CN109486311A - A kind of insect prevention radon preventing paint - Google Patents
A kind of insect prevention radon preventing paint Download PDFInfo
- Publication number
- CN109486311A CN109486311A CN201811550495.XA CN201811550495A CN109486311A CN 109486311 A CN109486311 A CN 109486311A CN 201811550495 A CN201811550495 A CN 201811550495A CN 109486311 A CN109486311 A CN 109486311A
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- Prior art keywords
- agent
- coating
- water
- radon
- insect
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Abstract
The invention discloses a kind of insect prevention radon preventing paints, it is characterised in that by forming following weight percentage components: water-based emulsion 15-50；Insect-proof agent 10-15；Titanium dioxide 5-30；Powdered whiting 10-30；Super-fine silicon micro-powder 5-30；Pentaerythrite 0-5；Mould inhibitor 0-5；Emulsifier 0.1-3；Film forming agent 0.1-3；Wetting agent 0.1-5；Defoaming agent 0.1-1；Water 10-40.The present invention overcomes the defects that common radon preventing paint coating does not have insect prevention effect, obtain a kind of not only with insect prevention effect, but also the coating material of the anti-radon of energy.
Description
Technical field
The present invention relates to a kind of insect prevention radon preventing paints.
Background technique
Radon is a kind of colourless, tasteless, extremely inactive inert gas of chemical property, it is always present in indoor and outdoor air
In, great diffusivity, dissolubility and adsorptivity can be dissolved in fat and various organic solvents, dissolution of the radon in fat
Degree is 125 times of water, and accounting is up to 55% in human body institute raying totality, is once classified as 19 kinds of causes by the World Health Organization (WHO)
One of cancer substance.Indoor Niton Pollution than outdoor high 25%-60%, and people daily about 80% time in various interior degree
It crosses, the radon in construction material, house foundation, life fuel, drinking water and open-air etc. has become a kind of " stealthy
Haze ".
The pests such as mosquito, fly can propagate a variety of diseases, they usually build up indoors, endanger human health, therefore room
The effect for inside commonly using various coating to complete Vermins-expelling vermins-proof is ideal.But the anti-radon supplied currently on the market applies
Material does not have the effect of insect prevention nearly all.
CN107603386A discloses a kind of safe free from extraneous odour coating, in parts by weight includes following component: pure acrylic acid
20-50 parts of lotion；12-30 parts of titanium dioxide；10-30 parts of powdered whiting；10-30 parts of silica dioxide granule；5-20 parts of bamboo charcoal powder；
2-10 parts of nano-titanium；0.1-3 parts of film forming agent；0.1-5 parts of wetting agent；0.1-1 parts of defoaming agent；10-30 parts of water, polypropylene powder 2-4
Part, 12-20 parts of stearic acid, 20-30 parts of activated Calcium carbonate, 50-70 parts of Chinese hawthorn seed extracting solution, 20-30 parts of orange peel extracting solution.The hair
It is bright by adding nanoscale particle, the slightly larger micron particles of compatibility partial size overcome anti-radon by the compounding of each component
Paint coatings are fine and close, and specific surface area is small, the ineffective defect of formaldehyde absorbing, obtain a kind of while having anti-radon, except formaldehyde
Coating.
CN102702905A discloses a kind of Radon-proof and formaldehyde-resista coating, in parts by weight includes following component: pure acrylic acid
Lotion 20-60；Titanium dioxide 12-30；Powdered whiting 10-30；Silica dioxide granule 10-30；Bamboo charcoal powder 5-20；Nano-titanium 2-
10；Film forming agent 0.1-3；Wetting agent 0.1-5；Defoaming agent 0.1-1；Water 10-30.The invention is matched by addition nanoscale particle
The slightly larger micron particles of 5 partial sizes overcome radon preventing paint coating densification by the compounding of each component, and specific surface area is small,
The ineffective defect of formaldehyde absorbing obtains a kind of while having anti-radon, the coating except formaldehyde.
