CN106313236A - Straw processing solution resistant to abrasion and scrubbing and preparation method thereof - Google Patents

Straw processing solution resistant to abrasion and scrubbing and preparation method thereof Download PDF

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Publication number
CN106313236A
CN106313236A CN201610718251.2A CN201610718251A CN106313236A CN 106313236 A CN106313236 A CN 106313236A CN 201610718251 A CN201610718251 A CN 201610718251A CN 106313236 A CN106313236 A CN 106313236A
Authority
CN
China
Prior art keywords
parts
straw
water
processing solution
polyvinyl chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610718251.2A
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Chinese (zh)
Inventor
王丽琼
杨东跃
杨思懿
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Anhui Meijing Arts And Crafts Co Ltd
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Anhui Meijing Arts And Crafts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Meijing Arts And Crafts Co Ltd filed Critical Anhui Meijing Arts And Crafts Co Ltd
Priority to CN201610718251.2A priority Critical patent/CN106313236A/en
Publication of CN106313236A publication Critical patent/CN106313236A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a straw processing solution resistant to abrasion and scrubbing. The straw processing solution resistant to abrasion and scrubbing is prepared from, by weight, 3-5 parts of waterborne amino resin, 3-5 parts of nano-scale silicon carbide, 0.1-0.2 part of pentaerythritol oleate, 1-2 parts of zinc stearate, 3-5 parts of polyethylene wax, 0.4-0.6 part of peregal o-10, 10-15 parts of modified polyvinyl chloride latex, 0.01-0.02 part of oxypropylene ethylene oxide glyceryl ether, 2-4 parts of styrene-acrylic emulsions and 40-50 parts of water. Through the straw processing solution, a transparent uniform coating can be formed on the surface of straw, the waterproof performance and water vapor permeability are excellent, and the straw material is well protected and is not prone to being affected with damp or mildew. Meanwhile, the straw processing solution has the characteristics of good abrasion and scrubbing resistance and is convenient to clean in daily life, and the service life of the straw product can be effectively prolonged.

