CN106189558A - A kind of high rigidity anticorrosion straw treatment fluid and preparation method thereof - Google Patents
A kind of high rigidity anticorrosion straw treatment fluid and preparation method thereof Download PDFInfo
- Publication number
- CN106189558A CN106189558A CN201610555956.7A CN201610555956A CN106189558A CN 106189558 A CN106189558 A CN 106189558A CN 201610555956 A CN201610555956 A CN 201610555956A CN 106189558 A CN106189558 A CN 106189558A
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- China
- Prior art keywords
- treatment fluid
- water
- high rigidity
- polyvinyl chloride
- straw treatment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high rigidity anticorrosion straw treatment fluid, it is to be prepared by the raw material of following weight parts: resol resins 35, nano-ceramic powder 35, Tissuemat E 35, peregal o 10 0.4 0.6, petroleum sodium sulfonate 0.1 0.2, Oleum Verniciae fordii 12, modified polyvinyl chloride emulsion 10 15, xanthan gum 0.1 0.2,4 methyl guaiacol and 4s 0.01 0.015, ethylene glycol ether acetate 0.5 1, water 40 50.The straw treatment fluid of the present invention can form the coating of clear homogeneous on straw surface, and it is water-fast, water vapour permeability is excellent, and stalk material plays good protective action, is difficult to make moist, go mouldy.Having the feature that hardness is high, antiseptic property is good, range is wide, and ruggedness is strong simultaneously.
Description
Technical field
The present invention relates to straw technical field of surface, particularly relate to a kind of high rigidity anticorrosion straw treatment fluid and system thereof
Preparation Method.
Background technology
China is large agricultural country, and stalk resource is the abundantest, and distribution is wide, and kind is many and yield is huge.At present, crops straw
The processing mode of the stalk overwhelming majority is to process at direct open incineration, and this not only causes the great wasting of resources, and causes big
Gas pollutes, and affects atmosphere quality.Straw has the advantages that quality is pliable and tough, cheap, is suitable for weaving industry, makes grass
Kinds of processes product and the article of everyday use such as cap, straw mat, hand basket, extension picture, can make full use of existing resource, alleviates ambient pressure, again can
Develop the value of straw substantially, meet consumer's market demand to baskets craft.But straw is as one
Vegetable material, its resistance to water is poor, is susceptible to go rotten, deliquescence, and case hardness is the highest, and antiseptic property is poor, is not only difficult to long-term
Preserve and use, and range is restricted, and have impact on the using value of straw baskets craft.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of high rigidity anticorrosion straw treatment fluid and
Preparation method.
The present invention is achieved by the following technical solutions:
A kind of high rigidity anticorrosion straw treatment fluid, it is to be prepared by the raw material of following weight parts:
Resol resins 3-5, nano-ceramic powder 3-5, Tissuemat E 3-5, peregal o-10 0.4-0.6, petroleum sodium sulfonate
0.1-0.2, Oleum Verniciae fordii 1-2, modified polyvinyl chloride emulsion 10-15, xanthan gum 0.1-0.2,4-methyl guaiacol and 4 0.01-0.015,
Ethylene glycol ether acetate 0.5-1, water 40-50；
Wherein modified polyvinyl chloride emulsion is prepared by the raw materials in: vinyl chloride 10-15, acrylic acid 3-5, and carboxymethyl is fine
Dimension element 0.5-1, trifluoro propyl methyl cyclotrisiloxane 0.3-0.5, potassium peroxydisulfate 0.01-0.02, nano titanium oxide 1-2, ten
Sodium dialkyl sulfate 0.05-0.1, water 20-30；The preparation method of modified polyvinyl chloride emulsion be first by sodium lauryl sulphate and
Carboxymethyl cellulose be added to the water stirring until being completely dissolved, be subsequently adding vinyl chloride, acrylic acid, nano titanium oxide and trifluoro
Hydroxypropyl methyl cyclotrisiloxane 800-1000r/min stirs 0.5-1h, is eventually adding remaining raw material 70-80 DEG C reaction 2-4h, cold
The most afterwards and get final product.
