CN105001743A - Coating special for wall - Google Patents

Coating special for wall Download PDF

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Publication number
CN105001743A
CN105001743A CN201510529976.2A CN201510529976A CN105001743A CN 105001743 A CN105001743 A CN 105001743A CN 201510529976 A CN201510529976 A CN 201510529976A CN 105001743 A CN105001743 A CN 105001743A
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CN
China
Prior art keywords
parts
wall
coating
tailor
antiseptic
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CN201510529976.2A
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Chinese (zh)
Inventor
龚重勇
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Huzhou Great Zhou Macromolecular Material Co Ltd
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Huzhou Great Zhou Macromolecular Material Co Ltd
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Priority to CN201510529976.2A priority Critical patent/CN105001743A/en
Publication of CN105001743A publication Critical patent/CN105001743A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a coating special for a wall, and the coating special for the wall comprises the following components in parts by weight: 80 to 120 parts of silicone acrylic emulsion, 60 to 80 parts of bentonite, 40 to 60 parts of sepiolite, 40 to 60 parts of titanium dioxide, 10 to 15 parts of sodium hexametaphosphate, 5 to 10 parts of methyl silicone oil, 5 to 10 parts of coalescing agents, 10 to 20 parts of light calcium carbonate, 1 to 5 parts of antibacterial agent, 1 to 5 parts of flame retardant and 250 to 350 parts of deionized water. The coating special for the wall has the characteristics of good synergistic effect among the components, rapid dry/wet curing, high bonding strength, short film-forming and drying time and good flintiness, especially the antibacterial agent is used, the coating special for the wall is green for environmental protection. The coating special for the wall has a good antibacterial effect; oxidized petroleum wax, pentaerythritol and ammonium phosphate are compounded for use to insure that the fireproof performance of the coating can reach the national primary standard of decorated fire retardant coating, and the safety of use is improved.

Description

A kind of body of wall tailor-(made) coating
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of body of wall tailor-(made) coating.
Background technology
Along with development and the growth in the living standard of society, cause global environment to go from bad to worse, and then the awareness of environment protection and health of people strengthens gradually, to the comfort level of living environment and security requirement more and more higher.And in people's living environment, the use of coating is essential, the performance of coating plays vital effect to living environment; therefore; the requirement of people to coating is also more and more higher, especially wishes to obtain the functional coating with multiple performance, in building coating field; environment protection and safety problem are inevitably more and more paid attention to; therefore, various body of wall tailor-(made) coating arises at the historic moment, existing coating for wall surface; function ratio is more single, cannot meet the requirement of user.
Summary of the invention
For the defect existed in prior art, the object of this invention is to provide a kind of body of wall tailor-(made) coating.
Described a kind of body of wall tailor-(made) coating, is characterized in that being made up of the component of following weight part: organosilicon crylic acid latex 80-120 part, wilkinite 60-80 part, sepiolite 40-60 part, titanium dioxide 40-60 part, Sodium hexametaphosphate 99 10-15 part, methyl-silicone oil 5-10 part, film coalescence aid 5-10 part, light calcium carbonate 10-20 part, antiseptic-germicide 1-5 part, fire retardant 1-5 part, deionized water 250-350 part.
Described a kind of body of wall tailor-(made) coating, is characterized in that being made up of the component of following weight part: organosilicon crylic acid latex 100-110 part, wilkinite 65-75 part, sepiolite 50-60 part, titanium dioxide 40-50 part, Sodium hexametaphosphate 99 12-14 part, methyl-silicone oil 6-8 part, film coalescence aid 6-8 part, light calcium carbonate 12-16 part, antiseptic-germicide 2-4 part, fire retardant 2-4 part, deionized water 300-350 part.
Described a kind of body of wall tailor-(made) coating, is characterized in that being made up of the component of following weight part: organosilicon crylic acid latex 105 parts, wilkinite 70 parts, sepiolite 55 parts, titanium dioxide 45 parts, Sodium hexametaphosphate 99 13 parts, methyl-silicone oil 7 parts, film coalescence aid 7 parts, light calcium carbonate 14 parts, antiseptic-germicide 3 parts, fire retardant 3 parts, deionized water 330 parts.
