CN106189837B - Preparation method of negative ion environment-friendly coating applied to surface of lampshade - Google Patents

Preparation method of negative ion environment-friendly coating applied to surface of lampshade Download PDF

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CN106189837B
CN106189837B CN201610574138.1A CN201610574138A CN106189837B CN 106189837 B CN106189837 B CN 106189837B CN 201610574138 A CN201610574138 A CN 201610574138A CN 106189837 B CN106189837 B CN 106189837B
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CN106189837A (en
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史玉桂
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Hebei Chenyang Industry and Trade Group Co Ltd
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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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Abstract

The invention discloses a preparation method of an anion environment-friendly coating applied to the surface of a lampshade, which comprises environment-friendly resin, a flame retardant, a modified aromatic amine curing agent, nano fluorescent powder, a Qinbuayan Jiaguo 754 photoinitiator, a polyether amine catalyst, hydroxyethyl cellulose, cerium dioxide, active mineral substance powder and the like.

Description

A kind of anion environmental protection coating production applied to cover surface
Technical field
The present invention relates to field of illuminating lamps, more particularly to a kind of anion environmental protection coating applied to cover surface to prepare Method.
Background technology
With the development and progress of society, the illumination that the green idea of people is more and more stronger thus green fills Put more to be favored by people, and increasingly ripe LED technology is because it is with efficient, energy-saving and environmental protection, service life length, work( The low advantage of rate, LED illumination lamp have gradually started to substitute traditional illuminator.
On the one hand, as the continuous rise of Global Temperature, the population of mosquito and quantity will all greatly improve, just increasingly threaten The health of the mankind.Mosquito except directly sting thorn suck blood, harass sleep in addition to, more seriously propagate a variety of diseases.The mosquito in China passes disease There are malaria, Filariasis, Japanese Type-B encephalitis and dengue fever（Or dengue hemorrhagic fever）Four classes, mosquito pass more important virosis Also yellow fever and various equine encephalitis etc..
On the other hand, by negative aeroion Technology application in electricity-saving lamp product, the electricity-saving lamp after use is long-term indoors Discharge negative aeroion, especially negative oxygen ion.Due to its in structure it is similar to ultra-oxygen anion free radical, therefore there is phase As bioactivity, biological cell living can be made negatively charged, so that virus loses attacking ability to cell；Meanwhile Negative oxygen ion can react with finishing pollution things such as formaldehyde, toluene, TVOC, product be nonpoisonous and tasteless carbon dioxide and Water, the generation of non-secondary pollution, with certain the effect of purifying the air of a room, for example, in artificial air's anion environment, Mould, bacterial population can reduce by more than 90% in air after measured.After negative oxygen ion is inhaled into human body, it can adjust neural emerging Put forth energy state, improve the ventilatory of lung, improve blood circulation, enhance metabolism, strengthen immune system ability, making one spirit and shake Put forth energy, improve operating efficiency etc., it also has certain treatment to make to many diseases such as hypertension, asthma, influenza, insomnia, arthritis With so people's anion is referred to as " vitamin in air " " long-lived element ".
So far, make conventional lamp product while there is mosquito dispersing and the Technology design of negative ion-releasing function not to have also See.
The content of the invention
In view of the deficienciess of the prior art, the technical problems to be solved by the invention, which are to provide one kind, is applied to lampshade table The anion environmental protection coating production in face, prepared coating not only long-term negative ion release, also have and certain drive mosquito Worm effect, while also there is certain antibacterial action, there is the effect achieved many things at one stroke.
