CN104140743A - Functional anti-static wall surface paint and preparation method thereof - Google Patents
Functional anti-static wall surface paint and preparation method thereof Download PDFInfo
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- CN104140743A CN104140743A CN201410395879.4A CN201410395879A CN104140743A CN 104140743 A CN104140743 A CN 104140743A CN 201410395879 A CN201410395879 A CN 201410395879A CN 104140743 A CN104140743 A CN 104140743A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Abstract
The invention discloses functional anti-static wall surface paint and a preparation method thereof, and aims at providing wall surface paint which is anti-static, environment-friendly, high in stain resistance, good in decoration effect, scrub-resistant, mildew-proof and anti-bacterial. According to the technical key points, the wall surface paint comprises a system A and a system B, wherein the mass ratio of the system A to the system B is 1: 1; the system A is prepared from a system A1 and a system A2; the system A1 is prepared from the following components in parts by mass: 12-18 parts of de-ionized water, 0.3-0.5 part of an anti-static agent, 25-30 parts of fillers and 1-3 parts of an assistant I; the system A2 is prepared from the following components in parts by mass: 35-50 parts of waterborne epoxy resin, 10-15 parts of pure acrylic emulsion, 1-4 parts of a reactive diluent and 0.2-1 part of a defoamer; and the system B is prepared from the following components in parts by mass: 20-30 parts of a waterborne curing agent, 0.5-1 part of an anti-static agent, 30-42 parts of fillers, 10-20 parts of conductive titanium dioxide, 0.5-2 parts of an assistant II and 15-25 parts of de-ionized water. The wall surface paint belongs to the technical field of coatings.
Description
Technical field
The present invention discloses a kind of wall paint, especially a kind of functional anti-electrostatic wall paint, and the present invention also discloses the preparation method of this wall paint, belongs to technical field of coatings.
Background technology
Flourish along with modern science and technology, more and more crowds are in the space that static is full of, and static is also more and more obvious to people's harm, when people is under static radiation for a long time, can lather, headache, uncomfortable in chest, expiratory dyspnea, cough etc.Static can absorbed air in a large amount of dust, and the dust of the larger absorption of charging property is more, and in dust, often contain multiple toxic substance and germ, light skin irritation, affect skin gloss, heavy make skin play the raw sore of abnormal pigmentary deposit on the skin, the more serious illnesss such as bronchial asthma and heart disorder that cause in addition.
Static not only has impact in people's daily life, and in work is produced, impact is also very huge.The harm of static to electron trade, static discharge can change the electrical property of semiconducter device, makes its degradation or damages.Static discharge also can be upset the normal running of electronics, causes equipment failure or damage.Static charge also can give rise to trouble at dust free chamber, and electrified body surface can attract pollutent, when the circuit part of silicon crystal or device, has been infected with dust, will cause in circuit unpredictable defect and affect its quality product.Static impact in chemical plant produces is also huge, be accompanied by stirring in chemical process, push, mill, rocking etc. in the friction between powder, transport of liquid, all can produce a large amount of static, in Chemical Manufacture, great majority are organic liquid gas, inflammable powder etc., if static one time integral easily cause too much fire failure.
Summary of the invention
For the problems referred to above, the invention provides a kind of utilization and lead electrostatic principle and in time the static guiding producing in buildings is gone out, thereby reduce static, daily life work is endangered to functional anti-electrostatic wall paint and preparation method thereof.
Last technical scheme of the present invention is such: this functional anti-electrostatic wall paint, by A system and the B system of mass ratio 1:1, formed, and described A system is made by slurrying stage A 1 system and paint stage A 2 systems;
Wherein:
Slurrying stage A 1 system is made by the component of following mass parts:
Paint stage A 2 systems are made by the component of following mass parts:
B system is made by the component of following mass parts:
Above-mentioned functional anti-electrostatic wall paint, No. 1 described auxiliary agent is comprised of 0.1～0.2 mass parts defoamer and 1.4～2.8 mass parts thickening materials.
Above-mentioned functional anti-electrostatic wall paint, the preferred water-based bisphenol A epoxide resin of described aqueous epoxy resins.
Above-mentioned functional anti-electrostatic wall paint, RS～2806 of the rich company of the preferred Ahmedabad of described pure-acrylic emulsion.
Above-mentioned functional anti-electrostatic wall paint, TIPAQUE ET～500W conductive titanium dioxide of the preferred Japanese Ishihara Sangyo Kaisha of described conductive titanium dioxide company.
Above-mentioned functional anti-electrostatic wall paint, the E10P of described preferred Henkel Corp. of reactive thinner.
