CN104858969A - Environmental protection wood flame retardation antiseptic - Google Patents
Environmental protection wood flame retardation antiseptic Download PDFInfo
- Publication number
- CN104858969A CN104858969A CN201410796171.XA CN201410796171A CN104858969A CN 104858969 A CN104858969 A CN 104858969A CN 201410796171 A CN201410796171 A CN 201410796171A CN 104858969 A CN104858969 A CN 104858969A
- Authority
- CN
- China
- Prior art keywords
- ammonium chloride
- flame retardation
- antiseptic
- wood
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002023 wood Substances 0.000 title claims abstract description 17
- 230000007613 environmental effect Effects 0.000 title abstract description 6
- 230000002421 anti-septic effect Effects 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- LWFBRHSTNWMMGN-UHFFFAOYSA-N 4-phenylpyrrolidin-1-ium-2-carboxylic acid;chloride Chemical compound Cl.C1NC(C(=O)O)CC1C1=CC=CC=C1 LWFBRHSTNWMMGN-UHFFFAOYSA-N 0.000 claims abstract description 8
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 8
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 8
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 8
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 8
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 claims abstract description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims abstract description 8
- 235000019838 diammonium phosphate Nutrition 0.000 claims abstract description 8
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 claims abstract description 8
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003755 preservative agent Substances 0.000 claims description 13
- 230000002335 preservative effect Effects 0.000 claims description 13
- BFDDMZKDAIOGFP-UHFFFAOYSA-N n,n-dimethyloctan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCC[NH+](C)C BFDDMZKDAIOGFP-UHFFFAOYSA-N 0.000 claims description 7
- -1 oxine ketone Chemical class 0.000 claims description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000779 smoke Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 abstract 1
- JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical compound CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005696 Diammonium phosphate Substances 0.000 abstract 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 229960003540 oxyquinoline Drugs 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 abstract 1
- 150000004685 tetrahydrates Chemical class 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses an environmental protection wood flame retardation antiseptic. The flame retardation antiseptic comprises the following ingredients, by weight, 15%-20% of guanylurea phosphate, 4%-6% of zinc borate, 8%-12% of diammonium phosphate, 6%-10% of nanometer titanium dioxide, 1%-4% of ammonium molybdate, 6%-9% of cupric dimethyldithio carbamate, 4%-8% of disodium octoborate tetrahydrate, 1%-3% of dioctyl dimethyl ammonium chloride, 1%-3% of tetradecyl benzyl dimethyl ammonium chloride, 1%-3% of 8-hydroxyquinoline, 0.5%-2% of fatty alcohol polyoxyethylene ether and 20%-50% of water. The beneficial effects are that the flame retardation antiseptic has advantages of high efficiency, no poison and meeting environmental protection requirements, and has advantages of excellent flame retardation smoke inhibition performances, broad-spectrum sterilization and insecticidal effects, excellent anticorrosion and mildew-resistant effects and the like for processing wood. The permeability is good, the leaching resistance is strong and the cost is low.
Description
Technical field
The present invention relates to Wooden modifying processing technology field, specifically a kind of environment-friendly type fire-retarding preservative for wood.
Background technology
Timber is a kind of natural organic, has obvious biological nature, easily by biological attack such as bacterium, worm, the raw boring in sea worms, and easy firing, easily moisture absorption, this will have impact on its effect and application greatly.Along with the raising of people's living standard, the demand of timber is also increased day by day.Making full use of existing timber resources, walk Sustainable Development Road, is the only way of China's timber industry development.Carrying out the process such as anticorrosion, fire-retardant to timber, is promote normal timber life, prevent fire, save one of timber and important channel of protecting forest resources.The timber that China uses at present after fire retardant, anticorrosive process is little, and mostly uses the mankind and the large traditional wood treatment agent of environmental hazard, and therefore a kind of efficient, environment-friendly type fire-retarding preservative for wood of Study and Development is very necessary.