The purpose of the present invention is achieved by the following technical solution：
A kind of anion environmental protection coating production applied to cover surface, it is characterised in that：Described environment-friendly coating By following component by weight：
Environment-friendly resin 15-25 parts by weight；Fire retardant 3-6 parts by weight；Curing agent 2-3.5 parts by weight；Nanometer Fluorescent material 0.1-0.2 parts by weight；The good solid 754 light trigger 1.5-3 parts by weight of vapour Ba Yan；Polyethers amine catalyst 0.5-0.7 weight Part；Hydroxyethyl cellulose 2-3 parts by weight；Ceria 0.1-0.15 parts by weight；Active mineral matter powder 0.75-1.3 parts by weight；In Medicine essential oil 0.6-1.1 parts by weight；Wherein, the environment-friendly resin is epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin Mixture, the mass ratio of the epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin is 1.5:1, the fire retardant For the mixture of ammonium polyphosphate, melamine and expanded graphites, the ammonium polyphosphate, melamine and expansion The mass ratio 1.5 of type graphite:1.2:1, described nano-phosphor be Ce and YAG mixture, the grain of the nano-phosphor Footpath≤13 μm, described active mineral matter powder are germanite, fluorite, tourmaline, six ring stones by weight 2.5：3：3.7：2 mixing Thing, wherein tourmaline are dravite and elbaite by weight 5：3 mixture, the particle diameter of the active mineral matter powder≤ 13 μm, the environment-friendly coating, which is made by the steps, to be formed：
It is S1, the environment-friendly resin of required parts by weight, fire retardant, nano-phosphor, hydroxyethyl cellulose, vapour Ba Yan is good solid 754 light triggers and polyethers amine catalyst are placed in mixer, are mixed well in 65-85 DEG C of next part high speed stirring, mixing time For 15-30 minutes, it is to be mixed uniformly after taken out from mixer, that is, mixture A is made, it is standby；
S2, by material fruit of Rangoon creeper's 65-85 parts by weight, aloe 20-25 parts by weight, callicarpa nudiflora 4-6 parts by weight, lavender 15-20 parts by weight, anemone vitifolia 3-5 parts by weight, Polygonum multiflower knotweed 3-5 parts by weight, peppermint 1-3 parts by weight, small tiller 1-3 parts by weight, Fruit of Chinese magnoliavine 1-3 parts by weight, marjoram 1.5-2.5 parts by weight and vanilla 1.5-2 parts by weight decontaminations, are placed in -20 together DEG C vacuum kettle 2-3 hours, be then placed in microwave dryer again and pre-processed, wherein drying time is 30-40 minutes, microwave Power is 17kw；
S3, the material after step S2 processing put into micronizer and is crushed to 60 mesh together, bulk drug powder is made, It is standby；
S4, obtained bulk drug powder in step S3 put into the extraction kettle of supercritical carbon dioxide extraction apparatus, adjusted Save extracting pressure 28MPa, 45 DEG C, carbon dioxide flow 1100L/h of extraction temperature, dynamic extraction 2 hours, directly in separating still Crude oil is collected in outlet with triangular flask, standby；
S5, obtained crude oil in step S4 is placed in 5 DEG C of environment freezed 70 minutes, then the crude oil after freezing is placed in and turned Speed is centrifuges 25 minutes in 17000r/min high speed freezing centrifuge, removing after the removal of impurity to be placed in 85 DEG C of vacuum tanks, to vacuumize 3 small When, i.e., obtained volatile oil B is standby；
S6, by purslane 3-4 parts by weight, red sage root 3-4 parts by weight, flaccid knotweed herb 3-4 parts by weight, tuber of stemona 7-9 parts by weight, wrinkled giant hyssop 3-4 parts by weight, root of langdu 3-4 parts by weight, cape jasmine 3-4 parts by weight, Radix Isatidis 15-18 parts by weight and spina date seed 3-4 parts by weight are washed Net drying, put into micronizer be crushed to 30 mesh together, then plus deionized water is soaked 5 hours, and amount of water is is soaked 7 times of bulk drug quality, are dispersed with stirring and mix well, and Traditional Chinese drug mixture is made, standby；
S7, by Traditional Chinese drug mixture made from step S6 in 80 DEG C decoct 2 hours, collect distillate, and add ether extraction, The volume ratio of distillate and ether is 2.5:1, upper oil phase is taken, then plus anhydrous sodium sulfate 0.1-0.25 parts by weight are dried Processing, i.e., obtained volatile oil C are standby；
S8, step S5 and S7 made volatile oil B and volatile oil C are mixed and mix well obtained miscella, then while stirring successively Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil are added, is sufficiently stirred 45 minutes, stands 30 minutes, crosses and filters out It is miscellaneous, essential oil of traditional Chinese medicine is produced, wherein, the quality of the miscella and Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil Than for 2：0.5：0.4：0.6：0.5；
S9, by mixture A made from essential oil of traditional Chinese medicine made from step S8 and step S1, at 70-80 DEG C, in mixer Concentrated compactness is mixed 15 minutes, obtains premix, and ceria, active mineral matter powder and modification are then added in premix Aromatic amine curing agent, at 65-85 DEG C, then concentrated compactness casts in the outer surface of lampshade after 35 minutes, solidification is stripped, i.e., Obtain environment-friendly coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following parts by weight：Surface-active 1.7 parts of agent, 0.2 part of Metadelphene, 1 part of butyl butyrate, 1.2 parts of eucalyptus oil, 0.5 part of acetic acid chlorhexidine, AEO 0.2 part of 1 part of sodium sulphate and sodium benzoate.
