CN106189603A - A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof - Google Patents
A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof Download PDFInfo
- Publication number
- CN106189603A CN106189603A CN201610719737.8A CN201610719737A CN106189603A CN 106189603 A CN106189603 A CN 106189603A CN 201610719737 A CN201610719737 A CN 201610719737A CN 106189603 A CN106189603 A CN 106189603A
- Authority
- CN
- China
- Prior art keywords
- parts
- environment protection
- protection coating
- ethanol extraction
- antibacterial environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof.Preparation method is as follows: (1), by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium dioxide, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1,000 1500 revs/min, and jitter time is 30 60 minutes；(2) above-mentioned slurry is ground to fineness 34 45 microns by grinder；(3) add alcohol ester 12, acrylic emulsion, Dodecyl trimethyl ammonium chloride, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir 40 60 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60 100 minutes are added.This coating uses environment-friendly type formula, has good fire resistance and antibacterial and mouldproof performance.
Description
Technical field
The present invention relates to building coating field, be specifically related to a kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof.
Background technology
Take the way at its surface-coated fireproof coating to carry out flameproof protection, not only can keep original organic synthesis material
The premium properties of material, and economic and practical.Fireproof coating application on organic synthesis material also holds out broad prospects.Additionally,
Common iron is heated to about 540 DEG C and i.e. loses structural strength.Xoncrete structure is the most easily opened under thermal-flame effect
Split disintegrate.Therefore, iron structure and xoncrete structure are carried out flameproof protection, make them can extend when fire occurs and become
The time that shape is destroyed, gain time for fire extinguishing, reduce fire damage, by the attention that people are the biggest.Aqueous fire-proof coating is main
With polymer emulsion as base material.On the one hand polymer to have stronger cementation, the various components in coating can be bonded in
Together, fireproof coating can form firm coating after drying, and the performance of coating is had important impact；On the other hand, coating is met
During fire, as macromolecular material, when decomposing carbonization, its carbide intensity unlike little molecule is much higher.City at present
The common water borne coating sold at mould proof aspect mainly to add the purpose reaching antibacterial in the way of antimildew and antibacterial agent, but this kind of
Antimildew and antibacterial agent has certain toxicity, and next does not reaches the effect of long-term antibacterial.
Summary of the invention
Solve the technical problem that: it is an object of the invention to provide a kind of nanometer fireproof antibacterial environment protection coating, be a kind of ring
Guarantor's type coating, has good fire protecting performance, and the fire resistance period of coating is long；This coating also has permanent biocidal property simultaneously.
Technical scheme: a kind of nanometer fireproof antibacterial environment protection coating, is prepared from by weight by following component: lightweight carbonic acid
Calcium 7-10 part, Pulvis Talci 3-5 part, Gypsum Fibrosum powder 3-5 part, titanium dioxide 15-25 part, ethylene glycol 1.5-2.5 part, softening water 80-120
Part, alcohol ester 12 2-3 part, acrylic emulsion 20-30 part, Dodecyl trimethyl ammonium chloride 0.5-1.5 part, octyl phenol polyoxy
Vinyl Ether 0.1-0.6 part, side primary leaf ethanol extraction 0.5-1.5 part, Herba Lysimachiae ethanol extraction 0.5-1.5 part, hydroxypropyl first
Base cellulose 5-7 part, APP 5-10 part, tripolycyanamide 3-6 part, tetramethylolmethane 2-4 part, ODOPB(10-(2,5-dihydroxy
Phenyl)-9,10-dihydro-9-oxy miscellaneous-10-phosphinylidyne miscellaneous phenanthrene-10 oxide) 3-5 part, nano graphene oxide 5-10 part.
It is further preferred that described a kind of nanometer fireproof antibacterial environment protection coating, following component prepare by weight and
Become: precipitated calcium carbonate 8-9 part, Pulvis Talci 4-5 part, Gypsum Fibrosum powder 4-5 part, titanium dioxide 18-22 part, ethylene glycol 1.8-2.2 part, softening
Water 90-110 part, alcohol ester 12 2.2-2.8 part, acrylic emulsion 22-28 part, Dodecyl trimethyl ammonium chloride 0.8-1.2 part,
Octylphenol polyoxyethylene ether 0.2-0.5 part, side primary leaf ethanol extraction 0.8-1.2 part, Herba Lysimachiae ethanol extraction 0.8-1.2
Part, hydroxypropyl methyl cellulose 6-7 part, APP 5-8 part, tripolycyanamide 3-5 part, tetramethylolmethane 2-3 part, ODOPB 3-4
Part, nano graphene oxide 6-9 part.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating, comprises the following steps:
(1) by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium dioxide, ethylene glycol, softening water, high speed dispersion is uniform, rate of dispersion
For 1000-1500 rev/min, jitter time is 30-60 minute；
(2) above-mentioned slurry is ground to fineness 34-45 micron by grinder；
(3) alcohol ester 12, acrylic emulsion, Dodecyl trimethyl ammonium chloride, Octylphenol polyoxyethylene ether, side primary are added
Leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir 40-60 minute；
(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60-100 are added
Minute.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, dispersion in described step (1)
Speed is 1200-1400 rev/min, and jitter time is 40-55 minute.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, fineness in described step (2)
34-40 micron.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, stirring in described step (3)
Time is 45-55 minute.
