CN106118340A - A kind of preparation method of environment protection type flame-retarding led heat radiation coating - Google Patents

A kind of preparation method of environment protection type flame-retarding led heat radiation coating Download PDF

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CN106118340A
CN106118340A CN201610574207.9A CN201610574207A CN106118340A CN 106118340 A CN106118340 A CN 106118340A CN 201610574207 A CN201610574207 A CN 201610574207A CN 106118340 A CN106118340 A CN 106118340A
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庄可香
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Abstract

The present invention relates to the preparation method of a kind of environment protection type flame-retarding led heat radiation coating, it is prepared from according to parts by weight by following component: hybrid resin 60 75 parts, sodium-based montmorillonite 3 4.5 parts, carboxylic styrene butadiene latex 4 6.5 parts, silicones metlyl branching silicone oil 1.5 2 parts, Polyethylene Glycol 0.7 1.2 parts, pentane 0.7 1.8 parts, nano silicon 1 2.5 parts, polyacrylonitrile-based carbon fibre 79 parts, Graphene 5 6.5 parts, aerosil 12 parts, fire retardant 5.5 7 parts etc., the present invention not only has great heat radiation effect, the most capable of releasing negative ion, there is certain removal formaldehyde simultaneously, toluene, effect of the finishing pollution things such as TVOC, there is boundless application prospect.

Description

A kind of preparation method of environment protection type flame-retarding led heat radiation coating
Technical field
The present invention relates to LED lamp heat radiation coating technical field, be specifically related to a kind of environment protection type flame-retarding led heat radiation coating Preparation method.
Background technology
Along with the development and progress of society, the environmental protection idea of people is increasingly stronger, thus the illumination dress of environmental protection Put and can more be favored by people, day by day ripe LED technology due to its have efficiently, energy-saving and environmental protection, length in service life, merit The advantages such as rate is low, LED illumination lamp the most gradually starts to replace traditional lighting.
LED electricity-saving lamp is actually a kind of compact, carries the LED of ballast, and lamp tube ends voltage is directly over Plasma state turns on and sends the ultraviolet of 253.7nm, and ultraviolet evokes light-emitting phosphor, due to filament during fluorescent lamp operation Temperature at about 1160K, more much lower than temperature 2200-2700K of electric filament lamp work, thus its life-span the most significantly prolong Long, arrive more than 5000 hours, due to the electric ballast that its operation efficiency is higher, there is not electric current as electric filament lamp simultaneously Heat effect, the energy conversion efficiency of fluorescent material is the highest, arrives more than every watt of 50 lumens, saves energy.
On the one hand, along with the continuous rising of Global Temperature, the population of mosquito and quantity all will be greatly improved, the most day by day threaten The health of the mankind.Mosquito, in addition to directly stining thorn and sucking blood, harass sleep, more seriously propagates multiple disease.The mosquito of China passes disease Having malaria, Filariasis, epidemic encephalitis type B and dengue fever (or dengue hemorrhagic fever) four class, mosquito passes more important virosis Also have yellow fever and various equine encephalitis etc..
On the other hand, by negative aeroion Technology application in electricity-saving lamp product, the electricity-saving lamp after using is long-term in indoor Release negative aeroion, especially negative oxygen ion.Owing to it is structurally similar to ultra-oxygen anion free radical, therefore there is phase As biological activity, it is possible to make live biological cell electronegative, so that virus loses the attacking ability to cell；Meanwhile, Negative oxygen ion can react with the finishing pollution thing such as formaldehyde, toluene, TVOC, product be nonpoisonous and tasteless carbon dioxide and Water, the generation of non-secondary pollution, there is certain effect purified the air of a room, such as, in artificial air's anion environment, In air, mycete, bacterial population can reduce by more than 90% after measured.After negative oxygen ion is inhaled into human body, can regulate neural emerging Put forth energy state, improve the ventilatory of lung, improve blood circulation, enhance metabolism, strengthen immune system ability, make people's spirit shake Putting forth energy, improve work efficiency etc., the numerous diseases such as hypertension, asthma, influenza, insomnia, arthritis are also had certain treatment to make by it With, so people's anion is called " vitamin in air " " long-lived element ".