The preparation method of a kind of high rigidity anticorrosion straw treatment fluid, comprises the following steps:
(1) nano-ceramic powder, Tissuemat E, Oleum Verniciae fordii, peregal o-10 and petroleum sodium sulfonate are added 110-120 in container jointly
Add after DEG C melting mixing in the water of 1/2-2/3 amount 90-95 DEG C, 800-1000r/min stir 0.5-1h, add modified after cooling
Polyvinyl chloride emulsion stirs, and obtains complex emulsions；
(2) 400-600r/min, 60-80 DEG C of stirring 0.5-1h after being mixed by remaining raw material, adds the Composite Milk in (1) after cooling
Liquid 1000-1500r/min stirs 5-10min, obtains high rigidity anticorrosion straw treatment fluid.
The invention have the advantage that
The present invention improves poisture-penetrability by acrylic acid and Modified by Carboxymethyl Cellulose, is changed by trifluoro propyl methyl cyclotrisiloxane
Property improve resistance to water, by compound ageing resistance and the mechanical property of improving of nano titanium oxide, prepared modified polyvinyl chloride breast
Obtaining straw treatment fluid after liquid is compounding with remaining raw material, can form the coating of clear homogeneous on straw surface, it is water-fast, poisture-penetrability
Can be excellent, stalk material is played good protective action, is difficult to make moist, go mouldy.Have that hardness is high, antiseptic property is good simultaneously
Feature, range is wide, and ruggedness is strong.
Detailed description of the invention
A kind of high rigidity anticorrosion straw treatment fluid, it is to be prepared by the raw material of following weight parts:
Resol resins 3, nano-ceramic powder 3, Tissuemat E 3, peregal o-10 0.4, petroleum sodium sulfonate 0.1, Oleum Verniciae fordii 1, change
Property polyvinyl chloride emulsion 10, xanthan gum 0.1,4 methyl guaiacol and 4s 0.01, ethylene glycol ether acetate 0.5, water 40；
Wherein modified polyvinyl chloride emulsion is prepared by the raw materials in: vinyl chloride 10, acrylic acid 3, carboxymethyl cellulose
0.5, trifluoro propyl methyl cyclotrisiloxane 0.3, potassium peroxydisulfate 0.01, nano titanium oxide 1, sodium lauryl sulphate 0.05,
Water 20；The preparation method of modified polyvinyl chloride emulsion is first sodium lauryl sulphate and carboxymethyl cellulose to be added to the water stirring
Until being completely dissolved, it is subsequently adding vinyl chloride, acrylic acid, nano titanium oxide and trifluoro propyl methyl cyclotrisiloxane 800r/
Min stirs 0.5h, is eventually adding remaining raw material 70 DEG C reaction 2h, after cooling and get final product.
The preparation method of a kind of high rigidity anticorrosion straw treatment fluid, comprises the following steps:
(1) nano-ceramic powder, Tissuemat E, Oleum Verniciae fordii, peregal o-10 and petroleum sodium sulfonate add in container 110 DEG C jointly melt
Add after melting mixing in the water of 1/2 amount 90 DEG C, 800r/min stir 0.5h, add modified polyvinyl chloride emulsion after cooling and stir equal
Even, obtain complex emulsions；
(2) after being mixed by remaining raw material, 400r/min, 60 DEG C of stirring 0.5h, add the complex emulsions 1000r/ in (1) after cooling
Min stirs 5min, obtains high rigidity anticorrosion straw treatment fluid.