Further, the preparation method of described a kind of nanometer fireproof antibacterial environment protection coating, ultrasonic in described step (4)
Ripple shear time is 70-90 minute.
Beneficial effect: the nanometer fireproof antibacterial environment protection coating of the present invention uses environment-friendly type formula, and this coating has very well
Fire protecting performance and antibacterial and mouldproof performance, when coating layer thickness is 7mm, fire resistance period up to 3.7 hours, this nanometer fireproof simultaneously
Antibacterial environment protection coating also has good biocidal property and mildew resistance, and it is 5.2% to colibacillary survival rate, depositing of melanomyces
Motility rate is 6.0%, and through 90 days, colibacillary survival rate was 7.5%, and the survival rate of melanomyces is 7.9%.
Detailed description of the invention
Embodiment 1
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 10 parts, Pulvis Talci
5 parts, Gypsum Fibrosum powder 3 parts, titanium dioxide 25 parts, ethylene glycol 2.5 parts, soften 120 parts of water, alcohol ester 12 parts, acrylic emulsion 20 parts,
Dodecyl trimethyl ammonium chloride 1.5 parts, Octylphenol polyoxyethylene ether 0.6 part, side primary leaf ethanol extraction 1.5 parts, money
Grass ethanol extraction 0.5 part, hydroxypropyl methyl cellulose 7 parts, APP 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts,
ODOPB 3 parts, nano graphene oxide 10 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1000 revs/min, and jitter time is 60 minutes；(2) by upper
State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir
Mix 60 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear are added
100 minutes.
Embodiment 2
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 7 parts, Pulvis Talci 3
Part, Gypsum Fibrosum powder 5 parts, titanium dioxide 15 parts, ethylene glycol 1.5 parts, soften 80 parts of water, alcohol ester 12 parts, acrylic emulsion 30 parts, ten
Dialkyl group trimethyl ammonium chloride 0.5 part, Octylphenol polyoxyethylene ether 0.1 part, side primary leaf ethanol extraction 0.5 part, Herba Lysimachiae
Ethanol extraction 1.5 parts, hydroxypropyl methyl cellulose 7 parts, APP 5 parts, tripolycyanamide 6 parts, tetramethylolmethane 4 parts, ODOPB
5 parts, nano graphene oxide 5 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1500 revs/min, and jitter time is 30 minutes；(2) by upper
State slurry and be ground to fineness 45 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir
Mix 40 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60 are added
Minute.
Embodiment 3
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by following component: precipitated calcium carbonate 9 parts, Pulvis Talci 5
Part, Gypsum Fibrosum powder 4 parts, titanium dioxide 22 parts, ethylene glycol 1.8 parts, soften 90 parts of water, alcohol ester 12 parts, acrylic emulsion 22 parts,
Dodecyl trimethyl ammonium chloride 0.8 part, Octylphenol polyoxyethylene ether 0.5 part, side primary leaf ethanol extraction 1.2 parts, money
Grass ethanol extraction 0.8 part, hydroxypropyl methyl cellulose 6 parts, APP 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts,
ODOPB 3 parts, nano graphene oxide 6 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1400 revs/min, and jitter time is 40 minutes；(2) by upper
State slurry and be ground to fineness 40 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir
Mix 45 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 70 are added
Minute.
Embodiment 4
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by following component: precipitated calcium carbonate 8 parts, Pulvis Talci 4
Part, Gypsum Fibrosum powder 5 parts, titanium dioxide 18 parts, ethylene glycol 2.2 parts, soften 110 parts of water, alcohol ester 12 parts, acrylic emulsion 28 parts,
Dodecyl trimethyl ammonium chloride 1.2 parts, Octylphenol polyoxyethylene ether 0.2 part, side primary leaf ethanol extraction 0.8 part, money
Grass ethanol extraction 1.2 parts, hydroxypropyl methyl cellulose 7 parts, APP 8 parts, tripolycyanamide 5 parts, tetramethylolmethane 3 parts,
ODOPB 4 parts, nano graphene oxide 9 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1200 revs/min, and jitter time is 55 minutes；(2) by upper
State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir
Mix 55 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 90 are added
Minute.
