CN103168795B - Meperfluthrin-containing compound insecticidal composition and application thereof - Google Patents
Meperfluthrin-containing compound insecticidal composition and application thereof Download PDFInfo
- Publication number
- CN103168795B CN103168795B CN201110442109.7A CN201110442109A CN103168795B CN 103168795 B CN103168795 B CN 103168795B CN 201110442109 A CN201110442109 A CN 201110442109A CN 103168795 B CN103168795 B CN 103168795B
- Authority
- CN
- China
- Prior art keywords
- component
- chlorine fluorine
- configuration
- chrysanthemum ester
- fluorine ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 0 *1C2(CC3)C1CC3*2 Chemical compound *1C2(CC3)C1CC3*2 0.000 description 2
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides an insecticide composition which is composed of an active compound component and an auxiliary component, wherein the active compound component accounts for 1-70 wt% of the insecticide composition, and is compounded from a component A and a component B in a weight ratio of 1:50-50:1; the component A is a pyrethroid compound of which the structure satisfies the following formula; and the component B is selected from any one of high-efficiency cyhalothrin, bifenthrin, deltamethrin, fenpropathrin, cypermethrin, high-efficiency cypermethrin, cis-cypermethrin, fenvalerate or S-fenvalerate. By compounding, the insecticidal composition provided by the invention has certain synergistic action in application.
Description
Technical field
The present invention relates to a kind of insecticides, be specifically related to a kind of complex insecticidal composition containing chlorine fluorine ether chrysanthemum ester.
Background technology
Chlorine fluorine ether chrysanthemum ester, English name (Meperfluthrin), be the new construction pyrethroid compound with independent intellectual property right that the exploitation of agrochemical work joint-stock company is raised in Jiangsu, this compound is mainly used in domestic hygiene preparation at present.
Again because the acid moieties of chlorine fluorine ether chrysanthemum ester is DV acid, cause its water splitting with at present large Tanaka use as cypermethrin etc. quite, therefore chlorine fluorine ether chrysanthemum ester has the feasibility applied large Tanaka.Prove through lot of experiments, chlorine fluorine ether chrysanthemum ester single dose uses in land for growing field crops can prevent and treat part target.
The example that pyrethroid compound is applied large Tanaka is a lot, but present circumstances is that most product is through using for many years, target is provided with resistance, when in the face of these resistance targets, the pyrethroid preventive effect of existing kind is poor, we find through experiment, when in the face of these resistant varieties, alone noval chemical compound chlorine fluorine ether chrysanthemum ester has good preventive effect, when we also to find in existing pyrethroid structure uses with chlorine fluorine ether chrysanthemum ester is composite containing cyano group or the higher product of indivedual killing activity in addition, faced by resistant variety there is certain synergistic effect.Existing kind is relatively low on cost in addition, and composite use is conducive to reducing use cost.
Summary of the invention
An object of the present invention is to provide a kind of good disinsection effect, and drug cost is low, and composite have synergy and the complex insecticidal composition containing chlorine fluorine ether chrysanthemum ester not easily developed immunity to drugs.
Another object of the present invention is to the Synthesis and applications that above-mentioned Pesticidal combination is provided.
Above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of insecticides, it is made up of former medicine component and auxiliary element, and former medicine component accounts for the 1-70% of insecticides gross weight, and former medicine component is made up of by the weight ratio of 1:50 ~ 50:1 is composite component A and B component; Described component A is the pyrethroid compound that structure meets following formula
Described B component be selected from gamma cyhalothrin, Biphenthrin, decis, fenpropathrin, cypermethrin, beta-cypermethrin, alpha-cypermethrin, sumicidin, S-sumicidin any one.