Above-mentioned functional anti-electrostatic wall paint, No. 2 described auxiliary agents are by 0.1～0.8 mass parts wetting agent, and 0.1～0.4 mass parts dispersion agent and 0.3～0.8 mass parts defoamer form.
Above-mentioned functional anti-electrostatic wall paint, described antistatic agent is ASA～150.
Above-mentioned functional anti-electrostatic wall paint, described color stuffing is by 4～10 mass parts calcium carbonate, and 16～23 mass parts titanium dioxides and 5～16 mass parts calcined kaolins form.
After provided by the invention, a technical scheme is such: above-mentioned functional anti-electrostatic wall paint preparation method, comprises the steps: successively
(1) component described in slurrying stage A 1 system is stirred to 60～120min in 1000～1200rpm, so that slurry fineness is less than 30um, and then add component described in paint stage A 2 systems, with 600～800rpm, stir 30～60min, filter, obtain component A;
(2) starting material described in B system are stirred to 60～90min in 1000～1200rpm and mix, filter, obtain B component;
(3) before application, component A and B component are mixed with 1:1, obtain functional anti-electrostatic wall paint.
Compared with prior art, technical scheme tool provided by the invention has the following advantages:
1) select stable aqueous epoxy resins as the main filmogen of coating, the good feature of environmental protection can be provided.Epoxy resin and solidifying agent form fine and close paint film can provide good coating surface effect.
2) select again collocation part pure-acrylic emulsion, as functional emulsion, be better coated the color stuffing in coating, and then make paint film finer and close.
3) by introducing conductive titanium dioxide, on the one hand its can be when being coated in body of wall can evenly smooth spreading out in paint film, form the conducting film of a continuous uniform, to derive timely static.Relatively, conductive titanium dioxide can provide better surface effect and covering effect for paint film, more meets effect and the aesthetic property of body of wall application for composite conductive powder and graphitized carbon black and electro-conductive fiber etc. on the other hand.
4) anti-electrostatic auxiliary agent is passed through to dissolved in boiled water, join in water-based system, discrete distribution forms better conductive path with conducting powder in crosslinked paint film, makes antistatic performance more stable.
5) described functional anti-electrostatic wall paint, by adjusting different resin proportionings, can obtain the effect of mercerising, shell light and dumb light, and is adjustablely made into the demand that different colours can meet upholstery.
Generally speaking, functional anti-electrostatic wall paint provided by the invention has anti-electrostatic, environmental protection, high resistant, good decorating effect, and scrubbing resistance, fungus-resistant, can meet the different requirements of decorating.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but do not form any limitation of the invention, and the change of the unsubstantiality content that anyone makes in the claims in the present invention protection domain, still in the claims in the present invention protection domain.
Embodiment 1
A kind of functional anti-electrostatic wall paint provided by the invention, consists of A system and the B system of following mass ratio 1:1:
A system
Slurrying stage A 1 system
First with part deionized water, antistatic agent is dissolved, again described component is dropped into successively in Scattered Kettle and (added while stirring), with 1200rpm, carry out dispersed with stirring, be less than 30um to slurry fineness, normal dispersion 60min, wherein the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Paint stage A 2 systems
Above-mentioned paint stage A 2 components are dropped into aforementioned slurrying stage A 1 component, and reduce stirring velocity to 600rpm, dispersed with stirring 60min, filtration, packing get final product to obtain functional anti-electrostatic wall paint A component.B system
First with part deionized water, antistatic agent is dissolved, above-mentioned starting material drop into Scattered Kettle (adding while stirring) successively again, with 1200rpm, carry out dispersed with stirring, are less than 30um to slurry fineness, normal dispersion 60, to 90min, filters and packages and gets final product to obtain functional anti-electrostatic wall paint B component.Wherein the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Before brushing, by the mass ratio of 1:1, evenly mix A, B system, then add A, B and measure approximately 10% water, more than effectively disperseing 2min, get final product tool lead static, decorative effect is excellent, the functional anti-electrostatic finish paint (shell light) of scrubbing resistance, fungus-resistant.
