CN106187521B - A kind of feces of livestock and poultry deodorant - Google Patents
A kind of feces of livestock and poultry deodorant Download PDFInfo
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- CN106187521B CN106187521B CN201610576971.XA CN201610576971A CN106187521B CN 106187521 B CN106187521 B CN 106187521B CN 201610576971 A CN201610576971 A CN 201610576971A CN 106187521 B CN106187521 B CN 106187521B
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- deodorant
- livestock
- feces
- poultry
- compost
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F3/00—Fertilisers from human or animal excrements, e.g. manure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
- Treatment Of Sludge (AREA)
- Housing For Livestock And Birds (AREA)
Abstract
The invention discloses a kind of feces of livestock and poultry deodorant, the deodorant is prepared by mass percentage by following raw material: flyash 50%~70%, silicon powder 17%~25%, additive 10%~17%, Inoculant 3%~9%, the additive are one or more substances of calper calcium peroxide, calcium oxide and Nanoscale Iron.Feces of livestock and poultry is handled using deodorant of the present invention, deodorant gradually or is disposably added in feces of livestock and poultry using spray appliance, is uniformly mixed by the ratio that stool quality 0.5%~5% is accounted for according to deodorant, with the passage of compost time, thorough deodorization can be completed after a week, deodorant of the present invention effectively can quickly remove the foul gas in feces of livestock and poultry, and be greatly improved to the technique of composting process, improve production efficiency, with low in cost, refuse reclamation, nontoxic feature.
Description
Technical field
The present invention relates to a kind of feces of livestock and poultry deodorant, belong to the processing technology field of debirs.
Background technique
China's livestock and poultry breeding industry is quickly grown, currently, about 2,700,000,000 tons of feces of livestock and poultry that China rural area generates every year.Although poultry
Poultry manure is also the precious resources in agricultural production, and nitrogen that domestic livestock and poultry farm year generates, phosphorus are respectively up to 15,970,000 tons and 363
Ten thousand tons, it is equivalent to the 78.9% and 57.4% of China's same period fertilizer amount, but being continuously increased with feces of livestock and poultry, it stacks on the spot
Stink is big, and mosquitos and flies is more, pollutes air and water source;Directly make fertilizer infectivity disease and insect pest, it is difficult to digest, be needed rapidly on the spot
Carry out harmless treatment.There are many method for innocent treatment, and wherein stacking ventilation aerobic fermentation is more common and easy to operate, fast
Spend faster processing method.In order to reduce the stink generation of stacking early period, accelerate the decomposition rate of waste, it would be desirable to poultry
Poultry manure carries out deodorizing process.Generated foul smell main component is NH in livestock excrement composting treatment process3And H2S.It is right at present
Generated foul smell available physical, chemistry and biological method are handled in Composting Process.Physical deodorization method mainly has washing
Method, absorption method, screening agent method and high-altitude diffusion method, chemical deodorization method mainly have direct combustion method, chemical oxidization method, neutralisation and
High-temperature oxidation, biological odor removal method are to be decomposed using microorganism, convert stink odor to reach deodorization purpose, therefore also cried micro-
Biological odor removal method.But compost deodorizing is carried out using the method for physics and chemistry, effect is preferable, but there is investment and operating cost
High, the problems such as secondary pollution is serious.Deodorization is carried out to compost using biological method, the effect in laboratory may be fine, but by
It is limited in microbial activity by environmental condition, it is difficult to ensure that the deodorizing effect of compost.
Patent 201510097566.5: " a kind of During High-Temperature Composting nitrogen-protecting deodorant and its application " propose use by calcium chloride,
The deodorant of iron chloride, alkyl glycosides and water composition, is added in raw material, to debirs During High-Temperature Composting using the method for spray
The processing of stink in the process.But the deodorant is liquid substance, is difficult to control the dosage of deodorant when in use, and spraying
During it is difficult to ensure that deodorant covering uniformity.
Patent 201410006033.7: " livestock and poultry farm deodorant and application " propose using by 15~50g acetic acid, 50
The copper sulphate of~100g is settled to 500ml preparation with water and obtains, deodorant is packed into open-top receptacle and is suspended on by vent window.
The deodorant is also liquid substance, in use, being not added directly into feces of livestock and poultry, cannot fundamentally solve asking for stink
Topic.
