CN105440852A - Granite-imitating rock chip paint and preparation method thereof - Google Patents
Granite-imitating rock chip paint and preparation method thereof Download PDFInfo
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- CN105440852A CN105440852A CN201510943286.1A CN201510943286A CN105440852A CN 105440852 A CN105440852 A CN 105440852A CN 201510943286 A CN201510943286 A CN 201510943286A CN 105440852 A CN105440852 A CN 105440852A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a granite-imitating rock chip paint which is prepared from the following components: water, nonionic type water soluble cellulose ether, bentonite, a 2-amino-2-methyl-1-propanol aqueous solution with the mass concentration of 90%, an acrylate emulsion, a defoaming agent, alcohol ester-12, a co-solvent, an antibacterial preservative, a rheological auxiliary agent, and compound rock chips. The shortcomings that conventional granite resources become increasingly scarce, color difference of batches is not stable and self weight is heavier to easily cause risks are overcome, and the granite-imitating rock chip paint has the advantages of lifelike effect, light self weight, stable color batches, convenient construction, capability of saving limited resources of granite, excellent storage stability, water resistance, strain resistance and weather resistance.
Description
Technical field
The present invention relates to the preparation method of a kind of artificial granite sliver paint and preparation method thereof, be applied in architectural decoration water-borne coatings field.
Background technology
Grouan owing to having even structure, quality is hard, beautiful appearance, ultimate compression strength are high, the not advantage such as easy-weathering, becomes one of main raw of top-grade building decoration of exterior wall.But in recent years, along with the increase of produced quantity, high-quality grouan mineral resources reduces day by day, and batch between aberration comparatively large, grouan is heavier in addition, can increase the heavy burden of buildings for exterior wall, and the risk dropped in addition, affects pedestrains safety.
Therefore provide a kind of can imitate grouan effect and color stability good, construct convenient, from artificial granite sliver paint of heavy and light and preparation method thereof oneself become when business urgently.
Summary of the invention
The invention provides a kind of artificial granite sliver paint and preparation method thereof, which overcome existing granite resource scarcity, batch aberration instability, the heavier shortcoming easily causing risk of conducting oneself with dignity day by day, have effect true to nature, from heavy and light, color batch is stablized, convenient, to save grouan limited resources of constructing, good, the water-fast resistant of stability in storage are weather-proof advantage.
Technical scheme of the present invention is as follows:
A kind of artificial granite sliver paint, it is formulated by the component of following weight ratio:
This artificial granite sliver paint selects the pure acrylic latex of emulsifier-free emulsion polymerization and surface-crosslinked technical finesse as film forming matter; can covered composite yarn sliver; form fine and close paint film, play a protective role and cohesive action, make the artificial granite sliver paint prepared have certain water-fast, weathering resistance.The formula of this artificial granite sliver paint is selected the collocation of Natvosol, wilkinite and auxiliary rheological agents as thickened systems and is coordinated selected usage ratio simultaneously, makes this sliver paint have package stability and workability concurrently.Wherein, wilkinite and Natvosol have comparatively high thixotropic, can prevent the sedimentation of compound sliver, improve stability in storage, and Natvosol can also effectively extend the water conservation time simultaneously.High-quality emulsion and compound sliver are mixed, adds various auxiliary agent adjustment performance, the effect of imitation grouan true to nature after construction, can be obtained, from heavy and light, colour stable between batch, and good, the water-fast resistant of stability in storage is weather-proof.
In addition, the compound sliver selecting high molecular polymer to make is as aggregate, and good stability between its batch, is not easy fragmentation under higher shear rates stirs, good stability in transport, storage process.Water can adopt common tap water or other clean water, its as dispersion emulsion, aggregate and various auxiliary agent dispersion, play adjusting viscosity, reduce costs, strengthen application property.The water dissolvable ether of cellulose of non-ionic type can be different molecular weight, and it is as a kind of rheology modifier, and it is mainly used for increasing viscosity, improves package stability and workability.Wilkinite its be mainly used for improving and lowly cut viscosity, improve stability in storage.The aqueous solution of 2-amino-2-methyl-1-propanol is as water-soluble multifunctional auxiliary agent, and it is mainly used for regulating potential of hydrogen, has the effect of thickening, dispersion and stabilising system.Described alcohol ester 12, as film coalescence aid, plays the plastic flow and elastic deformation that promote latex particle, reduces the minimum film-forming temperature of emulsion, improves the effect of paint film property.
Compare traditional granite stone material, the carrying cost of the artificial granite sliver paint that the application obtains is low, good stability between batch, and aberration is less, from heavy and light, can effectively alleviate body of wall burden, improves safety in utilization, also can save the limited resources of grouan simultaneously.
This artificial granite sliver paint, it is formulated by the component of following weight ratio:
The abrasion resistance of the artificial granite sliver paint of this optimum ratio is best.
Described wilkinite is natural montmorillonite or artificial modification's wilkinite.
Described acrylic ester emulsion is acrylate copolymer emulsion, and it adopts emulsifier-free emulsion polymerization, as film forming matter, provides better cohesive force and paint film fundamental property.