Description

A kind of wear-resisting scrubbing resistance straw treatment fluid and preparation method thereof
Technical field
The present invention relates to straw technical field of surface, particularly relate to a kind of wear-resisting scrubbing resistance straw treatment fluid and system thereof Preparation Method.
Background technology
China is large agricultural country, and stalk resource is the abundantest, and distribution is wide, and kind is many and yield is huge.At present, crops straw The processing mode of the stalk overwhelming majority is to process at direct open incineration, and this not only causes the great wasting of resources, and causes big Gas pollutes, and affects atmosphere quality.Straw has the advantages that quality is pliable and tough, cheap, is suitable for weaving industry, makes grass Kinds of processes product and the article of everyday use such as cap, straw mat, hand basket, extension picture, can make full use of existing resource, alleviates ambient pressure, again can Develop the value of straw substantially, meet consumer's market demand to baskets craft.But straw is as one Vegetable material, its resistance to water is poor, is susceptible to go rotten, deliquescence, and surface abrasion resistance damages, scrub performance is poor, it is difficult to for a long time Preserve and use, have impact on the using value of straw baskets craft.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of wear-resisting scrubbing resistance straw treatment fluid and Preparation method.
The present invention is achieved by the following technical solutions:
A kind of wear-resisting scrubbing resistance straw treatment fluid, it is to be prepared by the raw material of following weight parts:
Water-compatible amino resin 3-5, nanometer silicon carbide 3-5, PETO 0.1-0.2, zinc stearate 1-2, Tissuemat E 3-5, peregal o-10 0.4-0.6, modified polyvinyl chloride emulsion 10-15, polyoxypropylene ethylene oxide glycerin ether 0.01-0.02, Styrene-acrylic emulsion 2-4, water 40-50;
Wherein modified polyvinyl chloride emulsion is prepared by the raw materials in: vinyl chloride 10-15, acrylic acid 3-5, and carboxymethyl is fine Dimension element 0.5-1, trifluoro propyl methyl cyclotrisiloxane 0.3-0.5, potassium peroxydisulfate 0.01-0.02, nano titanium oxide 1-2, ten Sodium dialkyl sulfate 0.05-0.1, water 20-30;The preparation method of modified polyvinyl chloride emulsion be first by sodium lauryl sulphate and Carboxymethyl cellulose be added to the water stirring until being completely dissolved, be subsequently adding vinyl chloride, acrylic acid, nano titanium oxide and trifluoro Hydroxypropyl methyl cyclotrisiloxane 800-1000r/min stirs 0.5-1h, is eventually adding remaining raw material 70-80 DEG C reaction 2-4h, cold The most afterwards and get final product.
The preparation method of a kind of wear-resisting scrubbing resistance straw treatment fluid, comprises the following steps:
(1) nanometer silicon carbide, Tissuemat E, zinc stearate, peregal o-10 and PETO are added container jointly After middle 110-120 DEG C of melting mixing add 1/2-2/3 amount water in 90-95 DEG C, 800-1000r/min stir 0.5-1h, cool down Rear addition modified polyvinyl chloride emulsion and styrene-acrylic emulsion stir, and obtain complex emulsions;
(2) 400-600r/min, 60-80 DEG C of stirring 0.5-1h after being mixed by remaining raw material, adds the Composite Milk in (1) after cooling Liquid 1000-1500r/min stirs 5-10min, obtains wear-resisting scrubbing resistance straw treatment fluid.
The invention have the advantage that
The present invention improves poisture-penetrability by acrylic acid and Modified by Carboxymethyl Cellulose, is changed by trifluoro propyl methyl cyclotrisiloxane Property improve resistance to water, by compound ageing resistance and the mechanical property of improving of nano titanium oxide, prepared modified polyvinyl chloride breast Obtaining straw treatment fluid after liquid is compounding with remaining raw material, can form the coating of clear homogeneous on straw surface, it is water-fast, poisture-penetrability Can be excellent, stalk material is played good protective action, is difficult to make moist, go mouldy.Have simultaneously wear-resistant, scrub performance good Feature, it is simple to daily cleaning, can effectively extend the service life of stalk product.
Detailed description of the invention
A kind of wear-resisting scrubbing resistance straw treatment fluid, it is to be prepared by the raw material of following weight parts:
Water-compatible amino resin 3, nanometer silicon carbide 3, PETO 0.1, zinc stearate 1, Tissuemat E 3, peregal o- 10 0.4, modified polyvinyl chloride emulsion 10, polyoxypropylene ethylene oxide glycerin ether 0.01, styrene-acrylic emulsion 2, water 40;
Wherein modified polyvinyl chloride emulsion is prepared by the raw materials in: vinyl chloride 10, acrylic acid 3, carboxymethyl cellulose 0.5, trifluoro propyl methyl cyclotrisiloxane 0.3, potassium peroxydisulfate 0.01, nano titanium oxide 1, sodium lauryl sulphate 0.05, Water 20;The preparation method of modified polyvinyl chloride emulsion is first sodium lauryl sulphate and carboxymethyl cellulose to be added to the water stirring Until being completely dissolved, it is subsequently adding vinyl chloride, acrylic acid, nano titanium oxide and trifluoro propyl methyl cyclotrisiloxane 800r/ Min stirs 0.5h, is eventually adding remaining raw material 70 DEG C reaction 2h, after cooling and get final product.
The preparation method of a kind of wear-resisting scrubbing resistance straw treatment fluid, comprises the following steps:
(1) nanometer silicon carbide, Tissuemat E, zinc stearate, peregal o-10 and PETO are added container jointly In add after 110 DEG C of melting mixing in the water of 1/2 amount 90 DEG C, 800r/min stir 0.5h, addition modified polyvinyl chloride after cooling Emulsion and styrene-acrylic emulsion stir, and obtain complex emulsions;
(2) after being mixed by remaining raw material, 400r/min, 60 DEG C of stirring 0.5h, add the complex emulsions 1000r/ in (1) after cooling Min stirs 5min, obtains wear-resisting scrubbing resistance straw treatment fluid.
Above-mentioned prepared straw treatment fluid is carried out performance test, and result is as follows:
Project Testing result
Appearance of film Normally
Transparency Excellent
Fineness (μm) ≤10
Bin stability (50 DEG C) Without exception
Resistance to water (24h) Without exception

