CN102618102A - Antifogging agent composition and antifogging colored window film formed by same - Google Patents
Antifogging agent composition and antifogging colored window film formed by same Download PDFInfo
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- CN102618102A CN102618102A CN2012100781810A CN201210078181A CN102618102A CN 102618102 A CN102618102 A CN 102618102A CN 2012100781810 A CN2012100781810 A CN 2012100781810A CN 201210078181 A CN201210078181 A CN 201210078181A CN 102618102 A CN102618102 A CN 102618102A
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- acrylic acid
- acid adhesive
- adhesive layer
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- transparent
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- 239000000203 mixture Substances 0.000 title claims abstract description 68
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 141
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 141
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 109
- 239000012790 adhesive layer Substances 0.000 claims abstract description 90
- 229920006267 polyester film Polymers 0.000 claims abstract description 51
- 239000004698 Polyethylene Substances 0.000 claims abstract description 46
- -1 polyethylene Polymers 0.000 claims abstract description 46
- 229920000573 polyethylene Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims abstract description 10
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 6
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims abstract description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 78
- 239000000463 material Substances 0.000 claims description 58
- 239000002585 base Substances 0.000 claims description 56
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 52
- 239000000853 adhesive Substances 0.000 claims description 51
- 230000001070 adhesive effect Effects 0.000 claims description 51
- 239000012528 membrane Substances 0.000 claims description 50
- 239000007787 solid Substances 0.000 claims description 40
- 239000011248 coating agent Substances 0.000 claims description 37
- 238000000576 coating method Methods 0.000 claims description 37
- 239000000975 dye Substances 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 10
- 238000009998 heat setting Methods 0.000 claims description 9
- 230000006798 recombination Effects 0.000 claims description 8
- 238000005215 recombination Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000009740 moulding (composite fabrication) Methods 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 description 16
- 239000011521 glass Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000010410 layer Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 5
- 239000003086 colorant Substances 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000002688 persistence Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004218 Orcein Substances 0.000 description 1
- 206010047513 Vision blurred Diseases 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000019248 orcein Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Abstract
The invention relates to an antifogging agent composition and an antifogging colored window film formed by the same. The antifogging agent composition comprises 9-14wt% of hydrophilic resin, 55-76wt% of propylene glycol methyl ether, 3-10wt% of dimethyl methylamine, 1-5wt% of triethylene-diamine, 1-5wt% of leveling agent, 5-26wt% of isopropanol and 5-24wt% of ethanol. The antifogging colored window film comprises an antifogging agent coating layer (1), a first transparent polyester film or transparent polyethylene film substrate (2-1), a dyed acrylic acid adhesive layer (3-1), a second transparent polyester film or transparent polyethylene film substrate (2-2), an acrylic acid adhesive layer (3-2) and a releasing film (4) which are integrally composited, wherein the antifogging agent coating layer (1) is formed by the antifogging agent composition. The antifogging colored window film is antifogging, attractive, transparent and safe.
Description
Technical field
The present invention relates to a kind of antifogging agent composition and, be particularly suitable for sticking on glass surface or the glass surface in bathroom or the glass surface of automobile of buildings with antifog coloured fenestrated membrane that said composition forms.
Background technology
The glass surface knot mist of all kinds of glass door and windows brings very big inconvenience for production and life; And if the fenestrated membrane that the glass surface of automobile is pasted does not possess anti-fog function; Particularly behind knot mist under the situation of bad weather, make and person for driving a car's blurred vision bring very big hidden danger to safety.Antifog method mainly contains electrical heating method and uses anti-fog coating at present, but the former respond well price is high, the wasting of resources is big, and the latter just is sprayed on anti-fog coating surfaces such as glass, but can not solidify, so antifog persistence is poor.In addition, existing fenestrated membrane is difficult to take into account requirement antifog, attractive in appearance.Therefore, be badly in need of a kind of antifogging agent of exploitation and also can antifogging agent be applied on the fenestrated membrane, make fenestrated membrane not only attractive in appearance, transparent, persistent anti-fog effect is arranged again.
Summary of the invention
First purpose of the present invention is: provides a kind of and not only makes simply, and the good antifogging agent composition of antifog persistence.