So far, make conventional lamp heat radiation coating product have expelling mosquito and the technology of anion releasing health care simultaneously Design does not also have to be seen.
Summary of the invention
The deficiency existed for prior art, the technical problem to be solved is to provide dissipating of a kind of LED lamp Heat structure and light fixture, not only have preferable radiating effect, it is also possible to expelling mosquito, anion releasing, fresh air, same to seasonal epidemic pathogens Taste fragrance, character is gentle, has certain anophelifuge, antibacterial and remove effects of the finishing pollution things such as formaldehyde, toluene, TVOC.
It is an object of the invention to be achieved through the following technical solutions:
A kind of preparation method of environment protection type flame-retarding led heat radiation coating, described heat radiation coating by following component according to parts by weight It is prepared from: hybrid resin 60-75 weight portion, sodium-based montmorillonite 3-4.5 weight portion, carboxylic styrene butadiene latex 4-6.5 weight portion, silicon Resin metlyl branching silicone oil 1.5-2 weight portion, Polyethylene Glycol 0.7-1.2 weight portion, pentane 0.7-1.8 weight portion, nanometer two Silicon oxide 1-2.5 weight portion, polyacrylonitrile-based carbon fibre 7-9 weight portion, Graphene 5-6.5 weight portion, aerosil 1-2 Weight portion, fire retardant 5.5-7 weight portion, curing agent 4-6 weight portion, solvent 15-20 weight portion, ceria 0.1-0.15 weight portion, active mineral matter powder 1.5-2 weight portion, essential oil of traditional Chinese medicine 1.5-2.5 weight portion；Wherein, described compound tree Fat be the mass ratio of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin be 2:1-3:1；Described polypropylene Itrile group carbon fiber length is 0.01mm；Described fire retardant is the mixture of APP, tripolycyanamide and expanded graphites, institute State the mass ratio 2:1.5:1.3 of APP, tripolycyanamide and expanded graphites；Described solvent is DAA and butyl ester Mixture, the mass ratio of described DAA and butyl ester is 3:1-3:2；Described active mineral matter powder is germanite, fluorite, electricity Gas stone, gahnite are by weight the mixture of 2.5:3:3.5:1.7, and wherein tourmaline is that dravite and elbaite are by weight The amount mixture than 4:3, particle diameter≤15 μm of described active mineral matter powder, described heat radiation coating be made by the steps and Become:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex, silicones metlyl branching silicone oil, poly-second two by weight Alcohol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are put In blender, mixing well in the stirring of 80 DEG C of next part high speeds, mixing time is 40 minutes, to be mixed uniformly after take from blender Go out, i.e. prepare mixture A, standby；
S2, by material Caulis Vernoniae andersonii 65-85 weight portion, Rhizoma Acori Graminei 15-20 weight portion, Callicarpa nudiflora 4-6 weight portion, Hubei anemone Flower 3-5 weight portion, Cortex Albiziae 3-5 weight portion, Herba Lysimachiae foenum-graeci 1-3 weight portion, Fructus Gardeniae 3-4 weight portion, Radix Salviae Miltiorrhizae 3-4 weight portion, Herba polygoni hydropiperis Grass 3-4 weight portion, Radix Stemonae 5-8 weight portion decontamination, it is placed in vacuum still 2-3 hour of-20 DEG C together, is placed in microwave the most again Drying machine carries out pretreatment, and wherein drying time is 30-40 minute, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly exports at separating still Crude oil is collected with triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby；
S6, by Herba Pogostemonis 3-4 weight portion, Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3-4 weight portion, Fructus Gardeniae 3-4 weight portion, Radix Isatidis 15-18 weight portion, Semen Ziziphi Spinosae 3- 4 weight portions, Herba Menthae 1-3 weight portion, Origanum majorana 1.5-2.5 weight portion, vanilla 1.5-2 weight portion, Herba Portulacae 3-4 weight portion Cleaning and dry, put in super micron mill together and be crushed to 30 mesh, then add deionized water and soak 5 hours, amount of water is by being soaked 7 times of bubble crude drug quality, dispersed with stirring is mixed well, and prepares Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13-0.2 weight portion and be dried place Reason, i.e. prepares volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil, be sufficiently stirred for 45 minutes, stands 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, lemon The mass ratio of lemon quintessence oil and grapefruit essential oil is 2:0.5:0.5:0.6:0.4:0.5；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 70-80 DEG C, concentrates in blender Stirring mixing 15 minutes, obtains premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and change Property aromatic amine curing agent, at 70-80 DEG C, concentrate grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surface activity Agent 3-5 weight portion, diethyltoluamide 0.1-0.2, butyl butyrate 9-15 weight portion, Eucalyptus oil 10-13 weight portion, isopropyl myristate 1-2 weight portion, polyoxyethylenated alcohol sodium sulfate 10-15 weight portion and sodium benzoate 0.1-0.3 weight portion.
