CN104175666B - Intercept ultraviolet color anti-fog fenestrated membrane - Google Patents
Intercept ultraviolet color anti-fog fenestrated membrane Download PDFInfo
- Publication number
- CN104175666B CN104175666B CN201410390527.XA CN201410390527A CN104175666B CN 104175666 B CN104175666 B CN 104175666B CN 201410390527 A CN201410390527 A CN 201410390527A CN 104175666 B CN104175666 B CN 104175666B
- Authority
- CN
- China
- Prior art keywords
- ultraviolet
- base material
- sensitive adhesive
- adhesive layer
- fog
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 59
- 239000010410 layer Substances 0.000 claims abstract description 139
- 239000000463 material Substances 0.000 claims abstract description 126
- 239000002585 base Substances 0.000 claims abstract description 98
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 88
- 229920006267 polyester film Polymers 0.000 claims abstract description 88
- -1 polyethylene Polymers 0.000 claims abstract description 76
- 239000004698 Polyethylene Substances 0.000 claims abstract description 74
- 229920000573 polyethylene Polymers 0.000 claims abstract description 74
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 239000002904 solvent Substances 0.000 claims abstract description 45
- 238000004043 dyeing Methods 0.000 claims abstract description 41
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000012965 benzophenone Substances 0.000 claims abstract description 34
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000012964 benzotriazole Substances 0.000 claims abstract description 34
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 34
- 239000002250 absorbent Substances 0.000 claims abstract description 33
- 230000002745 absorbent Effects 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 238000001723 curing Methods 0.000 claims abstract description 25
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000853 adhesive Substances 0.000 claims abstract description 24
- 230000001070 adhesive effect Effects 0.000 claims abstract description 24
- 239000000975 dye Substances 0.000 claims abstract description 22
- 238000013007 heat curing Methods 0.000 claims abstract description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 18
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims abstract description 12
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 6
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 54
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 54
- 238000003756 stirring Methods 0.000 claims description 28
- 238000002360 preparation method Methods 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 10
- 150000003852 triazoles Chemical class 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical group OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 claims description 7
- 230000006798 recombination Effects 0.000 claims description 6
- 238000005215 recombination Methods 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 4
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- LYKRPDCJKSXAHS-UHFFFAOYSA-N phenyl-(2,3,4,5-tetrahydroxyphenyl)methanone Chemical compound OC1=C(O)C(O)=CC(C(=O)C=2C=CC=CC=2)=C1O LYKRPDCJKSXAHS-UHFFFAOYSA-N 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to and a kind of intercept ultraviolet color anti-fog fenestrated membrane, it to be dyeed pressure-sensitive adhesive layer (3), second polyester film or polyethylene film base material (2-2), ultraviolet-resistant pressure-sensitive adhesive layer (4) and mould release membrance (5) form and each layer is complex as a whole by anti-fog layer (1), first polyester film or polyethylene film base material (2-1), ultraviolet-resistant; Anti-fog layer (1) is made up of hydrophilic heat cure solvent type acrylic resin, propylene glycol monomethyl ether, dimethyl formamide, catalyst triethylene diamine, levelling agent, isopropyl alcohol, ethanol; Ultraviolet-resistant pressure-sensitive adhesive layer (4) is made up of the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, acrylic acid adhesive, curing agent and solvent composition; Ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) is made up of the mixed material of ultraviolet-resistant pressure-sensitive adhesive layer (4) and dyestuff.Fenestrated membrane of the present invention had both intercepted ultraviolet, antifog, appearance looks elegant again lastingly.
Description
Technical field
The present invention relates to the ultraviolet color anti-fog fenestrated membrane of a kind of obstruct, be particularly suitable for being pasted onto the glass surface of building or the glass surface of automobile.
Background technology
Furniture in building, carpet, artistic pictures, the fabrics such as curtain or automotive trim meeting accelerated ageing under sunlight or strong artificial light shine, especially under ultraviolet lighting, can photooxidative degradation be produced and cause greatly shortening its service life, at present, there is uv-shielding capacity difference and the problem such as ageing-resistant performance is not good in most domestic fenestrated membrane product, namely fenestrated membrane is to ultraviolet rejection rate < 90%, and along with the continuous increase of service time, the outward appearance of fenestrated membrane and physical property also can decline gradually, and above-mentioned fenestrated membrane product relies on electrical heating method and use anti-fog coating to realize antifog, but the former respond well price is high, the wasting of resources is large, anti-fog coating is just sprayed on the surfaces such as glass by the latter, but can not solidify, therefore antifog persistence difference and use inconvenient, color is more single again, unsightly.Therefore, be badly in need of exploitation one both endurable obstruct ultraviolets, and also have the fenestrated membrane that lasting anti-fog effect is attractive in appearance again, so that the interior trim of available protecting building or automobile and ensure that occupant is healthy, the interference of fog to security can also be reduced.
Summary of the invention
The object of the invention is: provide one efficiently can intercept ultraviolet, again can be antifog lastingly, and the ultraviolet color anti-fog fenestrated membrane of the obstruct of appearance looks elegant.