Embodiment 5
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by following component: precipitated calcium carbonate 8 parts, Pulvis Talci 4
Part, Gypsum Fibrosum powder 4 parts, titanium dioxide 20 parts, ethylene glycol 2 parts, soften 105 parts of water, alcohol ester 12 parts, acrylic emulsion 25 parts, ten
Dialkyl group trimethyl ammonium chloride 1 part, Octylphenol polyoxyethylene ether 0.3 part, side primary leaf ethanol extraction 1 part, Herba Lysimachiae ethanol
Extract 1 part, hydroxypropyl methyl cellulose 6 parts, APP 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts, ODOPB 3 parts,
Nano graphene oxide 8 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1400 revs/min, and jitter time is 55 minutes；(2) by upper
State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir
Mix 50 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 80 are added
Minute.
Comparative example 1
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 10 parts, Pulvis Talci
5 parts, Gypsum Fibrosum powder 3 parts, titanium dioxide 25 parts, ethylene glycol 2.5 parts, soften 120 parts of water, alcohol ester 12 parts, acrylic emulsion 20 parts,
Dodecyl trimethyl ammonium chloride 1.5 parts, Octylphenol polyoxyethylene ether 0.6 part, hydroxypropyl methyl cellulose 7 parts, polyphosphoric acid
Ammonium 5 parts, tripolycyanamide 3 parts, tetramethylolmethane 2 parts, ODOPB 3 parts, nano graphene oxide 10 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1000 revs/min, and jitter time is 60 minutes；(2) by upper
State slurry and be ground to fineness 34 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, hydroxypropyl methyl cellulose, stir 60 minutes；(4) add APP, tripolycyanamide,
Tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 100 minutes.
Comparative example 2
A kind of nanometer fireproof antibacterial environment protection coating, is prepared from weight portion by pressing composition: precipitated calcium carbonate 7 parts, Pulvis Talci 3
Part, Gypsum Fibrosum powder 5 parts, titanium dioxide 15 parts, ethylene glycol 1.5 parts, soften 80 parts of water, alcohol ester 12 parts, acrylic emulsion 30 parts, ten
Dialkyl group trimethyl ammonium chloride 0.5 part, Octylphenol polyoxyethylene ether 0.1 part, side primary leaf ethanol extraction 0.5 part, Herba Lysimachiae
Ethanol extraction 1.5 parts, hydroxypropyl methyl cellulose 7 parts, APP 5 parts, tripolycyanamide 6 parts, tetramethylolmethane 4 parts.
The preparation method of above-mentioned nanometer fireproof antibacterial environment protection coating is: (1) is by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium
White lead, ethylene glycol, softening water, high speed dispersion is uniform, and rate of dispersion is 1500 revs/min, and jitter time is 30 minutes；(2) by upper
State slurry and be ground to fineness 45 microns by grinder；(3) alcohol ester 12, acrylic emulsion, trimethyl chlorine are added
Change ammonium, Octylphenol polyoxyethylene ether, side primary leaf ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir
Mix 40 minutes；(4) APP, tripolycyanamide, tetramethylolmethane, ultrasonic shear 60 minutes are added.
The property indices of material of the present invention see table, it may be seen that this nanometer fireproof antibacterial environment protection coating has
Well fire resistance, when coating layer thickness is 7mm, fire resistance period was up to 3.7 hours；This nanometer fireproof antibacterial environment protection coating simultaneously
Also having good biocidal property and mildew resistance, it is 5.2% to colibacillary survival rate, and the survival rate of melanomyces is 6.0%, warp
Spending 90 days, colibacillary survival rate is 7.5%, and the survival rate of melanomyces is 7.9%.