It should be noted that the experiment proved that, appropriate ceria is added in active mineral matter powder（CeO2）, utilize The emittance of the rare earth element is high, and the characteristics of half degradation period limit for length, the anion production of active mineral matter powder can be significantly increased Rate, its principle are as follows：Ce in ceria4+Ce is changed under photoenvironment3+, in conversion process, electron-hole Recombination probability reduces, then in active mineral matter powder in the presence of the material electric field such as tourmaline, part electronics is passively with electric field side To displacement, electron-hole recombination probability reduces, so as in tourmaline/CeO2Substantial amounts of electricity is gathered in composite powder surface The energy of air molecule is solved, and then generates the negative aeroion of high concentration, while Ce3+Ce is oxidized into again4+, then repeat Foregoing conversion process；Meanwhile detected through practice, add titanium dioxide in the active mineral matter powder by the compound proportioning of the present invention Cerium component, the concentration than the active mineral matter powder anion of not added ceria is high more than 10 times, r rays and natural environment It is identical.
The present invention be based on traditional Chinese medicine, with reference to modern Chinese medicine pharmacological research, from the drug screening of existing Chinese medicine and instead Card is reviewed, gives full play to each component synergy, the effect of wherein primary raw material is described as follows.
The fruit of Rangoon creeper：, can at least having more than 1600 years history in treatment children's sufferer for famous anthelmintic of all times Anti-dermatophyte, Gan Wen, returns spleen stomach.Expelling parasites and food tagnancy.
Aloe：《Bencao Jingshu》：Aloe, tremble with fear can except heat, hardship can expel the heat-evil eliminating dampness, it is bitter can desinsection, to bitter to cold, therefore be except heat The key medicine of desinsection.Its main hot blast is unhappy, hot gas between chest side of body, improving eyesight, relieving palpitation, children epilepsy cool breeze, treats five infantile malnutrition due to digestive disturbances or intestinalparasites, kills three worm persons, heat Wind is then given birth to, heat energy makes one unhappy, and heat is except then hot gas self solves between wind-heat unhappiness and chest diaphragm.
It is callicarpa nudiflora：Verenaceae Japanses beauty-berry platymiscium, anti-inflammatory, detoxify, convergence, hemostasia effect.
Lavender can remove ant, except roach, except mite, when being placed under wardrobe, pillow, can not only replace camphor ball, moreover it is possible to stay The fragrance of one lower people that oozes, research find that lavender has obvious antibacterial action, and the linalool contained in lavender is lavender The main component of antibacterial, it can suppress 17 kinds of bacteriums（Including gram-negative bacteria and gram-positive bacteria）, 10 kinds of fungies life It is long.
Anemone vitifolia：①《Shaanxi Chinese herbal medicine》：" it is bitter, it is cool, it is slightly poisonous.”②《Often use Chinese herbal medicine in Sichuan》：" toil, temperature, It is slightly poisonous." removing toxic substances, apocenosis myogenic, scattered stasis detumescence, have and kill maggot, wriggler, change product, detumescence, dissipate the stasis of blood, control stubborn dermatitis, the favus of the scalp, malaria Disease, infantile malnutrition, dysentery, carbuncle furuncle sore swell, scrofula, traumatic injury.
Polygonum multiflower knotweed:Polygonum multiflower knotweed is mild-natured nontoxic, sweet and slightly bitter taste, enters the heart, Liver Channel, there is the effect of tranquilizing and blood nourishing, dispelling wind and removing obstruction in the meridians, Cure mainly the diseases such as few deficiency of Yin blood, restlessness of asrhenia type and insomnia, arthralgia pain due to rheumatism, itchy skin eruption.
Peppermint：For the dry aerial parts of labiate peppermint, dispelling wind and heat from the body, head clearing, relieving sore-throat promoting eruption, soothing the liver row Gas.
Small tiller：Evergreen shrubs, high 1-2 rice.Old branch cylinder, dark gray, sprout is faint yellow, has rib groove and wart point；Stem thorn Three bifurcateds, slotless is long 1.5-2 centimetres, homochromy with branch.Cure mainly：Hot gas in trusted subordinate is removed, kills parasites, controls metrorrhagia.Release name tiller, mountain Pomegranate.Smell：It is hardship, Great Cold, nontoxic.
The fruit of Chinese magnoliavine：For Magnoliacea plant, there is antibacterial action, to bacillus anthracis, staphylococcus aureus, white grapes ball Bacterium, typhoid bacillus, comma bacillus etc. have inhibitory action.