The technical scheme realizing the object of the invention is: the ultraviolet color anti-fog fenestrated membrane of a kind of obstruct, and its innovative point is,
It to be dyeed pressure-sensitive adhesive layer, second polyester film or polyethylene film base material, ultraviolet-resistant pressure-sensitive adhesive layer and mould release membrance form and each layer is complex as a whole by anti-fog layer, first polyester film or polyethylene film base material, ultraviolet-resistant; Described anti-fog layer ultraviolet light polymerization is combined on a surface of first polyester film or polyethylene film base material, ultraviolet-resistant dyeing pressure-sensitive adhesive layer heat cure be combined in first polyester film or polyethylene film base material another on the surface, a surface recombination of second polyester film or polyethylene film base material is at the outer surface of ultraviolet-resistant dyeing pressure-sensitive adhesive layer, the heat cure of ultraviolet-resistant pressure-sensitive adhesive layer be combined in second polyester film or polyethylene film base material another on the surface, mould release membrance is compounded in the outer surface of ultraviolet-resistant pressure-sensitive adhesive layer;
Described anti-fog layer is with hydrophilic heat cure solvent type acrylic resin SAA9019 ~ 14wt%, propylene glycol monomethyl ether 55 ~ 76wt%, dimethyl formamide 3 ~ 10wt%, catalyst triethylene diamine 1 ~ 5wt%, levelling agent BYK-3331 ~ 5wt%, isopropyl alcohol 5 ~ 26wt%, the antifogging agent composition that ethanol 5 ~ 24wt% mixes formation is coated on a surface of first polyester film or polyethylene film base material, temperature 80 ~ 150 DEG C, obtain after heat cure, wherein, the each component sum forming the antifogging agent composition of anti-fog layer is 100wt%, described SAA901 is the product grade of Xi'an Naviation Sanwo Chemical Co., Ltd.,
Described ultraviolet-resistant dyeing pressure-sensitive adhesive layer be coated in first polyester film or polyethylene film base material with the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, dyestuff, acrylic acid adhesive, curing agent and solvent composition another on the surface, temperature 80 ~ 150 DEG C, place 10 ~ 180 seconds Post RDBMS and obtain ultraviolet-resistant dyeing pressure-sensitive adhesive layer;
Described ultraviolet-resistant pressure-sensitive adhesive layer be coated in second polyester film or polyethylene film base material with the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, acrylic acid adhesive, curing agent and solvent composition another on the surface, temperature 80 ~ 150 DEG C, place 10 ~ 180 seconds Post RDBMS and obtain ultraviolet-resistant pressure-sensitive adhesive layer.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, the antifogging agent composition of described formation anti-fog layer, the mixed material forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer and the mixed material forming ultraviolet-resistant pressure-sensitive adhesive layer adopt jetting type coating, or scraper type coating process carries out applying.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, the mixed material forming described ultraviolet-resistant dyeing pressure-sensitive adhesive layer is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, dyestuff 0.05 ~ 10wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, above-mentioned each component sum is 100wt%, during preparation, each amounts of components is selected in above-mentioned scope, at environment temperature is 18 ~ 28 DEG C, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixes with solvent ethyl acetate and after stirring 12 ~ 18 minutes, add dyestuff and solvent toluene mixture and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, can save backup, wherein, benzophenone type ultraviolet absorbent is 2, 2', 4, 4'-tetrahydroxybenzophenone, benzotriazole ultraviolet absorber is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1, 1-dimethyl ethyl)-4-methylphenol, dyestuff is organic dyestuff.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, the mixed material forming described ultraviolet-resistant pressure-sensitive adhesive layer is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, above-mentioned each component sum is 100wt%, during preparation, each amounts of components is selected in above-mentioned scope, at environment temperature is 18 ~ 28 DEG C, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixes with solvent ethyl acetate and solvent toluene and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, can save backup, wherein, benzophenone type ultraviolet absorbent is 2, 2', 4, 4'-tetrahydroxybenzophenone, benzotriazole ultraviolet absorber is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1, 1-dimethyl ethyl)-4-methylphenol.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, described first polyester film or polyethylene film base material and second polyester film or polyethylene film base material are transparent polyester film or polyethylene film base material, or dyeing polyester film or polyethylene film base material or primary colors polyester film or polyethylene film base material, or ultraviolet-resistant polyester film or polyethylene film base material, or aluminized polyester film or polyethylene film base material, or magnetron sputtering polyester film or polyethylene film base material.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, described first polyester film or polyethylene film base material identical with the type of substrate that second polyester film or polyethylene film base material use, or different.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, described obstruct ultraviolet color anti-fog fenestrated membrane thickness is 72 ~ 444 μm, and wherein, the thickness of anti-fog layer is 1 ~ 5 μm; The thickness of first polyester film or polyethylene film base material is 20 ~ 175 μm; The thickness of ultraviolet-resistant dyeing pressure-sensitive adhesive layer is 6 ~ 25 μm; The thickness of second polyester film or polyethylene film base material is 20 ~ 175 μm; The thickness of ultraviolet-resistant pressure-sensitive adhesive layer is 6 ~ 25 μm; The thickness of mould release membrance is 19 ~ 39 μm.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, the thickness of described ultraviolet-resistant dyeing pressure-sensitive adhesive layer is identical with the thickness of ultraviolet-resistant pressure-sensitive adhesive layer, or different.
In the ultraviolet color anti-fog fenestrated membrane of the obstruct of technique scheme, the thickness of described first polyester film or polyethylene film base material is identical with the thickness of second polyester film or polyethylene film base material, or different.