Embodiment 2
The functional anti-electrostatic wall paint of another kind provided by the invention, consists of A system and the B system of following mass ratio 1:1:
A system
Slurrying stage A 1 system
First with part deionized water, antistatic agent is dissolved, again described component is dropped into successively in Scattered Kettle and (added while stirring), with 1200rpm, carry out dispersed with stirring, be less than 30um to slurry fineness, normal dispersion 60min, wherein the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Paint stage A 2 systems
Above-mentioned paint stage A 2 components are dropped into aforementioned slurrying stage A 1 component, and reduce stirring velocity to 600rpm, dispersed with stirring 60min, filtration, packing get final product to obtain functional anti-electrostatic wall paint A component.B system
First with part deionized water, antistatic agent is diluted, again above-mentioned starting material are dropped into successively in Scattered Kettle and (added while stirring), with 1200rpm, carry out dispersed with stirring, be less than 30um to slurry fineness, normal dispersion 60, to 90min, filters and packages and gets final product to obtain functional anti-electrostatic wall paint B component.Wherein, the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Before brushing, by the mass ratio of 1:1, evenly mix A, B system, then add A, B and measure approximately 10% water, more than effectively disperseing 2min, get final product tool lead static, decorative effect is excellent, the functional anti-electrostatic finish paint (mercerising) of scrubbing resistance, fungus-resistant.
Embodiment 3
The functional anti-electrostatic wall paint of another kind provided by the invention, consists of A system and the B system of following mass ratio 1:1:
A system
Slurrying stage A 1 system
Described component is dropped into successively in Scattered Kettle and (added while stirring), with 1200rpm, carry out dispersed with stirring, be less than 30um, normal dispersion 60min to slurry fineness, wherein the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Paint stage A 2 systems
Above-mentioned paint stage A 2 components are dropped into aforementioned slurrying stage A 1 component, and reduce stirring velocity to 600rpm, dispersed with stirring 60min, filtration, packing get final product to obtain functional anti-electrostatic wall paint A component.B system
First with part deionized water, antistatic agent is dissolved, above-mentioned starting material drop into successively in Scattered Kettle and (add while stirring) again, with 1200rpm, carry out dispersed with stirring, are less than 30um to slurry fineness, normal dispersion 60, to 90min, filters and packages and gets final product to obtain functional anti-electrostatic wall paint B component.Wherein, the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Before brushing, by the mass ratio of 1:1, evenly mix A, B system, then add A, B and measure approximately 10% water, more than effectively disperseing 2min, get final product tool lead static, decorative effect is excellent, the functional anti-electrostatic finish paint (shell light) of scrubbing resistance, fungus-resistant.
Embodiment 4
The functional anti-electrostatic wall paint of another kind provided by the invention, consists of A system and the B system of following mass ratio 1:1:
A system
Slurrying stage A 1 system
First with part deionized water, antistatic agent is dissolved, again described component is dropped into successively in Scattered Kettle and (added while stirring), with 1200rpm, carry out dispersed with stirring, be less than 30um to slurry fineness, normal dispersion 60min, wherein the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Paint stage A 2 systems
Above-mentioned paint stage A 2 components are dropped into aforementioned slurrying stage A 1 component, and reduce stirring velocity to 600rpm, dispersed with stirring 60min, filtration, packing get final product to obtain functional anti-electrostatic wall paint A component.B system
First with part deionized water, antistatic agent is dissolved, again above-mentioned starting material are dropped into successively in Scattered Kettle and (added while stirring), with 1200rpm, carry out dispersed with stirring, be less than 30um to slurry fineness, normal dispersion 60, to 90min, filters and packages and gets final product to obtain functional anti-electrostatic wall paint B component.Wherein, the aqueous solution of antistatic agent be at Scattered Kettle in whipped state, continually slowly add.
Before brushing, by the mass ratio of 1:1, evenly mix A, B system, then add the water of A, B total amount approximately 10%, more than effectively disperseing 2min, get final product tool lead static, decorative effect is excellent, the functional anti-electrostatic finish paint (dumb light) of scrubbing resistance, fungus-resistant.
Effect embodiment 1
The anti-electrostatic wall paint of the embodiment of the present invention two, to new wall construction, is compared new wall construction with common wall paint simultaneously.After brushing anti-electrostatic wall paint, with anti-electrostatic instrument, detect, surface resistivity is 1*10
6Ω is to 2*10
6Ω, and common wall paint is state of insulation, has proved that anti-electrostatic wall paint of the present invention has excellent anti-static ability, can effectively derive the static producing in life, production, reduces the harm of static.
Above-described embodiment is preferably embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and principle, substitutes, combination, simplify; all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (10)
1. a functional anti-electrostatic wall paint, is characterized in that, A system and the B system of mass ratio 1:1, consists of, and described A system is made by slurrying stage A 1 system and paint stage A 2 systems;
Wherein:
Slurrying stage A 1 system is made by the component of following mass parts:
Paint stage A 2 systems are made by the component of following mass parts:
B system is made by the component of following mass parts:
2. functional anti-electrostatic wall paint according to claim 1, is characterized in that, No. 1 described auxiliary agent is comprised of 0.1～0.2 mass parts defoamer and 1.4～2.8 mass parts thickening materials.