Component A described in the present invention can be 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl base-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters all stereoisomers in any one or two or more mixtures, these stereoisomers can be:
Rich dextrorotation 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl base-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester of cyclopropane 1 effective body burden >=55% of R configuration;
Cyclopropane 1 absolute configuration is R configuration, 1,32,3,5,6-tetrafluoro-4-methoxymethyl benzyl bases-(1R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters not distinguishing the dextrorotation of cis-trans isomerism;
Cyclopropane 1 absolute configuration is R configuration, 1, and 3 is trans-isomeric 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl base-(1R, 3S)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters (ISO called after chlorine fluorine ether chrysanthemum ester; Meperfluthrin);
Or
Cyclopropane 1 absolute configuration is R configuration, 1, and 3 is 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl bases-(1R, 3R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester of syn-isomerism.
The part by weight more preferably 1:10 ~ 10:1 of described component A and B component.
The preferred gamma cyhalothrin of described B component.
Described auxiliary element can be one or more the mixture in emulsifier, wetting agent, dispersant, disintegrant, antifreezing agent, thickener, defoamer, binding agent, filler, solvent or water.
Described emulsifier is selected from alkyl benzene calcium sulfonate, OP series phosphate, phenyl phenol polyoxyethanyl ether phosphate, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, benzyl dimethyl phenol polyoxyethyl ether, peaceful newborn 36#, phenethyl phenol polyoxyethanyl polypropylene-base ether, ethylene oxide-propylene oxide block copolymer, polyoxyethylene nonylphenol ether, OPEO, castor oil polyoxyethylene ether, alkylaryl polyoxyethylene polyoxypropylene ether, alkylaryl polyoxyethylene poly-oxygen propylene aether, Span series, one or more in TWEEN Series or fat alcohol alcohol APEO,
Described dispersant be selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate or fatty acid glyceride APEO one or more;
Described wetting agent be selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylbenzene polyoxyethylene ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, lauryl sodium sulfate, Nekal BX, wetting and penetrating agent F or DBSA one or more;
Described disintegrant be selected from ammonium sulfate, bentonite, urea, succinic acid, sodium bicarbonate, aluminium chloride or citric acid one or more;
Described antifreezing agent be selected from ethylene glycol, propane diols, glycerine, glycerine or urea one or more;
Described thickener be selected from xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate or polyvinyl alcohol one or more;
Described defoamer be selected from silicone compound, silicone oil, C8-10 aliphatic alcohols compound or C10-20 saturated fat acid compounds one or more;
Described binding agent be selected from polyvinyl alcohol, dextrin, CMC, polyvinylpyrrolidone, sodium alginate or wooden calcium sulfonate one or more;
Described filler be selected from kaolin, potter's clay, diatomite, bentonite, white carbon, attapulgite, starch or precipitated calcium carbonate one or more;
The solvent selected from methanol stated, ethanol, isopropyl alcohol, n-butanol, isobutanol, amylalcohol, toluene, dimethylbenzene, methyl how, in solvent naphtha 100#, solvent naphtha 150#, solvent naphtha 200#, benzinum, gasoline, kerosene, turpentine oil, cyclohexanone, methylisobutylketone one or more.
Pesticidal combination of the present invention can conventionally make various formulation, preferred missible oil, can wet-milling, water and milk, micro emulsion, suspending agent, water dispersible granules, and conventional formulation and the preparation method of these formulations are as follows:
Missible oil: the former medicine B component 1% ~ 60% of former medicine component A+, emulsifier 6% ~ 12%, solvent supply 100%;
Missible oil preparation method: by former medicine dissolution solvent, then add emulsifier, mixed dissolution under stirring, form single-phase transparent liquid;
Can wet-milling: the former medicine B component 1% ~ 70% of former medicine component A+, wetting agent 1% ~ 4%, dispersant 1% ~ 8%, filler supply 100%;
Can wet-milling preparation method: former medicine and wetting agent, dispersant, filler are mixed, pulverizes through airslide disintegrating mill one or many;
Water and milk: the former medicine B component 1% ~ 20% of former medicine component A+, emulsifier 8% ~ 15%, antifreezing agent 4% ~ 10%, thickener 0% ~ 1%, defoamer 0% ~ 0.5%, water supply 100%;
Water and milk preparation method: former medicine, solvent, emulsifiers dissolve are become oil phase.Water, antifreeze are mixed into aqueous phase, aqueous phase are joined oil phase under high shear agitation or oil phase is joined in aqueous phase;
Micro emulsion: the former medicine B component 1% ~ 20% of former medicine component A+, emulsifier 8% ~ 20%, antifreezing agent 4% ~ 10%, defoamer 0% ~ 0.5%, solvent 5% ~ 30%, water supply 100%;
Micro emulsion preparation method: after fully being mixed with emulsifier, solvent by former medicine, under agitation slowly add water, antifreezing agent and defoamer, forms water-in-oil emulsion, then agitating heating, is converted into oil-in-water type rapidly;
Suspending agent: the former medicine B component 1% ~ 20% of former medicine component A+, wetting agent 1% ~ 4%, dispersant 1% ~ 10%, antifreezing agent 1% ~ 8%, thickener 0.1% ~ 1%, defoamer 0.1% ~ 0.5%, water supply 100%;
Suspending agent preparation method: former medicine, wetting agent, dispersant, antifreeze and water are dropped into ball mill in proportion and is pulverized and mixed, then add thickener, defoamer and water and carry out ball milling, after ball milling, particle diameter is generally less than 5 microns, then adds residue water and carry out modulating;
Water dispersible granules: the former medicine B component 1% ~ 20% of former medicine component A+, wetting agent 1% ~ 4%, dispersant 1% ~ 10%, disintegrant 1% ~ 4%, binding agent 0.5% ~ 8%, filler supply 100%;
Water dispersible granules preparation method: former medicine, wetting agent, dispersant, disintegrant, filler are mixed, pulverizes with micro jet, adding binding agent through mediating, then adding after carrying out granulation, drying, screening in fluidized-bed granulation dryer.
The present invention also provides the described application of Pesticidal combination in control agricultural pests.
Described agricultural pests comprises the insect of orthoptera, thrips, Homoptera, Lepidoptera, diptera and mite class, further illustrate, pest control comprises Ban Chi locust section, Thripidae, Miridae, Pentatomiddae, Cicadellidae, Delphacidae, Aleyrodidae, Aphidiadae, Mian Jie section, diamond-back moth section, Pyralidae, Noctuidae, Lymantriidae, Sulfur butterfly, Carposinidae, Chrysomelidae, Culculionidae, Cecidomyiidae, Tephritidae, Agromyzidae, Anthomyiidae, Tetranychidae, leeched line mite section, Ye Zhao mite section, Eriophyidae etc.
Embodiment
Example of formulations 1:
Chlorine fluorine ether chrysanthemum ester and high-efficient lambda-cyhalothrin compound ratio are 1:10, actual feed intake into 0.5g chlorine fluorine ether chrysanthemum ester, 5g gamma cyhalothrin, alkyl benzene calcium sulfonate 6g, OPEO 4g, solvent naphtha 150# mend to 100g, throw and finish the i.e. obtained 5.5% chlorine fluorine ether chrysanthemum ester efficient cyhalothrin emulsifiable concentrate that stirs, be example of formulations 1.
Example of formulations 2 ~ 5
According to the compound proportion of chlorine fluorine ether chrysanthemum ester and gamma cyhalothrin in table 1, helper component is alkyl benzene calcium sulfonate 6g, OPEO 4g, solvent naphtha 150# mends to 100g, throws respectively and finishes the i.e. obtained example of formulations 2 ~ 5 that stirs:
Table 1
| Embodiment is numbered | Chlorine fluorine ether chrysanthemum ester (g) | Gamma cyhalothrin (g) | Compound proportion |
| 2 | 0.1 | 5 | 1:50 |
| 3 | 2.5 | 2.5 | 1:1 |
| 4 | 5 | 0.5 | 10:1 |
| 5 | 5 | 0.1 | 50:1 |
Example of formulations 6 ~ 8
According to chlorine fluorine ether chrysanthemum ester in table 2 and efficient cypermethrin compounded, helper component is 3g alkylbenzene polyoxyethylene ether phosphate, 4g lignosulfonates, kaolin are mended to 100g, pulverizes i.e. obtained example of formulations 6 ~ 8 after mixing through airslide disintegrating mill:
Table 2
| Embodiment is numbered | Chlorine fluorine ether chrysanthemum ester (g) | Beta-cypermethrin (g) | Compound proportion |
| 6 | 2 | 10 | 1:5 |
| 7 | 6 | 6 | 1:1 |
| 8 | 10 | 2 | 5:1 |
Example of formulations 9
Chlorine fluorine ether chrysanthemum ester and Biphenthrin compound proportion are 1:5, actually feed intake as 2g chlorine fluorine ether chrysanthemum ester, 10g Biphenthrin, 15g solvent naphtha 100#, 7g phenyl phenol polyoxyethanyl ether phosphate, 5g triethanolamine salt are mixed into oil phase, 5g propane diols and 57.5g water and are mixed into aqueous phase, aqueous phase being joined oil phase under high shear agitation or oil phase being joined in aqueous phase i.e. obtained 12% chlorine fluorine ether chrysanthemum ester Biphenthrin emulsion in water, be example of formulations 9.
Example of formulations 10
Chlorine fluorine ether chrysanthemum ester and decis compound proportion are 1:1, actual feed intake into 2.5g chlorine fluorine ether chrysanthemum ester, 2.5g decis, 5g aliphatic amine polyoxyethylene ether, 2g naphthalene sulfonate, 5g propane diols, 0.2g xanthans, 1g White Carbon black, 0.3g silicone oil compound, water mend to 100g.Mixed grinding makes 5% chlorine fluorine ether chrysanthemum ester decis suspending agent, is example of formulations 10.
Example of formulations 11
Chlorine fluorine ether chrysanthemum ester and cypermethrin compounded ratio are 1:2, actually feed intake as 2g chlorine fluorine ether chrysanthemum ester, 4g cypermethrin, 7g phenethyl phenol polyoxyethanyl polypropylene-base ether, 6g castor oil polyoxyethylene ether, 2g fatty acid glyceride, 20g solvent naphtha 200#, 5g ethanol are mixed into oil phase, 5g propane diols and 44.5 water and are mixed into aqueous phase, under agitation slowly in oil phase, add aqueous phase, be stirred to transparent i.e. obtained 6% chlorine fluorine ether chrysanthemum ester cypermethrin microemulsion, be example of formulations 11.
Example of formulations 12
Chlorine fluorine ether chrysanthemum ester and alpha-cypermethrin compound proportion are 1:9, actual feed intake into 7g chlorine fluorine ether chrysanthemum ester, 63g alpha-cypermethrin, 4g naphthalene sulfonate, 5g lignosulfonates, kaolin mend to 100g, pulverizing i.e. obtained 70% chlorine fluorine ether chrysanthemum ester alpha-cypermethrin through airslide disintegrating mill after mixing can wet-milling, is example of formulations 12
Example of formulations 13
Chlorine fluorine ether chrysanthemum ester and fenpropathrin compound proportion are 1:5, actual feed intake into 1g efficient chlorine fluorine cyanogen, 5g fenpropathrin, 6g neopelex, 4g alkylnaphthalene sulfonate formaldehyde condensation products, 1g CMC, diatomite mend to 100g.Co-grinding is granulated becomes 6% chlorine fluorine ether chrysanthemum ester fenpropathrin water dispersible granules, is example of formulations 13.
Example of formulations 14
Chlorine fluorine ether chrysanthemum ester and fenvalerate built ratio are 1:2, actual feed intake into 5g chlorine fluorine ether chrysanthemum ester, 10g sumicidin, alkyl benzene calcium sulfonate 5.5g, phenyl phenol polyoxyethanyl ether phosphate 3.5g, solvent naphtha 150# mend to 100g, throw and finish the i.e. obtained 15% chlorine fluorine ether chrysanthemum ester fenvalerate missible oil that stirs, be example of formulations 14.