Technique effect of the present invention is: the ultraviolet color anti-fog fenestrated membrane of obstruct of the present invention has composite construction, it to be dyeed pressure-sensitive adhesive layer, second polyester film or polyethylene film base material, ultraviolet-resistant pressure-sensitive adhesive layer and release film layer form and each layer is complex as a whole by anti-fog layer, first polyester film or polyethylene film base material, ultraviolet-resistant, and each layer has mutual synergy.The ultraviolet-resistant pressure-sensitive adhesive layer of the ultraviolet color anti-fog fenestrated membrane of obstruct of the present invention is by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, acrylic acid adhesive, the mixed material of curing agent and solvent be coated in second polyester film or polyethylene film base material another on the surface heat cure obtain, due to select benzophenone with the composite use of the ultraviolet absorber of benzotriazole and with consumption appropriate be suitable for other component coordinate, under each component is mutually collaborative, make the ultraviolet-resistant pressure-sensitive adhesive layer that formed can the high molecular energy of quencher excitation state effectively and have the ability of enough seizure free radical Sum decomposition hydrogen peroxide, therefore, effectively can slow down the photodegradation of ultraviolet light and there is lasting ultraviolet-resistant effect, fenestrated membrane life cycle is made to obtain corresponding prolongation, and ultraviolet-resistant dyeing pressure-sensitive adhesive layer is also containing dyestuff, can likes according to client, add the dyestuff of different colours, make appearance looks elegant of the present invention, and the antifogging agent composition of described anti-fog layer coordinates owing to have selected suitable hydrophilic heat cure solvent type acrylic resin SAA901 with other suitable components, under each component is mutually collaborative, surface after the curing of coating that this antifogging agent composition is formed is hydrophilic, little with the contact angle of water, therefore, very thin moisture film can be formed on this surface and mist can not be tied, thus producing anti-fog effect.Show according to great many of experiments, the antifogging agent composition of described anti-fog layer and the contact angle of water reach less than 6.5 °, and antifog persistence is good, antifogly reach more than 1 year; The ultraviolet-resistant rate of the ultraviolet color anti-fog fenestrated membrane of obstruct of the present invention reaches more than 99%, and ultraviolet-resistant performance is lasting; In addition, the preparation method of obstruct of the present invention ultraviolet color anti-fog fenestrated membrane is simple to operation, combine firmly between each layer, use very convenient, during use, after being peeled off by the outermost layer of mould release membrance, be pasted onto vehicle glass or glass of building surface, can ultraviolet be intercepted, again can antifog, appearance looks elegant also safety lastingly.
Accompanying drawing explanation
Fig. 1 is the structural representation that the present invention intercepts ultraviolet color anti-fog fenestrated membrane;
Fig. 2 is the chemical structural formula that the present invention intercepts ultraviolet color anti-fog fenestrated membrane benzophenone type ultraviolet absorbent 2,2', 4,4'-used tetrahydroxybenzophenone;
Fig. 3 is the chemical structural formula that the present invention intercepts ultraviolet color anti-fog fenestrated membrane benzotriazole used ultraviolet absorber 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1,1-dimethyl ethyl)-4-methylphenol.
Detailed description of the invention
Below in conjunction with drawings and Examples, the present invention is further described in detail, but not limited.
Embodiment is raw materials used, unless otherwise indicated, is commercially available industrial goods, can be buied by commercial channel.
As shown in Figure 1, to the ultraviolet color anti-fog fenestrated membrane of obstruct of the present invention it to be dyeed pressure-sensitive adhesive layer 3, second polyester film or polyethylene film base material 2-2, ultraviolet-resistant pressure-sensitive adhesive layer 4 and mould release membrance 5 form and each layer is complex as a whole by anti-fog layer 1, first polyester film or polyethylene film base material 2-1, ultraviolet-resistant; Described anti-fog layer 1 ultraviolet light polymerization is combined on a surface of first polyester film or polyethylene film base material 2-1, ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 heat cure be combined in first polyester film or polyethylene film base material 2-1 another on the surface, the surface recombination of second polyester film or polyethylene film base material 2-2 is at the outer surface of ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, ultraviolet-resistant pressure-sensitive adhesive layer 4 heat cure be combined in second polyester film or polyethylene film base material 2-2 another on the surface, mould release membrance 5 is compounded in the outer surface of ultraviolet-resistant pressure-sensitive adhesive layer 4;
Described anti-fog layer 1 is with hydrophilic heat cure solvent type acrylic resin SAA9019 ~ 14wt%, propylene glycol monomethyl ether 55 ~ 76wt%, dimethyl formamide 3 ~ 10wt%, catalyst triethylene diamine 1 ~ 5wt%, levelling agent BYK-3331 ~ 5wt%, isopropyl alcohol 5 ~ 26wt%, the antifogging agent composition that ethanol 5 ~ 24wt% mixes formation is coated on a surface of first polyester film or polyethylene film base material 2-1, temperature 80 ~ 150 DEG C, obtain after heat cure, wherein, the each component sum forming the antifogging agent composition of anti-fog layer is 100wt%, described SAA901 is the product grade of Xi'an Naviation Sanwo Chemical Co., Ltd.,
Described ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 be coated in first polyester film or polyethylene film base material 2-1 with the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, dyestuff, acrylic acid adhesive, curing agent and solvent composition another on the surface, temperature 80 ~ 150 DEG C, place 10 ~ 180 seconds Post RDBMS and obtain ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3;
Described ultraviolet-resistant pressure-sensitive adhesive layer 4 be coated in second polyester film or polyethylene film base material 2-2 with the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, acrylic acid adhesive, curing agent and solvent composition another on the surface, temperature 80 ~ 150 DEG C, place 10 ~ 180 seconds Post RDBMS and obtain ultraviolet-resistant pressure-sensitive adhesive layer 4.