3. functional anti-electrostatic wall paint according to claim 1, is characterized in that, the preferred water-based bisphenol A epoxide resin of described aqueous epoxy resins.
4. functional anti-electrostatic wall paint according to claim 1, is characterized in that, RS～2806 of the rich company of the preferred Ahmedabad of described pure-acrylic emulsion.
5. functional anti-electrostatic wall paint according to claim 1, is characterized in that, TIPAQUE ET～500W conductive titanium dioxide of the preferred Japanese Ishihara Sangyo Kaisha of described conductive titanium dioxide company.
6. functional anti-electrostatic wall paint according to claim 1, is characterized in that, the E10P of described preferred Henkel Corp. of reactive thinner.
7. functional anti-electrostatic wall paint according to claim 1, is characterized in that, No. 2 described auxiliary agents are by 0.1～0.8 mass parts wetting agent, and 0.1～0.4 mass parts dispersion agent and 0.3～0.8 mass parts defoamer form.
8. functional anti-electrostatic wall paint according to claim 1, is characterized in that, described antistatic agent is ASA～150.
9. functional anti-electrostatic wall paint according to claim 1, is characterized in that, described color stuffing is by 4～10 mass parts calcium carbonate, and 16～23 mass parts titanium dioxides and 5～16 mass parts calcined kaolins form.
10. functional anti-electrostatic wall paint preparation method claimed in claim 1, is characterized in that, comprises the steps: successively
(1) component described in slurrying stage A 1 system is stirred to 60～120min in 1000～1200rpm, so that slurry fineness is less than 30um, and then add component described in paint stage A 2 systems, with 600～800rpm, stir 30～60min, filter, obtain component A;
(2) starting material described in B system are stirred to 60～90min in 1000～1200rpm and mix, filter, obtain B component;
(3) before application, component A and B component are mixed with 1:1, obtain functional anti-electrostatic wall paint.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410395879.4A CN104140743A (en) | 2014-08-12 | 2014-08-12 | Functional anti-static wall surface paint and preparation method thereof |
| PCT/CN2015/079061 WO2016023391A1 (en) | 2014-08-12 | 2015-05-15 | Functional antistatic wall paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410395879.4A CN104140743A (en) | 2014-08-12 | 2014-08-12 | Functional anti-static wall surface paint and preparation method thereof |
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| CN104140743A true CN104140743A (en) | 2014-11-12 |
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| CN201410395879.4A Pending CN104140743A (en) | 2014-08-12 | 2014-08-12 | Functional anti-static wall surface paint and preparation method thereof |
Country Status (2)
| Country | Link |
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| CN (1) | CN104140743A (en) |
| WO (1) | WO2016023391A1 (en) |
Cited By (6)
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| CN105153874A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | High-adhesion wear-resistant waterborne electrostatic conducted anticorrosive coating |
| CN105153873A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | High-tenacity and high-strength waterborne electrostatic conducted anticorrosive coating |
| WO2016023391A1 (en) * | 2014-08-12 | 2016-02-18 | 广州亮豹涂料科技有限公司 | Functional antistatic wall paint and preparation method thereof |
| CN106010156A (en) * | 2016-08-12 | 2016-10-12 | 安庆市七仙女电器制造有限公司 | Electric iron antistatic paint and preparation method thereof |
| US11186743B2 (en) | 2017-06-02 | 2021-11-30 | Dow Global Technologies Llc | Waterborne epoxy coating composition |
| US11407917B2 (en) | 2016-11-02 | 2022-08-09 | Dow Global Technologies Llc | Coating composition |
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| CN111892852A (en) * | 2020-07-28 | 2020-11-06 | 浙江志强涂料有限公司 | Corrosion-resistant epoxy modified silicon-acrylic stone paint |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016023391A1 (en) * | 2014-08-12 | 2016-02-18 | 广州亮豹涂料科技有限公司 | Functional antistatic wall paint and preparation method thereof |
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| CN105153873A (en) * | 2015-09-09 | 2015-12-16 | 天长市银狐漆业有限公司 | High-tenacity and high-strength waterborne electrostatic conducted anticorrosive coating |
| CN106010156A (en) * | 2016-08-12 | 2016-10-12 | 安庆市七仙女电器制造有限公司 | Electric iron antistatic paint and preparation method thereof |
| US11407917B2 (en) | 2016-11-02 | 2022-08-09 | Dow Global Technologies Llc | Coating composition |
| US11186743B2 (en) | 2017-06-02 | 2021-11-30 | Dow Global Technologies Llc | Waterborne epoxy coating composition |
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| Publication number | Publication date |
|---|---|
| WO2016023391A1 (en) | 2016-02-18 |
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Application publication date: 20141112 |