CN106189582A - A kind of environmental protection emulsion paint and preparation method thereof - Google Patents
A kind of environmental protection emulsion paint and preparation method thereof Download PDFInfo
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- CN106189582A CN106189582A CN201610555551.3A CN201610555551A CN106189582A CN 106189582 A CN106189582 A CN 106189582A CN 201610555551 A CN201610555551 A CN 201610555551A CN 106189582 A CN106189582 A CN 106189582A
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- emulsion paint
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- protection emulsion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of environmental protection emulsion paint and preparation method thereof, relate to indoor emulsion paint technical field, described environmental protection emulsion paint is by latex powder, polyvinyl alcohol, active nano, tourmaline, mica powder, levelling agent, coalescents, hydroxyethyl cellulose, bamboo charcoal powder, photocatalyst, inorganic pigment, organic solvent, water forms, the environmental protection emulsion paint of the present invention uses the raw material of environment-protecting asepsis, not only will not give out the harmful gass such as formaldehyde, formaldehyde in air can also be carried out adsorption-decomposition function, reach to purify the effect of air, while ensureing environmental-protecting performance, the emulsion paint of the present invention also has the wearability of excellence, ageing resistace and scoring resistance.
Description
Technical field
The present invention relates to indoor emulsion paint technical field, be specifically related to a kind of environmental protection emulsion paint and preparation method thereof.
Background technology
At present, the health of self is increasingly paid attention to by people, for the selection of indoor coating, often health is placed on head
The position wanted.In indoor polluter, the topmost formaldehyde being derived from adhesive, formaldehyde be colourless, have strong
The irritative gas of abnormal smells from the patient, for highly toxic material, is defined as carcinogenic by World Health Organization (WHO) and causes deformed material.Therefore
People tend to select the emulsion paint of environmental protection.
Emulsion paint is also called synthetic resin emulsion coating, is the one of organic coating, is with synthetic resin emulsion as base material
Adding the class water paint that pigment, filler and various auxiliary agent are formulated, according to the difference of raw materials for production, emulsion paint mainly has
The kinds such as poly-vinyl acetate emulsion paint, vinyl acetate-acrylic latex paint, pure acrylic acid emulsion paint, styrene-acrylic latex coating；Environment is used according to product
Difference, be divided into interiro wall latex paint and exterior wall latex paint two kinds；Luster effect according to decoration can be divided into again unglazed, dumb light,
Half light, mercerising and have the types such as light.
In prior art, emulsion paint uses multiple formulations to eliminate harmful organic substance mostly, but existing environment friendly emulsion paint exists
While improving environmental-protecting performance, reduce other serviceabilities of emulsion paint accordingly, such as crack resistance, wearability, ageing resistance
Can etc., production cost is higher simultaneously.Therefore, how to prepare have concurrently environmental-protecting performance and high-performance environmentally-friendly emulsion paint decorations the present invention
Problem to be solved.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of environment friendly emulsion paint so that ensureing the same of environmental-protecting performance
Time have excellence wearability, ageing resistace.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of environmental protection emulsion paint, is made up of the material of following weight portion: latex powder 30-60 part, polyvinyl alcohol 20～
30 parts, active nano Al2O35～15 parts, tourmaline 1-5 part, mica powder 2-10 part, levelling agent 5-10 part, coalescents 2-5 part,
Hydroxyethyl cellulose 1-5 part, bamboo charcoal powder 2-5 part, photocatalyst 2-5 part, inorganic pigment 10-30 part, organic solvent 20～50 parts, water
30-45 part.
Preferably, described environmental protection emulsion paint, it is made up of the material of following weight portion: latex powder 30-45 part, polyethylene
Alcohol 25～28 parts, active nano Al2O36-12 part, tourmaline 1-5 part, mica powder 5～10 parts, levelling agent 5-8 part, coalescents
2-5 part, hydroxyethyl cellulose 3～5 parts, bamboo charcoal powder 2-5 part, photocatalyst 2-5 part, inorganic pigment 15～25 parts, organic solvent 35
～45 parts, water 30-45 part.
Preferably, described latex powder is acrylic resin, polyacrylic acid grafted polymer-modified, vinylacetate, chloroethene
One in the copolymer of alkene and the copolymer of vinyl laurate, higher aliphatic vinyl acetate, ethylene and vinylacetate or
Multiple.
