CN102964942B - Camouflage coating preventing infrared photography and infrared night vision reconnaissance - Google Patents

Camouflage coating preventing infrared photography and infrared night vision reconnaissance Download PDF

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Publication number
CN102964942B
CN102964942B CN201210545654.3A CN201210545654A CN102964942B CN 102964942 B CN102964942 B CN 102964942B CN 201210545654 A CN201210545654 A CN 201210545654A CN 102964942 B CN102964942 B CN 102964942B
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infrared
shanghai
night vision
resin
synolac
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CN102964942A (en
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彭锋
李斌
张耀东
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SHANGHAI HUAYI FINE CHEMICAL CO., LTD.
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SHANGHAI PAINT MANUFACTURE FACTORY
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Abstract

The invention relates to a camouflage coating preventing infrared photography and infrared night vision reconnaissance. The coating comprises the following components in percentage by weight: 10-30% of vinylidene chloride resin, 1-10% of modified alkyd resin, 1-15% of mixed pigment, 5-20% of filler, 1-5% of mixing aid, and 35-65% of mixed solvent. The invention further provides a preparation method and an application of the camouflage coating suitable for large weapons to prevent the infrared photography and the infrared night vision reconnaissance. According to the camouflage coating disclosed by the invention, the vinylidene chloride resin is modified with the alkyd resin to serve as film-forming resin base stock, pigments are selected and compounded, aids are selected and compounded, two roller machines are used for dispersion so as to achieve a preset fineness, and thus, the functional requirements on suitability to the large weapons and the camouflage effect are finally met.

Description

The camouflage paint that a kind of anti-infrared is taken a picture and infrared night vision is scouted
Technical field
The present invention relates to the coating industry in chemical industry, specifically, relate to cooperation and the processing technology of coating, more particularly, relate to and be a kind ofly applicable to large-scale weapons anti-infrared and take a picture and the camouflage paint of infrared night vision scouting and the preparation method and application of this coating.
Background technology
It is the most common in military affairs is also one of the most ripe Detection Techniques that visible ray and near infrared scout detection, its principle of work mainly utilizes object and background to the difference of visible ray and near infrared light reflectivity, produce larger contrast contrast gradient on the detector, thus detect target in background.
For the military target of non high temperature, the source of visible ray and near infrared light both can be sunlight, also can be the artificial lights such as infrared illumination bullet.Detect to defend the scouting of enemy to visible ray and near infrared light, the Camouflage painting of visible ray and near infrared light is obtained in countries in the world and develops rapidly, its Main Function is that paint is at target surface, by the reflection of simulation background to visible ray and near infrared light, thus reduce the contrast gradient of object and background at visible ray and near-infrared band.How to make camouflage paint well be attached on large-scale weapons, and desirable reflectivity be provided thus reach the camouflage effectiveness of expection, be this area coating industry one of the aspect that will pay close attention to emphatically.
Camouflage paint involved in the present invention develops just under this market background.This camouflage paint is by supervinyi chloride resin, and Synolac and urethane resin carry out modification, is equipped with chrome yellow, titanium dioxide pigment, charcoal blacks and reach the reflectivity requirements met in visible ray and near infrared range.
Summary of the invention
Just as above-mentioned, the present invention aims to provide a kind of camouflage paint being applicable to the photograph of large-scale weapons anti-infrared and anti-infrared night vision reconnaissance, also comprises the Synthesis and applications of this coating.。
For achieving the above object, the technical scheme that the present invention proposes is: provide a kind of camouflage paint being applicable to the photograph of large-scale weapons anti-infrared and anti-infrared night vision reconnaissance, by weight percentage, its composition comprises following component to this coating:
Wherein, the range of viscosities of described supervinyi chloride resin is 14 ~ 20s, and chlorinity scope is 61 ~ 65wt%; The mixture of one or more in the high-carbon black pigment C311 that the phthalocyanine blue S1730 that the chrome yellow 103 that the rutile titanium dioxide R930 that described hybrid pigment is selected from the red iron oxide 3602 of Shanghai one product pigment Company, Japanese Ishihara Sangyo Kaisha, Ltd. produces, Shanghai Chrome Yellow Plant produce, Shanghai Chemical Co., Ltd. of alliance produce, Shanghai Jiaohua Chemical Industry Development Company produce.
Described modified alkyd resin is selected from: the lipid acid in synthesis material used is the Synolac of Semen Lini oil, i.e. the 355-5 medium oil alkyd of Xinhua Resin Factory, Shanghai's product; Lipid acid in synthesis material used is Viscotrol C and through Abietyl modified Synolac, i.e. Xinhua Resin Factory, Shanghai's 3139 extra short oil Synolac of producing; Lipid acid in synthesis material used is the Synolac of Viscotrol C, namely Xinhua Resin Factory, Shanghai produce 3136-3 short oil-ity alcohol acid resin in the mixture of one or more.
Described mixed aid is selected from: the mixture of one or more in the drying promoter barium naphthenate that stablizer barium meta carbonate, toughner 52 paraffin, Changfeng Chemical Plant, Shanghai produce, matting agent HP230.
By weight percentage, its composition comprises described mixed solvent:
Acetone 10-30 % by weight
N-BUTYL ACETATE 10-40 % by weight
Toluene 50-80 % by weight.
Described stopping composition is selected from talcum powder or barium sulfate.
The preparation method of described coating, is characterized in that, the method comprises the steps:
(a), by the mixture kneader of one or more in the mixture of one or more in supervinyi chloride resin, hybrid pigment, filler, mixed aid, mediate evenly;
(b), uniform for kneading material is ground further through two roller machines, make it uniform subdivision fall apart, membrane section and naturally cooling;
(c), section is added in mixed solvent, dispersed with stirring, to after dissolving completely, adds one or more in Synolac, mixed aid, stirs, and namely obtains being applicable to large-scale weapons anti-infrared and takes a picture and the camouflage paint of anti-infrared night vision reconnaissance.
The purposes of this coating is applied on large-scale weapons, takes a picture and the camouflage paint of anti-infrared night vision reconnaissance as anti-infrared.With general paint thinner, coating is diluted to working viscosity 20-25s (being coated with-4 glasss) when applying, use aerial spraying, spray pressure is 0.4-0.6MPa, spraying twice, the overlay painting interval time is 2h at 23 ± 2 DEG C, dry film total thickness controls in 40-50 μm/2 roads, painting effect: flat appearance.
Of the present invention be applicable to large-scale weapons anti-infrared take a picture and the performance technologies index of camouflage paint of anti-infrared night vision reconnaissance and testing method in table 1
Table 1
The invention has the advantages that:
1, coating of the present invention is by Synolac modified vinyl perchloride resin, is equipped with special auxiliary agent to reach the camouflaging purpose of anti-infrared photograph and the anti-infrared night vision reconnaissance being applicable to large-scale weapons surface.This camouflage paint has at near-infrared band and to be similar to green plants or identical degree of reflection and extremely low infrared ray absorption rate, thus provides the so a kind of functional requirement of difference in brightness reducing or eliminate between large-scale weapons and background.
2, coating of the present invention adopts alkyd modified supervinyi chloride resin to be base-material, can provide good mechanical property and chemical resistance.
3, coating of the present invention belongs to one-pack type coating, and easily, dryness is fine simultaneously, and at room temperature 2h just can reach and do solid work, and can meet allegro paint spraying production technique in construction.
4, coating to be applicable under various environment, various execution conditions construction usage on multiple large-scale weapons.
Embodiment
Enumerate some embodiments to be below further described in detail the present invention, but protection scope of the present invention is in no way limited to these embodiments.
Embodiment 1
After 31 grams of supervinyi chloride resins, 1 gram of barium meta carbonate, 18 grams of chrome yellow, 0.5 gram of phthalocyanine blue, 3 grams of dibutyl phthalates, 2 gram of 52 paraffin, 30 grams of talcum powder are mixed in kneader, in two roller machines, carry out abundant hybrid subdivision fall apart, section after membrane, cooling;
After 40 grams of acetone, 55 grams of N-BUTYL ACETATEs, 92 grams of toluene are mixed, again above-mentioned section is dissolved into uniform liquid, drop into 20 grams of Synolac, 3 grams of dibutyl phthalates, 3 gram of 52 paraffin respectively to stir, finally add 1.5 grams of flatting silicas to be uniformly dispersed, sampling is after application is carried out on set iron surface, dry 24h under 23 ± 2 DEG C of conditions, filters after performance test (parameter is in table 2) is qualified, packaging.
Table 2
Embodiment 2
By 42 grams of supervinyi chloride resins, 1.4 grams of barium meta carbonates, 6 grams of red iron oxides, 20 grams of rutile titanium dioxides, 0.6 gram of high-carbon black pigment, 10 grams of barium sulfate, after 4 grams of dibutyl phthalates, 3 gram of 52 paraffin mix in kneader, in two roller machines, carry out abundant hybrid subdivision fall apart, section after membrane, cooling;
After 50 grams of acetone, 55 grams of N-BUTYL ACETATEs, 74 grams of toluene are mixed, above-mentioned section is dissolved into uniform liquid, drop into 25 grams of Synolac, 4 grams of dibutyl phthalates, 2 gram of 52 paraffin respectively to stir, finally add 3 grams of flatting silicas to be uniformly dispersed, sampling is after application is carried out on set iron surface, dry 24h under 23 ± 2 DEG C of conditions, filters after performance test (parameter is in table 2) is qualified, packaging.
Table 3
Embodiment 3
After 50 grams of supervinyi chloride resins, 1.8 grams of low barium sulfate, 1.2 grams of high-carbon black pigments, 0.3 gram of phthalocyanine blue, 20 grams of rutile titanium dioxides, 6 grams of dibutyl phthalates, 3 gram of 52 paraffin are mixed in kneader, in two roller machines, carry out abundant hybrid subdivision fall apart, section after membrane, cooling;
After 55 grams of acetone, 60 grams of N-BUTYL ACETATEs, 64.4 grams of toluene are mixed, after above-mentioned section is dissolved into uniform liquid, drop into 28 grams of Synolac, 4 grams of dibutyl phthalates, 2 gram of 52 paraffin respectively to stir, finally add 4 grams of flatting silicas, be uniformly dispersed, sample after application is carried out on set iron surface, dry 24h under 23 ± 2 DEG C of conditions, filter after performance test (parameter is in table 2) is qualified, packaging.
Table 4
Camouflage paint of the present invention is as film-forming resin base-material by Synolac modified vinyl perchloride resin, by the selection of the selection of pigment and composite, auxiliary agent and composite and disperse to reach regulation fineness by two roller machines, finally reach the functional requirement being applicable to large-scale weapons have camouflage effectiveness.

