CN106008878A - Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material - Google Patents
Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material Download PDFInfo
- Publication number
- CN106008878A CN106008878A CN201610528800.XA CN201610528800A CN106008878A CN 106008878 A CN106008878 A CN 106008878A CN 201610528800 A CN201610528800 A CN 201610528800A CN 106008878 A CN106008878 A CN 106008878A
- Authority
- CN
- China
- Prior art keywords
- polyester
- parts
- flame
- environment
- foaming material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses an environment-friendly high-flame-retardance foaming material for an agricultural pesticide bucket and a preparing method of the environment-friendly high-flame-retardance foaming material. The environment-friendly high-flame-retardance foaming material is prepared from isocyanate and a component material in the mass ratio of 1:0.7. The component material is prepared from, by mass, 35-45 parts of polyester 330, 25-35 parts of polyester 3360, 15-18 parts of polyester 400, 9-12 parts of polyester 400, 2.5-3.5 parts of silicon oil, 1.2-1.8 parts of a catalyst HPF1, 1.0-1.5 parts of a catalyst S20, 3-3.8 parts of water and 33-39 parts of a fire retardant TCPP. By the adoption of the material and the method, the prepared foaming material is high in flame retardant property and not prone to combustion when meeting fire, and thus the fireproof safety and personnel safety are ensured; besides, the prepared agricultural pesticide bucket is very light and capable of meeting the requirement for carrying and moving; due to the fact that environment-friendly raw materials serve as raw materials used for the foaming material, no toxic and harmful substance to the human body is released, and thus the requirement for environment friendliness is met.
Description
Technical field
The present invention relates to a kind of composite and preparation method thereof, a kind of agricultural explosive barrel environmental protection high flame-retardant foamed material and preparation method thereof.
Background technology
It is required for after agricultural planting spraying insecticide, and spray insecticide and be typically necessary the agricultural explosive barrel of use, existing agricultural explosive barrel is as parts important during spraying insecticide, its fire savety with it is critical that, existing agricultural explosive barrel is in addition to fire savety, also need to that there is light-weighted demand, to adapt to carry the requirement of movement, in order to reach this purpose, people attempt the various material material as agricultural explosive barrel, but also make safety reduce pursuing light-weighted while, usually there will be easy initiation fire situation when running into fault or accident to occur, the most not only met light-weighted demand but also there is fire resistance thus ensured that safety is an insoluble technical problem, additionally, existing agricultural explosive barrel material is not environmentally, effect on environment and harm are the biggest.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of fire resistance is high, lightweight and the agricultural explosive barrel environmental protection high flame-retardant foamed material of environmental protection and preparation method thereof.
In order to solve above-mentioned technical problem, the agricultural explosive barrel environmental protection high flame-retardant foamed material of the present invention, it is made up of following quality proportioning component, isocyanates: premixed systems=1:0.7, the composition of described premixed systems is based on following mass fraction, and concrete mass fraction is as follows:
Polyester 330 35-45 part
Polyester 3360 25-35 part
Polyester 400 15-18 part
Polyester 400 9-12 part
Silicone oil 158 2.5-3.5 part
Catalyst HPF1 1.2-1.8 part
Catalyst S20 1.0-1.5 part
Water 3-3.8 part
Fire retardant TCPP 33-39 part.
Described isocyanates is Yantai ten thousand China M200.
A kind of preparation method of above-mentioned agricultural explosive barrel environmental protection high flame-retardant foamed material, including following preparation process: first prepare premixed systems: polyester 330, polyester 3360, polyester 400, polyester 400, silicone oil 158, catalyst HPF1, catalyst S20, fire retardant TCPP and water are added in reactor and carry out hybrid reaction, mixing speed 80-120r/min, mixing time 6-8h premixed systems, the most again isocyanates is mixed homogeneously by the quality ratio of 1:0.7 with premixed systems, can be prepared by described expanded material.
After using above-mentioned material and method, due to recipe ingredient collocation, rationally and preparation method is proper so that the expanded material fire resistance of preparation is high, meets fire nonflammable, thus ensured fire savety and personal safety, it addition, the agricultural explosive barrel made, weight is the lightest, can adapt to carry the requirement of movement, owing to the use raw material of expanded material is environmental protection raw material, because without discharging material poisonous and hazardous to human body, having reached the requirement of environmental protection.
Detailed description of the invention
Below in conjunction with detailed description of the invention, agricultural explosive barrel environmental protection high flame-retardant foamed material of the present invention and preparation method thereof is described in further detail.
Embodiment one:
A kind of agricultural explosive barrel environmental protection high flame-retardant foamed material, being made up of following quality proportioning component, isocyanates: premixed systems=1:0.7, described described isocyanates is Yantai ten thousand China M200, the composition of a combination thereof material is based on following mass fraction, and concrete mass fraction is as follows:
Polyester 330 35-45 part
Polyester 3360 25-35 part
Polyester 400 15-18 part
Polyester 400 9-12 part
Silicone oil 158 2.5-3.5 part
Catalyst HPF1 1.2-1.8 part
Catalyst S20 1.0-1.5 part
Water 3-3.8 part
Fire retardant TCPP 33-39 part.