Marjoram：Can improve that mood is depressed and addictive disease, it is especially effective to liberal-mindedness and vigorous endurance stress symptom, can expand blood vessel, Hypotensive, mitigation and burden, help eliminate palpitaition, have excellent nerve to pacify and calm function.
Vanilla:There is special fragrance, have that antifatigue and mood is gloomy, help hormone secretion, anxiety of releiving and improvement Insomnia and other effects.The effect of with cardiac stimulant, cerebrum tonifying, stomach invigorating, removing toxic substances, wind dispelling, enhancing muscle strength, it is emerging to make aroma type nervous system Put forth energy agent and kidney-reinforcing drug, for treating hysteria, melancholia, impotence, abnormal heat and rheumatism.
Purslane：Portulacaceae annual herb plant.Plump succulence, hairless, high 10-30cm, be born in field roadside and The area without shade such as flower garden ruins.Domestic various regions are distributed.This kind is medical and edible dual purpose plant.Herb hyoscine, there are clearing heat and promoting diuresis, solution Malicious detumescence, anti-inflammatory, quench the thirst, diuresis.
The red sage root：It is bitter in taste, it is slightly cold.The thoughts of returning home, Liver Channel.《The southern regions of the Yunnan Province book on Chinese herbal medicine》Record：Bushing sedate, calming heart and tranquilizing mind.Control forgetful seized with terror Punching, palpitation with fear is insomnia, and has a stasis-dispelling and pain-killing, invigorate blood circulation, the effect of relieving restlessness that clears away heart-fire, for irregular menstruation, closed dysmenorrhea, abdominal mass product It is poly-, chest and abdomen shouting pain, hot numbness pain, sore.
Flaccid knotweed herb：To various shigella dysenteriaes in there is inhibitory action in test tube, current clinical medicine research shows, polygonum flaccidum tool There are antibacterial, antiviral, anti-inflammatory, anti-oxidant and other effects.
The tuber of stemona：Can mosquito expelling, resisting pathogenic microbes effect, to beta hemolytic streptococcus, meningococcus, golden yellow A variety of pathomycetes such as staphylococcus, staphylococcus albus, typhoid bacillus, pneumobacillus, yersinia pestis, bacillus anthracis have necessarily Inhibitory action, its infusion has killing action to mosquitos and flies larva, head louse, clothing lice and bedbug etc..
Wrinkled giant hyssop：Acrid flavour, slightly warm in nature.Effect：Dampness elimination inducing diaphoresis, solves the effect of administration, cures mainly dampness taste with, and chest gastral cavity is vexed swollen, Appetite is not fragrant, Nausea and vomiting；Summer summer-heat and damp is sleepy, uncomfortable in chest not relax, and the illnesss such as aversion to cold of catching cold is uncomfortable in chest, have compared with Strong suppression fungi effect and antibacterial action.
The root of langdu：The alias river root of langdu, continuous poison, RADIX STELLERAE, chervil, vexed fresh idea, Re Jiaba, eliminate completely, Chinese atropanthe root, one perfume, Medicine sieve foretells, it is raw pull, flourishing bavin headdress flower, monkey root, gelsemium elegan, with its root eliminating the phlegm, analgesic, disperse accumulations, desinsection in traditional Chinese medicine.
Cape jasmine：Its fruit is traditional Chinese medicine, the l batch medicine-food two-purpose resources that the category Ministry of Public Health promulgates, have protect liver, cholagogic, The effect such as decompression, calm, hemostasis, detumescence, has inhibitory action, to a variety of to corynebacterium diphtheriae, staphylococcus aureus, typhoid bacillus Dermatophyte also has different degrees of inhibitory action.
Radix Isatidis：Have inhibitory action to various bacteria, infusion to hay bacillus, staphylococcus aureus, sarcine, Escherichia coli, typhoid bacillus, paratyphosum Bacterium, dysentery（Will is congratulated, Freund）Bacillus, bacillus enteritidis etc. have different degrees of suppression Effect；Acetone leachate also has similar effect, and effective to hemolytic streptococcus.
Spina date seed:There are significant calm and syngignoscism and anticonvulsant action, according to《Book on Chinese herbal medicine is new again》Record：Soothing the liver is managed Gas, moisten the lung and nourish yin, middle benefit gas dampness removing, hold back gas hidroschesis, beneficial will, hearing-improing and eyesight improving.