The antifogging agent composition of described formation anti-fog layer 1, the mixed material forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 and the mixed material forming ultraviolet-resistant pressure-sensitive adhesive layer 4 adopt jetting type coating, or scraper type coating process carries out applying.
The mixed material forming described ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, dyestuff 0.05 ~ 10wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, above-mentioned each component sum is 100wt%, during preparation, each amounts of components is selected in above-mentioned scope, at environment temperature is 18 ~ 28 DEG C, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixes with solvent ethyl acetate and after stirring 12 ~ 18 minutes, add dyestuff and solvent toluene mixture and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, can save backup, wherein, benzophenone type ultraviolet absorbent is 2, 2', 4, 4'-tetrahydroxybenzophenone, benzotriazole ultraviolet absorber is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1, 1-dimethyl ethyl)-4-methylphenol, dyestuff is organic dyestuff.
The mixed material forming described ultraviolet-resistant pressure-sensitive adhesive layer 4 is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, above-mentioned each component sum is 100wt%, during preparation, each amounts of components is selected in above-mentioned scope, at environment temperature is 18 ~ 28 DEG C, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber and solvent ethyl acetate, solvent toluene mixes and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, can save backup, wherein, benzophenone type ultraviolet absorbent is 2, 2', 4, 4'-tetrahydroxybenzophenone, benzotriazole ultraviolet absorber is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1, 1-dimethyl ethyl)-4-methylphenol.
Described first polyester film or polyethylene film base material 2-1 and second polyester film or polyethylene film base material 2-2 are transparent polyester film or polyethylene film base material, or dyeing polyester film or polyethylene film base material or primary colors polyester film or polyethylene film base material, or ultraviolet-resistant polyester film or polyethylene film base material, or aluminized polyester film or polyethylene film base material, or magnetron sputtering polyester film or polyethylene film base material.
Described first polyester film or polyethylene film base material 2-1 identical with the type of substrate that second polyester film or polyethylene film base material 2-2 use, or different.
Described obstruct ultraviolet color anti-fog fenestrated membrane thickness is 72 ~ 444 μm, and wherein, the thickness of anti-fog layer 1 is 1 ~ 5 μm; The thickness of first polyester film or polyethylene film base material 2-1 is 20 ~ 175 μm; The thickness of ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 is 6 ~ 25 μm; The thickness of second polyester film or polyethylene film base material 2-2 is 20 ~ 175 μm; The thickness of ultraviolet-resistant pressure-sensitive adhesive layer 4 is 6 ~ 25 μm; The thickness of mould release membrance 5 is 19 ~ 39 μm.
The thickness of described ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 is identical with the thickness of ultraviolet-resistant pressure-sensitive adhesive layer 4, or different.
The thickness of described first polyester film or polyethylene film base material 2-1 is identical with the thickness of second polyester film or polyethylene film base material 2-2, or different.
Embodiment preparation intercepts ultraviolet color anti-fog fenestrated membrane
Concrete operations are as follows:
(A) raw material is prepared
1. base material is prepared
Thickness is first transparent polyester film base material 2-1 of 23 μm; Prepare second transparent polyester film base material 2-2 that thickness is 36 μm; Prepare the mould release membrance 5 that thickness is 23 μm;
2. preparation forms the antifogging agent composition A ~ C of anti-fog layer
The antifogging agent composition forming anti-fog layer is by hydrophilic heat cure solvent type acrylic resin SAA9019 ~ 14wt%, propylene glycol monomethyl ether 55 ~ 76wt%, dimethyl formamide 3 ~ 10wt%, catalyst triethylene diamine 1 ~ 5wt%, levelling agent BYK-3331 ~ 5wt%, isopropyl alcohol 5 ~ 26wt%, ethanol 5 ~ 24wt% mixes formation, wherein, each component sum forming the antifogging agent composition of anti-fog layer is 100wt%, specifically fills a prescription in table 1.
Take each component by table 1 formula ratio and put into container, at environment temperature is 18 ~ 28 DEG C, is uniformly mixed the antifogging agent composition A ~ C that can obtain respectively and form anti-fog layer, packages spare.
Table 1
note 1:SAA901 is the product grade of Xi'an Naviation Sanwo Chemical Co., Ltd.; Propylene glycol monomethyl ether, dimethyl formamide, triethylene diamine are Shanghai Experimental Reagent Co., Ltd.'s product; BYK-333 is the product grade of German Bi Ke chemical company; Isopropyl alcohol and ethanol are from Changzhou Asource Chemical Co., Ltd.;
Note 2:SAA901 properties of product: outward appearance is colourless transparent liquid, and its solid is divided into 44.5 ± 1wt%(150 DEG C of mensuration), viscosity is 5 ± 0.5cps/25 DEG C;
Note 3: above-mentioned raw materials used also can be replaced by the equivalents of different factory;
3. preparation forms the mixed material A ~ C of ultraviolet-resistant dyeing pressure-sensitive adhesive layer
The mixed material forming described ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3 is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, dyestuff 0.5 ~ 10wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% form, above-mentioned each component sum is 100wt%, specifically fills a prescription in table 2.