It should be noted that the experiment proved that, active mineral matter powder adds appropriate ceria (CeO2), utilize The emittance of this rare earth element is high, the feature of half degradation period limit for length, and the anion that active mineral matter powder can be significantly increased produces Rate, its principle is as follows: the Ce in ceria4+Ce is changed under photoenvironment3+, in conversion process, electron-hole Recombination probability reduces, then in active mineral matter powder under the effect of the material electric field such as tourmaline, part electronics is passively with electric field side To displacement, electron-hole recombination probability reduces, thus at tourmaline/CeO2Substantial amounts of electricity has been gathered on composite powder surface The energy of solution air molecule, and then create the negative aeroion of high concentration, Ce simultaneously3+It is oxidized into again Ce4+, then repeat Aforesaid conversion process；Meanwhile, through practice detection, be combined through the present invention active mineral matter powder of proportioning adds appropriate Ceria component, higher more than 10 times than without the concentration of active mineral matter powder anion adding ceria, r ray with from So environment is identical.
The present invention is based on motherland's traditional medicine, with reference to modern Chinese medicine pharmacological research, from the drug screening of existing Chinese medicine with anti- Reviewing card, give full play to each group of weight portion synergism, the effect brief introduction of the most each raw material is as follows.
Caulis Vernoniae andersonii: " Xinhua's book on Chinese herbal medicine outline ": fruit；Bitter in the mouth, cool in nature.There are heat clearing and inflammation relieving, blood circulation promoting and blood stasis dispelling, the merit of parasite killing Energy.For treating skin wrinkle, anthelmintic.
Rhizoma Acori Graminei: its flower, stem aromatic flavor, has the effect had one's ideas straightened out, eliminate the phlegm, dissipate wind, and epidemic disease of can dispelling Fructus Alpiniae Oxyphyllae, building body can Make spice or mosquito dispersing.
Callicarpa nudiflora: Verenaceae Callicarpa plant, antiinflammatory, removing toxic substances, convergence, hemostasia effect.
Herba Anemones Hupehensis: 1. " Shaanxi Chinese herbal medicine ": " bitter, cool, slightly poisonous." 2. " Chinese herbal medicine is commonly used in Sichuan ": " and toil, temperature, Slightly poisonous." removing toxic substances, evacuation of pus granulation promoting, dissipating blood stasis of subsiding a swelling, have and kill maggot, wriggler, change long-pending, detumescence, dissipating blood stasis, control stubborn dermatitis, tinea alba, malaria Disease, infantile malnutrition, dysentery, carbuncle furuncle swells, scrofula, traumatic injury.
Cortex Albiziae: for the dry bark of leguminous plant Herba Albiziae, Cortex Albiziae sweet-bitter flavor, property are flat, GUIXIN, Liver Channel；Herba Albiziae leatherware There is resolving stagnation for tranquilization, effect of promoting blood circulation and detumescence；Cortex Albiziae cures mainly melancholy insomnia, irritability, inside and outside carbuncle and ulcer, injury from falling down.
Herba Lysimachiae foenum-graeci: containing similar coumarin aromatic oil, essence can be refined, as the spice such as Nicotiana tabacum L. and face cream；In dry product cartonning Can Anti-moth-eating medicated clothing；Hyoscine again, has dispersing wind and cold, wards off dirty effect, control seasonal pathogen headache due to common cold, upper qi-stagnant lumbago, abdominal distention uncomfortable in chest, something lost Essence, ascarifuge etc., be famous and precious fragrant plant.
Fructus Gardeniae: its fruit is Chinese medicine, belong to Ministry of Public Health promulgate l criticize medicine-food two-purpose resource, have hepatoprotective, function of gallbladder promoting, Blood pressure lowering, calmness, stop blooding, the effect such as detumescence, diphtheria corynebacterium, staphylococcus aureus, Bacillus typhi are had inhibitory action, to multiple Dermatophytes also has inhibitory action in various degree.
Radix Salviae Miltiorrhizae: nature and flavor are bitter, are slightly cold.GUIXIN, Liver Channel." the southern regions of the Yunnan Province book on Chinese herbal medicine " is recorded: reinforcing the heart sedate, calming heart and tranquilizing mind.Control forgetful seized with terror Punching, palpitation with fear is insomnia, and has stasis-dispelling and pain-killing, promoting blood circulation to restore menstrual flow, the effect of the relieving restlessness that clears away heart-fire, and for menoxenia, amenorrhea dysmenorrhea, lump in the abdomen amasss Poly-, chest and abdomen twinge, pyretic arthralgia pain, skin infection.
Herba polygoni hydropiperis: all have inhibitory action, current clinical medicine research to show in test tube to various dysentery bacteriums, Herba polygoni hydropiperis has There are the effects such as antibacterial, antiviral, antiinflammatory, antioxidation.
The Radix Stemonae: can driving away mosquito, resisting pathogenic microbes effect, to beta hemolytic streptococcus, meningococcus, golden yellow The multiple pathomycetes such as staphylococcus, Staphylococcus albus, Bacillus typhi, pneumobacillus, bacillus pestis, anthrax bacillus have necessarily Inhibitory action, its infusion all has killing action to mosquitos and flies larva, head louse, clothing louse and Cimex bedbug etc..
Herba Pogostemonis: acrid in the mouth, slightly warm in nature.Effect: removing dampness for regulating stomach, the effect of administration of inducing sweat, solve, cure mainly dampness taste, breast gastral cavity is vexed swollen, Appetite is the most fragrant, Nausea and vomiting；Summer, heat-damp in summer was sleepy, uncomfortable in chest did not relaxed, and affection of exogenous wind-cold. the diseases such as aversion to cold is uncomfortable in chest, and have and have relatively Strong Fungistasis and antibacterial action.
The Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae): the another name river Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae), continuous poison, Radix Stellerae, chervil, vexed fresh idea, Re Jiaba, Herba Senecionis Dianthui, Radix scopoliae sinensis, perfume, Medicine sieve foretells, raw pull, flourishing bavin headdress flower, monkey root, Gelsemium elegans Benth., in Chinese medicine with its root eliminate the phlegm, pain relieving, removing food stagnancy, parasite killing.
Fructus Gardeniae: its fruit is Chinese medicine, belong to Ministry of Public Health promulgate l criticize medicine-food two-purpose resource, have hepatoprotective, function of gallbladder promoting, Blood pressure lowering, calmness, stop blooding, the effect such as detumescence, diphtheria corynebacterium, staphylococcus aureus, Bacillus typhi are had inhibitory action, to multiple Dermatophytes also has inhibitory action in various degree.
Radix Isatidis: various bacteria is had inhibitory action, infusion to bacillus subtilis, staphylococcus aureus, sarcine, Escherichia coli, Bacillus typhi, Salmonella paratyphi, dysentery (will he, Freund) bacillus, bacillus enteritidis etc. have suppression in various degree Effect；Acetone leachate also has similar effect, and effective to Hemolytic streptococcus.
Semen Ziziphi Spinosae: have the calmest and syngignoscism and anticonvulsant action, record according to " book on Chinese herbal medicine is the newest ": suppressing the hyperactive liver is managed Gas, nourishing lung-YIN, warming middle-JIAO dampness removing, astringing QI hidroschesis, benefit will, hearing-improing and eyesight improving.
Herba Menthae: for the dry aerial parts of labiate Herba Menthae, dispelling wind and heat pathogens, the clear profit head, sore-throat relieving rash, soothing the liver row Gas.
Origanum majorana: can improve that mood is depressed and addictive disease, especially effective to liberal-mindedness and vigorous endurance stress symptom, can expand blood vessel, Blood pressure lowering, alleviate and burden, help to eliminate cardiopalmus, have the nerve of excellence to pacify and calm function.