It should be noted that it is proven, after the red sage root, flaccid knotweed herb and the tuber of stemona of certain part by weight are compounded, no The ability of degerming antibacterial is only remarkably improved, can also produce a kind of delicate fragrance taste having no toxic side effect, it is refreshing, have certain Effect of refreshing oneself；Meanwhile be proven, the fruit of Rangoon creeper of certain part by weight, aloe, lavender and anemone vitifolia are answered After matching somebody with somebody, the mosquito dispersing ability of said composition is set to be significantly improved；In addition, the component such as callicarpa nudiflora, small tiller and fruit of Chinese magnoliavine is carried out After compatibility, the antibacterial degerming ability of composition is substantially increased, is detected through practice, the composition after compounding is to Staphylococcus aureus Bacterium, bacillus anthracis, Bacillus influenzae, micrococcus catarrhalis, pneumococcus, Escherichia coli, beta streptococcus, corynebacterium diphtheriae, typhoid bacillus, Green pus liver bacterium, shigella dysenteriae etc. more than 40, which plants germ, has certain suppression and killing action, the present invention is provided with certain resist Bacterium degerming ability.
The effect of the present invention：
The present invention is compounded using Chinese medicine and active mineral matter, the present invention can also be not only discharged negative with expelling mosquito Ion, fresh air, while fragrant odour, property is gentle, has the effect of body-building, mosquito repellent, antimycotic antiseptic.
Embodiment
Embodiment 1：
A kind of anion environmental protection coating production applied to cover surface, described environment-friendly coating are pressed by following component Formed according to parts by weight：
The parts by weight of environment-friendly resin 15；The parts by weight of fire retardant 6；The parts by weight of curing agent 2；Nano-phosphor 0.2 Parts by weight；The good solid parts by weight of 754 light trigger 1.5 of vapour Ba Yan；The parts by weight of polyethers amine catalyst 0.7；The weight of hydroxyethyl cellulose 2 Part；The parts by weight of ceria 0.15；The parts by weight of active mineral matter powder 0.75；The parts by weight of essential oil of traditional Chinese medicine 1.1；Wherein, the environmental protection Resin is the mixture of epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin, the epoxy soybean oil acrylate and The mass ratio of bisphenol A-type E51 epoxy resin is 1.5:1, the fire retardant is ammonium polyphosphate, melamine and intumescent stone The mixture of ink, the mass ratio 1.5 of the ammonium polyphosphate, melamine and expanded graphites:1.2:1, described nanometer Fluorescent material be Ce and YAG mixture, particle diameter≤13 μm of the nano-phosphor, described active mineral matter powder be germanite, Fluorite, tourmaline, six ring stones are by weight 2.5：3：3.7：2 mixture, wherein tourmaline are dravite and elbaite By weight 5：3 mixture, particle diameter≤13 μm of the active mineral matter powder, the environment-friendly coating are made by the steps Form：
It is S1, the environment-friendly resin of required parts by weight, fire retardant, nano-phosphor, hydroxyethyl cellulose, vapour Ba Yan is good solid 754 light triggers and polyethers amine catalyst are placed in mixer, are mixed well in 65 DEG C of next part high speed stirrings, mixing time 30 Minute, it is to be mixed uniformly after taken out from mixer, that is, mixture A is made, it is standby；
S2, by the parts by weight of the material fruit of Rangoon creeper 65, the parts by weight of aloe 25, callicarpa nudiflora 4 parts by weight, the parts by weight of lavender 20, The parts by weight of anemone vitifolia 3, the parts by weight of Polygonum multiflower knotweed 5, the parts by weight of peppermint 1, the small parts by weight of tiller 3, the parts by weight of the fruit of Chinese magnoliavine 1, sweet tea Ma Yu Blue 2.5 parts by weight, the parts by weight decontamination of vanilla 1.5 are placed in -20 DEG C of vacuum kettle 2 hours together, and being then placed in microwave again does Dry machine is pre-processed, and wherein drying time is 40 minutes, microwave power 17kw；
S3, the material after step S2 processing put into micronizer and is crushed to 60 mesh together, bulk drug powder is made, It is standby；
S4, obtained bulk drug powder in step S3 put into the extraction kettle of supercritical carbon dioxide extraction apparatus, adjusted Save extracting pressure 28MPa, 45 DEG C, carbon dioxide flow 1100L/h of extraction temperature, dynamic extraction 2 hours, directly in separating still Crude oil is collected in outlet with triangular flask, standby；