Each component is taken by table 2 formula ratio, at environment temperature is 18 ~ 28 DEG C, in container, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixes with solvent ethyl acetate and after stirring 12 ~ 18 minutes, add dyestuff and solvent toluene mixture and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, mixed material A ~ the C forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer can be obtained respectively, package spare.
Table 2
note 1: benzophenone type ultraviolet absorbent SUV1 is 2,2', 4,4'-tetrahydroxybenzophenone, as shown in Figure 2, benzotriazole ultraviolet absorber CBT is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1,1-dimethyl ethyl)-4-methylphenol to its chemical structural formula, its chemical structural formula as shown in Figure 3, and the two be Shanghai Zhi Xian Chemical Co., Ltd. produce; Ethyl acetate and toluene are from Changzhou Asource Chemical Co., Ltd.; Dyestuff is the Kelly green colouring material that dyeing limited company of sub-nation produces, its solids content 40wt%;
Note 2: above-mentioned raw materials used also can be replaced by the equivalents of different factory;
4. preparation forms the mixed material D ~ F of ultraviolet-resistant pressure-sensitive adhesive layer
The mixed material forming ultraviolet-resistant pressure-sensitive adhesive layer is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, and above-mentioned each component sum is 100wt%, specifically fills a prescription in table 3.
Each component is taken by table 3 formula ratio, at environment temperature is 18 ~ 28 DEG C, in container, first benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixed with solvent ethyl acetate and toluene and stir 12 ~ 18 minutes, adding acrylic acid adhesive stirs after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, mixed material D ~ the F forming ultraviolet-resistant pressure-sensitive adhesive layer can be obtained respectively, package spare.
Table 3
note 1: benzophenone type ultraviolet absorbent SUV1 is 2,2', 4,4'-tetrahydroxybenzophenone, as shown in Figure 2, benzotriazole ultraviolet absorber CBT is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1,1-dimethyl ethyl)-4-methylphenol to its chemical structural formula, its chemical structural formula as shown in Figure 3, and the two be Shanghai Zhi Xian Chemical Co., Ltd. produce; Ethyl acetate and toluene are from Changzhou Asource Chemical Co., Ltd.;
Note 2: above-mentioned raw materials used also can be replaced by the equivalents of different factory;
(B) preparation intercepts ultraviolet color anti-fog fenestrated membrane
1. preparation intercepts ultraviolet color anti-fog fenestrated membrane A
On a surface of transparent polyester film base material 2-1, after coating forms the antifogging agent composition A of anti-fog layer 1, temperature 80 ~ 150 DEG C, anti-fog layer 1 is obtained after heat cure, after applying at another of transparent polyester film base material 2-1 mixed material A forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer on the surface, temperature 80 ~ 130 DEG C, place 10 ~ 120 seconds Post RDBMS and obtain ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, the surface recombination of transparent polyester film base material 2-2 is at the outer surface of ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, apply the mixed material of the mixed material D forming ultraviolet-resistant pressure-sensitive adhesive layer on the surface at another of transparent polyester film base material 2-2 after, temperature 80 ~ 130 DEG C, place 10 ~ 120 seconds Post RDBMS and obtain ultraviolet-resistant pressure-sensitive adhesive layer 4, again mould release membrance 5 is compounded in ultraviolet-resistant pressure-sensitive adhesive layer 4 outer surface, thus obtain obstruct ultraviolet color anti-fog fenestrated membrane A(that each layer is complex as a whole as shown in Figure 1).
2. preparation intercepts ultraviolet color anti-fog fenestrated membrane B
On a surface of transparent polyester film base material 2-1, after coating forms the antifogging agent composition B of anti-fog layer 1, temperature 80 ~ 150 DEG C, anti-fog layer 1 is obtained after heat cure, after applying at another of transparent polyester film base material 2-1 mixed material B forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer on the surface, temperature 80 ~ 130 DEG C, place 10 ~ 120 seconds Post RDBMS and obtain ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, the surface recombination of transparent polyester film base material 2-2 is at the outer surface of ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, apply the mixed material of the mixed material E forming ultraviolet-resistant pressure-sensitive adhesive layer on the surface at another of transparent polyester film base material 2-2 after, temperature 80 ~ 130 DEG C, place 10 ~ 120 seconds Post RDBMS and obtain ultraviolet-resistant pressure-sensitive adhesive layer 4, again mould release membrance 5 is compounded in ultraviolet-resistant pressure-sensitive adhesive layer 4 outer surface, thus obtain obstruct ultraviolet color anti-fog fenestrated membrane B(that each layer is complex as a whole as shown in Figure 1).