Wherein, the polyester 400 of 15-18 part is produced by south, PORT OF ZHANGJIAGANG company, and the polyester 400 of 9-12 part is produced by Wuxi Zhan Tuo Science and Technology Ltd..
Embodiment two:
A kind of preparation method of above-mentioned agricultural explosive barrel environmental protection high flame-retardant foamed material, including following preparation process: first prepare premixed systems: by the polyester 330 of 35 parts, the polyester 3360 of 25 parts, the polyester 400 of 15 parts, the polyester 400 of 9 parts, the silicone oil 158 of 2.5 parts, the catalyst HPF1 of 1.2 parts, the catalyst S20 of 1.0 parts, the water of the fire retardant TCPP of 33 parts and 3 parts adds in reactor and carries out hybrid reaction, mixing speed 80r/min, mixing time 6h premixed systems, the most again isocyanates and premixed systems are compared by the quality of 1:0.7 and mix homogeneously, can be prepared by described expanded material.
Embodiment three:
A kind of preparation method of above-mentioned agricultural explosive barrel environmental protection high flame-retardant foamed material, including following preparation process: first prepare premixed systems: by the polyester 330 of 40 parts, the polyester 3360 of 30 parts, the polyester 400 of 16 parts, the polyester 400 of 11 parts, the silicone oil 158 of 3 parts, the catalyst HPF1 of 1.6 parts, the catalyst S20 of 1.2 parts, the water of the fire retardant TCPP of 35 parts and 3.4 parts adds in reactor and carries out hybrid reaction, mixing speed 100r/min, mixing time 7h premixed systems, the most again isocyanates and premixed systems are compared by the quality of 1:0.7 and mix homogeneously, can be prepared by described expanded material.
Embodiment four:
A kind of preparation method of above-mentioned agricultural explosive barrel environmental protection high flame-retardant foamed material, including following preparation process: first prepare premixed systems: by the polyester 330 of 45 parts, the polyester 3360 of 35 parts, the polyester 400 of 18 parts, the polyester 400 of 12 parts, the silicone oil 158 of 3.5 parts, the catalyst HPF1 of 1.8 parts, the catalyst S20 of 1.5 parts, the water of the fire retardant TCPP of 39 parts and 3.8 parts adds in reactor and carries out hybrid reaction, mixing speed 120r/min, mixing time 8h premixed systems, the most again isocyanates and premixed systems are compared by the quality of 1:0.7 and mix homogeneously, can be prepared by described expanded material.
It is below the fire resistance test result of the present invention agricultural explosive barrel environmental protection high flame-retardant foamed material:
Touchstone requires: the burning velocity of fire proofing should be not more than 100mm/min, if there is following situations, identifies result of the test the most on request, and assay is divided into A, B, C, D, E5 grade:
A:(0mm/min): sample is exposed to 15S in flame, extinguish burning things which may cause a fire disaster sample still unburned, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: when tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then it is assumed that meet standard-required.
C: burning velocity measured value (mm/min)
When tester, flame is measured at two and is extinguished between graticule, and when being unsatisfactory for the 2nd article of situation, then by criterion calculation burning velocity.
D: burning velocity measured value (mm/min)
When tester, flame combustion arrives the second graticule, or from the beginning of timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record burning time and burning extent and by criterion calculation burning velocity.
E: sample has burnt in flame ignition 15s and has arrived the first graticule, then it is assumed that sample can not meet the requirement of burning velocity.
Assay: A-B(0mm/min), the agricultural explosive barrel environmental protection high flame-retardant foamed material using the present embodiment to prepare meets fire resistance requirement.
Claims (3)
1. an agricultural explosive barrel environmental protection high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: premixed systems=1:0.7, and the composition of described premixed systems is based on following mass fraction, and concrete mass fraction is as follows:
Polyester 330 35-45 part
Polyester 3360 25-35 part
Polyester 400 15-18 part
Polyester 400 9-12 part
Silicone oil 158 2.5-3.5 part
Catalyst HPF1 1.2-1.8 part
Catalyst S20 1.0-1.5 part
Water 3-3.8 part
Fire retardant TCPP 33-39 part.
2. according to the agricultural explosive barrel environmental protection high flame-retardant foamed material described in claim 1, it is characterised in that: described isocyanates is Yantai ten thousand China M200.