Summary of the invention
The object of the present invention is to provide the environment-friendly type fire-retarding preservative for wood that a kind of flame-retardant smoke inhibition, anticorrosion, mildew-resistant, insect protected and the feature of environmental protection are good.
The technical solution adopted for the present invention to solve the technical problems is: a kind of environment-friendly type fire-retarding preservative for wood, and its component by mass percent proportioning is: guanylurea phosphate 15% ~ 20%, Firebrake ZB 4% ~ 6%, diammonium hydrogen phosphate 8% ~ 12%, nano titanium oxide 6% ~ 10%, ammonium molybdate 1% ~ 4%, cupric dimethyldithio carbamate 6% ~ 9%, four water eight Boratex 4% ~ 8%, two octyldimethyl ammonium chloride 1% ~ 3%, myristyl benzyl dimethyl ammonium chloride 1% ~ 3%, oxine ketone 1% ~ 3%, AEO 0.5% ~ 2%, water 20% ~ 50%.
The preparation method of above-mentioned a kind of environment-friendly type fire-retarding preservative for wood, comprises the following steps:
(1), each component is taken by weight ratio;
(2), guanylurea phosphate, Firebrake ZB, diammonium hydrogen phosphate, nano titanium oxide are added in agitator, mixed on low speed 1 ~ 3min, then AEO is added, high-speed stirred 15 ~ 30min, add water again, stirring at low speed 10 ~ 15min, then ammonium molybdate, cupric dimethyldithio carbamate, four water eight Boratexes, two octyldimethyl ammonium chloride, myristyl benzyl dimethyl ammonium chloride, oxine ketone is added, continue stirring 20 ~ 30min, obtain a kind of environment-friendly type fire-retarding preservative for wood of the present invention.
The invention has the beneficial effects as follows, the present invention has efficient, nontoxic and meets environmental requirement, and has the excellent advantage such as flame retarding and smoke suppressing properties, the sterilization and disinsection effect of wide spectrum, excellent anticorrosive mildewproof effect to process timber, and good penetrability, resistance leachability is strong, and cost is low.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below in conjunction with concrete preferred embodiment.
Embodiment 1:
A kind of environment-friendly type fire-retarding preservative for wood, its component by mass percent proportioning is: guanylurea phosphate 20%, Firebrake ZB 6%, diammonium hydrogen phosphate 12%, nano titanium oxide 10%, ammonium molybdate 4%, cupric dimethyldithio carbamate 9%, four water eight Boratex 8%, two octyldimethyl ammonium chloride 3%, myristyl benzyl dimethyl ammonium chloride 3%, oxine ketone 3%, AEO 2%, water 20%.
Preparation method: (1), take each component by weight ratio; (2), guanylurea phosphate, Firebrake ZB, diammonium hydrogen phosphate, nano titanium oxide are added in agitator, mixed on low speed 1 ~ 3min, then AEO is added, high-speed stirred 15 ~ 30min, add water again, stirring at low speed 10 ~ 15min, then ammonium molybdate, cupric dimethyldithio carbamate, four water eight Boratexes, two octyldimethyl ammonium chloride, myristyl benzyl dimethyl ammonium chloride, oxine ketone is added, continue stirring 20 ~ 30min, obtain a kind of environment-friendly type fire-retarding preservative for wood of the present invention.
Embodiment 2:
A kind of environment-friendly type fire-retarding preservative for wood, its component by mass percent proportioning is: guanylurea phosphate 15%, Firebrake ZB 4%, diammonium hydrogen phosphate 8%, nano titanium oxide 6%, ammonium molybdate 2%, cupric dimethyldithio carbamate 6%, four water eight Boratex 4%, two octyldimethyl ammonium chloride 2%, myristyl benzyl dimethyl ammonium chloride 1%, oxine ketone 1%, AEO 1%, water 50%.
Preparation method is with embodiment 1.