Described a kind of body of wall tailor-(made) coating, is characterized in that described antiseptic-germicide is that inorganic antiseptic and natural antibacterial agent mix with the weight of 2:1.
Described a kind of body of wall tailor-(made) coating, is characterized in that described inorganic antiseptic is the mixture of silver-colored calcium phosphate and silver zirconium phosphate, described silver-colored calcium phosphate: the weight ratio of silver zirconium phosphate is 1:1.
Described a kind of body of wall tailor-(made) coating, it is characterized in that described natural antibacterial agent is plant milk extract, described plant milk extract is the alcohol extract that Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish mix by the weight ratio of 1:1:0.5:0.5.
Described a kind of body of wall tailor-(made) coating, is characterized in that described fire retardant is the mixture of ammonium phosphate salt, tetramethylolmethane and oxidized petroleum wax, described ammonium phosphate salt: tetramethylolmethane: the weight ratio of oxidized petroleum wax is 9:3:7.
Described a kind of body of wall tailor-(made) coating, is characterized in that described plant milk extract adopts following methods preparation:
1) after Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish being cleaned up, dry respectively to water content be 20-40%;
2) get each raw material of formula ratio after step 1) process, pulverize after mixing, cross 60 mesh sieves, obtain mixed powder;
3) by solid-liquid ratio 1:10(g/mL) in mixed powder, add 95% ethanol, 95 DEG C of backflow extracting 3h, obtain extracting solution;
4) extracting solution filter paper filtration under diminished pressure, obtains a filtered solution, adds 95% ethanol with step (2) same volume in filter residue, by filter cleaner after upper method backflow extracting 2h, obtains secondary filtered solution; Filter residue always adds the ethanol of 95% of same volume, by filter cleaner after upper method extracting 2h, obtains three filtered solutions;
5) merge three filtered solutions, use Rotary Evaporators 35rpm, 60 DEG C of concentrated by rotary evaporations, to dry, obtain plant milk extract.
Synergistic effect between each composition of the present invention is good, has the features such as wet dry quick solidifying, cohesive strength is high, film forming is short for time of drying, and flintiness is good, the especially use of antiseptic-germicide, environmental protection.Good anti-bacterial effect; The composite use of oxidized petroleum wax, tetramethylolmethane and ammonium phosphate salt, guarantees that the fire resistance of coating reaches national finishing fire retardant paint primary standard, improves the security used.
Embodiment
The present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
A kind of body of wall tailor-(made) coating, is made up of the component of following weight part: organosilicon crylic acid latex 105 parts, wilkinite 70 parts, sepiolite 55 parts, titanium dioxide 45 parts, Sodium hexametaphosphate 99 13 parts, methyl-silicone oil 7 parts, film coalescence aid 7 parts, light calcium carbonate 14 parts, antiseptic-germicide 3 parts, fire retardant 3 parts, deionized water 330 parts.
Wherein, fire retardant is the mixture of ammonium phosphate salt, tetramethylolmethane and oxidized petroleum wax, ammonium phosphate salt: tetramethylolmethane: the weight ratio of oxidized petroleum wax is 9:3:7.
Antiseptic-germicide is that inorganic antiseptic and natural antibacterial agent mix with the weight of 2:1, inorganic antiseptic is that silver-colored calcium phosphate and silver zirconium phosphate mix by the weight ratio of 1:1, natural antibacterial agent is plant milk extract, and plant milk extract is the alcohol extract that Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish mix by the weight ratio of 1:1:0.5:0.5.Plant milk extract adopt following methods preparation: after 1) Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish being cleaned up, dry respectively to water content be 20-40%; 2) get each raw material of formula ratio after step 1) process, pulverize after mixing, cross 60 mesh sieves, obtain mixed powder; 3) by solid-liquid ratio 1:10(g/mL) in mixed powder, add 95% ethanol, 95 DEG C of backflow extracting 3h, obtain extracting solution; 4) extracting solution filter paper filtration under diminished pressure, obtains a filtered solution, adds 95% ethanol with step (2) same volume in filter residue, by filter cleaner after upper method backflow extracting 2h, obtains secondary filtered solution; Filter residue always adds the ethanol of 95% of same volume, by filter cleaner after upper method extracting 2h, obtains three filtered solutions; 5) merge three filtered solutions, use Rotary Evaporators 35rpm, 60 DEG C of concentrated by rotary evaporations, to dry, obtain plant milk extract.