CN1554719 discloses radon preventing paint, which includes putty, priming paint, finishing coat, is characterized in that described
Containing including composition polymer latex, composite fibre, filler, mould inhibitor, preservative, dispersing agent, stream in putty, priming paint and finishing coat
Become agent and ARP5, ARG6, ARB7 material.
CN1468915 discloses radon preventing paint, and the invention is by weight ratio are as follows: 49 parts of water, thickener 0.8 is then added
Part, 1.2 parts of dispersing agent, 24 parts of titanium dioxide, 0.6 part of fungicide, 0.8 part of defoaming agent, 1.6 parts of film forming agent after fully dispersed, are added
2 parts of 20 parts of acrylate lotion and ultra-fine silica aerogel, then it is fully dispersed, finally adjusting pH value is 9-9.5, and re-closed includes i.e.
It can.The invention is due to using technical solution as above, compared with prior art, has anti-radon effect good, and raw material sources are extensive, production
It is at low cost, simple production process, it is easy for construction the features such as.
Radon preventing paint is to cover radon gas radioactive source by fine and close dope layer, to reach the precipitation rate of radon for reducing substrate, drop
The effect of low interior radon gas radiation, wherein water-based emulsion is the most commonly used, but after solidifying for the water paint of anti-radon usually not
Have the effect of insecting driving insect, thus how to develop one kind not only there is anti-radon performance, but also the water paint with insect prevention effect is
One technical problem of this field.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art, and it is anti-that the object of the present invention is to provide one kind
Worm radon preventing paint.
In order to solve the above technical problems, the technical scheme adopted by the invention is that:
A kind of insect prevention radon preventing paint, it is characterised in that by forming following weight percentage components: water-based emulsion 15-50；Insect prevention
Agent 10-15；Titanium dioxide 10-30；Powdered whiting 10-30；Super-fine silicon micro-powder 5-30；Pentaerythrite 0-5；Mould inhibitor 0-5；Emulsification
Agent 0.1-3；Film forming agent 0.1-3；Wetting agent 0.1-5；Defoaming agent 0.1-1；Water 10-40；The sum of above-mentioned each component is absolutely.
Film layer of the coating of the present invention after coating film forming is fine and close, is not only able to isolation radon gas, closes radon gas
In paint film, harmless element is decayed to；And has insect prevention function.
In a preferred embodiment of the invention, water-based emulsion be acrylic emulsion or styrene-acrylic emulsion or silicone acrylic emulsion or
Tertiary vinegar (tertiary carbonic ester-vinylacetate) lotion or uncle third (tertiary carbonic ester-acrylate) lotion, wherein acrylic emulsion contains admittedly
Amount is 40-50wt%；Styrene-acrylic emulsion solid content is 42-58wt%；Silicone acrylic emulsion solid content is 40-52wt%；Tertiary vinegar (versatic acid
Ester-vinylacetate) emulsion solid content 45-56wt%；Uncle third (tertiary carbonic ester-acrylate) emulsion solid content 42-52wt%.
In a preferred embodiment of the invention, the insect-proof agent is methothrin or chlorine ethofenprox or Permethrin or amine
Pyrethroids.
In a preferred embodiment of the invention, the titanium dioxide be rutile type titanium white or anatase thpe white powder,
Wherein TiO2Content be not less than 97%.
In a preferred embodiment of the invention, the granularity of the super-fine silicon micro-powder is 2000-8000 mesh, SiO2Contain
Amount is not less than 98%.
The granularity of the powdered whiting is 800-2000 mesh, CaCO3Content is not less than 96%.
In a preferred embodiment of the invention, mould inhibitor, emulsifier, film forming agent, wetting agent, defoaming agent are commercially available
Product.
In a preferred embodiment of the invention, the water is deionization.
The present invention has the advantages that radon gas can be completely cut off by obtaining one kind by the compounding of each component, radon gas is made to be enclosed in paint
In film, but also with the coating of insect prevention performance.
Specific embodiment
By following specific embodiments, invention is further described in detail.