Example of formulations 15
Cis chlorine fluorine ether chrysanthemum ester and S-fenvalerate built ratio are 1:1, actual feed intake into 5g chlorine fluorine ether chrysanthemum ester, 5g S-sumicidin, alkyl benzene calcium sulfonate 5g, phenyl phenol polyoxyethanyl ether phosphate 4g, solvent naphtha 150# mend to 100g, throw and finish the i.e. obtained 10% chlorine fluorine ether chrysanthemum ester S-fenvalerate missible oil that stirs, be example of formulations 15.
Comparing embodiment 1
Feed intake 5g chlorine fluorine ether chrysanthemum ester, alkyl benzene calcium sulfonate 6g, OPEO 4g, solvent naphtha 150# benefit to 100g, throws and finish the i.e. obtained 5% chlorine fluorine ether chrysanthemum emulsifiable concentrate that stirs, be comparing embodiment 1.
Comparing embodiment 2
Feed intake 5g gamma cyhalothrin, alkyl benzene calcium sulfonate 6g, OPEO 4g, solvent naphtha 150# benefit to 100g, throws and finish the i.e. obtained 5% Aphox missible oil that stirs, be comparing embodiment 2.
Application Example one: the raw test of control brassicaceous vegetable (wild cabbage) insect is tested
Target: lepidoptera pest diamond-back moth (laboratory sensitive strain)
Method: embodiment 1 ~ 7 and comparing embodiment 1 ~ 4 are diluted 7 gradient concentrations with clear water respectively, blank is made with clear water process, employing leaf dipping method measures, the leaching of diameter 2cm cabbage leaves is taken out air-dry after into the liquid 10 seconds, 3 are placed in each culture dish, if 3 repetitions, picking three diamondback moth larvae in age, picking 10 in each culture dish, then put into 25 DEG C of illumination boxs, investigation survival borer population respectively after 48 hours, calculates lethality, Mortality data by 7 concentration gradients, calculate virulence regression equation, finally obtain LC50.Measurement result following (table 3):
Table 3 Application Example one test result
| Example of formulations | Active ingredient | Formulation | Proportionate relationship | LC50(mg/L) |
| Example of formulations 1 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 1:10 | 28.1 |
| Example of formulations 2 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 1:50 | 34.4 |
| Example of formulations 3 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 1:1 | 26.0 |
| Example of formulations 4 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 10:1 | 15.8 |
| Example of formulations 5 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 50:1 | 14.3 |
| Comparing embodiment 1 | Chlorine fluorine ether chrysanthemum ester | Missible oil | ? | 13.5 |
| Comparing embodiment 2 | Gamma cyhalothrin | Missible oil | ? | 36.4 |
By LC50 of composite embodiment each in the Application Example one and LC50 of single dose comparing embodiment, computational methods, with reference to the method being calculated mixture co-toxicity by toxicity index of Sun Yunpei, calculate co-toxicity coefficient.
The composite co-toxicity coefficient of table 4 the present invention measures
Test result shows, when chlorine fluorine ether chrysanthemum ester and gamma cyhalothrin proportionate relationship are between 1:50 ~ 50:1, its co-toxicity coefficient, all between 85 ~ 110, does not have obvious synergy, and the effect with addition can only be described.
Application Example two: the raw test of control brassicaceous vegetable (wild cabbage) insect is tested
Target: lepidoptera pest diamond-back moth (lab resistance strain)
Method: embodiment 1 ~ 7 and comparing embodiment 1 ~ 4 are diluted 7 gradient concentrations with clear water respectively, blank is made with clear water process, employing leaf dipping method measures, the leaching of diameter 2cm cabbage leaves is taken out air-dry after into the liquid 10 seconds, 3 are placed in each culture dish, if 3 repetitions, picking three diamondback moth larvae in age, picking 10 in each culture dish, then put into 25 DEG C of illumination boxs, investigation survival borer population respectively after 48 hours, calculates lethality, Mortality data by 7 concentration gradients, calculate virulence regression equation, finally obtain LC50.Measurement result following (table 5):
Table 5 Application Example two test result
| Example of formulations | Active ingredient | Formulation | Proportionate relationship | LC50(mg/L) |
| Example of formulations 1 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 1:10 | 66.5 |
| Example of formulations 2 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 1:50 | 94.0 |
| Example of formulations 3 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 1:1 | 45.2 |
| Example of formulations 4 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 10:1 | 28.2 |
| Example of formulations 5 | Chlorine fluorine ether chrysanthemum ester+gamma cyhalothrin | Missible oil | 50:1 | 26.4 |
| Comparing embodiment 1 | Chlorine fluorine ether chrysanthemum ester | Missible oil | ? | 26.2 |
| Comparing embodiment 2 | Gamma cyhalothrin | Missible oil | ? | 140.9 |
By LC50 of composite embodiment each in the Application Example one and LC50 of single dose comparing embodiment, computational methods, with reference to the method being calculated mixture co-toxicity by toxicity index of Sun Yunpei, calculate co-toxicity coefficient.