Described defoamer is any one in oil-based defoamer, silicone antifoam agent or emulsion type defoaming agent, plays better froth breaking and press down bubble effect in formula system.
Described solubility promoter is propylene glycol, effectively can extend the open hour, improves low tempertaure storage stability.
Described fungicidal preservative is the stable Kathon CG series bactericidal agent of divalent metal salt, has good sterilization and anticorrosion effect.
Described auxiliary rheological agents is nonionic polyurethane rheology modifier, and as a kind of synergistic thickening agent, it can better improve flowing and levelling property.
Described compound sliver is the colorful sliver mixture of different size, and the mixing of different size can provide better skeleton structure, and provides color.
The preparation method of this artificial granite sliver paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 500-750r/min stirs, Xiang Shuizhong adds water dissolvable ether of cellulose and the wilkinite of non-ionic type, stir 3-5min more afterwards, then add the aqueous solution of 2-amino-2-methyl-1-propanol under the rotating speed of 750-1000r/min stirs, then continue to stir 5-10min;
2. under the rotating speed of 700-750r/min stirs, add acrylic ester emulsion, defoamer, alcohol ester 12, solubility promoter and fungicidal preservative successively in the mixture that 1. step is prepared after, continue 3-5min again, add auxiliary rheological agents afterwards, then continue to stir 5-10min;
3., under the rotating speed of 750-1000r/min stirs, in the mixture that 2. step is prepared, slowly compound sliver is added, and after continuing fully to stir 10-15min, i.e. obtained artificial granite sliver paint.
The preparation technology of this artificial granite sliver paint is easy, is beneficial to construction.
Compared with prior art, the present patent application has the following advantages:
1) effect of imitation grouan that can be true to nature, can save the limited resources of grouan;
2) color lot stability;
3) good, the water-fast resistant of stability in storage is weather-proof;
4) from heavy and light, safety problems such as coming off is less likely to occur;
5) construct convenient, be beneficial to construction.
Embodiment
Below in conjunction with each embodiment, technical scheme of the present invention is described in detail.
Raw material sources:
Embodiment 1
A kind of artificial granite sliver paint, it is formulated by the component of following weight ratio:
This artificial granite sliver paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 700r/min stirs, Xiang Shuizhong adds water dissolvable ether of cellulose and the natural montmorillonite of non-ionic type, stir 4min more afterwards, under the rotating speed of 800r/min stirs, add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 92% again, then continue to stir 8min;
2. under the rotating speed of 720r/min stirs, add the stable Kathon CG series bactericidal agent of acrylate copolymer emulsion, oil-based defoamer, alcohol ester 12, propylene glycol and divalent metal salt successively in the mixture that 1. step is prepared after, continue 4min again, add nonionic polyurethane rheology modifier afterwards, then continue to stir 8min;
3., under the rotating speed of 800r/min stirs, in the mixture that 2. step is prepared, the colorful sliver mixture of different size is slowly added, and after continuing fully to stir 12min, i.e. obtained artificial granite sliver paint.
Embodiment 2
A kind of artificial granite sliver paint, it is formulated by the component of following weight ratio:
This artificial granite sliver paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 500r/min stirs, Xiang Shuizhong adds water dissolvable ether of cellulose and artificial modification's wilkinite of non-ionic type, stir 5min more afterwards, under the rotating speed of 750r/min stirs, add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 90% again, then continue to stir 10min;
2. under the rotating speed of 700r/min stirs, add acrylic ester emulsion, silicone antifoam agent, alcohol ester 12, solubility promoter and fungicidal preservative successively in the mixture that 1. step is prepared after, continue 5min again, add auxiliary rheological agents afterwards, then continue to stir 5min;
3., under the rotating speed of 750r/min stirs, in the mixture that 2. step is prepared, the colorful sliver mixture of formed objects is slowly added, and after continuing fully to stir 15min, i.e. obtained artificial granite sliver paint.
Embodiment 3
A kind of artificial granite sliver paint, it is formulated by the component of following weight ratio:
This artificial granite sliver paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 750r/min stirs, Xiang Shuizhong adds water dissolvable ether of cellulose and the wilkinite of non-ionic type, stir 3min more afterwards, then add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 95% under the rotating speed of 1000r/min stirs, then continue to stir 5min;
2. under the rotating speed of 750r/min stirs, add acrylic ester emulsion, emulsion type defoaming agent, alcohol ester 12, solubility promoter and fungicidal preservative successively in the mixture that 1. step is prepared after, continue 3min again, add auxiliary rheological agents afterwards, then continue to stir 10min;
3., under the rotating speed of 1000r/min stirs, in the mixture that 2. step is prepared, slowly compound sliver is added, and after continuing fully to stir 1min, i.e. obtained artificial granite sliver paint.
Embodiment 4
The difference of itself and embodiment 1 is: it is formulated by the component of following weight ratio,
Embodiment 5
The difference of itself and embodiment 2 is: it is formulated by the component of following weight ratio,
Experimental data
Wherein, standard-required is that examination criteria HG/T4343-2012 " aqueous colorful building coating " external application is non-resilient.