Embodiment 1:
A kind of fire-retardant radon preventing paint, includes following component by weight percentage:
Acrylic emulsion 25；
Insect-proof agent 15；
Titanium dioxide 12；
Powdered whiting 15；
Super-fine silicon micro-powder 5；
Pentaerythrite 2；
Mould inhibitor 1；
Emulsifier 0.2；
Film forming agent 0.3；
Wetting agent 0.3；
Defoaming agent 0.2；
Water is surplus.
Wherein acrylic emulsion solid content is 42wt%；Insect-proof agent is methothrin.
Preparation process: various raw materials are added in reaction kettle and heat mixing.
Paint film property index: flat appearance, surface drying 2h do solid work 15h, and anti-radon rate 83%, vermins-proof effect is shown in Table 1.
Embodiment 2:
A kind of fire-retardant radon preventing paint, includes following component by weight percentage:
Styrene-acrylic emulsion 30；
Insect-proof agent 15；
Titanium dioxide 10；
Powdered whiting 20；
Super-fine silicon micro-powder 5；
Pentaerythrite 1；
Mould inhibitor 0.5；
Emulsifier 0.2；
Film forming agent 0.2；
Wetting agent 0.3；
Defoaming agent 0.3；
Water is surplus.
Wherein styrene-acrylic emulsion solid content is 48wt%；Insect-proof agent is chlorine ethofenprox.
Preparation process: various raw materials are added in reaction kettle and heat mixing.
Paint film property index: flat appearance, surface drying 2h do solid work 16h, and anti-radon rate 82%, vermins-proof effect is shown in Table 1.
Embodiment 3:
A kind of fire-retardant radon preventing paint, includes following component by weight percentage:
Acrylic emulsion 22；
Insect-proof agent 20；
Titanium dioxide 15；
Powdered whiting 5；
Super-fine silicon micro-powder 10；
Pentaerythrite 4；
Mould inhibitor 1.2；
Emulsifier 0.3；
Film forming agent 0.3；
Wetting agent 0.2；
Defoaming agent 0.2；
Water is surplus.
Wherein acrylic emulsion solid content is 49wt%；Insect-proof agent is Permethrin.
Preparation process: various raw materials are added in reaction kettle and heat mixing.
Paint film property index: flat appearance, surface drying 3h do solid work 19h, and anti-radon rate 83%, vermins-proof effect is shown in Table 1.
Comparative example 1:
Except insect-proof agent methothrin is not added in component, other component and preparation method thereofs are same as Example 1.
Comparative example 2:
Except insect-proof agent chlorine ethofenprox is not added in component, other component and preparation method thereofs are same as Example 2.
Comparative example 3:
Except insect-proof agent Permethrin is not added in component, other component and preparation method thereofs are same as Example 3.
Insect prevention performance test:
Insect killing effect is monitored according to GB13917.1-92 " biological efficacy test ".Selection activity is quick, vitality is vigorous
Housefly selects the asbestos board of 6 pieces of 10*10cm ,-No. 6 plates of respectively No. 1 plate as object is killed respectively, and No. 1 plate coats embodiment
1 coating, the coating of No. 2 plate coating embodiments 2, the coating of No. 3 plate coating embodiments 3, the coating of No. 4 plate coating comparative examples 1,
The coating of No. 5 plate coating comparative examples 2, the coating of No. 6 plate coating comparative examples 3, is respectively covered with paint, lacquer, colour wash, etc. twice, and every minor tick is for 24 hours, dry to film
After dry, 5 houseflies are respectively placed on 6 blocks of asbestos boards, and covered with the special small beaker that ambient atmosphere circulates, make to do harm to
The scope of activities of worm only in a small space between asbestos board and beaker, is observed its insect killing effect, is averaged, and detects
It the results are shown in Table 1.
Insect killing effect data of 1 coating of table to housefly.
Knockdown time refers to that housefly is gone down the time that cannot be move freely, and the death time refers to that housefly is condensed to one thoroughly
The dead time.
The above is only a preferred embodiment of the present invention, is not intended to restrict the invention, it is clear that those skilled in the art can
To carry out various changes, modification without departing from the spirit and scope of the present invention to the present invention.If to these modifications of the invention
Within the scope of the claims of the present invention and its equivalent technology with modification, it all belongs to the scope of protection of the present invention.