3. preparation intercepts ultraviolet color anti-fog fenestrated membrane C
On a surface of transparent polyester film base material 2-1, after coating forms the antifogging agent composition C of anti-fog layer 1, temperature 80 ~ 150 DEG C, anti-fog layer 1 is obtained after heat cure, after applying at another of transparent polyester film base material 2-1 mixed material C forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer on the surface, temperature 80 ~ 130 DEG C, place 10 ~ 120 seconds Post RDBMS and obtain ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, the surface recombination of transparent polyester film base material 2-2 is at the outer surface of ultraviolet-resistant dyeing pressure-sensitive adhesive layer 3, apply the mixed material of the mixed material F forming ultraviolet-resistant pressure-sensitive adhesive layer on the surface at another of transparent polyester film base material 2-2 after, temperature 80 ~ 130 DEG C, place 10 ~ 120 seconds Post RDBMS and obtain ultraviolet-resistant pressure-sensitive adhesive layer 4, again mould release membrance 5 is compounded in ultraviolet-resistant pressure-sensitive adhesive layer 4 outer surface, thus obtain obstruct ultraviolet color anti-fog fenestrated membrane C(that each layer is complex as a whole as shown in Figure 1).
(C) the ultraviolet color anti-fog fenestrated membrane performance of obstruct is detected
The performance of the obstruct of above-mentioned preparation ultraviolet color anti-fog fenestrated membrane A ~ C is detected, the results are shown in Table 4.
Table 4
Note: in table 4, every data be the present invention as follows embodiment obtained intercept ultraviolet color anti-fog fenestrated membrane A ~ C carry out detect obtain:
1. water contact angle: use Japanese G-1 type contact angle instrument to test at the position, three, left, center, right of the anti-fog surface (i.e. anti-fog layer 1) intercepting ultraviolet color anti-fog fenestrated membrane, get the mean value of three site tests data;
2. light transmittance: adopt the solar film transmission measurement instrument (model LS103) that Lin Shang Science and Technology Ltd. of Shenzhen produces, carries out with reference to ASTMD1003 standard method;
3. anti-fog properties: under room temperature, it is above the water surface of 60 DEG C that the anti-fog surface (i.e. anti-fog layer 1) intercepting ultraviolet color anti-fog fenestrated membrane is placed in water temperature, its fenestrated membrane anti-fog surface (i.e. anti-fog layer 1) and water surface distance are 10cm, observe anti-fog layer 1 surface intercepting ultraviolet color anti-fog fenestrated membrane, whether hazed in 1 hour;
4. resistance to water: ultraviolet for obstruct color anti-fog fenestrated membrane is placed in respectively 0 DEG C, 20 DEG C, 40 DEG C water after 48 hours, observes the coating damage situation of the anti-fog layer 1 intercepting ultraviolet color anti-fog fenestrated membrane;
5. ultraviolet-resistant rate: adopt Japanese Shimadzu UV-3600 type spectrophotometer to test, with reference to standard GB/T/T2680;
6. peel strength: with reference to standard GB/T/T2792;
7. hardness: with reference to standard GB/T/T6739.
As can be seen from table 3 testing result, the ultraviolet color anti-fog fenestrated membrane of obstruct of the present invention, can be antifog lastingly, and ultraviolet-resistant rate > 99%, appearance looks elegant.Its product light transmission, hardness, peel strength all meet user's requirement.
Use the ultraviolet color anti-fog fenestrated membrane of obstruct of the present invention very simple, as long as according to after concrete size cutting, after being peeled off by the outermost layer of mould release membrance 5, be pasted onto glass surface.The glass such as building, automobile is pasted after the present invention intercepts ultraviolet color anti-fog fenestrated membrane, can play very well and intercept ultraviolet, appearance looks elegant, effect antifog lastingly.
Claims (7)
1. intercept a ultraviolet color anti-fog fenestrated membrane, it is characterized in that,
It to be dyeed pressure-sensitive adhesive layer (3), second polyester film or polyethylene film base material (2-2), ultraviolet-resistant pressure-sensitive adhesive layer (4) and mould release membrance (5) form and each layer is complex as a whole by anti-fog layer (1), first polyester film or polyethylene film base material (2-1), ultraviolet-resistant, described anti-fog layer (1) heat cure is combined on a surface of first polyester film or polyethylene film base material (2-1), ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) heat cure be combined in first polyester film or polyethylene film base material (2-1) another on the surface, a surface recombination of second polyester film or polyethylene film base material (2-2) dyes at ultraviolet-resistant the outer surface of pressure-sensitive adhesive layer (3), ultraviolet-resistant pressure-sensitive adhesive layer (4) heat cure be combined in second polyester film or polyethylene film base material (2-2) another on the surface, mould release membrance (5) is compounded in the outer surface of ultraviolet-resistant pressure-sensitive adhesive layer (4),
