CN106187521A - A kind of feces of livestock and poultry deodorizer - Google Patents

A kind of feces of livestock and poultry deodorizer Download PDF

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Publication number
CN106187521A
CN106187521A CN201610576971.XA CN201610576971A CN106187521A CN 106187521 A CN106187521 A CN 106187521A CN 201610576971 A CN201610576971 A CN 201610576971A CN 106187521 A CN106187521 A CN 106187521A
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deodorizer
livestock
poultry
feces
compost
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CN106187521B (en
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瞿广飞
陈晓天
刘树根
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Kunyu Environment Development Yunnan Co ltd
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Kunming University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)
  • Treatment Of Sludge (AREA)
  • Housing For Livestock And Birds (AREA)

Abstract

The invention discloses a kind of feces of livestock and poultry deodorizer, described deodorizer is prepared by mass percentage by following raw material: flyash 50%~70%, silica flour 17%~25%, additive 10%~17%, Inoculant 3%~9%, described additive is one or more materials of calper calcium peroxide, calcium oxide and Nanoscale Iron.Deodorizer of the present invention is utilized to process feces of livestock and poultry, account for the ratio of stool quality 0.5%~5% according to deodorizer, utilize spray appliance gradually or disposably deodorizer added in feces of livestock and poultry, being uniformly mixed, passage along with the compost time, can complete thorough deodorization after one week, the foul gas in feces of livestock and poultry can the most quickly be removed by deodorizer of the present invention, and is greatly improved the technique of composting process, improve production efficiency, have with low cost, refuse reclamation, nontoxic feature.