As seen from the above table, this artificial granite sliver paint stability in storage and every water-fast resistant weather resistance are all better than existing relevant coating standard, and implement 1 best results.
Artificial granite sliver paint of the present invention and preparation method thereof has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.
Claims (10)
1. an artificial granite sliver paint, is characterized in that: it is formulated by the component of following weight ratio,
2. artificial granite sliver paint according to claim 1, is characterized in that: it is formulated by the component of following weight ratio,
。
3. artificial granite sliver paint according to claim 1, is characterized in that: described wilkinite is natural montmorillonite or artificial modification's wilkinite.
4. artificial granite sliver paint according to claim 1, is characterized in that: described acrylic ester emulsion is acrylate copolymer emulsion.
5. artificial granite sliver paint according to claim 1, is characterized in that: described defoamer is any one in oil-based defoamer, silicone antifoam agent or emulsion type defoaming agent.
6. artificial granite sliver paint according to claim 1, is characterized in that: described solubility promoter is propylene glycol.
7. artificial granite sliver paint according to claim 1, is characterized in that: described fungicidal preservative is the stable Kathon CG series bactericidal agent of divalent metal salt.
8. artificial granite sliver paint according to claim 1, is characterized in that: described auxiliary rheological agents is nonionic polyurethane rheology modifier.
9. artificial granite sliver paint according to claim 1, is characterized in that: described compound sliver is the colorful sliver mixture of different size.
10. the artificial granite sliver paint according to any one of claim 1-9, is characterized in that: it comprises the step that next coming in order carry out,
1. under the rotating speed of 500-750r/min stirs, Xiang Shuizhong adds water dissolvable ether of cellulose and the wilkinite of non-ionic type, stir 3-5min more afterwards, then add the aqueous solution of 2-amino-2-methyl-1-propanol under the rotating speed of 750-1000r/min stirs, then continue to stir 5-10min;
2. under the rotating speed of 700-750r/min stirs, add acrylic ester emulsion, defoamer, alcohol ester 12, solubility promoter and fungicidal preservative successively in the mixture that 1. step is prepared after, continue again to stir 3-5min, add auxiliary rheological agents afterwards, then continue to stir 5-10min;
3., under the rotating speed of 750-1000r/min stirs, in the mixture that 2. step is prepared, slowly compound sliver is added, and after continuing fully to stir 10-15min, i.e. obtained artificial granite sliver paint.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107474730A (en) * | 2017-09-26 | 2017-12-15 | 阜南县腾祥工艺品有限公司 | A kind of true mineral varnish of artificial granite |
CN111807784A (en) * | 2020-07-17 | 2020-10-23 | 江苏爱富希新型建材股份有限公司 | Granite-like fiber cement board and preparation method and application thereof |
Citations (4)
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---|---|---|---|---|
CN102558973A (en) * | 2011-12-19 | 2012-07-11 | 河南省德嘉丽科技开发有限公司 | Actual granite imitation coating |
CN104559567A (en) * | 2014-12-30 | 2015-04-29 | 三棵树涂料股份有限公司 | Finishing-free stone-like paint and preparation method thereof |
CN104673021A (en) * | 2015-03-09 | 2015-06-03 | 广西启利新材料科技股份有限公司 | Stone-like paint prepared from ultra-thin colored slices |
CN105111872A (en) * | 2015-09-11 | 2015-12-02 | 三棵树涂料股份有限公司 | Elastic galling maishi paint and preparing method thereof |
-
2015
- 2015-12-16 CN CN201510943286.1A patent/CN105440852A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102558973A (en) * | 2011-12-19 | 2012-07-11 | 河南省德嘉丽科技开发有限公司 | Actual granite imitation coating |
CN104559567A (en) * | 2014-12-30 | 2015-04-29 | 三棵树涂料股份有限公司 | Finishing-free stone-like paint and preparation method thereof |
CN104673021A (en) * | 2015-03-09 | 2015-06-03 | 广西启利新材料科技股份有限公司 | Stone-like paint prepared from ultra-thin colored slices |
CN105111872A (en) * | 2015-09-11 | 2015-12-02 | 三棵树涂料股份有限公司 | Elastic galling maishi paint and preparing method thereof |
Non-Patent Citations (2)
Title |
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中国建筑标准设计研究院: "《外墙外保温建筑构造》", 28 February 2011 * |
陈泽森等: "《水性建筑涂料生产技术》", 31 January 2007 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107474730A (en) * | 2017-09-26 | 2017-12-15 | 阜南县腾祥工艺品有限公司 | A kind of true mineral varnish of artificial granite |
CN111807784A (en) * | 2020-07-17 | 2020-10-23 | 江苏爱富希新型建材股份有限公司 | Granite-like fiber cement board and preparation method and application thereof |
CN111807784B (en) * | 2020-07-17 | 2021-12-17 | 江苏爱富希新型建材股份有限公司 | Granite-like fiber cement board and preparation method and application thereof |
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