S5, obtained crude oil in step S4 is placed in 5 DEG C of environment freezed 70 minutes, then the crude oil after freezing is placed in and turned Speed is centrifuges 25 minutes in 17000r/min high speed freezing centrifuge, removing after the removal of impurity to be placed in 85 DEG C of vacuum tanks, to vacuumize 3 small When, i.e., obtained volatile oil B is standby；
S6, by the parts by weight of purslane 3, the parts by weight of the red sage root 4, the parts by weight of flaccid knotweed herb 3, the parts by weight of the tuber of stemona 9, the parts by weight of wrinkled giant hyssop 3, The parts by weight of the root of langdu 4, the parts by weight of cape jasmine 3, the parts by weight of Radix Isatidis 18, the parts by weight of spina date seed 3 clean drying, put into ultramicro grinding together 30 mesh are crushed in machine, then plus deionized water is soaked 5 hours, amount of water by 7 times of immersion bulk drug quality, be dispersed with stirring Mix well, Traditional Chinese drug mixture is made, it is standby；
S7, by Traditional Chinese drug mixture made from step S6 in 80 DEG C decoct 2 hours, collect distillate, and add ether extraction, The volume ratio of distillate and ether is 2.5:1, upper oil phase is taken, then plus processing is dried in the parts by weight of anhydrous sodium sulfate 0.1, I.e. obtained volatile oil C, it is standby；
S8, step S5 and S7 made volatile oil B and volatile oil C are mixed and mix well obtained miscella, then while stirring successively Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil are added, is sufficiently stirred 45 minutes, stands 30 minutes, crosses and filters out It is miscellaneous, essential oil of traditional Chinese medicine is produced, wherein, the quality of the miscella and Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil Than for 2：0.5：0.4：0.6：0.5；
S9, by mixture A made from essential oil of traditional Chinese medicine made from step S8 and step S1, at 70 DEG C, collect in mixer In be stirred 15 minutes, obtain premix, ceria, active mineral matter powder and modified virtue then added in premix Fragrant amine hardener, at 65 DEG C, then concentrated compactness casts in the outer surface of lampshade, the solidification demoulding, produces environmental protection after 35 minutes Coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following parts by weight：Surface-active 1.7 parts of agent, 0.2 part of Metadelphene, 1 part of butyl butyrate, 1.2 parts of eucalyptus oil, 0.5 part of acetic acid chlorhexidine, AEO 0.2 part of 1 part of sodium sulphate and sodium benzoate.
Embodiment 2：
A kind of anion environmental protection coating production applied to cover surface, the environment-friendly coating by following component according to Parts by weight form：
The parts by weight of environment-friendly resin 19；The parts by weight of fire retardant 5；The parts by weight of curing agent 3；Nano-phosphor 0.15 Parts by weight；The good solid parts by weight of 754 light trigger 2 of vapour Ba Yan；The parts by weight of polyethers amine catalyst 0.6；The weight of hydroxyethyl cellulose 2.5 Part；The parts by weight of ceria 0.15；The parts by weight of active mineral matter powder 1；The parts by weight of essential oil of traditional Chinese medicine 1；Wherein, the environment-friendly resin is The mixture of epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin, the epoxy soybean oil acrylate and bisphenol-A The mass ratio of type E51 epoxy resin is 1.5:1, the fire retardant is ammonium polyphosphate, melamine and expanded graphites Mixture, the mass ratio 1.5 of the ammonium polyphosphate, melamine and expanded graphites:1.2:1, described nano fluorescent Powder be Ce and YAG mixture, particle diameter≤13 μm of the nano-phosphor, described active mineral matter powder be germanite, fluorite, Tourmaline, six ring stones are by weight 2.5：3：3.7：2 mixture, wherein tourmaline be dravite and elbaite by weight Than 5：3 mixture, particle diameter≤13 μm of the active mineral matter powder, the environment-friendly coating, which is made by the steps, to be formed：
It is S1, the environment-friendly resin of required parts by weight, fire retardant, nano-phosphor, hydroxyethyl cellulose, vapour Ba Yan is good solid 754 light triggers and polyethers amine catalyst are placed in mixer, are mixed well in 75 DEG C of next part high speed stirrings, mixing time 25 Minute, it is to be mixed uniformly after taken out from mixer, that is, mixture A is made, it is standby；