The technical scheme that realizes first purpose of the present invention is: a kind of antifogging agent composition, its innovative point are that it is that following component mixes formation at normal temperatures, and the proportioning of its each component is following:
Hydrophilic resin 9～14 wt%
Propylene glycol monomethyl ether 55～76 wt%
Dimethyl-methylamine 3～10 wt%
Triethylene diamine 1～5 wt%
Flow agent 1～5 wt%
Virahol 5～26 wt%
Ethanol 5～24 wt%
Above-mentioned each component sum is 100 wt%;
Said hydrophilic resin is hydrophilic acrylate's quasi-oligomer;
Said antifogging agent composition is at 80 ℃～150 ℃ film-formings.
In above-mentioned antifogging agent composition, said hydrophilic resin is the SAA901 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Said flow agent is the BYK-333 product of German Bi Ke chemical company.
Second purpose of the present invention is: provide a kind of can lastingly antifog attractive in appearance, transparent again antifog coloured fenestrated membrane.
The technical scheme that realizes second purpose of the present invention is: antifog coloured fenestrated membrane that the above-mentioned antifogging agent composition of a kind of usefulness forms; Its innovative point is, it is to be constituted and compoundly be one by antifogging agent coating, first transparent polyester film or transparent polyethylene film base material, painted acrylic acid adhesive layer, second transparent polyester film or transparent polyethylene film base material, acrylic acid adhesive layer and dicing film; The thermofixation of said antifogging agent coating is combined on the surface of first transparent polyester film or transparent polyethylene film base material; The thermofixation of painted acrylic acid adhesive layer is combined on another surface of first transparent polyester film or transparent polyethylene film base material; A surface recombination of second transparent polyester film or transparent polyethylene film base material is at painted acrylic acid adhesive layer outside surface; The thermofixation of acrylic acid adhesive layer is combined on another surface of second transparent polyester film or transparent polyethylene film base material, and dicing film is compounded in acrylic acid adhesive layer outside surface;
Said antifogging agent coating is to be coated on the surface of first transparent polyester film or transparent polyethylene film base material with above-mentioned antifogging agent composition, 80～150 ℃ of temperature, places that 10～180 seconds after fixing form;
Said painted acrylic acid adhesive layer is to be coated on another surface of first transparent polyester film or transparent polyethylene film base material with the mixture that contains dyestuff; 80～130 ℃ of temperature, place that 10～120 seconds after fixing form, wherein; The mixture that contains dyestuff is to be 0.01～3.0: 9～60 with mass ratio: 0.003～0.02: 5～24: 3～12 dyestuff: acrylic acid adhesive: solidifying agent: butanone: toluene is raw material; In envrionment temperature is under 18～28 ℃, earlier butanone and dyestuff are mixed and stir 8～12 minutes after, add toluene and acrylic acid adhesive again; After mixing and stir 12～18 minutes; Add the solidifying agent restir after 18～22 minutes, its viscosity is 80～300 centipoises
A surface recombination of said second transparent polyester film or transparent polyethylene film base material is at painted acrylic acid adhesive layer outside surface;
Said acrylic acid adhesive layer is to be coated on another surface of second transparent polyester film or transparent polyethylene film base material with the acrylic acid adhesive mixture; 80～130 ℃ of temperature; Place that 10～120 seconds after fixing form, wherein, the acrylic acid adhesive mixture is to be 4～50: 0.003～0.2 with mass ratio: 1～15: 2～35 acrylic acid adhesive: solidifying agent: toluene: butanone is a raw material; In envrionment temperature is under 18～28 ℃; After earlier butanone, toluene and acrylic acid adhesive being mixed and stir 12～18 minutes, adding solidifying agent restir formed after 18～22 minutes, and its viscosity is 80～300 centipoises.
In above-mentioned antifog coloured fenestrated membrane; Acrylic acid adhesive in said painted acrylic acid adhesive layer and the acrylic acid adhesive layer is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 4.5wt%～5.5wt%; Acrylic acid adhesive in perhaps said painted acrylic acid adhesive layer and the acrylic acid adhesive layer is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 4.5wt%～5.5wt%; Acrylic acid adhesive in the perhaps said painted acrylic acid adhesive layer is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 4.5wt%～5.5wt%, and the acrylic acid adhesive in the acrylic acid adhesive layer is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 4.5wt%～5.5wt%; Acrylic acid adhesive in the perhaps said painted acrylic acid adhesive layer is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 4.5wt%～5.5wt%, and the acrylic acid adhesive in the acrylic acid adhesive layer is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 40wt%～45wt%; Solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 4.5wt%～5.5wt%.