Description

A kind of feces of livestock and poultry deodorizer
Technical field
The present invention relates to a kind of feces of livestock and poultry deodorizer, belong to the processing technology field of debirs.
Background technology
China's livestock and poultry breeding industry quickly grows, at present, and the feces of livestock and poultry that China rural area produces every year about 2,700,000,000 tons.Although poultry Poultry manure is also the precious resources in agricultural production, and nitrogen, phosphorus that domestic livestock and poultry farm year produces reach 15,970,000 tons and 363 respectively Ten thousand tons, be equivalent to the 78.9% and 57.4% of China's fertilizer amount same period, but be as being continuously increased of feces of livestock and poultry, stack on the spot Stink is big, and mosquitos and flies is many, contaminated air and water source;Directly make fertilizer infectivity disease and insect pest, it is difficult to digest on the spot, need rapidly Carry out harmless treatment.Method for innocent treatment is a lot, and wherein stacking ventilation aerobic fermentation is more to commonly use and easy and simple to handle, fast Spend processing method faster.Occur to reduce the stink of stacking early stage, accelerate the decomposition rate of garbage, it would be desirable to poultry Poultry manure carries out deodorization process.In livestock excrement composting processing procedure, produced foul smell main component is NH3And H2S.The most right In Composting Process, produced foul smell available physical, chemistry and biological method process.Physical deodorization method mainly has washing Method, absorption method, screening agent method and high-altitude diffusion method, chemical deodorizing method mainly have direct combustion method, chemical oxidization method, neutralisation and High-temperature oxidation, biological odor removal method is to utilize microorganism to decompose, convert foul smell composition to reach deodorization purpose, the most also cries micro- Biological odor removal method.But the method using physics and chemistry carries out compost deodorizing, effect is preferable, but there is investment and operating cost The problems such as high, secondary pollution is serious.Using biological method that compost is carried out deodorization, the effect at laboratory may be fine, but by Limited by environmental condition in microbial activity, it is difficult to ensure that the deodorizing effect of compost.
Patent 201510097566.5: " a kind of During High-Temperature Composting nitrogen-protecting deodorant and application " thereof propose to use by calcium chloride, Iron chloride, alkyl polyglucoside and the deodorizer of water composition, utilize the method for spray to join in raw material, to debirs During High-Temperature Composting During the process of stink.But this deodorizer is liquid substance, it is difficult to control the dosage of deodorizer in use, and at spray During it is difficult to ensure that the covering uniformity of deodorizer.
Patent 201410006033.7: " livestock and poultry farm deodorizer and application " propose use by 15~50g acetic acid, 50 ~the copper sulfate water of 100g is settled to 500ml preparation and obtains, in deodorizer is loaded open-top receptacle and be suspended on by vent window. This deodorizer is also liquid substance, during use, is not added directly in feces of livestock and poultry, it is impossible to fundamentally solve asking of stink Topic.
Summary of the invention
It is an object of the invention to provide a kind of feces of livestock and poultry deodorizer, described deodorizer utilizes chemicals and biological system The synergism of agent carries out stink process to feces of livestock and poultry;Deodorizer is micro-nano type particulate matter, uses the method sprayed to add In feces of livestock and poultry, it is possible not only to uniform fold and the problem that can fundamentally solve stink;Described deodorizer is by following Raw material prepares by mass percentage: flyash 50%~70%, silica flour 17%~25%, additive 10%~17%, Inoculant 3% ~9%, described additive is one or more materials of calper calcium peroxide, calcium oxide and Nanoscale Iron.
Preferably, flyash of the present invention, calper calcium peroxide, calcium oxide, the granularity of Inoculant are 1000~2500 mesh, receive The granularity of meter Tie is 70~100nm, and the granularity of silica flour is 200~500 mesh;The difference of granular size is defined by adsorption Composite particles, flyash, additive and Inoculant absorption are at the surface of silicon powder particle formation composite particles, and each material can be sent out Wave its most due effect.
The preparation method of deodorizer of the present invention is: according to mass ratio, additive, Inoculant are sequentially added into flyash In, it is sufficiently mixed uniformly, then silica flour is joined in the mixture of mix homogeneously, mix homogeneously and get final product.
Inoculant of the present invention is the material in ferment in second time stage during livestock excrement composting.
Flyash of the present invention is the solid waste that coal-burning power plant discharges, and it is mainly composed of: SiO2、Al2O3、FeO、 Fe2O3、CaO、MgO 、K2O、 Na2O、MnO2Deng, major part is oxide soluble in water, with water react generation alkaline matter with Volatile fatty acid reacts formation salt, can greatly reduce the generation amount of this important malodorous compound of volatile fatty acid.
Present invention also offers the application in livestock excrement composting of the feces of livestock and poultry micro-nano deodorizer, particularly as follows: compost is opened During the beginning, account for stool quality 0.5~the ratio of 5% according to deodorizer, utilize spray appliance gradually or disposably deodorizer be sprayed into In feces of livestock and poultry, it is uniformly mixed and carries out compost, along with the passage of compost time, thorough deodorization after one week, can be completed.
The present invention is given shown in spray appliance (Fig. 1);Deodorizer is entered by drain hole 1, and air is by air inlet 3 manually Deodorizer composite particles is blown in pipeline 4 by aerator 2 air blast, is sprayed away by the sprinkling mouth 5 below pipeline, and aerator can With the wind-force that offer is the biggest, make deodorizer composite particles be opened by dispersed after spraying mouth, reach the effect of uniform fold.
Compared with prior art, it is an advantage of the current invention that:
(1) the feces of livestock and poultry deodorizer of the present invention processes feces of livestock and poultry, and worm's ovum, pathogen contamination reduce, and the most effectively reduce poultry The generation amount of smelly metallic substance during excrement composting, granularity is the least, be directly sprayed onto livestock excrement composting raw material when using In just can reach the effect of all standing.
(2) flyash in the feces of livestock and poultry micro-nano deodorizer of the present invention is the highest in China's yield, and harm is big, therefore up to Effect to changing waste into resources.
(3) the feces of livestock and poultry micro-nano deodorizer of the present invention is notable to deodorizing effect during livestock excrement composting.Through test Measuring, stink just can eliminate about compost one week after, and compared with the Traditional compost deodorization time, the stink elimination time does sth. in advance 15 days Above.
(4) preparation method is simple, with low cost, easy to use.
Accompanying drawing explanation
Fig. 1 is the structural representation of sprinkler;
Fig. 2 is the structural representation of composite particles.
In Fig. 1: 1-drain hole;2-aerator;3-air inlet;4-breather line;5-sprays mouth.
Detailed description of the invention
The technical solution of the present invention is further illustrated below in conjunction with specific embodiment, but scope not office It is limited to described content.
Embodiment 1