S2, by the parts by weight of the material fruit of Rangoon creeper 85, the parts by weight of aloe 20, callicarpa nudiflora 6 parts by weight, the parts by weight of lavender 15, The parts by weight of anemone vitifolia 5, the parts by weight of Polygonum multiflower knotweed 3, the parts by weight of peppermint 3, the small parts by weight of tiller 1, the parts by weight of the fruit of Chinese magnoliavine 3, sweet tea Ma Yu Blue 1.5 parts by weight, the parts by weight decontamination of vanilla 2 are placed in -20 DEG C of vacuum kettle 2.5 hours together, and being then placed in microwave again does Dry machine is pre-processed, and wherein drying time is 35 minutes, microwave power 17kw；
S3, the material after step S2 processing put into micronizer and is crushed to 60 mesh together, bulk drug powder is made, It is standby；
S4, obtained bulk drug powder in step S3 put into the extraction kettle of supercritical carbon dioxide extraction apparatus, adjusted Save extracting pressure 28MPa, 45 DEG C, carbon dioxide flow 1100L/h of extraction temperature, dynamic extraction 2 hours, directly in separating still Crude oil is collected in outlet with triangular flask, standby；
S5, obtained crude oil in step S4 is placed in 5 DEG C of environment freezed 70 minutes, then the crude oil after freezing is placed in and turned Speed is centrifuges 25 minutes in 17000r/min high speed freezing centrifuge, removing after the removal of impurity to be placed in 85 DEG C of vacuum tanks, to vacuumize 3 small When, i.e., obtained volatile oil B is standby；
S6, by the parts by weight of purslane 4, the parts by weight of the red sage root 3, the parts by weight of flaccid knotweed herb 4, the parts by weight of the tuber of stemona 7, the parts by weight of wrinkled giant hyssop 4, The parts by weight of the root of langdu 3, the parts by weight of cape jasmine 4, the parts by weight of Radix Isatidis 15, the parts by weight of spina date seed 4 clean drying, put into ultramicro grinding together 30 mesh are crushed in machine, then plus deionized water is soaked 5 hours, amount of water by 7 times of immersion bulk drug quality, be dispersed with stirring Mix well, Traditional Chinese drug mixture is made, it is standby；
S7, by Traditional Chinese drug mixture made from step S6 in 80 DEG C decoct 2 hours, collect distillate, and add ether extraction, The volume ratio of distillate and ether is 2.5:1, upper oil phase is taken, then plus processing is dried in the parts by weight of anhydrous sodium sulfate 0.2, I.e. obtained volatile oil C, it is standby；
S8, step S5 and S7 made volatile oil B and volatile oil C are mixed and mix well obtained miscella, then while stirring successively Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil are added, is sufficiently stirred 45 minutes, stands 30 minutes, crosses and filters out It is miscellaneous, essential oil of traditional Chinese medicine is produced, wherein, the quality of the miscella and Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil Than for 2：0.5：0.4：0.6：0.5；
S9, by mixture A made from essential oil of traditional Chinese medicine made from step S8 and step S1, at 75 DEG C, collect in mixer In be stirred 15 minutes, obtain premix, ceria, active mineral matter powder and modified virtue then added in premix Fragrant amine hardener, at 70 DEG C, then concentrated compactness casts in the outer surface of lampshade, the solidification demoulding, produces environmental protection after 35 minutes Coating.
Remaining is the same as embodiment 1.
The test index of lampshade prepared by Example 1 and Example 2 of the present invention is as follows：
（1）Smell inspection：Sense organ, nonirritant peculiar smell.
（2）Repelling effect is tested.
Contrast test is carried out according to ordinary lamp and lantern of the prior art and above-described embodiment 1 and the repelling effect of embodiment 2, Test data is see table 1.
Conclusion：Example 1 and Example 2 of the present invention can play preferable mosquito-repelling function, with the market ordinary lamp and lantern
Compare, the present invention has obviously repelling effect.
（3）Anionic textiles.
Using negative ion testing equipment, it is made primarily directed to timber, ore, ceramic material, negative ion powder to related Commodity（Such as negative ion clothing, necklace, woollen blanket）Measurement is made Deng the anion quantity discharged.
Test result is shown in Table 2.
Conclusion：The embodiment of the present invention 1, embodiment 2 can be with sustained release negative aeroions, with ordinary lamps of the prior art Tool compares, and the present invention has obviously advantage.