In above-mentioned antifog coloured fenestrated membrane, said antifog coloured fenestrated membrane thickness is 78～441 μ m, and wherein, the thickness of antifogging agent coating is 1～2 μ m; The thickness of first transparent polyester film or transparent polyethylene film base material is 23～175 μ m; The thickness of painted acrylic acid adhesive layer is 6～25 μ m; The thickness of second transparent polyester film or transparent polyethylene film base material is 23～175 μ m; The acrylic acid adhesive layer is 6～25 μ m; The thickness of dicing film is 19～39 μ m.
In above-mentioned antifog coloured fenestrated membrane, the thickness of said painted acrylic acid adhesive layer is identical with the thickness of acrylic acid adhesive layer, and is perhaps different.
In above-mentioned antifog coloured fenestrated membrane, the thickness of said first transparent polyester film or transparent polyethylene film base material is identical with the thickness of second transparent polyester film or transparent polyethylene film base material, and is perhaps different.
Technique effect of the present invention is: the 1. antifogging agent composition of technical scheme of the present invention, owing to selected suitable hydrophilic resin to cooperate with other suitable components, each amounts of components is appropriate; Down collaborative each other in each component; Make that the surface behind the curing of coating that said composition forms is hydrophilic, little with the contact angle of water, therefore; Can form as thin as a wafer moisture film on this surface and can not tie mist, thereby produce anti-fog effect.Show that according to a large amount of experiments the contact angle of filming after the curing of antifogging agent composition of the present invention with water reaches below 6.5 °, antifog persistence is good, antifog reaching more than 1 year.Each component of antifogging agent composition of the present invention is easy to get, and prepares simply, easy to operate, and production cost is low; 2. antifog coloured fenestrated membrane of the present invention has composite structure; It is to be constituted and compoundly be one by antifogging agent coating, first transparent polyester film or transparent polyethylene film base material, painted acrylic acid adhesive layer, second transparent polyester film or transparent polyethylene film base material, acrylic acid adhesive layer and dicing film, and each layer has mutual synergy.Antifog coloured fenestrated membrane of the present invention is above-mentioned antifogging agent composition of the present invention to be coated in solidify the back on the surface of first transparent polyester film or transparent polyethylene film base material and form the antifogging agent coating; Therefore; Can form as thin as a wafer moisture film at the antifogging agent coatingsurface of fenestrated membrane and can not tie mist, reach antifog effect; Set painted acrylic acid adhesive layer in antifog coloured fenestrated membrane of the present invention; Can be according to client's difference hobby and requirement; Be mixed with the painted acrylic acid adhesive of different colours with dyes in different colors or dye mixture; It is coated on another surface of first transparent polyester film or transparent polyethylene film base material, solidifies the painted acrylic acid adhesive layer that the back just can obtain different colours, and then obtain the fenestrated membrane of different colours; Simple and convenient, and the material that antifog coloured each layer of fenestrated membrane of the present invention selected for use all has good transmittance.Therefore, the transmittance of antifog coloured fenestrated membrane of the present invention can reach more than 70% and (see table 2).In addition, antifog coloured fenestrated membrane preparation method of the present invention is simple to operation, combines between each layer firmly, uses very conveniently, and the glass surface that sticks on automobile or glass door and window after the dicing film outermost layer peeled off can be realized antifog, decorative effect.
Description of drawings
Fig. 1 is the structural representation of the antifog coloured fenestrated membrane of the present invention.
Embodiment
Below in conjunction with accompanying drawing and embodiment the present invention is made further specific descriptions, but not limited.
Each embodiment is raw materials used, unless otherwise indicated, is commercially available industrial goods, can buy through the commercial channel.
Antifogging agent composition of the present invention is that following component mixes formation at normal temperatures, and the proportioning of its each component is following:
Hydrophilic resin 9～14 wt%
Propylene glycol monomethyl ether 55～76 wt%
Dimethyl-methylamine 3～10 wt%
Triethylene diamine 1～5 wt%
Flow agent 1～5 wt%
Virahol 5～26 wt%
Ethanol 5～24 wt%
Above-mentioned each component sum is 100 wt%;
Said hydrophilic resin is hydrophilic acrylate's quasi-oligomer;
Said antifogging agent composition is at 80 ℃～150 ℃ film-formings.
Embodiment 1 preparation antifogging agent composition A～C
1. fill a prescription
Concrete prescription is seen table 1.