Embodiment 2
A kind of body of wall tailor-(made) coating, is made up of the component of following weight part: organosilicon crylic acid latex 80 parts, wilkinite 80 parts, sepiolite 40 parts, titanium dioxide 60 parts, Sodium hexametaphosphate 99 10 parts, methyl-silicone oil 10 parts, film coalescence aid 5 parts, light calcium carbonate 20 parts, antiseptic-germicide 1 part, fire retardant 5 parts, deionized water 250 parts.
Wherein, fire retardant is the mixture of ammonium phosphate salt, tetramethylolmethane and oxidized petroleum wax, ammonium phosphate salt: tetramethylolmethane: the weight ratio of oxidized petroleum wax is 9:3:7.
Antiseptic-germicide is that inorganic antiseptic and natural antibacterial agent mix with the weight of 2:1, inorganic antiseptic is that silver-colored calcium phosphate and silver zirconium phosphate mix by the weight ratio of 1:1, natural antibacterial agent is plant milk extract, and plant milk extract is the alcohol extract that Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish mix by the weight ratio of 1:1:0.5:0.5.Plant milk extract adopt following methods preparation: after 1) Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish being cleaned up, dry respectively to water content be 20-40%; 2) get each raw material of formula ratio after step 1) process, pulverize after mixing, cross 60 mesh sieves, obtain mixed powder; 3) by solid-liquid ratio 1:10(g/mL) in mixed powder, add 95% ethanol, 95 DEG C of backflow extracting 3h, obtain extracting solution; 4) extracting solution filter paper filtration under diminished pressure, obtains a filtered solution, adds 95% ethanol with step (2) same volume in filter residue, by filter cleaner after upper method backflow extracting 2h, obtains secondary filtered solution; Filter residue always adds the ethanol of 95% of same volume, by filter cleaner after upper method extracting 2h, obtains three filtered solutions; 5) merge three filtered solutions, use Rotary Evaporators 35rpm, 60 DEG C of concentrated by rotary evaporations, to dry, obtain plant milk extract.
Embodiment 3
A kind of body of wall tailor-(made) coating, is made up of the component of following weight part: organosilicon crylic acid latex 110 parts, wilkinite 65 parts, sepiolite 60 parts, titanium dioxide 40 parts, Sodium hexametaphosphate 99 14 parts, methyl-silicone oil 6 parts, film coalescence aid 8 parts, light calcium carbonate 12 parts, antiseptic-germicide 4 parts, fire retardant 2 parts, deionized water 350 parts.
Wherein, fire retardant is the mixture of ammonium phosphate salt, tetramethylolmethane and oxidized petroleum wax, ammonium phosphate salt: tetramethylolmethane: the weight ratio of oxidized petroleum wax is 9:3:7.
Antiseptic-germicide is that inorganic antiseptic and natural antibacterial agent mix with the weight of 2:1, inorganic antiseptic is that silver-colored calcium phosphate and silver zirconium phosphate mix by the weight ratio of 1:1, natural antibacterial agent is plant milk extract, and plant milk extract is the alcohol extract that Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish mix by the weight ratio of 1:1:0.5:0.5.Plant milk extract adopt following methods preparation: after 1) Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish being cleaned up, dry respectively to water content be 20-40%; 2) get each raw material of formula ratio after step 1) process, pulverize after mixing, cross 60 mesh sieves, obtain mixed powder; 3) by solid-liquid ratio 1:10(g/mL) in mixed powder, add 95% ethanol, 95 DEG C of backflow extracting 3h, obtain extracting solution; 4) extracting solution filter paper filtration under diminished pressure, obtains a filtered solution, adds 95% ethanol with step (2) same volume in filter residue, by filter cleaner after upper method backflow extracting 2h, obtains secondary filtered solution; Filter residue always adds the ethanol of 95% of same volume, by filter cleaner after upper method extracting 2h, obtains three filtered solutions; 5) merge three filtered solutions, use Rotary Evaporators 35rpm, 60 DEG C of concentrated by rotary evaporations, to dry, obtain plant milk extract.
Embodiment 4
Formulation for coating material is with embodiment 1, and difference is, fire retardant is the mixture of ammonium phosphate salt, tetramethylolmethane and oxidized petroleum wax, ammonium phosphate salt: tetramethylolmethane: the weight ratio of oxidized petroleum wax is 9:3:4.
Antiseptic-germicide is that inorganic antiseptic and natural antibacterial agent mix with the weight of 2:1, inorganic antiseptic is that silver-colored calcium phosphate and silver zirconium phosphate mix by the weight ratio of 1:1, natural antibacterial agent is plant milk extract, and plant milk extract is the alcohol extract that Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish mix by the weight ratio of 1:1:1:1.
Performance test
Test the VOC content of above-mentioned coating according to GB18582-2008, test the sticking power of above-mentioned coating, time of drying and impact resistance according to GB1720, GB1728, GB1732, the results are shown in Table 1.
Table 1 performance test
Sterilant is tested: Chaetomium globosum bacterium, Aspergillus flavus are spread evenly across and scribble on the slide glass of above-mentioned coating, after 0,5,15,30,60,120 hour, be gently stained with bacterium liquid by swab stick is placed in physiological saline, vibration, get 0.5ml in culture dish, add substratum, cultivate 48 hours in incubator, take out number colony number, according to formulae discovery sterilizing rate: sterilizing rate=(after initial colony number-sterilization colony number)/initial colony number × 100%, the results are shown in Table 2.
Table 2 sterilization is tested
As can be seen from table 1 and table 2, coating antibiosis performance of the present invention is good, environmental protection, solidification are quick, has excellent flame retardant properties, is applicable to applying.
Coating embodiment 1-embodiment 4 prepared detects by GB15442.1-1995 " classification of finishing fire retardant paint fire resistance and the classification of test method fire resistance ", and detected result is in table 3 and table 4.
Table 3
Table 4

Claims (8)

1. a body of wall tailor-(made) coating, is characterized in that being made up of the component of following weight part: organosilicon crylic acid latex 80-120 part, wilkinite 60-80 part, sepiolite 40-60 part, titanium dioxide 40-60 part, Sodium hexametaphosphate 99 10-15 part, methyl-silicone oil 5-10 part, film coalescence aid 5-10 part, light calcium carbonate 10-20 part, antiseptic-germicide 1-5 part, fire retardant 1-5 part, deionized water 250-350 part.
2. a kind of body of wall tailor-(made) coating according to claim 1, is characterized in that being made up of the component of following weight part: organosilicon crylic acid latex 100-110 part, wilkinite 65-75 part, sepiolite 50-60 part, titanium dioxide 40-50 part, Sodium hexametaphosphate 99 12-14 part, methyl-silicone oil 6-8 part, film coalescence aid 6-8 part, light calcium carbonate 12-16 part, antiseptic-germicide 2-4 part, fire retardant 2-4 part, deionized water 300-350 part.
3. a kind of body of wall tailor-(made) coating according to claim 1, is characterized in that being made up of the component of following weight part: organosilicon crylic acid latex 105 parts, wilkinite 70 parts, sepiolite 55 parts, titanium dioxide 45 parts, Sodium hexametaphosphate 99 13 parts, methyl-silicone oil 7 parts, film coalescence aid 7 parts, light calcium carbonate 14 parts, antiseptic-germicide 3 parts, fire retardant 3 parts, deionized water 330 parts.
4. a kind of body of wall tailor-(made) coating according to claim 1 or 2 or 3, is characterized in that described antiseptic-germicide is that inorganic antiseptic and natural antibacterial agent mix with the weight of 2:1.
5. a kind of body of wall tailor-(made) coating according to claim 4, is characterized in that described inorganic antiseptic is the mixture of silver-colored calcium phosphate and silver zirconium phosphate, described silver-colored calcium phosphate: the weight ratio of silver zirconium phosphate is 1:1.
6. a kind of body of wall tailor-(made) coating according to claim 4, it is characterized in that described natural antibacterial agent is plant milk extract, described plant milk extract is the alcohol extract that Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish mix by the weight ratio of 1:1:0.5:0.5.
7. a kind of body of wall tailor-(made) coating according to claim 1 or 2 or 3, is characterized in that described fire retardant is the mixture of ammonium phosphate salt, tetramethylolmethane and oxidized petroleum wax, described ammonium phosphate salt: tetramethylolmethane: the weight ratio of oxidized petroleum wax is 9:3:7.
8. a kind of body of wall tailor-(made) coating according to claim 6, is characterized in that described plant milk extract adopts following methods preparation:
1) after Ginkgo Leaf, the bletilla striata, Meng Zongzhu and horseradish being cleaned up, dry respectively to water content be 20-40%;
2) get each raw material of formula ratio after step 1) process, pulverize after mixing, cross 60 mesh sieves, obtain mixed powder;
3) by solid-liquid ratio 1:10(g/mL) in mixed powder, add 95% ethanol, 95 DEG C of backflow extracting 3h, obtain extracting solution;
4) extracting solution filter paper filtration under diminished pressure, obtains a filtered solution, adds 95% ethanol with step (2) same volume in filter residue, by filter cleaner after upper method backflow extracting 2h, obtains secondary filtered solution; Filter residue always adds the ethanol of 95% of same volume, by filter cleaner after upper method extracting 2h, obtains three filtered solutions;
5) merge three filtered solutions, use Rotary Evaporators 35rpm, 60 DEG C of concentrated by rotary evaporations, to dry, obtain plant milk extract.
CN201510529976.2A 2015-08-26 2015-08-26 Coating special for wall Pending CN105001743A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105368364A (en) * 2015-11-23 2016-03-02 苏州盖德精细材料有限公司 Method for preparing antibacterial epoxy resin pouring sealant
CN106189603A (en) * 2016-08-25 2016-12-07 代长华 A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof

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CN103113801A (en) * 2012-12-26 2013-05-22 青岛科瑞新型环保材料有限公司 Multifunctional environment-friendly interior wall paint
CN103351824A (en) * 2013-06-29 2013-10-16 青岛共好检测技术有限公司 Energy-saving environment-friendly anti-fouling paint
CN104017445A (en) * 2014-06-06 2014-09-03 湖州百胜涂料有限公司 Water-based coating
CN104031510A (en) * 2014-06-27 2014-09-10 无锡市崇安区科技创业服务中心 Building external wall bactericidal paint and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN102911566A (en) * 2012-10-26 2013-02-06 清远市普塞呋磷化学有限公司 Waterproof efficient intumescent fire retardant coating
CN103113801A (en) * 2012-12-26 2013-05-22 青岛科瑞新型环保材料有限公司 Multifunctional environment-friendly interior wall paint
CN103351824A (en) * 2013-06-29 2013-10-16 青岛共好检测技术有限公司 Energy-saving environment-friendly anti-fouling paint
CN104017445A (en) * 2014-06-06 2014-09-03 湖州百胜涂料有限公司 Water-based coating
CN104031510A (en) * 2014-06-27 2014-09-10 无锡市崇安区科技创业服务中心 Building external wall bactericidal paint and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105368364A (en) * 2015-11-23 2016-03-02 苏州盖德精细材料有限公司 Method for preparing antibacterial epoxy resin pouring sealant
CN106189603A (en) * 2016-08-25 2016-12-07 代长华 A kind of nanometer fireproof antibacterial environment protection coating and preparation method thereof

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Application publication date: 20151028