Vanilla: have special fragrance, has resisting fatigue and mood is gloomy, help hormone secretion, anxiety of releiving and improvement The effects such as insomnia.There is heart tonifying, supplementing the brain, stomach invigorating, removing toxic substances, wind dispelling, effect of enhancing muscle strength, make aroma type nervous system emerging Put forth energy agent and kidney-reinforcing drug, be used for treating hysteria, melancholia, sexual impotence, deficiency-heat and rheumatism.
Herba Portulacae: Portulacaceae annual herb plant.Plump succulence, without hair, high 10-30cm, be born in roadside, field and The area without shade such as ruins, flower garden.All there is distribution domestic various places.This kind is medicine food dual purpose plant.Herb hyoscine, has clearing away heat-damp and promoting diuresis, solution Poison detumescence, antiinflammatory, quench the thirst, diuresis.
It should be noted that be proven, after carrying out the Radix Salviae Miltiorrhizae of certain part by weight, Herba polygoni hydropiperis and the Radix Stemonae compounding, no Only it is remarkably improved degerming antibacterial ability, also can produce a kind of delicate fragrance taste having no side effect, refreshing, have certain Effect of refreshing oneself；, it is proven meanwhile, the Caulis Vernoniae andersonii of certain part by weight, Rhizoma Acori Graminei, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) and Herba Anemones Hupehensis are carried out After Fu Pei, the mosquito dispersing ability of said composition is made to be significantly improved；It addition, Callicarpa nudiflora, Fructus Gardeniae, Semen Ziziphi Spinosae, Radix Isatidis and After the components such as Herba Portulacae carry out compatibility, substantially increase the antibacterial degerming ability of compositions, through practice detection, the combination after compounding Thing is to staphylococcus aureus, anthrax bacillus, hemophilus influenza, micrococcus catarrhalis, streptococcus pneumoniae, escherichia coli, group B streptococcus, white Larynx bacillus, Bacillus typhi, green pus liver bacterium, dysentery bacteriums etc. more than 40 are planted pathogenic bacteria and have certain suppression and killing action.
The effect of the present invention:
The present invention uses Chinese medicine to compound with active mineral matter, makes the present invention not only have preferable radiating effect, it is also possible to drive Mosquito, anion releasing, fresh air, simultaneously fragrant odour, character is gentle, has anophelifuge, antibacterial and effect of health care.
Detailed description of the invention
Embodiment 1:
A kind of preparation method of environment protection type flame-retarding led heat radiation coating, described heat radiation coating by following component according to weight portion numeral system For forming: hybrid resin 60 weight portion, sodium-based montmorillonite 4.5 weight portion, carboxylic styrene butadiene latex 4 weight portion, silicones methyl props up Chain silicone oil 2 weight portion, Polyethylene Glycol 0.7 weight portion, pentane 1.8 weight portion, nano silicon 1 weight portion, polyacrylonitrile Base carbon fibre 9 weight portion, Graphene 5 weight portion, aerosil 2 weight portion, fire retardant 5.5 weight portion, modified aromatic amine Firming agent 6 weight portion, solvent 15 weight portion, ceria 0.1 weight portion, active mineral matter powder 2 weight portion, essential oil of traditional Chinese medicine 1.5 Weight portion；Wherein, described hybrid resin is the quality of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin Ratio is 3:1；The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is APP, tripolycyanamide and swollen The mixture of swollen type graphite, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites；Described Solvent is the mixture of DAA and butyl ester, and the mass ratio of described DAA and butyl ester is 3:1；Described active mineral matter Powder is the mixture of germanite, fluorite, tourmaline, gahnite 2.5:3:3.5:1.7 by weight, and wherein tourmaline is that magnesium is electric The mixture of stone and elbaite 4:3 by weight, particle diameter≤15 μm of described active mineral matter powder, described heat radiation coating passes through Following steps are prepared from:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex, silicones metlyl branching silicone oil, poly-second two by weight Alcohol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are put In blender, mixing well in the stirring of 80 DEG C of next part high speeds, mixing time is 40 minutes, to be mixed uniformly after take from blender Go out, i.e. prepare mixture A, standby；