3. the preparation method of an agricultural explosive barrel environmental protection high flame-retardant foamed material as claimed in claim 1, it is characterized in that, including following preparation process: first prepare premixed systems: polyester 330, polyester 3360, polyester 400, polyester 400, silicone oil 158, catalyst HPF1, catalyst S20, fire retardant TCPP and water are added in reactor and carry out hybrid reaction, mixing speed 80-120r/min, mixing time 6-8h premixed systems, the most again isocyanates is mixed homogeneously by the quality ratio of 1:0.7 with premixed systems, can be prepared by described expanded material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610528800.XA CN106008878A (en) | 2016-07-07 | 2016-07-07 | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610528800.XA CN106008878A (en) | 2016-07-07 | 2016-07-07 | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106008878A true CN106008878A (en) | 2016-10-12 |
Family
ID=57107382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610528800.XA Pending CN106008878A (en) | 2016-07-07 | 2016-07-07 | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106008878A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298744A (en) * | 2017-06-30 | 2017-10-27 | 扬中市天正合成材料研究中心 | A kind of low-position bumper guard environmental protection flame retardant expanded material and preparation method |
| CN107312145A (en) * | 2017-06-30 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of combined bumper environmental protection flame retardant polyurethane foam material and preparation method |
| CN107312143A (en) * | 2017-06-29 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of bumper environmental protection flame retardant expanded material and preparation method |
| CN107312144A (en) * | 2017-06-30 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of high-order bumper environmental protection flame retardant polyurethane foam material and preparation method |
| CN107325249A (en) * | 2017-06-30 | 2017-11-07 | 扬中市天正合成材料研究中心 | A kind of spacecraft luggage boxboard environment-friendly polyurethane expanded material and preparation method thereof |
| CN108117629A (en) * | 2017-06-30 | 2018-06-05 | 扬中市天正合成材料研究中心 | Polyester foamed material for automobile inner cover plate and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530375A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant automotive engine hood composite material and preparation method thereof |
| CN104530345A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant vehicle door inner handle composite material and preparation method thereof |
| CN104530950A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof |
-
2016
- 2016-07-07 CN CN201610528800.XA patent/CN106008878A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530375A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant automotive engine hood composite material and preparation method thereof |
| CN104530345A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant vehicle door inner handle composite material and preparation method thereof |
| CN104530950A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312143A (en) * | 2017-06-29 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of bumper environmental protection flame retardant expanded material and preparation method |
| CN107298744A (en) * | 2017-06-30 | 2017-10-27 | 扬中市天正合成材料研究中心 | A kind of low-position bumper guard environmental protection flame retardant expanded material and preparation method |
| CN107312145A (en) * | 2017-06-30 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of combined bumper environmental protection flame retardant polyurethane foam material and preparation method |
| CN107312144A (en) * | 2017-06-30 | 2017-11-03 | 扬中市天正合成材料研究中心 | A kind of high-order bumper environmental protection flame retardant polyurethane foam material and preparation method |
| CN107325249A (en) * | 2017-06-30 | 2017-11-07 | 扬中市天正合成材料研究中心 | A kind of spacecraft luggage boxboard environment-friendly polyurethane expanded material and preparation method thereof |
| CN108117629A (en) * | 2017-06-30 | 2018-06-05 | 扬中市天正合成材料研究中心 | Polyester foamed material for automobile inner cover plate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106008878A (en) | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material | |
| CN106008873A (en) | Environment-friendly high-flame-retardant foaming material for tap water pipe and preparation method of environment-friendly high-flame-retardant foaming material | |
| CN106188460A (en) | A kind of sanitary ware environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106046298A (en) | Packing bucket environment-friendly high-flame-retardancy foam material and preparation method thereof | |
| CN106146795A (en) | A kind of automobile-used face shield environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106046296A (en) | Environmentally friendly high-flame-retardant foaming material of garbage bin and preparation method of environmentally friendly high-flame-retardant foaming material | |
| CN106008888A (en) | Environment-friendly high-flame-retardance polyurethane foam material for square stools and tables and chairs and preparation method of material | |
| CN106084169A (en) | A kind of greening bark moulding environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106117495A (en) | A kind of concrete boat Inner wall of ship body polyurethane environmental protection high flame-retardant foamed material and preparation method | |
| CN106146793A (en) | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106084168A (en) | A kind of petroleum pipeline environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106188459A (en) | A kind of auto lamp bowl polyester foamed material of environmental protection high fire-retardance and preparation method thereof | |
| CN106008885A (en) | Environment-friendly high-flame-resistance polyurethane foaming material for fender and preparing method thereof | |
| CN106046289A (en) | Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material | |
| CN106008887A (en) | High-toughness elastomer environment-friendly high-flame-retardancy foaming material and preparation method thereof | |
| CN106046300A (en) | Environment-friendly foam material with high flame retardance for shells of agricultural spraying machines and method for preparing environment-friendly foam material | |
| CN106008874A (en) | Environment-friendly and highly-flame-retardant foam material for goods shelf and preparation method of foam material | |
| CN106008886A (en) | Environment-friendly high-fire-resistance rigid foam polyurethane door and window inner container filling foaming material and preparation method | |
| CN106008884A (en) | Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material | |
| CN106046306A (en) | Environmentally friendly high-flame-retardant polyurethane foaming material for tank body of oil tank truck and preparation method of environmentally friendly high-flame-retardant polyurethane foaming material | |
| CN106084167A (en) | A kind of semi-rigid elastomer environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106146794A (en) | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106146782A (en) | A kind of pedal environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106084165A (en) | A kind of packaging environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN107298744A (en) | A kind of low-position bumper guard environmental protection flame retardant expanded material and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |