefficient of the present invention
Mosquito-repellent incense | KT50 | Poison exponent (TI) | Theoretical toxicity index (TTI) | Actual toxicity index (ATI) | Co-toxicity coefficient (CTC) |
The coiled mosquito-repellent incense I | 2.59 | - | 101.2 | 146.3 | 144.6 |
Coiled mosquito-repellent incense | 3.48 | 108.9 | - | - | - |
Ⅱ | |||||
The coiled mosquito-repellent incense III | 3.79 | 100 | ?- | ?- | ?- |
From above experimental data and result as can be known, the mosquito activity (for the A level) of killing of Pesticidal combination of the present invention is better than chlorine fluorine ether chrysanthemum ester list agent (for the B level), is better than decis list agent (for defective) greatly.The co-toxicity coefficient that this Pesticidal combination kills mosquito is 144.6, obviously greater than 100, illustrates that this Pesticidal combination has synergistic effect.
Application Example 2
The methyl alcohol of the decis of 0.08 weight portion chlorine fluorine ether chrysanthemum ester, 0.18 weight portion and 59.74 weight portions mixed be prepared into the Pesticidal combination insecticide solution, the solution that obtains is put into the aerosol jar of band valve, under the condition of pressurization, in the aerosol jar, inject the dimethyl ether of 40.0 weight portions by valve, obtain a kind of insect aerosol I, wherein chloride fluorine ether chrysanthemum ester 0.008w/w%, decis 0.018w/w%.
Reference embodiment 3
The methyl alcohol of 0.26 weight portion chlorine fluorine ether chrysanthemum ester and 59.74 weight portions mixed be prepared into the Pesticidal combination insecticide solution, the solution that obtains is put into the aerosol jar of band valve, under the condition of pressurization, in the aerosol jar, inject the dimethyl ether of 40.0 weight portions by valve, obtain a kind of insect aerosol II, wherein chloride fluorine ether chrysanthemum ester 0.026w/w%.
Reference embodiment 4
The methyl alcohol of 0.26 weight portion decis and 59.74 weight portions mixed be prepared into the Pesticidal combination insecticide solution, the solution that obtains is put into the aerosol jar of band valve, under the condition of pressurization, in the aerosol jar, inject the dimethyl ether of 40.0 weight portions by valve, obtain a kind of insect aerosol III, wherein contain decis 0.026w/w%.
Test implementation example 2
Application Example 2, reference embodiment 3 and reference embodiment 4 prepared insect aerosols are contrasted by the test of pesticide effectiveness that GB/T 13917.2-2009 carries out kill mosquito, and the examination worm is the female insect of not sucking blood in 3-5 days after Culex quinquefasciatus (Culex pipiens quinque fasciatus) is sprouted wings.Detailed process is: draw 30 of examination mosquitos with mosquito sucking tube; put into cylinder unit described in the GB/T13917.2-2009 (3.1); after waiting to try worm recovery normal activity, above-mentioned insect aerosol tube is horizontal, and nozzle downward vertically; aim at the insecticide-spraying hole on the cylinder sealing device; spray the 1.0g medicament, clog circular hole with plug immediately then, draw back dividing plate behind the 1min; down and out mosquito number is write down in timing immediately respectively when 1min, 2min, 3min, 4min, 5min.The mosquito of will going down behind the 20min moves in the cleaning dependent insect cage, recovers feeding standard, and 24h checks dead borer population.Four repetitions are established in test, and the used aerosol of repeated test is taked in different aerosol containers at random.The retest data are pressed linear weighted function Return Law calculating K T50 value and virulence regression equation.