Summary of the invention
The purpose of the present invention is to provide a kind of feces of livestock and poultry deodorant, the deodorant utilizes chemicals and biology system
The synergistic effect of agent carries out stink processing to feces of livestock and poultry;Deodorant is micro-nano type particulate matter, is added using the method for sprinkling
Into feces of livestock and poultry, not only stink can be solved the problems, such as with uniform fold but also fundamentally;The deodorant is by following
Raw material is prepared by mass percentage: flyash 50%~70%, silicon powder 17%~25%, additive 10%~17%, Inoculant 3%
~9%, the additive is one or more substances of calper calcium peroxide, calcium oxide and Nanoscale Iron.
Preferably, flyash of the present invention, calper calcium peroxide, calcium oxide, Inoculant granularity be 1000~2500 mesh, receive
The granularity of meter Tie is 70~100nm, and the granularity of silicon powder is 200~500 mesh;The difference of granular size is formd by suction-operated
Composite particles, the surface that flyash, additive and Inoculant are adsorbed on silicon powder particle form composite particles, and each substance can be sent out
Wave its respectively due effect.
Deodorant of the present invention the preparation method comprises the following steps: additive, Inoculant are sequentially added flyash according to mass ratio
In, it is sufficiently mixed uniformly, is then added to silicon powder in uniformly mixed mixture, be uniformly mixed to obtain the final product.
Inoculant of the present invention is the material in secondary fermentation stage during livestock excrement composting.
Flyash of the present invention is the solid waste of coal-burning power plant's discharge, main component are as follows: SiO2、Al2O3、FeO、
Fe2O3、CaO、MgO 、K2O、 Na2O、MnO2Deng, most of is oxide soluble easily in water, react with water generate alkaline matter and
Volatile fatty acid reacts forming salt, can greatly reduce the yield of this important malodorous compound of volatile fatty acid.
The present invention also provides application of the feces of livestock and poultry micro-nano deodorant in livestock excrement composting, specifically: compost is opened
When the beginning, the ratio of stool quality 0.5~5% is accounted for according to deodorant, gradually or is disposably sprayed into deodorant using spray appliance
In feces of livestock and poultry, it is uniformly mixed carry out compost, with the passage of compost time, thorough deodorization can be completed after a week.
The present invention provides shown in spray appliance (Fig. 1);Deodorant is entered by drain hole 1, and air is passed through manual by air inlet 3
Deodorant composite particles are blown in pipeline 4 by 2 air blast of air blower, are sprayed away by the sprinkling mouth 5 below pipeline, air blower can
To provide very big wind-force, makes deodorant composite particles by evenly spreading out after sprinkling mouth, achieve the effect that uniform fold.
Compared with the prior art, the advantages of the present invention are as follows:
(1) feces of livestock and poultry deodorant of the invention handles feces of livestock and poultry, and worm's ovum, pathogen contamination are reduced, be finally effectively reduced
The yield of smelly metallic substance during livestock excrement composting, granularity is very small, is directly sprayed onto livestock excrement composting when using
It just can reach the effect of all standing in raw material.
(2) flyash in feces of livestock and poultry micro-nano deodorant of the invention is very high in China's yield, and harm is big, therefore reachable
To the effect of waste resource recovery.
(3) feces of livestock and poultry micro-nano deodorant of the invention is significant to deodorizing effect during livestock excrement composting.Through testing
Measurement, stink can be eliminated in the latter week left and right of compost, and compared with the Traditional compost deodorization time, stink eliminates the time and does sth. in advance 15 days
More than.
(4) preparation method is simple, low in cost, easy to use.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of sprinkler;
Fig. 2 is the structural schematic diagram of composite particles.
In Fig. 1: 1- drain hole;2- air blower;3- air inlet;4- ventilation pipe;5- sprays mouth.
Specific embodiment
Further illustrate technical solution of the invention combined with specific embodiments below, but the scope of the present invention not office
It is limited to the content.
Embodiment 1
Feces of livestock and poultry deodorant described in the present embodiment is prepared by mass percentage by following raw material: flyash 65%, silicon
Powder 20%, calcium oxide 5%, Nanoscale Iron 5%, Inoculant 5%;State flyash, calper calcium peroxide, calcium oxide, Inoculant granularity be 1000
~1200 mesh, the granularity of Nanoscale Iron are 70~80nm, and the granularity of silicon powder is 200~250 mesh.
Aerobic compost is carried out using cow manure as composting material, cow dung water content is about 86%, the initial moisture of composting material
Content is between 55%~65%, and compost environment temperature is about 25 DEG C, and the additive amount of deodorant is with the quality percentage of compost raw material
Than meter, concrete operations are as follows:
(1) before compost starts, deodorant is mixed in 1% ratio of feces of livestock and poultry with composting material, is stirred evenly, i.e.,
It can.