Claims (2)
1. an environment-friendly type fire-retarding preservative for wood, it is characterized in that, its component by mass percent proportioning is: guanylurea phosphate 15% ~ 20%, Firebrake ZB 4% ~ 6%, diammonium hydrogen phosphate 8% ~ 12%, nano titanium oxide 6% ~ 10%, ammonium molybdate 1% ~ 4%, cupric dimethyldithio carbamate 6% ~ 9%, four water eight Boratex 4% ~ 8%, two octyldimethyl ammonium chloride 1% ~ 3%, myristyl benzyl dimethyl ammonium chloride 1% ~ 3%, oxine ketone 1% ~ 3%, AEO 0.5% ~ 2%, water 20% ~ 50%.
2. the preparation method of a kind of environment-friendly type fire-retarding preservative for wood according to claim 1, is characterized in that, comprise the following steps:
(1), each component is taken by weight ratio;
(2), guanylurea phosphate, Firebrake ZB, diammonium hydrogen phosphate, nano titanium oxide are added in agitator, mixed on low speed 1 ~ 3min, then AEO is added, high-speed stirred 15 ~ 30min, add water again, stirring at low speed 10 ~ 15min, then ammonium molybdate, cupric dimethyldithio carbamate, four water eight Boratexes, two octyldimethyl ammonium chloride, myristyl benzyl dimethyl ammonium chloride, oxine ketone is added, continue stirring 20 ~ 30min, obtain a kind of environment-friendly type fire-retarding preservative for wood of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410796171.XA CN104858969A (en) | 2014-12-22 | 2014-12-22 | Environmental protection wood flame retardation antiseptic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410796171.XA CN104858969A (en) | 2014-12-22 | 2014-12-22 | Environmental protection wood flame retardation antiseptic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104858969A true CN104858969A (en) | 2015-08-26 |
Family
ID=53905348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410796171.XA Pending CN104858969A (en) | 2014-12-22 | 2014-12-22 | Environmental protection wood flame retardation antiseptic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104858969A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106363742A (en) * | 2016-10-26 | 2017-02-01 | 广西大学 | Sterilization and smoke suppression halogen-free wood fire retardant |
| CN108544615A (en) * | 2018-04-23 | 2018-09-18 | 浙江粤强家具科技有限公司 | A kind of impregnating fluid for Chinese fir board |
| CN108608550A (en) * | 2018-05-03 | 2018-10-02 | 李建州 | A kind of agricultural crop straw anti-corrosive antibacterial flame retardant fibre board and preparation method thereof |
| CN108748525A (en) * | 2018-06-15 | 2018-11-06 | 广西壮族自治区林业科学研究院 | A kind of the Compositional type copper compound preservative and anti-corrosion method of Masson pine timber |
| CN110883897A (en) * | 2019-11-05 | 2020-03-17 | 李珂 | Anti-corrosion shaving board and manufacturing process thereof |
-
2014
- 2014-12-22 CN CN201410796171.XA patent/CN104858969A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106363742A (en) * | 2016-10-26 | 2017-02-01 | 广西大学 | Sterilization and smoke suppression halogen-free wood fire retardant |
| CN108544615A (en) * | 2018-04-23 | 2018-09-18 | 浙江粤强家具科技有限公司 | A kind of impregnating fluid for Chinese fir board |
| CN108608550A (en) * | 2018-05-03 | 2018-10-02 | 李建州 | A kind of agricultural crop straw anti-corrosive antibacterial flame retardant fibre board and preparation method thereof |
| CN108748525A (en) * | 2018-06-15 | 2018-11-06 | 广西壮族自治区林业科学研究院 | A kind of the Compositional type copper compound preservative and anti-corrosion method of Masson pine timber |
| CN110883897A (en) * | 2019-11-05 | 2020-03-17 | 李珂 | Anti-corrosion shaving board and manufacturing process thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150826 |