Above-mentioned prepared straw treatment fluid is carried out performance test, and result is as follows:
| Project | Testing result |
| Appearance of film | Normally |
| Transparency | Excellent |
| Fineness (μm) | ≤10 |
| Bin stability (50 DEG C) | Without exception |
| Resistance to water (24h) | Without exception |
| Hardness | 1H |
Claims (2)
1. a high rigidity anticorrosion straw treatment fluid, it is characterised in that it is to be prepared by the raw material of following weight parts:
Resol resins 3-5, nano-ceramic powder 3-5, Tissuemat E 3-5, peregal o-10 0.4-0.6, petroleum sodium sulfonate
0.1-0.2, Oleum Verniciae fordii 1-2, modified polyvinyl chloride emulsion 10-15, xanthan gum 0.1-0.2,4-methyl guaiacol and 4 0.01-0.015,
Ethylene glycol ether acetate 0.5-1, water 40-50；
Described modified polyvinyl chloride emulsion is prepared by the raw materials in: vinyl chloride 10-15, acrylic acid 3-5, and carboxymethyl is fine
Dimension element 0.5-1, trifluoro propyl methyl cyclotrisiloxane 0.3-0.5, potassium peroxydisulfate 0.01-0.02, nano titanium oxide 1-2, ten
Sodium dialkyl sulfate 0.05-0.1, water 20-30；The preparation method of modified polyvinyl chloride emulsion be first by sodium lauryl sulphate and
Carboxymethyl cellulose be added to the water stirring until being completely dissolved, be subsequently adding vinyl chloride, acrylic acid, nano titanium oxide and trifluoro
Hydroxypropyl methyl cyclotrisiloxane 800-1000r/min stirs 0.5-1h, is eventually adding remaining raw material 70-80 DEG C reaction 2-4h, cold
The most afterwards and get final product.
The preparation method of a kind of high rigidity anticorrosion straw treatment fluid the most according to claim 1, it is characterised in that include with
Lower step:
(1) nano-ceramic powder, Tissuemat E, Oleum Verniciae fordii, peregal o-10 and petroleum sodium sulfonate are added 110-120 in container jointly
Add after DEG C melting mixing in the water of 1/2-2/3 amount 90-95 DEG C, 800-1000r/min stir 0.5-1h, add modified after cooling
Polyvinyl chloride emulsion stirs, and obtains complex emulsions；
(2) 400-600r/min, 60-80 DEG C of stirring 0.5-1h after being mixed by remaining raw material, adds the Composite Milk in (1) after cooling
Liquid 1000-1500r/min stirs 5-10min, obtains high rigidity anticorrosion straw treatment fluid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610555956.7A CN106189558A (en) | 2016-07-14 | 2016-07-14 | A kind of high rigidity anticorrosion straw treatment fluid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610555956.7A CN106189558A (en) | 2016-07-14 | 2016-07-14 | A kind of high rigidity anticorrosion straw treatment fluid and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189558A true CN106189558A (en) | 2016-12-07 |
Family
ID=57476182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610555956.7A Pending CN106189558A (en) | 2016-07-14 | 2016-07-14 | A kind of high rigidity anticorrosion straw treatment fluid and preparation method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN106189558A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486877A (en) * | 2018-04-04 | 2018-09-04 | 安徽恒益纺织科技有限公司 | A kind of technique of removal children's towel formaldehyde |
| CN108532301A (en) * | 2018-04-04 | 2018-09-14 | 安徽恒益纺织科技有限公司 | One kind removing formaldehyde children's towel |
| CN109735176A (en) * | 2019-01-08 | 2019-05-10 | 吉林建筑大学 | A kind of preparation method of energy conservation and environmental protection building thermal-insulating coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1618866A (en) * | 2004-10-11 | 2005-05-25 | 华东理工大学 | Preparation method of polyvinyl chloride/inorganic rigid particle composite resin |
| CN104342002A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Anti-corrosion coating capable of emitting aromatic odor for glass door and preparation method of anti-corrosion coating |
-
2016
- 2016-07-14 CN CN201610555956.7A patent/CN106189558A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1618866A (en) * | 2004-10-11 | 2005-05-25 | 华东理工大学 | Preparation method of polyvinyl chloride/inorganic rigid particle composite resin |
| CN104342002A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Anti-corrosion coating capable of emitting aromatic odor for glass door and preparation method of anti-corrosion coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486877A (en) * | 2018-04-04 | 2018-09-04 | 安徽恒益纺织科技有限公司 | A kind of technique of removal children's towel formaldehyde |
| CN108532301A (en) * | 2018-04-04 | 2018-09-14 | 安徽恒益纺织科技有限公司 | One kind removing formaldehyde children's towel |
| CN109735176A (en) * | 2019-01-08 | 2019-05-10 | 吉林建筑大学 | A kind of preparation method of energy conservation and environmental protection building thermal-insulating coating |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
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| RJ01 | Rejection of invention patent application after publication |