Preferably, described inorganic pigment ferrum oxide, ferroso-ferric oxide, titanium dioxide, white carbon black, cobalt oxide, nickel oxide, oxidation
One or more in zinc etc..
Preferably, during described organic solvent is ethanol, ethylene glycol, isopropanol, glycerol, butyl acetate, Hexalin
Plant or multiple.
The preparation method of a kind of environment friendly emulsion paint, comprises the following steps:
(1), bamboo charcoal powder is placed in the water of 50-60 DEG C, adds active nano Al2O3, be slowly stirred 30-40 minute, after add
Enter mica powder, inorganic pigment and tourmaline, after grinding 20～30min, be cooled to room temperature；
(2), latex powder, polyvinyl alcohol, hydroxyethyl cellulose, photocatalyst are together added in organic solvent, be sufficiently stirred for
After, at 70～80 DEG C, it is incubated 5～15min, is subsequently adding levelling agent and coalescents, stirs；
(3), the mixture of (1) and (2) is mixed, at 30-60min ultrasonic to mixture, finally prepare emulsion paint.
Beneficial effects of the present invention: the invention provides a kind of environment friendly emulsion paint, the present invention is permissible by adding bamboo charcoal powder
Effectively the harmful organic gas in emulsion paint and abnormal flavour are adsorbed；Light touches under conditions of illumination, can be to indoor product
The organic volatiles such as the formaldehyde given birth to and volatilize decompose, and reach the effect purified the air of a room；Active nano Al2O3Permissible
Improve the overall wearability of paint coatings, scoring resistance, meanwhile, add Al2O3Coating there is more preferable light resistance and weather-proof
Property, it is therefore prevented that coating produces slight crack etc. affects the phenomenon of outward appearance；Hydroxyethyl cellulose promotes the dispersion of each component, protects moisture, anti-
The only the most quick-drying slight crack caused of paint coatings, meanwhile, ultrasonic disperse also promotes effective dispersion of each component；The present invention adds
Tourmaline in coating, with the hydrone effect in air after, produce-OH free radical, to finishing in produce formaldehyde have
Well decomposition.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one
Divide embodiment rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making
The every other embodiment obtained under creative work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
The preparation method of a kind of environment friendly emulsion paint, comprises the following steps:
(1), 2 parts of bamboo charcoal powder are placed in the water of 45 parts 50 DEG C, add 6 parts of active nano Al2O3, it is slowly stirred 30-40 and divides
Clock, rear 5 parts of mica powders, 25 parts of inorganic pigments and the 2 parts of tourmaline of adding, after grinding 20～30min, it is cooled to room temperature；
(2), by 30 parts of latex powder, 25 parts of polyvinyl alcohol, 3 parts of hydroxyethyl celluloses, 2 parts of photocatalysts together add 45 parts has
In machine solvent, after being sufficiently stirred for, at 70～80 DEG C, it is incubated 5～15min, is subsequently adding 8 parts of levelling agents and 3 parts of coalescents,
Stir；
(3), the mixture of (1) and (2) is mixed, at 30min ultrasonic to mixture, finally prepare emulsion paint.
Through measuring, after the emulsion paint of the present embodiment uses, in 24 hours, indoor content of formaldehyde reduces 68%,
In 96 hours, content of formaldehyde reduces 76%；720 as a child content of formaldehyde reduce 97.5%, and after emulsion paint is completely dried
Through cold and heat succeed each other experiment and the humidity oscillation experiment of 2000 lab scales, metope is without abnormal phenomenas such as foaming, crackings.
Embodiment 2:
The preparation method of a kind of environment friendly emulsion paint, comprises the following steps:
(1), 4 parts of bamboo charcoal powder are placed in the water of 45 parts 50-60 DEG C, add 5 parts of active nano Al2O3, it is slowly stirred 30-
40 minutes, rear 8 parts of mica powders, 15 parts of inorganic pigments and the 3 parts of tourmaline of adding, after grinding 20～30min, it is cooled to room temperature；
(2), by 35 parts of latex powder, 30 parts of polyvinyl alcohol, 3 parts of hydroxyethyl celluloses, 4 parts of photocatalysts together add 50 parts has
In machine solvent, after being sufficiently stirred for, at 70～80 DEG C, it is incubated 5～15min, is subsequently adding 5 parts of levelling agents and 5 parts of coalescents,
Stir；
(3), the mixture of (1) and (2) is mixed, at 30-60min ultrasonic to mixture, finally prepare emulsion paint.
