CN106363742A - Sterilization and smoke suppression halogen-free wood fire retardant - Google Patents
Sterilization and smoke suppression halogen-free wood fire retardant Download PDFInfo
- Publication number
- CN106363742A CN106363742A CN201610942977.4A CN201610942977A CN106363742A CN 106363742 A CN106363742 A CN 106363742A CN 201610942977 A CN201610942977 A CN 201610942977A CN 106363742 A CN106363742 A CN 106363742A
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- parts
- free wood
- halogen
- flame retardant
- sterilizing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a sterilization and smoke suppression halogen-free wood fire retardant. The sterilization and smoke suppression halogen-free wood fire retardant is composed of, by mass, 40-80 parts of guanyl urea phosphate, 30-50 parts of urea, 10-20 parts of zinc borate, 5-10 parts of ammonium molybdate, 3-10 parts of pentaerythritol, 1-20 parts of ammonium dihydrogen phosphate, 12-25 parts of silica sol, 3-15 parts of decabromodiphenyl ether, 5-10 parts of fatty alcohol-polyoxyethylene ether, 1-20 parts of hexadecyltrimethoxysilane, and 1-20 parts of nanometer titania modified by one of Pt, Ag and Fe<3+>. The sterilization and smoke suppression halogen-free wood fire retardant is good in flame retardant property, high in anti-moisture absorption property and leaching resistance, good in stability, completely non-poisonous and low in cost and has the smoke suppression and sterilization effects.
Description
Technical field
The present invention relates to fire proofing technical field is and in particular to a kind of sterilizing presses down cigarette halogen-free wood flame retardant.
Background technology
Timber is a kind of preferably building, furniture, interior decoration materials, but the inflammability of timber but limits making of it
With.Wood fire retardant be then a class pass through promote formed charcoal, formed sealing coat, release non-combustible gas, terminate radical reaction,
Absorb the mechanism such as calory burning, make the inflammable safety in utilization becoming fire retardant, timber being significantly greatly increased of timber.
At present, wood fire retardant is mainly by halogen and its compound flame retardant, metal hydroxide combustion inhibitor, phosphorus series non-halogen
Fire retardant, boron flame retardant, phenols fire retardant, frw fire retardant etc..Halogen and its compound flame retardant are because producing cigarette and having poison
Body, people are rarely employed, and metal hydroxide combustion inhibitor can suppress the formation of smog, nontoxic, non-corrosiveness but for fire-retardant
When, addition is big, and the homogeny of organic substance is poor.Wood fire retardant relatively conventional at present mainly has phosphorus series non-halogen fire-retardant
Agent, boron flame retardant, phenols fire retardant, frw fire retardant.
Frw fire retardant is a kind of phosphorus, nitrogen, the BACN of boron composite highly effective, and it is anti-corrosion etc. many because having fire-retardant, suppression cigarette
Kind of function, and be widely used the advantages of the color of timber, hygroscopicity, physical write and processing characteristics are no affected substantially.Mesh
Before, the existing patent No. 201210480273.1 announces a kind of sterilizing suppression cigarette halogen-free wood flame retardant, preparation method and its usage, its
Including phosphoric acid, carbamide, catalyst, water and Ludox；It has effect that is fire-retardant, eliminating formaldehyde, also has preferable size steady
Determine function.The patent No. 201410357447.4 announces a kind of composite flame-retardant agent, preparation method and its usage, and it includes polysilicon acid phosphorus
Acid dihydride aluminum solutions and nitrogen phosphorus fire retardant solution, wherein, the quality of nitrogen phosphorus fire retardant solution and polysilicon acid phosphate dihydrogen aluminum solution
Than for 100:20-50.It has the advantages that preferably fire-retardant, suppression cigarette, resistance to water soak and good stability.Although in above-mentioned patent
Fire retardant has fire-retardant, suppression cigarette, good stability, the low advantage of hydroscopicity, but its bactericidal and bacteriostatic effect does not project.
Content of the invention
It is an object of the invention to, for prior art, provide a kind of sterilizing suppression cigarette halogen-free wood flame retardant.
For achieving the above object, the present invention adopts the following technical scheme that: a kind of sterilizing suppression cigarette halogen-free wood flame retardant is by matter
The following raw material composition of amount point: 40～80 parts of guanyl-urea-phosphate, 30～50 parts of carbamide, 10～20 parts of Firebrake ZB, ammonium molybdate 5～
10 parts, 3～10 parts of tetramethylolmethane, 1～20 part of ammonium dihydrogen phosphate, 12～25 parts of Ludox, 3～15 parts of deca-BDE, fat
5～10 parts of polyoxyethylenated alcohol, 1～20 part of hexadecyl trimethoxy silane, through pt, ag, fe3+The nano-silica of arbitrary modification
Change 1～20 part of titanium.
Wherein, described fe3+For fe2o3.
Wherein, described through pt, ag, fe3+The nano titanium oxide percentage composition of the nano titanium oxide of arbitrary modification is
80～90%.
The preparation method that a kind of sterilizing of the present invention presses down cigarette halogen-free wood flame retardant comprises the following steps: claims by weight ratio
Take each component, then by guanylurea phosphate, carbamide, diammonium phosphate, Firebrake ZB, ammonium molybdate, tetramethylolmethane, deca-BDE and warp
pt、ag、fe3+The nano titanium oxide mix homogeneously of arbitrary modification, is subsequently adding Ludox, fatty alcohol-polyoxyethylene ether and 16
Alkyl trimethoxysilane stirs 20～30min, then ball milling 1～2h, makes uniform, stable mixture, obtains final product the present invention's
A kind of sterilizing suppression cigarette halogen-free wood flame retardant
In the present invention, through pt, ag, fe3+The nano titanium oxide of arbitrary modification has compared to single nano titanium oxide
There is more preferable photocatalytic activity, it has very strong photocatalytic activity under the illumination conditions such as sunshine, electric filament lamp, uviol lamp, its
There is very strong killing action to antibacterial, funguses, algae, virus etc., there is very strong anti-microbial property.
In the present invention, guanylurea phosphate, diammonium phosphate, carbamide, Firebrake ZB, the silicon compound compositional flame-retardant of Ludox
Can be good, add ammonium molybdate and improve fire retardant smoke suppressing, the leach resistance of Ludox is good, auxiliary adds deca-BDE and fat
Fat polyoxyethylenated alcohol improves anti-moisture absorption property and the stability of fire retardant, and tetramethylolmethane is carbon forming agent, improves wood fire retardant
Flame retarding and smoke suppressing properties.
The invention has the beneficial effects as follows: present invention sterilizing suppression cigarette halogen-free wood flame retardant fire resistance is good, has suppression cigarette, goes out
Bacterium effect, its resistance to water soak and resistance leachability are strong, stablize, totally nontoxic, low cost.
Specific embodiment
With reference to specific embodiment, to further instruction of the present invention.
Embodiment 1
A kind of sterilizing suppression cigarette halogen-free wood flame retardant is made up of the following raw material that quality is divided: 70 parts of guanyl-urea-phosphate, urine
40 parts of element, 15 parts of Firebrake ZB, 6 parts of ammonium molybdate, 9 parts of tetramethylolmethane, 15 parts of ammonium dihydrogen phosphate, 20 parts of Ludox, deca-BDE
10 parts, 8 parts of fatty alcohol-polyoxyethylene ether, 13 parts of hexadecyl trimethoxy silane, through pt modify 15 parts of nano titanium oxide；
The nano titanium oxide percentage composition of the described nano titanium oxide modified through pt is 85%.
Its preparation method comprises the following steps: weigh each component by weight ratio, then by guanylurea phosphate, carbamide, phosphoric acid
Hydrogen diammonium, Firebrake ZB, ammonium molybdate, tetramethylolmethane, deca-BDE and the nano titanium oxide mix homogeneously modified through pt, then
Add Ludox, fatty alcohol-polyoxyethylene ether and hexadecyl trimethoxy silane stirring 25min, then ball milling 1h, make uniformly,
Stable mixture, obtains final product a kind of sterilizing suppression cigarette halogen-free wood flame retardant of the present invention.
Embodiment 2
A kind of sterilizing suppression cigarette halogen-free wood flame retardant is made up of the following raw material that quality is divided: 40 parts of guanyl-urea-phosphate, urine
50 parts of element, 10 parts of Firebrake ZB, 10 parts of ammonium molybdate, 3 parts of tetramethylolmethane, 20 parts of ammonium dihydrogen phosphate, 12 parts of Ludox, deca-BDE
15 parts, 5 parts of fatty alcohol-polyoxyethylene ether, 20 parts of hexadecyl trimethoxy silane, through fe3+The nano titanium oxide 20 modified
Part；Described through fe3+The nano titanium oxide percentage composition of the nano titanium oxide modified is 90%.
Its preparation method comprises the following steps: weigh each component by weight ratio, then by guanylurea phosphate, carbamide, phosphoric acid
Hydrogen diammonium, Firebrake ZB, ammonium molybdate, tetramethylolmethane, deca-BDE and through fe3+The nano titanium oxide mix homogeneously modified, so
Add Ludox, fatty alcohol-polyoxyethylene ether and hexadecyl trimethoxy silane stirring 30min afterwards, then ball milling 2h, make all
Even, stable mixture, obtains final product a kind of sterilizing suppression cigarette halogen-free wood flame retardant of the present invention.
Embodiment 3
A kind of sterilizing suppression cigarette halogen-free wood flame retardant is made up of the following raw material that quality is divided: 40 parts of guanyl-urea-phosphate, urine
50 parts of element, 20 parts of Firebrake ZB, 5 parts of ammonium molybdate, 10 parts of tetramethylolmethane, 1 part of ammonium dihydrogen phosphate, 25 parts of Ludox, deca-BDE 3
Part, 10 parts of fatty alcohol-polyoxyethylene ether, 1 part of hexadecyl trimethoxy silane, 1 part of the nano titanium oxide modified through ag；Institute
The nano titanium oxide percentage composition of the nano titanium oxide modified through ag stated is 80%.
Its preparation method comprises the following steps: weigh each component by weight ratio, then by guanylurea phosphate, carbamide, phosphoric acid
Hydrogen diammonium, Firebrake ZB, ammonium molybdate, tetramethylolmethane, deca-BDE and the nano titanium oxide mix homogeneously modified through ag, then
Add Ludox, fatty alcohol-polyoxyethylene ether and hexadecyl trimethoxy silane stirring 25min, then ball milling 2h, make uniformly,
Stable mixture, obtains final product a kind of sterilizing suppression cigarette halogen-free wood flame retardant of the present invention.
Embodiment 4
A kind of sterilizing suppression cigarette halogen-free wood flame retardant is made up of the following raw material that quality is divided: 50 parts of guanyl-urea-phosphate, urine
35 parts of element, 14 parts of Firebrake ZB, 8 parts of ammonium molybdate, 6 parts of tetramethylolmethane, 15 parts of ammonium dihydrogen phosphate, 15 parts of Ludox, deca-BDE
12 parts, 8 parts of fatty alcohol-polyoxyethylene ether, 12 parts of hexadecyl trimethoxy silane, through ag modify 12 parts of nano titanium oxide；
The nano titanium oxide percentage composition of the described nano titanium oxide modified through ag is 88%.
Its preparation method comprises the following steps: weigh each component by weight ratio, then by guanylurea phosphate, carbamide, phosphoric acid
Hydrogen diammonium, Firebrake ZB, ammonium molybdate, tetramethylolmethane, deca-BDE and the nano titanium oxide mix homogeneously modified through ag, then
Add Ludox, fatty alcohol-polyoxyethylene ether and hexadecyl trimethoxy silane stirring 20min, then ball milling 2h, make uniformly,
Stable mixture, obtains final product a kind of sterilizing suppression cigarette halogen-free wood flame retardant of the present invention.
Claims (4)
1. a kind of sterilizing suppression cigarette halogen-free wood flame retardant is it is characterised in that it is made up of the following raw material that quality is divided: dicyandiamidines phosphorus
40～80 parts of hydrochlorate, 30～50 parts of carbamide, 10～20 parts of Firebrake ZB, 5～10 parts of ammonium molybdate, 3～10 parts of tetramethylolmethane, di(2-ethylhexyl)phosphate
1～20 part of hydrogen ammonium, 12～25 parts of Ludox, 3～15 parts of deca-BDE, 5～10 parts of fatty alcohol-polyoxyethylene ether, cetyl
1～20 part of trimethoxy silane, 1～20 part of the nano titanium oxide through the arbitrary modification of pt, ag, fe3+.
2. a kind of sterilizing suppression cigarette halogen-free wood flame retardant according to claim 1 is it is characterised in that described fe3+For
fe2o3.
3. a kind of sterilizing suppression cigarette halogen-free wood flame retardant according to claim 1 it is characterised in that described through pt, ag,
fe3+The nano titanium oxide percentage composition of the nano titanium oxide of arbitrary modification is 80～90%.
4. press down the preparation method of cigarette halogen-free wood flame retardant according to a kind of arbitrary described sterilizing of claims 1 to 3, its feature exists
In comprising the following steps: weigh each component by weight ratio, then by guanylurea phosphate, carbamide, diammonium phosphate, Firebrake ZB, molybdenum
Sour ammonium, tetramethylolmethane, deca-BDE and through pt, ag, fe3+The nano titanium oxide mix homogeneously of arbitrary modification, is subsequently adding
Ludox, fatty alcohol-polyoxyethylene ether and hexadecyl trimethoxy silane stir 20～30min, then ball milling 1～2h, make all
Even, stable mixture, obtains final product a kind of sterilizing suppression cigarette halogen-free wood flame retardant of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610942977.4A CN106363742A (en) | 2016-10-26 | 2016-10-26 | Sterilization and smoke suppression halogen-free wood fire retardant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610942977.4A CN106363742A (en) | 2016-10-26 | 2016-10-26 | Sterilization and smoke suppression halogen-free wood fire retardant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106363742A true CN106363742A (en) | 2017-02-01 |
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ID=57892993
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610942977.4A Pending CN106363742A (en) | 2016-10-26 | 2016-10-26 | Sterilization and smoke suppression halogen-free wood fire retardant |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114407152A (en) * | 2022-02-15 | 2022-04-29 | 江山欧派门业股份有限公司 | Wood-bamboo fire retardant and preparation method thereof |
| CN114516100A (en) * | 2022-02-15 | 2022-05-20 | 江山花木匠家居有限公司 | Flame-retardant plywood and preparation method thereof |
| CN114525095A (en) * | 2022-02-16 | 2022-05-24 | 江山花木匠家居有限公司 | Phenolic resin adhesive and production method thereof |
| CN115609708A (en) * | 2022-09-14 | 2023-01-17 | 福建木盾生物化工有限公司 | Composite water-based protective agent for decoration wood, and preparation and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104015241A (en) * | 2014-06-25 | 2014-09-03 | 湖北楚风竹韵科技有限公司 | Production method of mould-proof, anti-bacterial and flame-retardant wall decoration bamboo curtain |
| CN104858969A (en) * | 2014-12-22 | 2015-08-26 | 王玉燕 | Environmental protection wood flame retardation antiseptic |
| CN104858975A (en) * | 2014-12-22 | 2015-08-26 | 王玉燕 | Wood fire retardant |
-
2016
- 2016-10-26 CN CN201610942977.4A patent/CN106363742A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104015241A (en) * | 2014-06-25 | 2014-09-03 | 湖北楚风竹韵科技有限公司 | Production method of mould-proof, anti-bacterial and flame-retardant wall decoration bamboo curtain |
| CN104858969A (en) * | 2014-12-22 | 2015-08-26 | 王玉燕 | Environmental protection wood flame retardation antiseptic |
| CN104858975A (en) * | 2014-12-22 | 2015-08-26 | 王玉燕 | Wood fire retardant |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114407152A (en) * | 2022-02-15 | 2022-04-29 | 江山欧派门业股份有限公司 | Wood-bamboo fire retardant and preparation method thereof |
| CN114516100A (en) * | 2022-02-15 | 2022-05-20 | 江山花木匠家居有限公司 | Flame-retardant plywood and preparation method thereof |
| CN114525095A (en) * | 2022-02-16 | 2022-05-24 | 江山花木匠家居有限公司 | Phenolic resin adhesive and production method thereof |
| CN115609708A (en) * | 2022-09-14 | 2023-01-17 | 福建木盾生物化工有限公司 | Composite water-based protective agent for decoration wood, and preparation and application thereof |
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Application publication date: 20170201 |