Table 1
Annotating 1:SAA901 is the product grade of Xi'an Naviation Sanwo Chemical Co., Ltd.'s hydrophilic resin; Propylene glycol monomethyl ether, dimethyl-methylamine, triethylene diamine are Shanghai experiment reagent ltd product; BYK-333 is the product grade of German Bi Ke chemical company; Virahol and ethanol are from Changzhou Asource chemical industry ltd;
Annotate the 2:SAA901 product performance: outward appearance is a colourless transparent liquid, and composition is the hydrophilic acrylate
Quasi-oligomer, solid are divided into 44.5 ± 1wt% (150 ℃ of mensuration), and viscosity is 5 ± 0.5cps/25 ℃.
2. preparation
Take by weighing each component by table 1 formula ratio and put into container, mix at normal temperatures and can make antifogging agent composition A～C respectively, packing.
The antifog coloured fenestrated membrane of the present invention is shown in accompanying drawing 1, and it is to be constituted and compoundly be one by antifogging agent coating 1, first transparent polyester film or transparent polyethylene film base material 2-1, painted acrylic acid adhesive layer 3-1, second transparent polyester film or transparent polyethylene film base material 2-2, acrylic acid adhesive layer 3-2 and dicing film 4; Said antifogging agent coating 1 thermofixation is combined on the surface of first transparent polyester film or transparent polyethylene film base material 2-1; Painted acrylic acid adhesive layer 3-1 thermofixation is combined on another surface of first transparent polyester film or transparent polyethylene film base material 2-1; The surface recombination of second transparent polyester film or transparent polyethylene film base material 2-2 is at painted acrylic acid adhesive layer 3-1 outside surface; Acrylic acid adhesive layer 3-2 thermofixation is combined on another surface of second transparent polyester film or transparent polyethylene film base material 2-2, and dicing film 4 is compounded in acrylic acid adhesive layer 3-2 outside surface.
The antifog coloured fenestrated membrane of embodiment 2 preparations
Concrete operations are following:
(A) prepare raw material
1. preparing thickness is first transparent polyester film base material 2-1 of 23 μ m, and thickness is second transparent polyester film base material 2-2 of 23 μ m, and thickness is the dicing film 4 of 23 μ m;
2. prepare the antifogging agent composition A that embodiment 1 makes;
3. preparation forms the mixture that contains dyestuff of painted acrylic acid adhesive layer 3-1
By dyestuff: acrylic acid adhesive: solidifying agent: butanone: the mass ratio of toluene is 0.01: 9.0:0.003: prepare above-mentioned each component at 5: 3; In envrionment temperature is under 18～28 ℃, earlier butanone and dyestuff are mixed and stir 10 minutes after, add toluene and acrylic acid adhesive again; After mixing and stir 15 minutes; Add the solidifying agent restir after 20 minutes, its viscosity is 80～300 centipoises, can preserve subsequent use;
Wherein, Acrylic acid adhesive is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 40wt%～45wt%, and solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 4.5wt%～5.5wt%; Dyestuff is the Kelly blue dyes that dyeing limited-liability company of inferior nation produces, and its solids content 40wt%, butanone and toluene are that Changzhou Asource chemical industry ltd produces;
Used above-mentioned raw materials also can be used the equivalents replacement of different factories;
4. preparation forms the acrylic acid adhesive mixture of acrylic acid adhesive layer 3-2
By acrylic acid adhesive: solidifying agent: butanone: the mass ratio of toluene is 10: 0.13: 5: 3 prepare above-mentioned each component; In envrionment temperature is under 18～28 ℃; After earlier butanone, toluene and acrylic acid adhesive being mixed and stir 12～18 minutes; Add the solidifying agent restir after 18～22 minutes, measuring viscosity is 80～300 centipoises, can preserve subsequent use;
Wherein, Acrylic acid adhesive is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 4.5wt%～5.5wt%, and butanone and toluene are that Changzhou Asource chemical industry ltd produces;
Used above-mentioned raw materials also can be used the equivalents replacement of different factories;
(B) the antifog coloured fenestrated membrane of preparation
On the surface of first transparent polyester film base material 2-1, after coating forms the antifogging agent composition A of antifogging agent coating 1,80～150 ℃ of temperature; Place 10～180 seconds after fixing, form antifogging agent coating 1, on another surface of first transparent polyester film base material 2-1; After applying the mixture that contains dyestuff that forms painted acrylic acid adhesive layer 3-1; 80～130 ℃ of temperature, form painted acrylic acid adhesive layer 3-1 after placing 10～120 seconds after fixing, then with the surface recombination of second transparent polyester film base material 2-2 on painted acrylic acid adhesive layer 3-1 outside surface; Then on another surface of second transparent polyester film base material 2-2; After applying the mixture that forms acrylic acid adhesive layer 3-2,, place 10～120 seconds after fixing and form acrylic acid adhesive layer 3-2 80～130 ℃ of temperature; Again dicing film 4 is compounded in acrylic acid adhesive layer 3-2 outside surface, thereby obtains that each layer is compound to be antifog coloured fenestrated membrane of one (shown in accompanying drawing 1);
Wherein, the thickness of antifogging agent coating 1 is 1～2 μ m; The thickness of painted acrylic acid adhesive layer 3-1 is 6～25 μ m; The thickness of acrylic acid adhesive layer 3-2 is 6～25 μ m; The thickness of said painted acrylic acid adhesive layer 3-1 is identical with the thickness of acrylic acid adhesive layer 3-2, and is perhaps different.