(2) raw material and deodorant after mixing, carry out During High-Temperature Composting, temperature raising period forced ventilation, and rate of venting is
1.0m3/ min detects composting process heap body core temperature.
(3) stop ventilation when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every
It is primary every turning in 3 days, it ferments 35 days and completes During High-Temperature Composting.
(4) with every metering in 5 days, H in 5 days is detected2S volatile quantity.
(5) handle 1: the present embodiment deodorant is handled
Processing 2: no added deodorant handles (control)
Table 1 is the present embodiment deodorant to cow dung compost H2The influence of S volatile quantity
As shown in Table 1, addition deodorant can significantly reduce H during cow dung compost2The volatile quantity of S.It adds at deodorant
Reason 10 days H before compost2S volatile quantity, which is substantially less than, to be compareed, and the processing is nearly no detectable H after compost 11 days2The volatilization of S;Control
Group processing is in 21 days H of compost2The volatile quantity of S is also relatively high.
Embodiment 2
Feces of livestock and poultry deodorant described in the present embodiment is prepared by mass percentage by following raw material: flyash 60%, silicon
Powder 22%, calcium oxide 8%, calper calcium peroxide 7%, Inoculant 3%;State flyash, calper calcium peroxide, calcium oxide, Inoculant granularity be
1300~1500 mesh, the granularity of Nanoscale Iron are 80~90nm, and the granularity of silicon powder is 300~350 mesh.
Aerobic compost is carried out using swine excrement as composting material, pig manure water content is about 80%, and the initial moisture of composting material contains
Amount is between 55%~65%, and compost environment temperature is about 25 DEG C, and the additive amount of deodorant is with the mass percent of compost raw material
Meter, concrete operations are as follows:
(1) before compost starts, deodorant is mixed in 3% ratio of feces of livestock and poultry with composting material, is stirred evenly, i.e.,
It can.
(2) raw material and deodorant after mixing, carry out During High-Temperature Composting, temperature raising period forced ventilation, and rate of venting is
1.0m3/ min detects composting process heap body core temperature.
(3) stop ventilation when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every
It is primary every turning in 4 days, it ferments 25 days and completes During High-Temperature Composting.
(4) handle 1: the present embodiment deodorant is handled
Processing 2: no added deodorant handles (control)
(5) Testing index: stink index uses six grades of classification: Ms0: Ms1: odorless feels stink, Ms2 reluctantly:
Faint stink, Ms3: apparent stink, Ms4: very strong stink, Ms5: insufferable stink.
Table 2 is influence of the deodorant to pig manure stink
As can be seen from Table 2, addition deodorant processing smelly degree maximum value during the entire process of compost is less than control, addition
Deodorant processing odorless after compost 15 days generates, and to 15 days stink maximums of compost are impinged upon, compost is thrown away on the 25th day when completing
It can smell stink.Illustrate that deodorant is obvious to pig manure deodorizing effect.
Embodiment 3
Feces of livestock and poultry deodorant described in the present embodiment is prepared by mass percentage by following raw material: flyash 70%, silicon
Powder 11%, calcium oxide 15%, Inoculant 4%;State flyash, calper calcium peroxide, calcium oxide, Inoculant granularity be 1800~2000 mesh,
The granularity of Nanoscale Iron is 90~100nm, and the granularity of silicon powder is 450~500 mesh.
Aerobic compost is carried out by composting material of feces of chicken as, chicken manure water content is about 70%, and the initial moisture of composting material contains
Amount is between 55%~65%, and compost environment temperature is about 20 DEG C, and the additive amount of deodorant is with the mass percent of compost raw material
Meter, concrete operations are as follows:
(1) before compost starts, deodorant is mixed in 2% ratio of feces of livestock and poultry with composting material, is stirred evenly, i.e.,
It can.
(2) raw material and deodorant after mixing, carry out During High-Temperature Composting, temperature raising period forced ventilation, and rate of venting is
1.0m3/min detects composting process heap body core temperature.
(3) stop ventilation when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every
It is primary every turning in 4 days, it ferments 25 days and completes During High-Temperature Composting.
(4) with every metering in 5 days, Ammonia valatilization amount in 5 days is detected.
(5) handle 1: the present embodiment deodorant is handled
Processing 2: no added deodorant handles (control)
Table 3 is influence of the deodorant to chicken manure compost Ammonia valatilization amount
As shown in Table 3, addition deodorant can significantly reduce the volatile quantity of ammonia in Chicken Manure Compost.Control treatment is in compost mistake
Volatilization total amount in journey is 123.78mg, and the volatilization total amount of addition deodorant processing ammonia in composting process is 40.2mg, right
Volatilization total amount according to processing ammonia is 3.08 times for adding deodorant and going out.