The property indices of table 1 nanometer fireproof antibacterial environment protection coating
Claims (7)
1. a nanometer fireproof antibacterial environment protection coating, it is characterised in that be prepared from by weight by following component: lightweight carbonic acid
Calcium 7-10 part, Pulvis Talci 3-5 part, Gypsum Fibrosum powder 3-5 part, titanium dioxide 15-25 part, ethylene glycol 1.5-2.5 part, softening water 80-120
Part, alcohol ester 12 2-3 part, acrylic emulsion 20-30 part, Dodecyl trimethyl ammonium chloride 0.5-1.5 part, octyl phenol polyoxy
Vinyl Ether 0.1-0.6 part, side primary leaf ethanol extraction 0.5-1.5 part, Herba Lysimachiae ethanol extraction 0.5-1.5 part, hydroxypropyl first
Base cellulose 5-7 part, APP 5-10 part, tripolycyanamide 3-6 part, tetramethylolmethane 2-4 part, ODOPB 3-5 part, nano oxidized
Graphene 5-10 part.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 1, it is characterised in that by following component by weight
Part is prepared from: precipitated calcium carbonate 8-9 part, Pulvis Talci 4-5 part, Gypsum Fibrosum powder 4-5 part, titanium dioxide 18-22 part, ethylene glycol 1.8-
2.2 parts, softening water 90-110 part, alcohol ester 12 2.2-2.8 part, acrylic emulsion 22-28 part, Dodecyl trimethyl ammonium chloride
0.8-1.2 part, Octylphenol polyoxyethylene ether 0.2-0.5 part, side primary leaf ethanol extraction 0.8-1.2 part, Herba Lysimachiae ethanol carry
Take thing 0.8-1.2 part, hydroxypropyl methyl cellulose 6-7 part, APP 5-8 part, tripolycyanamide 3-5 part, tetramethylolmethane 2-3
Part, ODOPB 3-4 part, nano graphene oxide 6-9 part.
3. the preparation method of a nanometer fireproof antibacterial environment protection coating, it is characterised in that comprise the following steps:
(1) by precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum powder, titanium dioxide, ethylene glycol, softening water, high speed dispersion is uniform, rate of dispersion
For 1000-1500 rev/min, jitter time is 30-60 minute；
(2) above-mentioned slurry is ground to fineness 34-45 micron by grinder；
(3) alcohol ester 12, acrylic emulsion, Dodecyl trimethyl ammonium chloride, Octylphenol polyoxyethylene ether, the primary leaf in side are added
Ethanol extraction, Herba Lysimachiae ethanol extraction, hydroxypropyl methyl cellulose, stir 40-60 minute；
(4) adding APP, tripolycyanamide, tetramethylolmethane, ODOPB, nano graphene oxide, ultrasonic shear 60-100 divides
Clock.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, it is characterised in that: described step (1) is divided
Scattered speed is 1200-1400 rev/min, and jitter time is 40-55 minute.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, it is characterised in that: thin in described step (2)
Degree 34-40 micron.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, it is characterised in that: described step is stirred in (3)
The time of mixing is 45-55 minute.
A kind of nanometer fireproof antibacterial environment protection coating the most according to claim 3, described in its feature: described step (4) is ultrasonic
Ripple shear time is 70-90 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610719737.8A CN106189603A (en) | 2016-08-25 | 2016-08-25 | A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610719737.8A CN106189603A (en) | 2016-08-25 | 2016-08-25 | A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189603A true CN106189603A (en) | 2016-12-07 |
Family
ID=57523582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610719737.8A Withdrawn CN106189603A (en) | 2016-08-25 | 2016-08-25 | A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106189603A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163630A (en) * | 2017-06-12 | 2017-09-15 | 成都金玉雄辉建筑工程有限公司 | A kind of environmental protection coating material and preparation method thereof |
| CN107473699A (en) * | 2017-08-22 | 2017-12-15 | 佛山市因诺维生物科技有限公司 | A kind of indoor mildew resistant paint |
| CN108677537A (en) * | 2018-04-28 | 2018-10-19 | 安徽恒益纺织科技有限公司 | A kind of fire retardant, anticorrosive slurry of cotton |
| WO2022133661A1 (en) * | 2020-12-21 | 2022-06-30 | 张辉航 | Ultraviolet-curable white primer for fireproof layer |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10251557A (en) * | 1997-03-12 | 1998-09-22 | Dainippon Ink & Chem Inc | Coating composition and coated metallic steel plate |
| CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
| CN103059516A (en) * | 2013-01-08 | 2013-04-24 | 天津市凯华绝缘材料有限公司 | Fast-cure epoxy powder composition |
| CN104774509A (en) * | 2015-04-22 | 2015-07-15 | 北京碧海舟腐蚀防护工业股份有限公司 | Fireproof paint |
| CN105001743A (en) * | 2015-08-26 | 2015-10-28 | 湖州大周高分子材料有限公司 | Coating special for wall |
| CN105131792A (en) * | 2015-09-30 | 2015-12-09 | 高碑店市安普特种防火材料制造有限公司 | Intumescent type multifunctional fire retardant coating containing nano-graphite sheets |
| CN105199462A (en) * | 2015-10-28 | 2015-12-30 | 漳州三德利油漆涂料有限公司 | Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof |
| CN105544306A (en) * | 2015-11-26 | 2016-05-04 | 张建刚 | Making method of graphene oxide-containing antibiosis and mildew prevention wallpaper |
-
2016
- 2016-08-25 CN CN201610719737.8A patent/CN106189603A/en not_active Withdrawn
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10251557A (en) * | 1997-03-12 | 1998-09-22 | Dainippon Ink & Chem Inc | Coating composition and coated metallic steel plate |
| CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
| CN103059516A (en) * | 2013-01-08 | 2013-04-24 | 天津市凯华绝缘材料有限公司 | Fast-cure epoxy powder composition |
| CN104774509A (en) * | 2015-04-22 | 2015-07-15 | 北京碧海舟腐蚀防护工业股份有限公司 | Fireproof paint |
| CN105001743A (en) * | 2015-08-26 | 2015-10-28 | 湖州大周高分子材料有限公司 | Coating special for wall |
| CN105131792A (en) * | 2015-09-30 | 2015-12-09 | 高碑店市安普特种防火材料制造有限公司 | Intumescent type multifunctional fire retardant coating containing nano-graphite sheets |
| CN105199462A (en) * | 2015-10-28 | 2015-12-30 | 漳州三德利油漆涂料有限公司 | Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof |
| CN105544306A (en) * | 2015-11-26 | 2016-05-04 | 张建刚 | Making method of graphene oxide-containing antibiosis and mildew prevention wallpaper |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163630A (en) * | 2017-06-12 | 2017-09-15 | 成都金玉雄辉建筑工程有限公司 | A kind of environmental protection coating material and preparation method thereof |
| CN107473699A (en) * | 2017-08-22 | 2017-12-15 | 佛山市因诺维生物科技有限公司 | A kind of indoor mildew resistant paint |
| CN108677537A (en) * | 2018-04-28 | 2018-10-19 | 安徽恒益纺织科技有限公司 | A kind of fire retardant, anticorrosive slurry of cotton |
| WO2022133661A1 (en) * | 2020-12-21 | 2022-06-30 | 张辉航 | Ultraviolet-curable white primer for fireproof layer |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106189603A (en) | A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof | |
| CN103289453B (en) | Anti-bacteria deodorizing inorganic functional coating and preparation method thereof | |
| CN101914329B (en) | Nano multifunctional outer wall heat preservation coating | |
| CN103965780B (en) | A kind of woodenware lacquer tree fat coating and preparation method thereof | |
| CN103088634B (en) | Spirocyclic phosphate expansive type low-smoke coating flame retardance cellulose textile and preparation method thereof | |
| CN105694550A (en) | Single-component waterborne inorganic terrace paint formula and manufacturing technology | |
| CN111154364A (en) | Interior wall water paint and preparation method thereof | |
| CN109294347A (en) | A kind of Gao Baose water paint and production method | |
| TW200740697A (en) | Yttrium oxide composition, method of preparing the same, and method of forming yttrium oxide layer using the same | |
| CN109096920A (en) | A kind of exterior wall alkali-resistant primer and preparation method thereof | |
| CN101343447B (en) | Composite exterior wall paint of inorganic polysiloxane and emulsion, and preparation thereof | |
| CN104858969A (en) | Environmental protection wood flame retardation antiseptic | |
| CN105482587A (en) | Environment-friendly water-based nano-structure wood paint and preparation method thereof | |
| CN104927616A (en) | Ultrathin steel-structure fireproof water paint and preparation method thereof | |
| CN108707405A (en) | A method of addition modified nano oxide compound prepares wood artwork antibacterial and mouldproof abrasion resistant fire blocking coating | |
| CN108456466A (en) | A kind of high performance nano paint and preparation method thereof | |
| CN101633812A (en) | Flexible texture coating and preparation method thereof | |
| CN102911570B (en) | Environmental-friendly decorative fire retardant coating and preparation method thereof | |
| CN104910738A (en) | Art texture water paint and preparation method thereof | |
| CN109233641A (en) | The aqueous colorful building coating and preparation method thereof of super resistance to wiping spot-resistant | |
| CN104858970A (en) | Multi-function wood modifier and preparation method thereof | |
| CN103351746A (en) | Preparation method of antibacterial environmentally-friendly interior wall coating | |
| CN106986606A (en) | It is a kind of for the waterproof ceramic coating on cement matrix surface and preparation method thereof | |
| CN105440852A (en) | Granite-imitating rock chip paint and preparation method thereof | |
| CN105860688A (en) | Finishing fire-retardant paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20161207 |
|
| WW01 | Invention patent application withdrawn after publication |