S2, by material Caulis Vernoniae andersonii 65 weight portion, Rhizoma Acori Graminei 20 weight portion, Callicarpa nudiflora 4 weight portion, Herba Anemones Hupehensis 5 weight Part, Cortex Albiziae 3 weight portion, Herba Lysimachiae foenum-graeci 3 weight portion, Fructus Gardeniae 3 weight portion, Radix Salviae Miltiorrhizae 4 weight portion, Herba polygoni hydropiperis 3 weight portion, the Radix Stemonae 8 weight Amount part decontamination, is placed in the vacuum still 2 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, be wherein dried Time is 30 minutes, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly exports at separating still Crude oil is collected with triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby；
S6, by Herba Pogostemonis 3 weight portion, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 4 weight portion, Fructus Gardeniae 3 weight portion, Radix Isatidis 18 weight portion, Semen Ziziphi Spinosae 3 weight portion, thin Lotus 3 weight portion, Origanum majorana 2.5 weight portion, vanilla 1.5 weight portion, Herba Portulacae 4 weight portion is cleaned and is dried, and puts into super together Atomizer is crushed to 30 mesh, then adds deionized water and soak 5 hours, amount of water by 7 times of immersion crude drug quality, stir Mix dispersion to mix well, prepare Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13 weight portion and be dried process, i.e. Prepare volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil, be sufficiently stirred for 45 minutes, stands 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, lemon The mass ratio of lemon quintessence oil and grapefruit essential oil is 2:0.5:0.5:0.6:0.4:0.5；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 70 DEG C, concentrates in blender and stirs Mix mixing 15 minutes, obtain premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and change Property aromatic amine curing agent, at 73 DEG C, concentrate grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surface activity Agent 3 weight portion, diethyltoluamide 0. 2 weight portion, butyl butyrate 9 weight portion, Eucalyptus oil 4 weight portion, isopropyl myristate 1 weight Part, polyoxyethylenated alcohol sodium sulfate 15 weight portion and sodium benzoate 0.1 weight portion.
Embodiment 2:
A kind of preparation method of environment protection type flame-retarding led heat radiation coating, described heat radiation coating by following component according to weight portion numeral system For forming: hybrid resin 75 weight portion, sodium-based montmorillonite 3 weight portion, carboxylic styrene butadiene latex 6.5 weight portion, silicones methyl props up Chain silicone oil 1.5 weight portion, Polyethylene Glycol 1.2 weight portion, pentane 0.7 weight portion, nano silicon 2.5 weight portion, poly-third Alkene itrile group carbon fiber 8 weight portion, Graphene 6 weight portion, aerosil 1.5 weight portion, fire retardant 6 weight portion, modified virtue Fragrant amine hardener 5 weight portion, solvent 17 weight portion, ceria 0.15 weight portion, active mineral matter powder 1.7 weight portion, Chinese medicine Quintessence oil 2 weight portion；Wherein, described hybrid resin is the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin Mass ratio be 3:1；The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is APP, tripolycyanamide And the mixture of expanded graphites, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites； Described solvent is the mixture of DAA and butyl ester, and the mass ratio of described DAA and butyl ester is 3:2；Described activity Mineral powder is the mixture of germanite, fluorite, tourmaline, gahnite 2.5:3:3.5:1.7 by weight, and wherein tourmaline is The mixture of dravite and elbaite 4:3 by weight, particle diameter≤15 μm of described active mineral matter powder, described heat-radiation coating Material is made by the steps and forms:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex, silicones metlyl branching silicone oil, poly-second two by weight Alcohol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are put In blender, mixing well in the stirring of 80 DEG C of next part high speeds, mixing time is 40 minutes, to be mixed uniformly after take from blender Go out, i.e. prepare mixture A, standby；
