CN106146794A - A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof - Google Patents
A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof Download PDFInfo
- Publication number
- CN106146794A CN106146794A CN201610531424.XA CN201610531424A CN106146794A CN 106146794 A CN106146794 A CN 106146794A CN 201610531424 A CN201610531424 A CN 201610531424A CN 106146794 A CN106146794 A CN 106146794A
- Authority
- CN
- China
- Prior art keywords
- parts
- automobile
- environmental protection
- polyester
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6648—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6655—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a kind of commercial affairs automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof.It is made up of following quality proportioning component, isocyanates: premixed systems=1:1.65, the composition of described premixed systems is based on following mass fraction, and concrete mass fraction is as follows: polyester 10,100 16 20 parts, polyester 3,360 55 58 parts, strengthen glass 45 55 parts, silicone oil AK8860 3.0 3.5 parts, triethanolamine 8 10 parts, catalyst HP 54 1.2 1.7 parts, catalyst HP 80 1.6 1.9 parts, 3.0 3.8 parts of water, fire retardant TCEP 40 45 parts.After using above-mentioned material and method, the expanded material fire resistance making preparation is high, meet fire nonflammable, thus ensured fire savety and the personal safety of whole vehicle, it addition, use the automobile-used ceiling that this material is made, weight is the lightest, can adapt to the weight demands of vehicle, be environmental protection raw material due to the use raw material of expanded material and collocation is reasonable, because of without discharging material poisonous and hazardous to human body.
Description
Technical field
The present invention relates to a kind of composite and preparation method thereof, specifically a kind of commercial affairs automobile-used ceiling environmental protection high resistant
Combustion expanded material and preparation method thereof.
Background technology
Along with the development of auto industry, automobile-used ceiling is as the important parts of automobile, and its fire savety is being to closing weight
, existing automobile-used ceiling is in addition to fire savety, in addition it is also necessary to have light-weighted demand, to adapt to vehicle entirety weight
The requirement of amount, in order to reach this purpose, people attempt the various material material as automobile-used ceiling, but are pursuing light weight
Also make safety reduce while change, usually there will be easy initiation fire situation when running into fault or accident and occur, the most such as
What had the most not only met light-weighted demand but also had had fire resistance thus ensure that safety is an insoluble technical problem, separately
Outward, not environmentally, effect on environment and harm are the biggest for existing automobile-used ceiling material.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of fire resistance is high, lightweight and the automobile-used ceiling environmental protection of environmental protection
High flame-retardant foamed material and preparation method thereof.
In order to solve above-mentioned technical problem, the automobile-used ceiling environmental protection high flame-retardant foamed material of the present invention, following quality join
Ratio component constitute, isocyanates: premixed systems=1:1.65, the composition of described premixed systems based on following mass fraction, concrete mass parts
Number is as follows:
Polyester 10100 16-20 part
Polyester 3360 55-58 part
Strengthen glass 45-55 part
Silicone oil AK8860 3.0-3.5 part
Triethanolamine 8-10 part
Catalyst HP-54 1.2-1.7 part
Catalyst HP-80 1.6-1.9 part
Water 3.0-3.8 part
Fire retardant TCEP 40-45 part.
Described isocyanates is Mitsui MR200.
The preparation method of a kind of above-mentioned automobile-used ceiling environmental protection high flame-retardant foamed material, including following preparation process: first make
Standby premixed systems: by polyester 10100, polyester 3360, strengthen glass, silicone oil AK8860, triethanolamine, catalyst HP-54, catalysis
Agent HP-80, fire retardant TCEP and water addition reactor carry out hybrid reaction, mixing speed 80-120r/min, mixing time
6-8h premixed systems, the most again isocyanates is mixed homogeneously by the quality ratio of 1:1.65 with premixed systems, can be prepared by institute
State expanded material.
After using above-mentioned material and method, due to recipe ingredient collocation, rationally and preparation method is proper so that preparation
Expanded material fire resistance is high, meets fiery nonflammable, thus has ensured fire savety and the personal safety of whole vehicle, separately
Outward, using the automobile-used ceiling that this material is made, weight is the lightest, it is possible to adapt to the weight demands of vehicle, due to expanded material
Use raw material to be environmental protection raw material and collocation is reasonable, because of without discharging material poisonous and hazardous to human body.
Detailed description of the invention
Below in conjunction with detailed description of the invention, to automobile-used ceiling environmental protection high flame-retardant foamed material of the present invention and preparation method thereof
It is described in further detail.
Embodiment one:
A kind of automobile-used ceiling environmental protection high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: premixed systems=1:
1.65, described isocyanates is Mitsui MR200, the composition of a combination thereof material based on following mass fraction, concrete mass parts
Number is as follows:
Polyester 10100 16-20 part
Polyester 3360 55-58 part
Strengthen glass 45-55 part
Silicone oil AK8860 3.0-3.5 part
Triethanolamine 8-10 part
Catalyst HP-54 1.2-1.7 part
Catalyst HP-80 1.6-1.9 part
Water 3.0-3.8 part
Fire retardant TCEP 40-45 part.