Experimental data and the results are shown in Table 1, table 2:
Table 1, Pesticidal combination of the present invention and control compounds kill mosquito master data
The average dead worm rate (%) of table 2 Pesticidal combination of the present invention and control compounds KT50 value and 24h
Aerosol | Virulence regression equation | KT50 | The average dead worm rate (%) of 24h |
The aerosol I | y=2.5188x+3.8711 R 2=0.9903 | 2.81 | 100 |
The aerosol II | y=3.1807x+3.2861 R 2=0.9983 | 3.46 | 100 |
The aerosol III | y=2.7909x+3.3017 R 2=0.9968 | 4.06 | 95.3 |
Table 3 Pesticidal combination co-toxicity coefficient of the present invention
Aerosol | KT50 | Poison exponent | Theoretical virulence | Actual poison | Co-toxicity coefficient |
(TI) | Index (TTI) | Power index (ATI) | (CTC) | ||
The aerosol I | 2.81 | - | 105.3 | 144.5 | 137.2 |
The aerosol II | 3.46 | 117.3 | - | - | - |
The aerosol III | 4.06 | 100 | - | - | - |
From above experimental data and result as can be known, the mosquito activity (for the A level) of killing of Pesticidal combination of the present invention is better than chlorine fluorine ether chrysanthemum ester list agent (for the A level), is better than decis list agent (for the B level) greatly.The co-toxicity coefficient that this Pesticidal combination kills mosquito is 137.2, obviously greater than 100, illustrates that this Pesticidal combination has synergistic effect.
Test implementation example 3
Application Example 2, reference embodiment 4, reference embodiment 5 and reference embodiment 6 prepared insect aerosols are carried out the test of pesticide effectiveness contrast of fly eradication by GB/T 13917.2-2009, the examination worm is housefly (Musca domestica), sprouts wings back the 3rd day the-the 5th day adult.Detailed process is: draw 30 of examination flies with inhaling the fly pipe; put into cylinder unit described in the GB/T 13917.2-2009 (3.1); after waiting to try worm recovery normal activity, above-mentioned insect aerosol tube is horizontal, and nozzle downward vertically; aim at the insecticide-spraying hole on the cylinder sealing device; spray the 1.0g medicament, clog circular hole with plug immediately then, draw back dividing plate behind the 1min; down and out fly borer population is write down in timing immediately respectively when 1min, 2min, 4min, 6min, 8min.The fly worm of will going down behind the 20min moves in the cleaning dependent insect cage, recovers feeding standard, and 24h checks dead borer population.Four repetitions are established in test, and the used aerosol of repeated test is taked in different aerosol containers at random.The retest data are pressed linear weighted function Return Law calculating K T50 value and virulence regression equation.
Experimental data and the results are shown in Table 1, table 2:
Table 1, Pesticidal combination of the present invention and control compounds fly eradication master data
The average dead worm rate (%) of table 2 Pesticidal combination of the present invention and control compounds KT50 value and 24h
Aerosol | Virulence regression equation | KT50 | The average dead worm rate (%) of 24h |
The aerosol I | y=2.3955x+3.9253 | 2.81 | 100 |
R 2=0.9933 | |||
The aerosol II | y=2.7993x+3.3458 R 2=0.9931 | 3.90 | 97.3 |
The aerosol III | y=2.8048x+3.0753 R 2=0.996 | 4.86 | 76.7 |
Table 3 Pesticidal combination co-toxicity coefficient of the present invention
Aerosol | KT50 | Poison exponent (TI) | Theoretical toxicity index (TTI) | Actual toxicity index (ATI) | Co-toxicity coefficient (CTC) |
The aerosol I | 2.81 | - | 107.6 | 173.0 | 160.8 |
The aerosol II | 3.9 | 124.6 | - | - | - |
The aerosol III | 4.86 | 100 | - | - | - |
From above experimental data and result as can be known, the fly activity (for the A level) of killing of Pesticidal combination of the present invention is better than chlorine fluorine ether chrysanthemum ester list agent (for the B level), is better than decis list agent (for defective) greatly.The co-toxicity coefficient that this Pesticidal combination kills fly is 160.8, obviously greater than 100, illustrates that this Pesticidal combination has synergistic effect.
Test implementation example 4
Application Example 2, reference embodiment 4, reference embodiment 5 and reference embodiment 6 prepared insect aerosols are killed the test of pesticide effectiveness contrast of blattaria by GB/T 13917.2-2009, the examination worm is Groton bug (Bluttella germanica), 10 ages in days-15 age in days adult, male and female half and half.Detailed process is: get 20 of Groton bugs; put into cylinder unit described in the GB/T 13917.2-2009 (3.1); after waiting to try worm recovery normal activity; above-mentioned insect aerosol tube is horizontal, and nozzle is aimed at the insecticide-spraying hole on the cylinder sealing device downward vertically; spray the 1.0g medicament; clog circular hole with plug immediately then, down and out blattaria number is write down in timing immediately respectively when 2min, 3min, 4min, 5min, 6min.The blattaria of will going down behind the 20min moves in the cleaning dependent insect cage, recovers feeding standard, and 72h checks dead borer population.Four repetitions are established in test, and the used aerosol of repeated test is taked in different aerosol containers at random.The retest data are pressed linear weighted function Return Law calculating K T50 value and virulence regression equation.