Through measuring, after the emulsion paint of the present embodiment uses, in 24 hours, indoor content of formaldehyde reduces 56%,
In 96 hours, content of formaldehyde reduces 64%；720 as a child content of formaldehyde reduce 89.6%, and after emulsion paint is completely dried
Through cold and heat succeed each other experiment and the humidity oscillation experiment of 2000 lab scales, metope is without abnormal phenomenas such as foaming, crackings.
Embodiment 3:
The preparation method of a kind of environment friendly emulsion paint, comprises the following steps:
(1), 5 parts of bamboo charcoal powder are placed in the water of 30 parts 50-60 DEG C, add 12 parts of active nano Al2O3, it is slowly stirred 30-
40 minutes, rear 10 parts of mica powders, 30 parts of inorganic pigments and the 5 parts of tourmaline of adding, after grinding 20～30min, it is cooled to room temperature；
(2), by 45 parts of latex powder, 20 parts of polyvinyl alcohol, 1 part of hydroxyethyl cellulose, 2 parts of photocatalysts together add 35 parts has
In machine solvent, after being sufficiently stirred for, at 70～80 DEG C, it is incubated 5～15min, is subsequently adding 10 parts of levelling agents and 3 parts of coalescents,
Stir；
(3), the mixture of (1) and (2) is mixed, at 30-60min ultrasonic to mixture, finally prepare emulsion paint.
Through measuring, after the emulsion paint of the present embodiment uses, in 24 hours, indoor content of formaldehyde reduces 62%,
In 96 hours, content of formaldehyde reduces 70.6%；720 as a child content of formaldehyde reduce 90.3%, and emulsion paint is completely dried
After through 2000 lab scales cold and heat succeed each other experiment and humidity oscillation experiment, metope is without abnormal phenomenas such as foaming, crackings.
Embodiment 4:
The preparation method of a kind of environment friendly emulsion paint, comprises the following steps:
(1), 4 parts of bamboo charcoal powder are placed in the water of 40 parts 50-60 DEG C, add 15 parts of active nano Al2O3, it is slowly stirred 30-
40 minutes, rear 2 parts of mica powders, 10 parts of inorganic pigments and the 1 part of tourmaline of adding, after grinding 20～30min, it is cooled to room temperature；
(2), by 60 parts of latex powder, 28 parts of polyvinyl alcohol, 5 parts of hydroxyethyl celluloses, 5 parts of photocatalysts together add 20 parts has
In machine solvent, after being sufficiently stirred for, at 70～80 DEG C, it is incubated 5～15min, is subsequently adding 5 parts of levelling agents and 2 parts of coalescents,
Stir；
(3), the mixture of (1) and (2) is mixed, at 30-60min ultrasonic to mixture, finally prepare emulsion paint.
Through measuring, after the emulsion paint of the present embodiment uses, in 24 hours, indoor content of formaldehyde reduces 43%,
In 96 hours, content of formaldehyde reduces 72%；720 as a child content of formaldehyde reduce 92.3%, and after emulsion paint is completely dried
Through cold and heat succeed each other experiment and the humidity oscillation experiment of 2000 lab scales, metope is without abnormal phenomenas such as foaming, crackings.
To sum up, the embodiment of the present invention has the advantages that the emulsion paint of the present invention uses the former of environment-protecting asepsis
Material, not only will not give out the harmful gass such as formaldehyde, moreover it is possible to the formaldehyde in air is carried out adsorption-decomposition function, reaches to purify air
Effect, while ensureing environmental-protecting performance, the emulsion paint of the present invention also has wearability, ageing resistace and the scratch resistant of excellence
Property.