Embodiment two:
The preparation method of a kind of above-mentioned automobile-used ceiling environmental protection high flame-retardant foamed material, including following preparation process: first prepare group
Close material: by 3360,45 parts of reinforcing glass fibers of polyester of the polyester 10100,55 parts of 16 parts, the silicone oil AK8860 of 3.0 parts, 8
Triethanolamine, the catalyst HP-54 of 1.2 parts, the catalyst HP-80 of 1.6 parts, the fire retardant TCEP of 40 parts and 3.0 parts of part
Water adds in reactor and carries out hybrid reaction, mixing speed 80r/min, mixing time 6h premixed systems, the most again by different
Cyanate is mixed homogeneously by the quality ratio of 1:1.65 with premixed systems, can be prepared by described expanded material.
Embodiment three:
The preparation method of a kind of above-mentioned automobile-used ceiling environmental protection high flame-retardant foamed material, including following preparation process: first prepare group
Close material: by 3360,50 parts of reinforcing glass fibers of polyester of the polyester 10100,57 parts of 18 parts, the silicone oil AK8860 of 3.2 parts, 9
Triethanolamine, the catalyst HP-54 of 1.5 parts, the catalyst HP-80 of 1.8 parts, the fire retardant TCEP of 42 parts and 3.4 parts of part
Water adds in reactor and carries out hybrid reaction, mixing speed 100r/min, mixing time 7h premixed systems, the most again by different
Cyanate is mixed homogeneously by the quality ratio of 1:1.65 with premixed systems, can be prepared by described expanded material.
Embodiment four:
The preparation method of a kind of above-mentioned automobile-used ceiling environmental protection high flame-retardant foamed material, including following preparation process: first prepare group
Close material: by 3360,55 parts of reinforcing glass fibers of polyester of the polyester 10100,58 parts of 20 parts, the silicone oil AK8860 of 3.5 parts, 10
Triethanolamine, the catalyst HP-54 of 1.7 parts, the catalyst HP-80 of 1.9 parts, the fire retardant TCEP of 45 parts and 3.8 parts of part
Water adds in reactor and carries out hybrid reaction, mixing speed 120r/min, mixing time 8h premixed systems, the most again by different
Cyanate is mixed homogeneously by the quality ratio of 1:1.65 with premixed systems, can be prepared by described expanded material.
It is below the fire resistance test result of automobile-used ceiling environmental protection high flame-retardant foamed material of the present invention:
Touchstone requires: the burning velocity of fire proofing should be not more than 100mm/min, if there is following situations, respectively by wanting
Seeking mark result of the test, assay is divided into A, B, C, D, E5 grade:
A:(0mm/min): sample is exposed to 15S in flame, extinguish burning things which may cause a fire disaster sample still unburned, or sample can burn, but flame
Extinguish before reaching the first measurement graticule, can count without burning extent.
B: when tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then it is assumed that meet
Standard-required.
C: burning velocity measured value (mm/min)
When tester, flame is measured at two and is extinguished between graticule, and when being unsatisfactory for the 2nd article of situation, then presses standard meter
Calculate burning velocity.
D: burning velocity measured value (mm/min)
When tester, flame combustion arrives the second graticule, or from the beginning of timing, the long-time smoulder of sample, then may be used
With termination test during 20min when tester, and record burning time and burning extent and by criterion calculation burning velocity.
E: sample has burnt in flame ignition 15s and has arrived the first graticule, then it is assumed that sample can not meet burning speed
The requirement of degree.
Assay: A-B(0mm/min), use automobile-used ceiling environmental protection high flame-retardant foamed material symbol prepared by the present embodiment
Close fire resistance requirement.
Claims (4)
1. an automobile-used ceiling environmental protection high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: premixed systems=
1:1.65, the composition of described premixed systems is based on following mass fraction, and concrete mass fraction is as follows:
Polyester 10100 16-20 part
Polyester 3360 55-58 part
Glass fibre 45-55 part
Silicone oil AK8860 3.0-3.5 part
Triethanolamine 8-10 part
Catalyst HP-54 1.2-1.7 part
Catalyst HP-80 1.6-1.9 part
Water 3.0-3.8 part
Fire retardant TCEP 40-45 part.
2. according to the automobile-used ceiling environmental protection high flame-retardant foamed material described in claim 1, it is characterised in that: described isocyanates is
Mitsui MR200.
3. according to the automobile-used ceiling environmental protection high flame-retardant foamed material described in claim 1, it is characterised in that: described glass fibre is
Reinforcing glass fiber.