Described anti-fog layer (1) is with hydrophilic heat cure solvent type acrylic resin SAA9019 ~ 14wt%, propylene glycol monomethyl ether 55 ~ 76wt%, dimethyl formamide 3 ~ 10wt%, catalyst triethylene diamine 1 ~ 5wt%, levelling agent BYK-3331 ~ 5wt%, isopropyl alcohol 5 ~ 26wt%, the antifogging agent composition that ethanol 5 ~ 24wt% mixes formation is coated on a surface of first polyester film or polyethylene film base material (2-1), temperature 80 ~ 150 DEG C, obtain after heat cure, wherein, the each component sum forming the antifogging agent composition of anti-fog layer is 100wt%, described SAA901 is the product grade of Xi'an Naviation Sanwo Chemical Co., Ltd.,
Described ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) be coated in first polyester film or polyethylene film base material (2-1) with the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, dyestuff, acrylic acid adhesive, curing agent and solvent composition another on the surface, temperature 80 ~ 150 DEG C, place 10 ~ 180 seconds Post RDBMS and obtain ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3), the mixed material forming described ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, dyestuff 0.05 ~ 10wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, above-mentioned each component sum is 100wt%, during preparation, each amounts of components is selected in above-mentioned scope, at environment temperature is 18 ~ 28 DEG C, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixes with solvent ethyl acetate and after stirring 12 ~ 18 minutes, add dyestuff and solvent toluene mixture and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, can save backup, wherein, benzophenone type ultraviolet absorbent is 2, 2', 4, 4'-tetrahydroxybenzophenone, benzotriazole ultraviolet absorber is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1, 1-dimethyl ethyl)-4-methylphenol, dyestuff is organic dyestuff,
Described ultraviolet-resistant pressure-sensitive adhesive layer (4) be coated in second polyester film or polyethylene film base material (2-2) with the mixed material of benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber, acrylic acid adhesive, curing agent and solvent composition another on the surface, temperature 80 ~ 150 DEG C, place 10 ~ 180 seconds Post RDBMS and obtain ultraviolet-resistant pressure-sensitive adhesive layer (4), the mixed material forming described ultraviolet-resistant pressure-sensitive adhesive layer (4) is by benzophenone type ultraviolet absorbent 0.2 ~ 2.0wt%, benzotriazole ultraviolet absorber 0.2 ~ 2.0wt%, solvent ethyl acetate 20 ~ 35wt%, solvent toluene 10 ~ 25wt%, acrylic acid adhesive 50 ~ 65wt%, curing agent 0.5 ~ 2.0wt% forms, above-mentioned each component sum is 100wt%, during preparation, each amounts of components is selected in above-mentioned scope, at environment temperature is 18 ~ 28 DEG C, first by benzophenone type ultraviolet absorbent, benzotriazole ultraviolet absorber mixes with solvent ethyl acetate and solvent toluene and after stirring 12 ~ 18 minutes, add acrylic acid adhesive, stir after 18 ~ 22 minutes, add after curing agent stirs 12 ~ 18 minutes again, measuring viscosity with rotation viscometer or Cai's grace cup is 80 ~ 300 centipoises, can save backup, wherein, benzophenone type ultraviolet absorbent is 2, 2', 4, 4'-tetrahydroxybenzophenone, benzotriazole ultraviolet absorber is 2-(the chloro-2H-124 Triazole of 5--2-base)-6-(1, 1-dimethyl ethyl)-4-methylphenol.
2. the ultraviolet color anti-fog fenestrated membrane of obstruct according to claim 1, it is characterized in that, the antifogging agent composition of described formation anti-fog layer (1), the mixed material forming ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) and the mixed material forming ultraviolet-resistant pressure-sensitive adhesive layer (4) adopt jetting type coating, or scraper type coating process carries out applying.
3. the ultraviolet color anti-fog fenestrated membrane of obstruct according to claim 1, it is characterized in that, described first polyester film or polyethylene film base material (2-1) and second polyester film or polyethylene film base material (2-2) are transparent polyester film or polyethylene film base material, or dyeing polyester film or polyethylene film base material or primary colors polyester film or polyethylene film base material, or ultraviolet-resistant polyester film or polyethylene film base material, or aluminized polyester film or polyethylene film base material, or magnetron sputtering polyester film or polyethylene film base material.
4. the ultraviolet color anti-fog fenestrated membrane of obstruct according to claim 3, is characterized in that, described first polyester film or polyethylene film base material (2-1) identical with the type of substrate that second polyester film or polyethylene film base material (2-2) use, or different.
5. the ultraviolet color anti-fog fenestrated membrane of obstruct according to claim 1, is characterized in that, described obstruct ultraviolet color anti-fog fenestrated membrane thickness is 72 ~ 444 μm, and wherein, the thickness of anti-fog layer (1) is 1 ~ 5 μm; The thickness of first polyester film or polyethylene film base material (2-1) is 20 ~ 175 μm; The thickness of ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) is 6 ~ 25 μm; The thickness of second polyester film or polyethylene film base material (2-2) is 20 ~ 175 μm; The thickness of ultraviolet-resistant pressure-sensitive adhesive layer (4) is 6 ~ 25 μm; The thickness of mould release membrance (5) is 19 ~ 39 μm.
6. the ultraviolet color anti-fog fenestrated membrane of obstruct according to claim 5, is characterized in that, the thickness of described ultraviolet-resistant dyeing pressure-sensitive adhesive layer (3) is identical with the thickness of ultraviolet-resistant pressure-sensitive adhesive layer (4), or different.