It should be noted that in this article, the relational terms of such as first and second or the like is used merely to a reality
Body or operation separate with another entity or operating space, and deposit between not necessarily requiring or imply these entities or operating
Relation or order in any this reality.And, term " includes ", " comprising " or its any other variant are intended to
Comprising of nonexcludability, so that include that the process of a series of key element, method, article or equipment not only include that those are wanted
Element, but also include other key elements being not expressly set out, or also include for this process, method, article or equipment
Intrinsic key element.In the case of there is no more restriction, statement " including ... " key element limited, it is not excluded that
Including process, method, article or the equipment of described key element there is also other identical element.
Above example only in order to technical scheme to be described, is not intended to limit；Although with reference to previous embodiment
The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent；And these amendment or
Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. an environmental protection emulsion paint, it is characterised in that be made up of the material of following weight portion: latex powder 30-60 part, poly-second
Enol 20～30 parts, active nano Al2O35～15 parts, tourmaline 1-5 part, mica powder 2-10 part, levelling agent 5-10 part, film forming help
Agent 2-5 part, hydroxyethyl cellulose 1-5 part, bamboo charcoal powder 2-5 part, photocatalyst 2-5 part, inorganic pigment 10-30 part, organic solvent 20
～50 parts, water 30-45 part.
2. environmental protection emulsion paint as claimed in claim 1, it is characterised in that be made up of the material of following weight portion: latex
Powder 30-45 part, polyvinyl alcohol 25～28 parts, active nano Al2O36-12 part, tourmaline 1-5 part, mica powder 5～10 parts, levelling
Agent 5-8 part, coalescents 2-5 part, hydroxyethyl cellulose 3～5 parts, bamboo charcoal powder 2-5 part, photocatalyst 2-5 part, inorganic pigment 15～
25 parts, organic solvent 35～45 parts, water 30-45 part.
3. environmental protection emulsion paint as claimed in claim 1, it is characterised in that described latex powder be acrylic resin, poly-third
Olefin(e) acid graft-modified polymers, vinylacetate, vinyl chloride and the copolymer of vinyl laurate, higher aliphatic vinyl acetate,
One or more in the copolymer of ethylene and vinylacetate.
4. environmental protection emulsion paint as claimed in claim 1, it is characterised in that described inorganic pigment ferrum oxide, four oxidations three
One or more in ferrum, titanium dioxide, white carbon black, cobalt oxide, nickel oxide, zinc oxide etc..
5. environmental protection emulsion paint as claimed in claim 1, it is characterised in that described organic solvent is ethanol, ethylene glycol, different
One or more in propanol, glycerol, butyl acetate, Hexalin, polyvinyl alcohol.
6. the preparation method of the environmental protection emulsion paint as described in Claims 1 to 5 is arbitrary, it is characterised in that include with
Lower step:
(1), bamboo charcoal powder is placed in the water of 50-60 DEG C, adds active nano Al2O3, it is slowly stirred 30-40 minute, adds cloud afterwards
Female powder, inorganic pigment and tourmaline, after grinding 20～30min, be cooled to room temperature；
(2), latex powder, polyvinyl alcohol, hydroxyethyl cellulose, photocatalyst are together added in organic solvent, after being sufficiently stirred for,
It is incubated 5～15min at 70～80 DEG C, is subsequently adding levelling agent and coalescents, stirs；
(3), the mixture of (1) and (2) is mixed, at 30-60min ultrasonic to mixture, finally prepare emulsion paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610555551.3A CN106189582A (en) | 2016-07-14 | 2016-07-14 | A kind of environmental protection emulsion paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610555551.3A CN106189582A (en) | 2016-07-14 | 2016-07-14 | A kind of environmental protection emulsion paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106189582A true CN106189582A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610555551.3A Pending CN106189582A (en) | 2016-07-14 | 2016-07-14 | A kind of environmental protection emulsion paint and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987702A (en) * | 2017-12-15 | 2018-05-04 | 卿小艳 | A kind of production method of environment friendly emulsion paint |
| CN114133804A (en) * | 2021-12-23 | 2022-03-04 | 广东库赫新材料科技有限公司 | Production process of water-based industrial paint with good corrosion resistance effect |
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2016
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987702A (en) * | 2017-12-15 | 2018-05-04 | 卿小艳 | A kind of production method of environment friendly emulsion paint |
| CN114133804A (en) * | 2021-12-23 | 2022-03-04 | 广东库赫新材料科技有限公司 | Production process of water-based industrial paint with good corrosion resistance effect |
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