Experimental data and the results are shown in Table 1, table 2:
Table 1, Pesticidal combination of the present invention and the control compounds blattaria master data of going out
The average dead worm rate (%) of table 2 Pesticidal combination of the present invention and control compounds KT50 value and 72h
Aerosol | Virulence regression equation | KT50 | The average dead worm rate (%) of 72h |
The aerosol I | y=4.5274x+2.9227 R 2=0.992 | 2.88 | 100 |
The aerosol II | y=5.038x+1.8822 R 2=0.9901 | 4.16 | 95 |
The aerosol III | y=4.0934x+1.9778 R 2=0.9919 | 5.47 | 75 |
Table 3 Pesticidal combination co-toxicity coefficient of the present invention
Aerosol | KT50 | Poison exponent (TI) | Theoretical toxicity index (TTI) | Actual toxicity index (ATI) | Co-toxicity coefficient (CTC) |
The aerosol I | 2.88 | - | 109.7 | 189.9 | 173.2 |
The aerosol II | 4.16 | 131.5 | - | - | - |
The aerosol III | 5.47 | 100 | - | - | - |
From above experimental data and result as can be known, the cockroach activity (for the A level) of killing of Pesticidal combination of the present invention is better than chlorine fluorine ether chrysanthemum ester list agent (for the B level), is better than decis list agent (for defective) greatly.The co-toxicity coefficient that this Pesticidal combination kills cockroach is 173.2, obviously greater than 100, illustrates that this Pesticidal combination has synergistic effect.
Claims (3)
1. composition pesticide and application thereof, it is characterized in that: comprise following proportion of masses: chlorine fluorine ether chrysanthemum ester: decis is 1: 99~99: 1.
2. according to a kind of composition pesticide and the application thereof of claims 1, it is characterized in that: described controlling object sanitary insect pest comprise Groton bug, health mosquito and health fly wherein one or more.
3. according to a kind of composition pesticide and the application thereof of claims 1, it is characterized in that: described Pesticidal combination is prepared into the disc type disinsecting mosquito repellant incense made and insect aerosol is wherein a kind of.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103168795A (en) * | 2011-12-26 | 2013-06-26 | 江苏扬农化工股份有限公司 | Meperfluthrin-containing compound insecticidal composition and application thereof |
CN106234405B (en) * | 2016-07-30 | 2018-11-02 | 江苏功成生物科技有限公司 | A kind of Pesticidal combination containing fluorine chlorine ether pyrethroids and ethofenprox and its application |
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CN101283683A (en) * | 2008-05-26 | 2008-10-15 | 张子平 | Sustained release fly trapping and killing medicine product and method |
CN101473842A (en) * | 2009-01-23 | 2009-07-08 | 江苏扬农化工股份有限公司 | Insecticidal composition |
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- 2010-06-02 CN CN2010102006080A patent/CN101953369A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101283683A (en) * | 2008-05-26 | 2008-10-15 | 张子平 | Sustained release fly trapping and killing medicine product and method |
CN101473842A (en) * | 2009-01-23 | 2009-07-08 | 江苏扬农化工股份有限公司 | Insecticidal composition |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103168795A (en) * | 2011-12-26 | 2013-06-26 | 江苏扬农化工股份有限公司 | Meperfluthrin-containing compound insecticidal composition and application thereof |
CN103168795B (en) * | 2011-12-26 | 2015-01-07 | 江苏扬农化工股份有限公司 | Meperfluthrin-containing compound insecticidal composition and application thereof |
CN106234405B (en) * | 2016-07-30 | 2018-11-02 | 江苏功成生物科技有限公司 | A kind of Pesticidal combination containing fluorine chlorine ether pyrethroids and ethofenprox and its application |
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