7. the ultraviolet color anti-fog fenestrated membrane of obstruct according to claim 5, is characterized in that, the thickness of described first polyester film or polyethylene film base material (2-1) is identical with the thickness of second polyester film or polyethylene film base material (2-2), or different.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410390527.XA CN104175666B (en) | 2014-08-08 | 2014-08-08 | Intercept ultraviolet color anti-fog fenestrated membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410390527.XA CN104175666B (en) | 2014-08-08 | 2014-08-08 | Intercept ultraviolet color anti-fog fenestrated membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104175666A CN104175666A (en) | 2014-12-03 |
| CN104175666B true CN104175666B (en) | 2016-04-20 |
Family
ID=51957154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410390527.XA Active CN104175666B (en) | 2014-08-08 | 2014-08-08 | Intercept ultraviolet color anti-fog fenestrated membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104175666B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107160801A (en) * | 2017-05-15 | 2017-09-15 | 张家港康得新光电材料有限公司 | A kind of primary colors film |
| CN108219700B (en) * | 2017-12-29 | 2023-07-28 | 常州山由帝杉防护材料制造有限公司 | Preparation method of color functional layer of window film, window film containing color functional layer and preparation method of window film |
| CN111430550A (en) * | 2020-03-26 | 2020-07-17 | 杭州纤纳光电科技有限公司 | Perovskite battery component with ultraviolet protection layer and preparation method thereof |
| CN114989716A (en) * | 2022-07-08 | 2022-09-02 | 广东本研新材料科技有限公司 | Light-resistant coating composition for nail polish gel bottle surface, nail polish gel bottle and preparation method of nail polish gel bottle |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201566187U (en) * | 2009-10-30 | 2010-09-01 | 常州山由帝杉防护材料制造有限公司 | Uvioresistant color protecting scrapping resistance window film |
| CN102618102A (en) * | 2012-03-23 | 2012-08-01 | 常州山由帝杉防护材料制造有限公司 | Antifogging agent composition and antifogging colored window film formed by same |
| CN202986257U (en) * | 2012-12-27 | 2013-06-12 | 武汉羿阳科技有限公司 | Novel heat insulation ceramic window film |
| CN103146317A (en) * | 2013-02-20 | 2013-06-12 | 武汉羿阳科技有限公司 | Heat insulation window film for shielding full-wave-band infrared and ultraviolet rays, and its making method |
-
2014
- 2014-08-08 CN CN201410390527.XA patent/CN104175666B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201566187U (en) * | 2009-10-30 | 2010-09-01 | 常州山由帝杉防护材料制造有限公司 | Uvioresistant color protecting scrapping resistance window film |
| CN102618102A (en) * | 2012-03-23 | 2012-08-01 | 常州山由帝杉防护材料制造有限公司 | Antifogging agent composition and antifogging colored window film formed by same |
| CN202986257U (en) * | 2012-12-27 | 2013-06-12 | 武汉羿阳科技有限公司 | Novel heat insulation ceramic window film |
| CN103146317A (en) * | 2013-02-20 | 2013-06-12 | 武汉羿阳科技有限公司 | Heat insulation window film for shielding full-wave-band infrared and ultraviolet rays, and its making method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104175666A (en) | 2014-12-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104149453B (en) | Intercept ultraviolet fenestrated membrane | |
| CN104175664B (en) | Intercept ultraviolet thermal-insulation window film | |
| CN104149433B (en) | Intercept ultraviolet fenestrated membrane | |
| CN102618102B (en) | Antifogging agent composition and antifogging colored window film formed by same | |
| CN102863854B (en) | High chlorinated potyethlene anti-corrosive paint and preparation method thereof | |
| CN104175666B (en) | Intercept ultraviolet color anti-fog fenestrated membrane | |
| CN103703036B (en) | Monolayer film and hydrophilic material comprising same | |
| US20150207001A1 (en) | Colored glass and solar cell assembly using the same | |
| CN104149431B (en) | Intercept ultraviolet color anti-fog thermal-insulation window film | |
| CN106218172A (en) | Photochromic fenestrated membrane | |
| CN102618101B (en) | Antifoggant composition and antifog and heat-insulation colored window film formed by composition | |
| CN105199558A (en) | Coil coating having special anode oxidation effect and special for aluminum plate coiled material and preparation method of coil coating | |
| WO2010079923A3 (en) | Transparent color coating composition containing nanosize dispersed pigments, coated substrate and method for preparing same | |
| CN104226567B (en) | A kind of clear transparent composite coating painting method of UV resistant | |
| CN104175665B (en) | Intercept ultraviolet coloured thermal-insulation window film | |
| CN104149432B (en) | Intercept ultraviolet clear anti-fog fenestrated membrane | |
| CN103254715B (en) | Transparent acrylic acid intermediate-coating paint base stock and preparation method thereof | |
| CN107059473B (en) | Colour code book, colour code aluminized paper and colour code aluminized paper processing technology | |
| CN103265878A (en) | Powder coating for vacuum coating and bottom layer of metal substrate and preparation method of powder coating | |
| CN204054825U (en) | The ultraviolet color anti-fog fenestrated membrane of a kind of obstruct | |
| CN204054821U (en) | Intercept ultraviolet reflection fenestrated membrane | |
| CN204054823U (en) | The ultraviolet clear anti-fog fenestrated membrane of a kind of obstruct | |
| CN204196385U (en) | The ultraviolet color anti-fog thermal-insulation window film of a kind of obstruct | |
| CN104403552B (en) | Outdoor use high-performance optical storage-spontaneous luminous membrane preparation method | |
| CN204054824U (en) | The ultraviolet coloured thermal-insulation window film of a kind of obstruct |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 213000 Wujin Economic Development Zone, Jiangsu, Changzhou Patentee after: Jiangsu Aerospace Shanyou Technology Co.,Ltd. Address before: No. 3 Daoxiang West Road, Wujin Economic Development Zone, Changzhou City, Jiangsu Province, China Patentee before: CHANGZHOU SANYOU DISSAN PROTECTIVE MATERIAL MANUFACTURING Co.,Ltd. |
|
| CP03 | Change of name, title or address |