Described in the present embodiment, feces of livestock and poultry deodorizer is prepared by mass percentage by following raw material: flyash 65%, silica flour 20%, calcium oxide 5%, Nanoscale Iron 5%, Inoculant 5%;State flyash, calper calcium peroxide, calcium oxide, the granularity of Inoculant be 1000~ 1200 mesh, the granularity of Nanoscale Iron is 70~80nm, and the granularity of silica flour is 200~250 mesh.
Carrying out aerobic compost using cow manure as composting material, cattle manure water content is about 86%, the initial moisture of composting material Content is between 55%~65%, and compost environment temperature is about 25 DEG C, and the addition of deodorizer is with the raw-material percent mass of compost Than meter, concrete operations are as follows:
(1) before compost starts, deodorizer is mixed with composting material in 1% ratio of feces of livestock and poultry, stirs,.
(2) after raw material and deodorizer mix homogeneously, carrying out During High-Temperature Composting, temperature raising period forced ventilation, rate of venting is 1.0m3/ min, detects composting process heap body core temperature.
(3) stopping ventilating when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every Every turning in 3 days once, fermentation completes During High-Temperature Composting in 35 days.
(4) with metering in every 5 days, H in detecting 5 days2S volatile quantity.
(5) 1 is processed: the present embodiment deodorizer processes
Process 2: process (comparison) without adding deodorizer
Table 1 is that the present embodiment deodorizer is to cow dung compost H2The impact of S volatile quantity
As shown in Table 1, add deodorizer and can significantly reduce H during cow dung compost2The volatile quantity of S.Add deodorizer to process First 10 days H of compost2S volatile quantity be substantially less than comparison, compost after 11 days this process be nearly no detectable H2The volatilization of S;At matched group Reason is at 21 days H of compost2The volatile quantity of S is the highest.
Embodiment 2
Described in the present embodiment, feces of livestock and poultry deodorizer is prepared by mass percentage by following raw material: flyash 60%, silica flour 22%, calcium oxide 8%, calper calcium peroxide 7%, Inoculant 3%;State flyash, calper calcium peroxide, calcium oxide, the granularity of Inoculant are 1300 ~1500 mesh, the granularity of Nanoscale Iron is 80~90nm, and the granularity of silica flour is 300~350 mesh.
Carrying out aerobic compost using swine excrement as composting material, pig manure water content is about 80%, and the initial moisture of composting material contains Amount is between 55%~65%, and compost environment temperature is about 25 DEG C, and the addition of deodorizer is with the raw-material mass percent of compost Meter, concrete operations are as follows:
(1) before compost starts, deodorizer is mixed with composting material in 3% ratio of feces of livestock and poultry, stirs,.
(2) after raw material and deodorizer mix homogeneously, carrying out During High-Temperature Composting, temperature raising period forced ventilation, rate of venting is 1.0m3/ min, detects composting process heap body core temperature.
(3) stopping ventilating when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every Every turning in 4 days once, fermentation completes During High-Temperature Composting in 25 days.
(4) 1 is processed: the present embodiment deodorizer processes
Process 2: process (comparison) without adding deodorizer
(5) Testing index: stink index uses six grades of classification method: Ms0: odorless, Ms1: feel stink reluctantly, Ms2: faint Stink, Ms3: significantly stink, Ms4: the strongest stink, Ms5: insufferable stink.
Table 2 is the deodorizer impact on pig manure stink
As can be seen from Table 2, add deodorizer process compost whole during smelly degree maximum less than comparison, add deodorization Agent processes odorless after compost 15 days and produces, and to impinging upon 15 days stink maximums of compost, within when compost completes the 25th day, throws away audible To stink.Illustrate that deodorizer is obvious to pig manure deodorizing effect.
Embodiment 3
Described in the present embodiment, feces of livestock and poultry deodorizer is prepared by mass percentage by following raw material: flyash 70%, silica flour 11%, calcium oxide 15%, Inoculant 4%;State flyash, calper calcium peroxide, calcium oxide, the granularity of Inoculant are 1800~2000 mesh, receive The granularity of meter Tie is 90~100nm, and the granularity of silica flour is 450~500 mesh.
Carrying out aerobic compost with feces of chicken as composting material, chicken manure water content is about 70%, and the initial moisture of composting material contains Amount is between 55%~65%, and compost environment temperature is about 20 DEG C, and the addition of deodorizer is with the raw-material mass percent of compost Meter, concrete operations are as follows:
(1) before compost starts, deodorizer is mixed with composting material in 2% ratio of feces of livestock and poultry, stirs,.
(2) after raw material and deodorizer mix homogeneously, carrying out During High-Temperature Composting, temperature raising period forced ventilation, rate of venting is 1.0m3/min, detects composting process heap body core temperature.
(3) stopping ventilating when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every Every turning in 4 days once, fermentation completes During High-Temperature Composting in 25 days.
(4) with metering in every 5 days, Ammonia valatilization amount in detecting 5 days.
(5) 1 is processed: the present embodiment deodorizer processes
Process 2: process (comparison) without adding deodorizer
Table 3 is the deodorizer impact on chicken excrement composting Ammonia valatilization amount
As shown in Table 3, add deodorizer and can significantly reduce the volatile quantity of ammonia in Chicken Manure Compost.Control treatment is in composting process Volatilization total amount be 123.78mg, add deodorizer process in composting process the volatilization total amount of ammonia be 40.2mg, at comparison The volatilization total amount of reason ammonia is 3.08 times that interpolation deodorizer goes out.
Embodiment 4
Described in the present embodiment, feces of livestock and poultry deodorizer is prepared by mass percentage by following raw material: flyash 50%, silica flour 25%, calcium oxide 17%, Inoculant 8%;State flyash, calper calcium peroxide, calcium oxide, the granularity of Inoculant are 2300~2500 mesh, receive The granularity of meter Tie is 80~90nm, and the granularity of silica flour is 300~400 mesh.
Carrying out aerobic compost with feces of chicken as composting material, chicken manure water content is about 70%, and the initial moisture of composting material contains Amount is between 55%~65%, and compost environment temperature is about 20 DEG C, and the addition of deodorizer is with the raw-material mass percent of compost Meter, concrete operations are as follows:
(1) before compost starts, deodorizer is mixed with composting material in 5% ratio of feces of livestock and poultry, stirs,.
(2) after raw material and deodorizer mix homogeneously, carrying out During High-Temperature Composting, temperature raising period forced ventilation, rate of venting is 1.0m3/min, detects composting process heap body core temperature.
(3) stopping ventilating when central temperature reaches 60 DEG C, ferment, fermentation temperature maintains 60~70 DEG C, every Every turning in 4 days once, fermentation completes During High-Temperature Composting in 25 days.
(4) with metering in every 5 days, Ammonia valatilization amount in detecting 5 days.
(5) 1 is processed: the present embodiment deodorizer processes
Process 2: process (comparison) without adding deodorizer
Table 4 is the deodorizer impact on chicken excrement composting Ammonia valatilization amount
As shown in Table 4, add deodorizer processing the volatilization total amount of ammonia in composting process is ammonia in 31.5mg, with embodiment 3 Gas volatilization total amount is that 40.2mg compares and decreases 8.7mg, illustrate that the amount of interpolation deodorizer is the most, and the generation amount of ammonia is the fewest.