Claims (7)
1. a kind of insect prevention radon preventing paint, it is characterised in that by forming following weight percentage components: water-based emulsion 15-50；It is anti-
Worm agent 10-15；Titanium dioxide 10-30；Powdered whiting 10-30；Super-fine silicon micro-powder 5-30；Pentaerythrite 0-5；Mould inhibitor 0-5；Cream
Agent 0.1-3；Film forming agent 0.1-3；Wetting agent 0.1-5；Defoaming agent 0.1-1；Water 10-40；The sum of above-mentioned each component is percent
Hundred.
2. coating as described in claim 1, which is characterized in that the water-based emulsion is acrylic emulsion or styrene-acrylic emulsion or silicon
Acrylic emulsion or tertiary vinegar (tertiary carbonic ester-vinylacetate) lotion or uncle third (tertiary carbonic ester-acrylate) lotion, wherein acrylic acid
Emulsion solid content is 40-50wt%；Styrene-acrylic emulsion solid content is 42-58wt%；Silicone acrylic emulsion solid content is 40-52wt%；Uncle
Vinegar (tertiary carbonic ester-vinylacetate) emulsion solid content 45-56wt%；Uncle third (tertiary carbonic ester-acrylate) emulsion solid content
42-52wt%.
3. coating as described in claim 1, which is characterized in that the insect-proof agent is methothrin or chlorine ethofenprox or Permethrin
Or tetramethrin.
4. coating as described in claim 1, which is characterized in that the titanium dioxide is rutile type titanium white or anatase titanium dioxide
Powder, wherein TiO2Content be not less than 97%.
5. coating as described in claim 1, which is characterized in that the granularity of the super-fine silicon micro-powder is 2000-8000 mesh,
SiO2Content is not less than 98%.
6. coating as described in claim 1, which is characterized in that the granularity of the powdered whiting is 800-2000 mesh,
CaCO3Content is not less than 96%.
7. coating as described in claim 1, which is characterized in that the water is deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811550495.XA CN109486311A (en) | 2018-12-18 | 2018-12-18 | A kind of insect prevention radon preventing paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811550495.XA CN109486311A (en) | 2018-12-18 | 2018-12-18 | A kind of insect prevention radon preventing paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109486311A true CN109486311A (en) | 2019-03-19 |
Family
ID=65710598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811550495.XA Pending CN109486311A (en) | 2018-12-18 | 2018-12-18 | A kind of insect prevention radon preventing paint |
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| CN (1) | CN109486311A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256881A (en) * | 2019-06-21 | 2019-09-20 | 东莞大宝化工制品有限公司 | Inorganic mosquito-proof coating of one kind and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1515635A (en) * | 2003-01-02 | 2004-07-28 | 上海富臣化工有限公司 | Radon-proofing wall surface paint |
| CN105017909A (en) * | 2015-08-26 | 2015-11-04 | 湖州大周高分子材料有限公司 | Insecticide coating for inner walls |
| JP2016214575A (en) * | 2015-05-20 | 2016-12-22 | 住江織物株式会社 | carpet |
-
2018
- 2018-12-18 CN CN201811550495.XA patent/CN109486311A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1515635A (en) * | 2003-01-02 | 2004-07-28 | 上海富臣化工有限公司 | Radon-proofing wall surface paint |
| JP2016214575A (en) * | 2015-05-20 | 2016-12-22 | 住江織物株式会社 | carpet |
| CN105017909A (en) * | 2015-08-26 | 2015-11-04 | 湖州大周高分子材料有限公司 | Insecticide coating for inner walls |
Non-Patent Citations (1)
| Title |
|---|
| 李焕德 等: "《急性中毒毒物检测与诊疗》", 31 March 2000, 湖南科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110256881A (en) * | 2019-06-21 | 2019-09-20 | 东莞大宝化工制品有限公司 | Inorganic mosquito-proof coating of one kind and preparation method thereof |
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Application publication date: 20190319 |