Claims (2)

1. a wear-resisting scrubbing resistance straw treatment fluid, it is characterised in that it is to be prepared by the raw material of following weight parts:
Water-compatible amino resin 3-5, nanometer silicon carbide 3-5, PETO 0.1-0.2, zinc stearate 1-2, Tissuemat E 3-5, peregal o-10 0.4-0.6, modified polyvinyl chloride emulsion 10-15, polyoxypropylene ethylene oxide glycerin ether 0.01-0.02, Styrene-acrylic emulsion 2-4, water 40-50;
Described modified polyvinyl chloride emulsion is prepared by the raw materials in: vinyl chloride 10-15, acrylic acid 3-5, and carboxymethyl is fine Dimension element 0.5-1, trifluoro propyl methyl cyclotrisiloxane 0.3-0.5, potassium peroxydisulfate 0.01-0.02, nano titanium oxide 1-2, ten Sodium dialkyl sulfate 0.05-0.1, water 20-30;The preparation method of modified polyvinyl chloride emulsion be first by sodium lauryl sulphate and Carboxymethyl cellulose be added to the water stirring until being completely dissolved, be subsequently adding vinyl chloride, acrylic acid, nano titanium oxide and trifluoro Hydroxypropyl methyl cyclotrisiloxane 800-1000r/min stirs 0.5-1h, is eventually adding remaining raw material 70-80 DEG C reaction 2-4h, cold The most afterwards and get final product.
The preparation method of a kind of wear-resisting scrubbing resistance straw treatment fluid the most according to claim 1, it is characterised in that include with Lower step:
(1) nanometer silicon carbide, Tissuemat E, zinc stearate, peregal o-10 and PETO are added container jointly After middle 110-120 DEG C of melting mixing add 1/2-2/3 amount water in 90-95 DEG C, 800-1000r/min stir 0.5-1h, cool down Rear addition modified polyvinyl chloride emulsion and styrene-acrylic emulsion stir, and obtain complex emulsions;
(2) 400-600r/min, 60-80 DEG C of stirring 0.5-1h after being mixed by remaining raw material, adds the Composite Milk in (1) after cooling Liquid 1000-1500r/min stirs 5-10min, obtains wear-resisting scrubbing resistance straw treatment fluid.
CN201610718251.2A 2016-08-24 2016-08-24 Straw processing solution resistant to abrasion and scrubbing and preparation method thereof Pending CN106313236A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610718251.2A CN106313236A (en) 2016-08-24 2016-08-24 Straw processing solution resistant to abrasion and scrubbing and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610718251.2A CN106313236A (en) 2016-08-24 2016-08-24 Straw processing solution resistant to abrasion and scrubbing and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106313236A true CN106313236A (en) 2017-01-11

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CN201610718251.2A Pending CN106313236A (en) 2016-08-24 2016-08-24 Straw processing solution resistant to abrasion and scrubbing and preparation method thereof

Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108972790A (en) * 2018-08-07 2018-12-11 安徽嘉美工艺品有限公司 A kind of mould proof fixation liquid of straw plaited straw

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104341985A (en) * 2014-10-14 2015-02-11 凤阳徽亨商贸有限公司 Water-resistant scrubbing-resistant waterborne coating for glass door and preparation method of water-resistant scrubbing-resistant waterborne coating

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104341985A (en) * 2014-10-14 2015-02-11 凤阳徽亨商贸有限公司 Water-resistant scrubbing-resistant waterborne coating for glass door and preparation method of water-resistant scrubbing-resistant waterborne coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108972790A (en) * 2018-08-07 2018-12-11 安徽嘉美工艺品有限公司 A kind of mould proof fixation liquid of straw plaited straw

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