S2, by material Caulis Vernoniae andersonii 85 weight portion, Rhizoma Acori Graminei 15 weight portion, Callicarpa nudiflora 6 weight portion, Herba Anemones Hupehensis 3 weight Part, Cortex Albiziae 5 weight portion, Herba Lysimachiae foenum-graeci 1 weight portion, Fructus Gardeniae 4 weight portion, Radix Salviae Miltiorrhizae 3 weight portion, Herba polygoni hydropiperis 4 weight portion, the Radix Stemonae 5 weight Amount part decontamination, is placed in the vacuum still 3 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, be wherein dried Time is 40 minutes, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly exports at separating still Crude oil is collected with triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby；
S6, by Herba Pogostemonis 4 weight portion, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3 weight portion, Fructus Gardeniae 4 weight portion, Radix Isatidis 15 weight portion, Semen Ziziphi Spinosae 4 weight portion, thin Lotus 1 weight portion, Origanum majorana 1.5 weight portion, vanilla 2 weight portion, Herba Portulacae 3 weight portion is cleaned and is dried, puts into ultra micro together Pulverizer is crushed to 30 mesh, then adds deionized water and soak 5 hours, amount of water by 7 times of immersions crude drug quality, stir Dispersion is mixed well, and prepares Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.18 weight portion and be dried process, i.e. Prepare volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil, be sufficiently stirred for 45 minutes, stands 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, lemon The mass ratio of lemon quintessence oil and grapefruit essential oil is 2:0.5:0.5:0.6:0.4:0.5；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 75 DEG C, concentrates in blender and stirs Mix mixing 15 minutes, obtain premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and change Property aromatic amine curing agent, at 80 DEG C, concentrate grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surface activity Agent 5 weight portion, diethyltoluamide 0.1 weight portion, butyl butyrate 15 weight portion, Eucalyptus oil 7 weight portion, isopropyl myristate 2 weight Part, polyoxyethylenated alcohol sodium sulfate 10 weight portion and sodium benzoate 0.3 weight portion.
Remaining is with embodiment 1.
The test index of Example 1 and Example 2 of the present invention is as follows:
(1) abnormal smells from the patient inspection: sense organ, nonirritant abnormal flavour.
(2) technical performance index, testing result such as table 1:
(3) repelling effect test.
Carry out according to the repelling effect of ordinary lamp and lantern heat radiation coating of the prior art with above-described embodiment 1 and embodiment 2 Contrast test, test data ask for an interview table 2.
Conclusion: Example 1 and Example 2 of the present invention all can play preferable mosquito-repelling function, dissipates with ordinary lamp and lantern on market Hot coating compares, and the present invention has obviously repelling effect.
(4) anionic textiles.
Use anion test instrument, be primarily directed to timber, Ore, ceramic material, negative ion powder are made to relevant The anion quantity that commodity (such as anion medicated clothing, necklace, woollen blanket) etc. are discharged makes measurement.
Test result is shown in Table 3.
Conclusion: the embodiment of the present invention 1, embodiment 2 can be with sustained release negative aeroions, with ordinary lamps of the prior art The heat radiation coating of tool compares, and the present invention has obviously advantage.

Claims (2)

1. the preparation method of an environment protection type flame-retarding led heat radiation coating, it is characterised in that: described heat radiation coating is by following component It is prepared from according to parts by weight: hybrid resin 60-75 weight portion, sodium-based montmorillonite 3-4.5 weight portion, carboxylic styrene butadiene latex 4- 6.5 weight portions, silicones metlyl branching silicone oil 1.5-2 weight portion, Polyethylene Glycol 0.7-1.2 weight portion, pentane 0.7-1.8 weight Amount part, nano silicon 1-2.5 weight portion, polyacrylonitrile-based carbon fibre 7-9 weight portion, Graphene 5-6.5 weight portion, gas phase Silica 1-2 weight portion, fire retardant 5.5-7 weight portion, curing agent 4-6 weight portion, solvent 15-20 weight Part, ceria 0.1-0.15 weight portion, active mineral matter powder 1.5-2 weight portion, essential oil of traditional Chinese medicine 1.5-2.5 weight portion；Wherein, Described hybrid resin be the mass ratio of the mixture of phenolic resin and epoxy resin, phenolic resin and epoxy resin be 2:1-3:1； The a length of 0.01mm of described polyacrylonitrile-based carbon fibre；Described fire retardant is APP, tripolycyanamide and expanded graphites Mixture, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites；Described solvent is two Pyruvic alcohol and the mixture of butyl ester, the mass ratio of described DAA and butyl ester is 3:1-3:2；Described active mineral matter powder is Germanite, fluorite, tourmaline, gahnite by weight the mixture of 2.5:3:3.5:1.7, wherein tourmaline be dravite and Elbaite is by weight the mixture of 4:3, particle diameter≤15 μm of described active mineral matter powder, and described heat radiation coating is by as follows Step is prepared from:
S1, weigh hybrid resin, sodium-based montmorillonite, carboxylic styrene butadiene latex, silicones metlyl branching silicone oil, poly-second two by weight Alcohol, pentane, nano silicon, polyacrylonitrile-based carbon fibre, Graphene, aerosil, fire retardant and solvent are put In blender, mixing well in the stirring of 80 DEG C of next part high speeds, mixing time is 40 minutes, to be mixed uniformly after take from blender Go out, i.e. prepare mixture A, standby；
S2, by material Caulis Vernoniae andersonii 65-85 weight portion, Rhizoma Acori Graminei 15-20 weight portion, Callicarpa nudiflora 4-6 weight portion, Hubei anemone Flower 3-5 weight portion, Cortex Albiziae 3-5 weight portion, Herba Lysimachiae foenum-graeci 1-3 weight portion, Fructus Gardeniae 3-4 weight portion, Radix Salviae Miltiorrhizae 3-4 weight portion, Herba polygoni hydropiperis Grass 3-4 weight portion, Radix Stemonae 5-8 weight portion decontamination, it is placed in vacuum still 2-3 hour of-20 DEG C together, is placed in microwave the most again Drying machine carries out pretreatment, and wherein drying time is 30-40 minute, and microwave power is 17kw；
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With；
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 28MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, dynamic extraction 2 hours, directly exports at separating still Crude oil is collected with triangular flask, standby；
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby；
S6, by Herba Pogostemonis 3-4 weight portion, Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3-4 weight portion, Fructus Gardeniae 3-4 weight portion, Radix Isatidis 15-18 weight portion, Semen Ziziphi Spinosae 3- 4 weight portions, Herba Menthae 1-3 weight portion, Origanum majorana 1.5-2.5 weight portion, vanilla 1.5-2 weight portion, Herba Portulacae 3-4 weight portion Cleaning and dry, put in super micron mill together and be crushed to 30 mesh, then add deionized water and soak 5 hours, amount of water is by being soaked 7 times of bubble crude drug quality, dispersed with stirring is mixed well, and prepares Traditional Chinese drug mixture, standby；
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13-0.2 weight portion and be dried place Reason, i.e. prepares volatile oil C, standby；
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, Fructus Citri Limoniae quintessence oil and grapefruit essential oil, be sufficiently stirred for 45 minutes, stands 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Fructus Tritici aestivi quintessence oil, Geranium Essential, Herba Saussureae Involueratae quintessence oil, lemon The mass ratio of lemon quintessence oil and grapefruit essential oil is 2:0.5:0.5:0.6:0.4:0.5；
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared prepare with step S1, at 70-80 DEG C, concentrates in blender Stirring mixing 15 minutes, obtains premix material, standby；
S10, premix material step S9 prepared put into ball mill, then add ceria, active mineral matter powder and change Property aromatic amine curing agent, at 70-80 DEG C, concentrate grind 4.5 hours, filter decontamination, i.e. obtain heat radiation coating.
The preparation method of a kind of environment protection type flame-retarding led heat radiation coating the most according to claim 1, it is characterised in that: in step Essential oil of traditional Chinese medicine in rapid S8 also includes the component of following weight portion: surfactant 3-5 weight portion, diethyltoluamide 0.1-0.2 weight Part, butyl butyrate 9-15 weight portion, Eucalyptus oil 4-7 weight portion, isopropyl myristate 1-2 weight portion, aliphatic alcohol polyethenoxy Ether sodium sulfate 10-15 weight portion and sodium benzoate 0.1-0.3 weight portion.
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CN105504966A (en) * 2016-02-19 2016-04-20 魏本武 Novel lithographic plate offset printing ink

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JP2009102462A (en) * 2007-10-20 2009-05-14 Nippon Shokubai Co Ltd Heat radiating coated film
CN102649896A (en) * 2012-05-29 2012-08-29 邱璟 Novel high heat conduction and heat dissipation coating and manufacturing method thereof
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