Claims (4)

1. a feces of livestock and poultry deodorizer, it is characterised in that: prepared by mass percentage by following raw material: flyash 50% ~70%, silica flour 17%~25%, additive 10%~17%, Inoculant 3%~9%, described additive be calper calcium peroxide, calcium oxide and One or more materials of Nanoscale Iron.
Feces of livestock and poultry deodorizer the most according to claim 1, it is characterised in that: flyash, calper calcium peroxide, calcium oxide, inoculation The granularity of agent is 1000~2500 mesh, and the granularity of Nanoscale Iron is 70~100nm, and the granularity of silica flour is 200~500 mesh.
Feces of livestock and poultry deodorizer the most according to claim 1, it is characterised in that: described Inoculant is livestock excrement composting process The material in middle ferment in second time stage.
Feces of livestock and poultry deodorizer the most according to claim 1, it is characterised in that: feces of livestock and poultry deodorizer is applied in animal dung Just in compost, account for the ratio of stool quality 0.5%~5% according to deodorizer, utilize spray appliance gradually or disposable by deodorization Agent is sprayed and is added in feces of livestock and poultry, is uniformly mixed.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106665373A (en) * 2016-12-28 2017-05-17 苏州倍儿壮养殖装备科技有限公司 Livestock and poultry breeding shed ventilating device
CN109650974A (en) * 2019-01-14 2019-04-19 湖南大学 Nitrogen loss and the method for improving composting production fertilizer efficiency in composting process are reduced using ferriferous oxide nano material
CN110563519A (en) * 2019-08-27 2019-12-13 昆明理工大学 Method for preparing composite inoculant through electromagnetic enhancement and application
CN114409458A (en) * 2021-12-24 2022-04-29 华夏瑞天(北京)生物科技有限公司 Livestock and poultry manure treatment material, livestock and poultry manure treatment method and organic fertilizer
CN115141043A (en) * 2022-06-29 2022-10-04 牛勇 Green organic fertilizer and preparation process thereof

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CN104649750A (en) * 2013-11-18 2015-05-27 青岛水世界环保科技有限公司 Deodorant for high-temperature composting process
CN105272476A (en) * 2015-11-16 2016-01-27 刘伟 Livestock and poultry excrement composting deodorant

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106665373A (en) * 2016-12-28 2017-05-17 苏州倍儿壮养殖装备科技有限公司 Livestock and poultry breeding shed ventilating device
CN109650974A (en) * 2019-01-14 2019-04-19 湖南大学 Nitrogen loss and the method for improving composting production fertilizer efficiency in composting process are reduced using ferriferous oxide nano material
CN109650974B (en) * 2019-01-14 2021-07-09 湖南大学 Method for reducing nitrogen loss in composting process and improving fertilizer efficiency of compost product by using iron oxide nano material
CN110563519A (en) * 2019-08-27 2019-12-13 昆明理工大学 Method for preparing composite inoculant through electromagnetic enhancement and application
CN114409458A (en) * 2021-12-24 2022-04-29 华夏瑞天(北京)生物科技有限公司 Livestock and poultry manure treatment material, livestock and poultry manure treatment method and organic fertilizer
CN115141043A (en) * 2022-06-29 2022-10-04 牛勇 Green organic fertilizer and preparation process thereof

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