Claims (4)

1. the camouflage paint that anti-infrared is taken a picture and infrared night vision is scouted, it is characterized in that, by weight percentage, this system component comprises:
Wherein, the range of viscosities of described supervinyi chloride resin is 14 ~ 20s, and chlorinity scope is 61 ~ 65 % by weight; The mixture of one or more in the high-carbon black pigment C311 that the phthalocyanine blue S1730 that the chrome yellow 103 that the rutile titanium dioxide R930 that described hybrid pigment is selected from the red iron oxide 3602 of Shanghai one product pigment Company, Japanese Ishihara Sangyo Kaisha, Ltd. produces, Shanghai Chrome Yellow Plant produce, Shanghai Chemical Co., Ltd. of alliance produce, Shanghai Jiaohua Chemical Industry Development Company produce;
Described modified alkyd resin is selected from: the lipid acid in synthesis material used is the Synolac of Semen Lini oil, i.e. the 355-5 medium oil alkyd of Xinhua Resin Factory, Shanghai's product; Lipid acid in synthesis material used is Viscotrol C and through Abietyl modified Synolac, i.e. Xinhua Resin Factory, Shanghai's 3139 extra short oil Synolac of producing; Lipid acid in synthesis material used is the Synolac of Viscotrol C, namely Xinhua Resin Factory, Shanghai produce 3136-3 short oil-ity alcohol acid resin in the mixture of one or more;
Described mixed aid is selected from: the mixture of one or more in the drying promoter barium naphthenate that stablizer barium meta carbonate, toughner 52 paraffin, Changfeng Chemical Plant, Shanghai produce, matting agent HP230;
Described mixed solvent is counted as weight percents, and its composition comprises:
Acetone 10-30 % by weight
N-BUTYL ACETATE 10-40 % by weight
Toluene 50-80 % by weight.
2. camouflage paint according to claim 1, is characterized in that: described stopping composition is selected from talcum powder or barium sulfate.
3. according to a preparation method for the camouflage paint described in claim 1-2, it is characterized in that, the method comprises the steps:
(a), by the mixture kneader of one or more in the mixture of one or more in supervinyi chloride resin, hybrid pigment, filler, mixed aid, mediate evenly;
(b), uniform for kneading material is ground further through two roller machines, make it uniform subdivision fall apart, membrane section and naturally cooling;
(c), section is added in mixed solvent, dispersed with stirring, to after dissolving completely, adds one or more in Synolac, mixed aid, stirs, and namely obtains being applicable to large-scale weapons anti-infrared and takes a picture and the camouflage paint of anti-infrared night vision reconnaissance.
4. want an application for the camouflage paint prepared described in 1-2 according to right, it is characterized in that, this coating can be coated with the effect being contained in and large-scale weapons or component playing anti-infrared photograph and night vision reconnaissance.
CN201210545654.3A 2012-12-14 2012-12-14 Camouflage coating preventing infrared photography and infrared night vision reconnaissance Active CN102964942B (en)

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CN104073085B (en) * 2014-04-16 2017-02-01 常州佳尔科仿真器材有限公司 Fluorocarbon camouflage coating for preventing detection of visible light and near infrared and preparation method thereof

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* Cited by examiner, † Cited by third party
Title
防近红外侦察伪装涂料技术研究;费逸伟等;《红外技术》;20030131;第25卷(第01期);88-92 *

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Patentee before: Shanghai Huayi Fine Chemical Co., Ltd. Shanghai paint factory