Claims (1)

  1. A kind of 1. anion environmental protection coating production applied to cover surface, it is characterised in that：Described environment-friendly coating by Following component is by weight：
    Environment-friendly resin 15-25 parts by weight；Fire retardant 3-6 parts by weight；Curing agent 2-3.5 parts by weight；Nano fluorescent Powder 0.1-0.2 parts by weight；The good solid 754 light trigger 1.5-3 parts by weight of vapour Ba Yan；Polyethers amine catalyst 0.5-0.7 parts by weight；Hydroxyl Ethyl cellulose 2-3 parts by weight；Ceria 0.1-0.15 parts by weight；Active mineral matter powder 0.75-1.3 parts by weight；Chinese medicine essence Oily 0.6-1.1 parts by weight；Wherein, the environment-friendly resin is the mixed of epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin The mass ratio of compound, the epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin is 1.5:1, the fire retardant is more The mixture of APP, melamine and expanded graphites, the ammonium polyphosphate, melamine and intumescent stone The mass ratio 1.5 of ink:1.2:1, described nano-phosphor is Ce and YAG mixture, the particle diameter of the nano-phosphor≤ 13 μm, described active mineral matter powder is germanite, fluorite, tourmaline, six ring stones by weight 2.5：3：3.7：2 mixture, Wherein tourmaline is dravite and elbaite by weight 5：3 mixture, the μ of the particle diameter of the active mineral matter powder≤13 M, the environment-friendly coating, which is made by the steps, to be formed：
    S1, by the environment-friendly resin of required parts by weight, fire retardant, nano-phosphor, hydroxyethyl cellulose, vapour Ba Yan good solid 754 Light trigger and polyethers amine catalyst are placed in mixer, are mixed well in 65-85 DEG C of next part high speed stirring, mixing time is 15-30 minutes, it is to be mixed uniformly after taken out from mixer, that is, mixture A is made, it is standby；
    S2, by material fruit of Rangoon creeper's 65-85 parts by weight, aloe 20-25 parts by weight, callicarpa nudiflora 4-6 parts by weight, lavender 15-20 Parts by weight, anemone vitifolia 3-5 parts by weight, Polygonum multiflower knotweed 3-5 parts by weight, peppermint 1-3 parts by weight, small tiller 1-3 parts by weight, the fruit of Chinese magnoliavine 1-3 parts by weight, marjoram 1.5-2.5 parts by weight and vanilla 1.5-2 parts by weight decontaminations, -20 DEG C true is placed in together Empty kettle 2-3 hours, microwave dryer being then placed in again and is pre-processed, wherein drying time is 30-40 minutes, and microwave power is 17kw；
    S3, the material after step S2 processing put into micronizer and be crushed to 60 mesh together, bulk drug powder is made, it is standby With；
    S4, obtained bulk drug powder in step S3 put into the extraction kettle of supercritical carbon dioxide extraction apparatus, regulation extraction Pressure power 28MPa, 45 DEG C, carbon dioxide flow 1100L/h of extraction temperature, dynamic extraction 2 hours, directly exported in separating still Crude oil is collected with triangular flask, it is standby；
    S5, obtained crude oil in step S4 is placed in 5 DEG C of environment freezed 70 minutes, then the crude oil after freezing is placed in rotating speed and is Centrifuged 25 minutes in 17000r/min high speed freezing centrifuge, remove after the removal of impurity to be placed in 85 DEG C of vacuum tanks and vacuumize 3 hours, i.e., Obtained volatile oil B, it is standby；
    S6, by purslane 3-4 parts by weight, red sage root 3-4 parts by weight, flaccid knotweed herb 3-4 parts by weight, tuber of stemona 7-9 parts by weight, wrinkled giant hyssop 3-4 Parts by weight, root of langdu 3-4 parts by weight, cape jasmine 3-4 parts by weight, Radix Isatidis 15-18 parts by weight and spina date seed 3-4 parts by weight, which are cleaned, dries It is dry, put into micronizer be crushed to 30 mesh together, then plus deionized water is soaked 5 hours, and amount of water is is soaked raw material 7 times of medicine quality, are dispersed with stirring and mix well, and Traditional Chinese drug mixture is made, standby；
    S7, by Traditional Chinese drug mixture made from step S6 in 80 DEG C decoct 2 hours, collect distillate, and add ether extraction, distillation The volume ratio of liquid and ether is 2.5:1, upper oil phase is taken, then plus place is dried in anhydrous sodium sulfate 0.1-0.25 parts by weight Reason, i.e., obtained volatile oil C are standby；
    S8, step S5 and S7 made volatile oil B and volatile oil C are mixed and mix well obtained miscella, then sequentially added while stirring Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil, it is sufficiently stirred 45 minutes, stands 30 minutes, filtering and impurity removing, i.e., Essential oil of traditional Chinese medicine is obtained, wherein, the mass ratio of the miscella and Peppermint essential oil, Rosa Damascana, sarranine flower essential oil and needle juniper essential oil is 2：0.5：0.4：0.6：0.5；
    S9, by mixture A made from essential oil of traditional Chinese medicine made from step S8 and step S1, at 70-80 DEG C, concentrated in mixer It is stirred 15 minutes, obtains premix, ceria, active mineral matter powder and modified aromatic is then added in premix Amine hardener, at 65-85 DEG C, then concentrated compactness casts in the outer surface of lampshade, the solidification demoulding, produces ring after 35 minutes Protect coating.
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