Embodiment 4
Feces of livestock and poultry deodorant described in the present embodiment is prepared by mass percentage by following raw material: flyash 50%, silicon
Powder 25%, calcium oxide 17%, Inoculant 8%;State flyash, calper calcium peroxide, calcium oxide, Inoculant granularity be 2300~2500 mesh,
The granularity of Nanoscale Iron is 80~90nm, and the granularity of silicon powder is 300~400 mesh.
Aerobic compost is carried out by composting material of feces of chicken as, chicken manure water content is about 70%, and the initial moisture of composting material contains
Amount is between 55%~65%, and compost environment temperature is about 20 DEG C, and the additive amount of deodorant is with the mass percent of compost raw material
Meter, concrete operations are as follows:
(1) before compost starts, deodorant is mixed in 5% ratio of feces of livestock and poultry with composting material, is stirred evenly, i.e.,
It can.
(2) raw material and deodorant after mixing, carry out During High-Temperature Composting, temperature raising period forced ventilation, and rate of venting is
1.0m3/min detects composting process heap body core temperature.
(3) stop ventilation when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every
It is primary every turning in 4 days, it ferments 25 days and completes During High-Temperature Composting.
(4) with every metering in 5 days, Ammonia valatilization amount in 5 days is detected.
(5) handle 1: the present embodiment deodorant is handled
Processing 2: no added deodorant handles (control)
Table 4 is influence of the deodorant to chicken manure compost Ammonia valatilization amount
As shown in Table 4, the volatilization total amount of addition deodorant processing ammonia in composting process is 31.5mg, with embodiment 3
Middle Ammonia valatilization total amount is 40.2mg compared to 8.7mg is reduced, and illustrates that the amount for adding deodorant is more, the yield of ammonia is got over
It is few.
Claims (2)
1. a kind of feces of livestock and poultry deodorant, it is characterised in that: be prepared by mass percentage by following raw material: flyash 50%
~70%, silicon powder 17%~25%, additive 10%~17%, Inoculant 3%~9%, the additive be calper calcium peroxide, calcium oxide and
One or more substances of Nanoscale Iron;
The flyash, calper calcium peroxide, calcium oxide, Inoculant granularity be 1000~2500 mesh, the granularity of Nanoscale Iron is 70~
100nm, the granularity of silicon powder are 200~500 mesh;
The Inoculant is the material in secondary fermentation stage during livestock excrement composting.
2. feces of livestock and poultry deodorant according to claim 1, it is characterised in that: applying feces of livestock and poultry deodorant in animal dung
Just in compost, the ratio of stool quality 0.5%~5% is accounted for according to deodorant, using spray appliance gradually or disposably by deodorization
Agent sprinkling is added in feces of livestock and poultry, is uniformly mixed.
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CN106665373A (en) * | 2016-12-28 | 2017-05-17 | 苏州倍儿壮养殖装备科技有限公司 | Livestock and poultry breeding shed ventilating device |
CN109650974B (en) * | 2019-01-14 | 2021-07-09 | 湖南大学 | Method for reducing nitrogen loss in composting process and improving fertilizer efficiency of compost product by using iron oxide nano material |
CN110563519A (en) * | 2019-08-27 | 2019-12-13 | 昆明理工大学 | Method for preparing composite inoculant through electromagnetic enhancement and application |
CN114409458A (en) * | 2021-12-24 | 2022-04-29 | 华夏瑞天(北京)生物科技有限公司 | Livestock and poultry manure treatment material, livestock and poultry manure treatment method and organic fertilizer |
CN115141043A (en) * | 2022-06-29 | 2022-10-04 | 牛勇 | Green organic fertilizer and preparation process thereof |
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CN102701433A (en) * | 2012-05-31 | 2012-10-03 | 中国环境科学研究院 | Biological filter deodorization filler and preparation method |
CN104649750A (en) * | 2013-11-18 | 2015-05-27 | 青岛水世界环保科技有限公司 | Deodorant for high-temperature composting process |
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CN105272476A (en) * | 2015-11-16 | 2016-01-27 | 刘伟 | Livestock and poultry excrement composting deodorant |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN102701433A (en) * | 2012-05-31 | 2012-10-03 | 中国环境科学研究院 | Biological filter deodorization filler and preparation method |
CN104649750A (en) * | 2013-11-18 | 2015-05-27 | 青岛水世界环保科技有限公司 | Deodorant for high-temperature composting process |
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