When applying antifogging agent composition, the mixture that contains dyestuff and acrylic acid adhesive mixture, can adopt the coating of spray formula, or the scraper type coating.
The antifog coloured fenestrated membrane of embodiment 3 preparations
Concrete operations are following:
(A) prepare raw material
1. preparing thickness is first transparent polyester film base material 2-1 of 50 μ m, and thickness is second transparent polyester film base material 2-2 of 50 μ m, and thickness is the dicing film 4 of 23 μ m;
2. prepare the antifogging agent composition B that embodiment 1 makes;
3. preparation forms the mixture that contains dyestuff of painted acrylic acid adhesive layer 3-1
By dyestuff: acrylic acid adhesive: solidifying agent: butanone: the mass ratio of toluene is 0.15: 25: 0.01: prepare above-mentioned each component at 17: 7; In envrionment temperature is under 18～28 ℃, earlier butanone and dyestuff are mixed and stir 10 minutes after, add toluene, acrylic acid adhesive again; After mixing and stir 15 minutes; Add the solidifying agent restir after 20 minutes, measuring viscosity is 110 centipoises, can preserve subsequent use;
Wherein, Acrylic acid adhesive is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 40wt%～45wt%, and solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 4.5wt%～5.5wt%; Dyestuff is the Kelly orchil that dyeing limited-liability company of inferior nation produces, and its solids content 40wt%, butanone and toluene are that Changzhou Asource chemical industry ltd produces;
Used above-mentioned raw materials also can be used the equivalents replacement of different factories;
4. preparation forms the acrylic acid adhesive mixture of acrylic acid adhesive layer 3-2
By acrylic acid adhesive: solidifying agent: toluene: the mass ratio of butanone is 25: 0.008: 8: 18 prepare above-mentioned each component; In envrionment temperature is under 18～28 ℃; After earlier butanone, toluene and acrylic acid adhesive being mixed and stir 12～18 minutes; Add the solidifying agent restir after 18～22 minutes, measuring viscosity is 80～300 centipoises, can preserve subsequent use;
Wherein, Acrylic acid adhesive is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 4.5wt%～5.5wt%, and butanone and toluene are that Changzhou Asource chemical industry ltd produces;
Used above-mentioned raw materials also can be used the equivalents replacement of different factories;
(B) the antifog coloured fenestrated membrane of preparation
On the surface of first transparent polyester film base material 2-1; After applying the antifogging agent composition B that forms antifogging agent coating 1; 80～150 ℃ of temperature, place and formed antifogging agent coating 1 behind the after fixing in 10～180 seconds, on another surface of first transparent polyester film base material 2-1; After applying the mixture that contains dyestuff that forms painted acrylic acid adhesive layer 3-1; 80～130 ℃ of temperature, form dyeing acrylic acid adhesive layer 3-1 after placing 10～120 seconds after fixing, then with the surface recombination of second transparent polyester base material 2-2 on dyeing acrylic acid adhesive layer 3-1 outside surface; Then on another surface of second transparent polyester film base material 2-2; After applying the acrylic acid adhesive mixture that forms acrylic acid adhesive layer 3-2,, place 10～120 seconds after fixing and form acrylic acid adhesive layer 3-2 80～130 ℃ of temperature; Again dicing film 4 is compounded on the outside surface of acrylic acid adhesive layer 3-2, thereby obtains that each layer is compound to be antifog coloured fenestrated membrane of one (shown in accompanying drawing 1);
Wherein, the thickness of antifogging agent coating 1 is 1～2 μ m; The thickness of painted acrylic acid adhesive layer 3-1 is 6～25 μ m; The thickness of acrylic acid adhesive layer 3-2 is 6～25 μ m; The thickness of said painted acrylic acid adhesive layer 3-1 is identical with the thickness of acrylic acid adhesive layer 3-2, and is perhaps different.