The composite co-toxicity coefficient of table 6 the present invention measures
Test result shows, when chlorine fluorine ether chrysanthemum ester and gamma cyhalothrin proportionate relationship are between 1:50 ~ 50:1, its co-toxicity coefficient is all greater than 100, and especially when proportionate relationship is between 1:10 ~ 10:1, its co-toxicity coefficient is all greater than 110, shows synergistic effect.
Claims (5)
1. an insecticides, is characterized in that: it is made up of former medicine component and auxiliary element, and former medicine component accounts for the 1-70% of insecticides gross weight, and former medicine component is made up of by the weight ratio of 1:10 ~ 10:1 is composite component A and B component; Described component A is the pyrethroid compound that structure meets following formula
Described B component is gamma cyhalothrin.
2. insecticides according to claim 1, is characterized in that: described component A is selected from one or more the mixture in following pyrethroid compound:
Rich dextrorotation 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl base-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester of cyclopropane 1 effective body burden >=55% of R configuration;
Cyclopropane 1 absolute configuration is R configuration, 1,32,3,5,6-tetrafluoro-4-methoxymethyl benzyl bases-(1R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters not distinguishing the dextrorotation of cis-trans isomerism;
Cyclopropane 1 absolute configuration is R configuration, 1, and 3 is trans-isomeric 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl bases-(1R, 3S)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester;
Or
Cyclopropane 1 absolute configuration is R configuration, 1, and 3 is 2,3,5,6-tetrafluoro-4-methoxymethyl benzyl bases-(1R, 3R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's ester of syn-isomerism.
3. insecticides according to claim 1 is killing the application in getting rid of insects as pesticidal preparations.
4. application according to claim 3, is characterized in that: the formulation of described pesticidal preparations is missible oil, suspending agent or water dispersible granules.
5. application according to claim 3, is characterized in that: described insect comprises the insect of Lepidoptera, thrips, Homoptera, diptera or mite class.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110442109.7A CN103168795B (en) | 2011-12-26 | 2011-12-26 | Meperfluthrin-containing compound insecticidal composition and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110442109.7A CN103168795B (en) | 2011-12-26 | 2011-12-26 | Meperfluthrin-containing compound insecticidal composition and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103168795A CN103168795A (en) | 2013-06-26 |
| CN103168795B true CN103168795B (en) | 2015-01-07 |
Family
ID=48629346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110442109.7A Active CN103168795B (en) | 2011-12-26 | 2011-12-26 | Meperfluthrin-containing compound insecticidal composition and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103168795B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105594728A (en) * | 2014-11-24 | 2016-05-25 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing Meperfluthrin and Beta cypermethrin |
| CN106234405B (en) * | 2016-07-30 | 2018-11-02 | 江苏功成生物科技有限公司 | A kind of Pesticidal combination containing fluorine chlorine ether pyrethroids and ethofenprox and its application |
| CN108244108B (en) * | 2016-12-28 | 2021-08-24 | 江苏扬农化工股份有限公司 | Long-acting fly killing hanging strip capable of actively attracting flies and killing flies |
| CN113229291A (en) * | 2021-06-07 | 2021-08-10 | 南京荣诚生物科技有限公司 | Combined synergistic wettable pesticide powder, preparation method and pesticide |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101953368A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing chlorine fluorine ethofenprox and beta-cypermethrin and application thereof |
| CN101953362A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing meperfluthrin and bifenthrin and application thereof |
| CN101953369A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof |
| CN101953370A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composite containing chlorine fluorine ethofenprox and cypermethrin and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010143863A (en) * | 2008-12-19 | 2010-07-01 | Sumika Life Tech Co Ltd | Method for preventing spider webbing |
-
2011
- 2011-12-26 CN CN201110442109.7A patent/CN103168795B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101953368A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing chlorine fluorine ethofenprox and beta-cypermethrin and application thereof |
| CN101953362A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing meperfluthrin and bifenthrin and application thereof |
| CN101953369A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composition containing chlorine fluorine ethofenprox and deltamethrin and application thereof |
| CN101953370A (en) * | 2010-06-02 | 2011-01-26 | 深圳诺普信农化股份有限公司 | Composite containing chlorine fluorine ethofenprox and cypermethrin and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2010-143863A 2010.07.01 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103168795A (en) | 2013-06-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103300019B (en) | Pesticidal composition | |
| CN103168795B (en) | Meperfluthrin-containing compound insecticidal composition and application thereof | |
| CN103355319A (en) | Insecticidal composition containing pyridalyl and biological source | |
| CN103283744A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN103168794B (en) | Meperfluthrin-containing compound insecticidal composition and application thereof | |
| CN102599169B (en) | Tolfenpyrad-containing insecticidal composition | |
| CN102302035A (en) | Pesticide composition containing methoxyfenozide | |
| CN104663693A (en) | Composition containing pyriminostrobin and application of composition | |
| CN102246818A (en) | Insecticidal composition containing organophosphorus compound | |
| CN103168791B (en) | Meperfluthrin-containing compound insecticidal composition and application thereof | |
| CN102100235A (en) | Insecticidal composition containing sulfoxaflor and pyrethroid | |
| CN108013045A (en) | A kind of agricultural insecticide composition containing fluorine pyrrole furanone and Tolfenpyrad | |
| CN104222124B (en) | Ethyl pleocidin and bistrifluron complex composition | |
| CN102210320A (en) | Sulfoxaflor-containing insecticidal composition | |
| CN104738046A (en) | Insecticidal composition containing pyridine quinazoline and cyhalodiamide | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN103168792B (en) | Meperfluthrin-containing compound insecticidal composition and application thereof | |
| CN102972421A (en) | Insecticidal composition containing emamectin benzoate and triflumuron | |
| CN103168793B (en) | Meperfluthrin-containing compound insecticidal composition and application thereof | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN103168797B (en) | Meperfluthrin-containing compound insecticidal composition and application thereof | |
| CN102845459B (en) | Insecticidal composition containing flubendiamide and dichlorvos | |
| CN108174852A (en) | The Pesticidal combination of the mite nitrile of azoles containing second and Amitraz | |
| CN103719126A (en) | Weeding composite containing beflubutamid and sulfonylurea | |
| CN104855404A (en) | Insecticidal combination containing tetrachloro worm amide and diafenthiuron |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Qi Mingzhu Inventor after: Jia Wei Inventor after: Li Anming Inventor after: Shao Hongjun Inventor after: Kuang Jianbo Inventor before: Qi Mingzhu Inventor before: Jia Wei Inventor before: Li Anmin Inventor before: Shao Hongjun Inventor before: Kuang Jianbo |
|
| CB03 | Change of inventor or designer information | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20130626 Assignee: Jiangsu Aijin crop Technology Group Co.,Ltd. Assignor: JIANGSU YANGNONG CHEMICAL Co.,Ltd.|JIANGSU YOUTH CHEMICAL Co.,Ltd. Contract record no.: X2022990000196 Denomination of invention: A compound insecticidal composition containing permethrin and its application Granted publication date: 20150107 License type: Common License Record date: 20220402 |
|
| EE01 | Entry into force of recordation of patent licensing contract |