4. the preparation method of an automobile-used ceiling environmental protection high flame-retardant foamed material as claimed in claim 1, it is characterised in that include
Following preparation process: first prepare premixed systems: by polyester 10100, polyester 3360, strengthen glass, silicone oil AK8860, three ethanol
Amine, catalyst HP-54, catalyst HP-80, fire retardant TCEP and water addition reactor carry out hybrid reaction, mixing speed
80-120r/min, mixing time 6-8h premixed systems, isocyanates and premixed systems are pressed the mass ratio of 1:1.65 the most again
Mix homogeneously, can be prepared by described expanded material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610531424.XA CN106146794A (en) | 2016-07-07 | 2016-07-07 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610531424.XA CN106146794A (en) | 2016-07-07 | 2016-07-07 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106146794A true CN106146794A (en) | 2016-11-23 |
Family
ID=58062170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610531424.XA Pending CN106146794A (en) | 2016-07-07 | 2016-07-07 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106146794A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107266643A (en) * | 2017-07-04 | 2017-10-20 | 扬中市天正合成材料研究中心 | A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method |
| CN107312144A (en) * | 2017-06-30 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of high-order bumper environmental protection flame retardant polyurethane foam material and preparation method |
| CN108976374A (en) * | 2018-06-28 | 2018-12-11 | 扬中市天正合成材料研究中心 | Environmental protection flame retardant polyurethane foam material and preparation method thereof for Cowes spy's instrument desk |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356331A (en) * | 2014-11-13 | 2015-02-18 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant composite material for doors/windows of furniture |
| CN104403071A (en) * | 2014-11-13 | 2015-03-11 | 扬中市天正合成材料研究中心 | Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead |
| CN104530351A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant automotive interior soft roof composite material and preparation method thereof |
| CN105237704A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for high-speed train bar counters, and preparation method thereof |
| CN105237717A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation cruises bulkhead acid and alkali resistance storage PU foam material and preparation method thereof |
-
2016
- 2016-07-07 CN CN201610531424.XA patent/CN106146794A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530351A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant automotive interior soft roof composite material and preparation method thereof |
| CN104356331A (en) * | 2014-11-13 | 2015-02-18 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant composite material for doors/windows of furniture |
| CN104403071A (en) * | 2014-11-13 | 2015-03-11 | 扬中市天正合成材料研究中心 | Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead |
| CN105237704A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for high-speed train bar counters, and preparation method thereof |
| CN105237717A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation cruises bulkhead acid and alkali resistance storage PU foam material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312144A (en) * | 2017-06-30 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of high-order bumper environmental protection flame retardant polyurethane foam material and preparation method |
| CN107266643A (en) * | 2017-07-04 | 2017-10-20 | 扬中市天正合成材料研究中心 | A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method |
| CN108976374A (en) * | 2018-06-28 | 2018-12-11 | 扬中市天正合成材料研究中心 | Environmental protection flame retardant polyurethane foam material and preparation method thereof for Cowes spy's instrument desk |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106146795A (en) | A kind of automobile-used face shield environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106188460A (en) | A kind of sanitary ware environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106008873A (en) | Environment-friendly high-flame-retardant foaming material for tap water pipe and preparation method of environment-friendly high-flame-retardant foaming material | |
| CN106046296A (en) | Environmentally friendly high-flame-retardant foaming material of garbage bin and preparation method of environmentally friendly high-flame-retardant foaming material | |
| CN106117495A (en) | A kind of concrete boat Inner wall of ship body polyurethane environmental protection high flame-retardant foamed material and preparation method | |
| CN106046298A (en) | Packing bucket environment-friendly high-flame-retardancy foam material and preparation method thereof | |
| CN106008878A (en) | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material | |
| CN106008888A (en) | Environment-friendly high-flame-retardance polyurethane foam material for square stools and tables and chairs and preparation method of material | |
| CN106084168A (en) | A kind of petroleum pipeline environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106188459A (en) | A kind of auto lamp bowl polyester foamed material of environmental protection high fire-retardance and preparation method thereof | |
| CN106146793A (en) | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106084169A (en) | A kind of greening bark moulding environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN107474213A (en) | Thick stick environmental protection flame retardant polyurethane foam material and preparation method under a kind of bumper | |
| CN106046289A (en) | Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material | |
| CN106008885A (en) | Environment-friendly high-flame-resistance polyurethane foaming material for fender and preparing method thereof | |
| CN107325247A (en) | A kind of secondary battery jar assembly polyurethane rings environment friendly flame-retardant expanded material and preparation method | |
| CN106146794A (en) | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106008887A (en) | High-toughness elastomer environment-friendly high-flame-retardancy foaming material and preparation method thereof | |
| CN105237715A (en) | Environmental-protection and high-flame retardation yacht shell composite material and preparation method thereof | |
| CN106146782A (en) | A kind of pedal environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN107266649A (en) | Air inlet pipe assembly environmental protection flame retardant expanded material and preparation method | |
| CN106008874A (en) | Environment-friendly and highly-flame-retardant foam material for goods shelf and preparation method of foam material | |
| CN107298744A (en) | A kind of low-position bumper guard environmental protection flame retardant expanded material and preparation method | |
| CN106008884A (en) | Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material | |
| CN106046306A (en) | Environmentally friendly high-flame-retardant polyurethane foaming material for tank body of oil tank truck and preparation method of environmentally friendly high-flame-retardant polyurethane foaming material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161123 |
|
| RJ01 | Rejection of invention patent application after publication |