When applying antifogging agent composition, the mixture that contains dyestuff and acrylic acid adhesive mixture, can adopt the coating of spray formula, or the scraper type coating.
The antifog coloured fenestrated membrane of embodiment 4 preparations
Concrete operations are following:
(A) prepare raw material
1. preparing thickness is first transparent polyethylene film base material 2-1 of 75 μ m, and thickness is second transparent polyethylene film base material 2-2 of 50 μ m, and thickness is the dicing film 4 of 39 μ m;
2. prepare the antifogging agent composition C that embodiment 1 makes;
3. preparation forms the mixture that contains dyestuff of painted acrylic acid adhesive layer 3-1
By dyestuff: acrylic acid adhesive: solidifying agent: butanone: the mass ratio of toluene is 3: 50: 0.02: prepare above-mentioned each component at 24: 12; In envrionment temperature is under 18～28 ℃, earlier butanone and dyestuff are mixed and stir 10 minutes after, add toluene, acrylic acid adhesive again; After mixing and stir 15 minutes; Add the solidifying agent restir after 20 minutes, measuring viscosity is 110 centipoises, can preserve subsequent use;
Wherein, Acrylic acid adhesive is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 40wt%～45wt%, and solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 4.5wt%～5.5wt%; Dyestuff is the Kelly green colouring material that dyeing limited-liability company of inferior nation produces, and its solids content 40wt%, butanone and toluene are that Changzhou Asource chemical industry ltd produces;
Used above-mentioned raw materials also can be used the equivalents replacement of different factories;
4. preparation forms the acrylic acid adhesive mixture of acrylic acid adhesive layer 3-2
By acrylic acid adhesive: solidifying agent: toluene: the mass ratio of butanone is 50: 0.015: 15: 35 prepare above-mentioned each component; In envrionment temperature is under 18～28 ℃; After earlier butanone, toluene and acrylic acid adhesive being mixed and stir 12～18 minutes; Add the solidifying agent restir after 18～22 minutes, measuring viscosity is 80～300 centipoises, can preserve subsequent use;
Wherein, Acrylic acid adhesive is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 4.5wt%～5.5wt%, and butanone and toluene are that Changzhou Asource chemical industry ltd produces;
Used above-mentioned raw materials also can be used the equivalents replacement of different factories;
(B) the antifog coloured fenestrated membrane of preparation
On the surface of first transparent polyethylene film base material 2-1; After applying the antifogging agent composition C that forms antifogging agent coating 1; 80～150 ℃ of temperature, place 10～180 seconds after fixing and form antifogging agent coating 1, on another surface of first transparent polyethylene film base material 2-1; After applying the mixture that contains dyestuff that forms painted acrylic acid adhesive layer 3-1; 80～130 ℃ of temperature, place 10～120 seconds after fixing and form painted acrylic acid adhesive layer 3-1, then with the surface recombination of second transparent polyethylene film base material 2-2 on the outside surface of painted acrylic acid adhesive layer 3-1; Then on another surface of second transparent polyethylene film base material 2-2; After applying the acrylic acid adhesive mixture that forms acrylic acid adhesive layer 3-2,, place 10～120 seconds after fixing and form acrylic acid adhesive layer 3-2 80～130 ℃ of temperature; Again dicing film 4 is compounded on the outside surface of acrylic acid adhesive layer 3-2, thereby obtains that each layer is compound to be antifog coloured fenestrated membrane of one (shown in accompanying drawing 1);
Wherein, the thickness of antifogging agent coating 1 is 1～2 μ m; The thickness of painted acrylic acid adhesive layer 3-1 is 6～25 μ m; The thickness of acrylic acid adhesive layer 3-2 is 6～25 μ m; The thickness of said painted acrylic acid adhesive layer 3-1 is identical with the thickness of acrylic acid adhesive layer 3-2, and is perhaps different.
When applying antifogging agent composition, the mixture that contains dyestuff and acrylic acid adhesive mixture, can adopt the coating of spray formula, or the scraper type coating.
Detect antifog coloured fenestrated membrane performance
Antifog coloured fenestrated membrane performance to embodiment 2～4 preparations detects, and the result sees table 2.
Table 2
| Test item | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Water contact angle | 6.5° | 5.8° | 6.3° |
| Stripping strength | 1485gf/in | 1600gf/in | 1621gf/in |
| Transmittance | 70％～88％ | 70％～88％ | 70％～88％ |
| Antifog property | Do not haze | Do not haze | Do not haze |
| Water tolerance | Do not have damaged | Do not have damaged | Do not have damaged |
| Hardness | 2H | 2H | 2H |
Annotate: in the table 2, each association is the antifog coloured fenestrated membrane of the present invention (embodiment 2～4) to be detected to obtain as follows:
1. water contact angle: use Japanese G-1 type contact angle appearance to test, get the MV of three site tests data at three positions, left, center, right of the anti-cloudy surface (being antifogging agent coating 1) of antifog coloured fenestrated membrane; 2. stripping strength: with reference to standard GB/T 2792;
3. transmittance: adopt the Shenzhen woods to attend the solar film transmission measurement appearance (model LS103) that Science and Technology Ltd. produces, standard method is carried out with reference to ASTM D1003;
4. antifog property: under the room temperature; It is 60 ℃ water surface top that the anti-cloudy surface (being antifogging agent coating 1) of antifog coloured fenestrated membrane is placed water temperature; Its fenestrated membrane prevents that cloudy surface (being antifogging agent coating 1) and water surface distance are 10cm; Observe antifogging agent coating 1 surface of antifog coloured fenestrated membrane, in 1 hour, whether haze;
5. water tolerance: place 0 ℃, 20 ℃, 40 ℃ water after 48 hours respectively antifog coloured fenestrated membrane, observe the coating damage situation of the antifogging agent coating 1 of antifog coloured fenestrated membrane;
6. hardness: with reference to standard GB/T 6739.
Can find out from table 2 detected result, by of the present invention antifog coloured fenestrated membrane (embodiment 2～4) that antifogging agent composition of the present invention forms, can be effectively antifog attractive in appearance again, transparent.Product water tolerance, hardness, the equal The profile of stripping strength.
Use the antifog coloured fenestrated membrane of the present invention very simple, need only, after dicing film 4 outermost layers are peeled off, stick on glass surface and get final product according to after the concrete size cutting.After pasting antifog coloured fenestrated membrane on the vehicle glass, can finely play anti-fog effect, not only attractive in appearance, also can avoid the glass fragmentation to hurt sb.'s feelings.
Claims (7)
1. an antifogging agent composition is characterized in that, it is that following component mixes formation at normal temperatures, and the proportioning of its each component is following:
Hydrophilic resin 9～14 wt%
Propylene glycol monomethyl ether 55～76 wt%
Dimethyl-methylamine 3～10 wt%
Triethylene diamine 1～5 wt%
Flow agent 1～5 wt%
Virahol 5～26 wt%
Ethanol 5～24 wt%
Above-mentioned each component sum is 100 wt%;
Said hydrophilic resin is hydrophilic acrylate's quasi-oligomer;
Said antifogging agent composition is at 80 ℃～150 ℃ film-formings.
2. antifogging agent composition according to claim 1 is characterized in that, said hydrophilic resin is the SAA901 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Said flow agent is the BYK-333 product of German Bi Ke chemical company.
3. antifog coloured fenestrated membrane that forms with the antifogging agent composition of claim 1; It is characterized in that it is to be constituted and compoundly be one by antifogging agent coating (1), first transparent polyester film or transparent polyethylene film base material (2-1), painted acrylic acid adhesive layer (3-1), second transparent polyester film or transparent polyethylene film base material (2-2), acrylic acid adhesive layer (3-2) and dicing film (4); Said antifogging agent coating (1) thermofixation is combined on the surface of first transparent polyester film or transparent polyethylene film base material (2-1); Painted acrylic acid adhesive layer (3-1) thermofixation is combined on another surface of first transparent polyester film or transparent polyethylene film base material (2-1); A surface recombination of second transparent polyester film or transparent polyethylene film base material (2-2) is at painted acrylic acid adhesive layer (3-1) outside surface; Acrylic acid adhesive layer (3-2) thermofixation is combined on another surface of second transparent polyester film or transparent polyethylene film base material (2-2), and dicing film (4) is compounded in acrylic acid adhesive layer (3-2) outside surface;
Said antifogging agent coating (1) is to be coated on the surface of first transparent polyester film or transparent polyethylene film base material (2-1) with the described antifogging agent composition of claim 1,80～150 ℃ of temperature, places that 10～180 seconds after fixing form;
Said painted acrylic acid adhesive layer (3-1) is to be coated on another surface of first transparent polyester film or transparent polyethylene film base material (2-1) with the mixture that contains dyestuff; 80～130 ℃ of temperature; Place that 10～120 seconds after fixing form, wherein, the mixture that contains dyestuff is to be 0.01～3.0: 9～60 with mass ratio: 0.003～0.02: 5～24: 3～12 dyestuff: acrylic acid adhesive: solidifying agent: butanone: toluene is raw material; In envrionment temperature is under 18～28 ℃; After earlier butanone and dyestuff being mixed and stir 8～12 minutes, add toluene and acrylic acid adhesive again, mix and stir 12～18 minutes after; Add the solidifying agent restir after 18～22 minutes, its viscosity is 80～300 centipoises;
A surface recombination of said second transparent polyester film or transparent polyethylene film base material (2-2) is at painted acrylic acid adhesive layer (3-1) outside surface;
Said acrylic acid adhesive layer (3-2) is to be coated on another surface of second transparent polyester film or transparent polyethylene film base material (2-2) with the acrylic acid adhesive mixture; 80～130 ℃ of temperature; Place that 10～120 seconds after fixing form; Wherein, The acrylic acid adhesive mixture is to be 4～50: 0.003～0.2 with mass ratio: 1～15: 2～35 acrylic acid adhesive: solidifying agent: toluene: butanone is a raw material, is under 18～28 ℃ in envrionment temperature, earlier butanone, toluene and acrylic acid adhesive are mixed and stir 12～18 minutes after; Adding solidifying agent restir formed after 18～22 minutes, and its viscosity is 80～300 centipoises.
4. antifog coloured fenestrated membrane according to claim 3; It is characterized in that; Acrylic acid adhesive in said painted acrylic acid adhesive layer (3-1) and the acrylic acid adhesive layer (3-2) is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 40wt%～45wt%, and solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 4.5wt%～5.5wt%;
Acrylic acid adhesive in perhaps said painted acrylic acid adhesive layer (3-1) and the acrylic acid adhesive layer (3-2) is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 4.5wt%～5.5wt%;
Acrylic acid adhesive in the perhaps said painted acrylic acid adhesive layer (3-1) is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces; Its solid is divided into 4.5wt%～5.5wt%, and the acrylic acid adhesive in the acrylic acid adhesive layer (3-2) is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces, and its solid is divided into 4.5wt%～5.5wt%;
Acrylic acid adhesive in the perhaps said painted acrylic acid adhesive layer (3-1) is the WA-240 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 40wt%～45wt%; Solidifying agent is the KS-05 that Kailanda Industry Co., Ltd., Shanghai produces; Its solid is divided into 4.5wt%～5.5wt%, and the acrylic acid adhesive in the acrylic acid adhesive layer (3-2) is the SAA1401 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 40wt%～45wt%; Solidifying agent is the SAC12 that Xi'an Naviation Sanwo Chemical Co., Ltd. produces, and its solid is divided into 4.5wt%～5.5wt%.
5. antifog coloured fenestrated membrane according to claim 3 is characterized in that, said antifog coloured fenestrated membrane thickness is 78～441 μ m, and wherein, the thickness of antifogging agent coating (1) is 1～2 μ m; The thickness of first transparent polyester film or transparent polyethylene film base material (2-1) is 23～175 μ m; The thickness of painted acrylic acid adhesive layer (3-1) is 6～25 μ m; The thickness of second transparent polyester film or transparent polyethylene film base material (2-2) is 23～175 μ m; Acrylic acid adhesive layer (3-2) is 6～25 μ m; The thickness of dicing film (4) is 19～39 μ m.
6. antifog coloured fenestrated membrane according to claim 5 is characterized in that, the thickness of said painted acrylic acid adhesive layer (3-1) is identical with the thickness of acrylic acid adhesive layer (3-2), and is perhaps different.
7. antifog coloured fenestrated membrane according to claim 5; It is characterized in that; The thickness of said first transparent polyester film or transparent polyethylene film base material (2-1) is identical with the thickness of second transparent polyester film or transparent polyethylene film base material (2-2), and is perhaps different.
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