CN106008884A - Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material - Google Patents
Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material Download PDFInfo
- Publication number
- CN106008884A CN106008884A CN201610527978.2A CN201610527978A CN106008884A CN 106008884 A CN106008884 A CN 106008884A CN 201610527978 A CN201610527978 A CN 201610527978A CN 106008884 A CN106008884 A CN 106008884A
- Authority
- CN
- China
- Prior art keywords
- flame
- parts
- polyethers
- environment
- retardance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Abstract
The invention discloses an environment-friendly high-flame-retardance foaming material for automobile instrument trim and a preparing method of the environment-friendly high-flame-retardance foaming material. The environment-friendly high-flame-retardance foaming material is prepared from isocyanate and a component material in the mass ratio of 1:1.7. The component material is specifically prepared from, by mass, 48-55 parts of polyether 4110, 25-28 parts of polyether 3450, 40-45 parts of polyether 1300, 4-5 parts of a stabilizing agent AK8803, 0.9-1.3 parts of a catalyst HP11, 3.0-4.2 parts of water and 38-45 parts of a fire retardant TCPP. After the material and the method are adopted, the prepared foam material is high in high-flame-retardance property and not prone to combustion when meeting fire, and thus the fireproof safety and personnel safety of a whole automobile are ensured; besides, due to the fact that environment-friendly raw materials serve as raw materials used for the foaming material, no toxic and harmful substance to the human body is released, and thus the requirement for environment friendliness is met.
Description
Technical field
The present invention relates to a kind of composite and preparation method thereof, the automotive meter of specifically a kind of imitative peach wood (color wood)
Table interior trim environmental protection high flame-retardant foamed material and preparation method thereof.
Background technology
Along with the development of auto industry, automobile instrument interior trim is as auto parts machinery, and its fire savety is being most important
, existing automobile instrument interior trim is in addition to fire savety, in addition it is also necessary to have the requirement of environmental protection, in order to reach this mesh
, people attempt the various material material as automobile instrument interior trim, but also make safety while pursuing environmental protection
Reduce, usually there will be when running into fault or accident easy initiation fire situation and occur, the most not only met environmental protection demand but also
There is fire resistance thus ensure that safety is an insoluble technical problem.
Summary of the invention
It is high that the technical problem to be solved in the present invention is to provide the automobile instrument interior trim environmental protection high, environmental protection of a kind of fire resistance
Flame-retardant foam material and preparation method thereof.
In order to solve above-mentioned technical problem, the automobile instrument interior trim of present invention environmental protection high flame-retardant foamed material, by following
Quality proportioning component is constituted, and isocyanates: premixed systems=1:1.7, the composition of described premixed systems is based on following mass fraction, specifically
Mass fraction is as follows:
Polyethers 4110 48-55 part
Polyethers 3450 25-28 part
Polyethers 1300 40-45 part
Stabilizer AK8803 4-5 part
Catalyst HP11 0.9-1.3 part
Water 3.0-4.2 part
Fire retardant TCPP 38-45 part.
Described isocyanates is Mitsui MR200.
A kind of preparation method of above-mentioned automobile instrument interior trim environmental protection high flame-retardant foamed material, including following preparation process:
First premixed systems is prepared: by polyethers 4110, polyethers 3450, polyethers 1300, stabilizer AK8803, catalyst HP11, fire retardant
TCPP and water add and carry out hybrid reaction in reactor, mixing speed 80-120r/min, mixing time 6-8h combination
Material, mixs homogeneously isocyanates by the quality ratio of 1:1.7 with premixed systems, can be prepared by described expanded material.
After using above-mentioned material and method, due to recipe ingredient collocation, rationally and preparation method is proper so that preparation
Expanded material fire resistance is high, meets fiery nonflammable, thus has ensured fire savety and the personal safety of whole vehicle, separately
Outward, owing to the use raw material of expanded material is environmental protection raw material, because without discharging material poisonous and hazardous to human body, arriving
Environmental requirement.
Detailed description of the invention
Below in conjunction with detailed description of the invention, automobile instrument interior trim environmental protection high flame-retardant foamed material and the system thereof to the present invention
Preparation Method is described in further detail.
Embodiment one:
A kind of automobile instrument interior trim environmental protection high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: combination
Material=1:1.7, described isocyanates is Mitsui MR200, the composition of a combination thereof material based on following mass fraction, concrete matter
Amount number is as follows:
Polyethers 4110 48-55 part
Polyethers 3450 25-28 part
Polyethers 1300 40-45 part
Stabilizer AK8803 4-5 part
Catalyst HP11 0.9-1.3 part
Water 3.0-4.2 part
Fire retardant TCPP 38-45 part.
Embodiment two:
The preparation method of a kind of above-mentioned automobile instrument interior trim environmental protection high flame-retardant foamed material, including following preparation process: first
Prepare premixed systems: by the stabilizer AK8803 of the polyethers 1300,4 parts of the polyethers 3450,40 parts of the polyethers 4110,25 parts of 48 parts,
The water addition reactor of the catalyst HP11 of 0.9 part, the fire retardant TCPP of 38 parts and 3.0 parts carries out hybrid reaction, stirring speed
Degree 80r/min, mixing time 6h premixed systems, the most again isocyanates is mixed by the mass ratio of 1:1.7 with premixed systems
Uniformly, can be prepared by described expanded material.
Embodiment three:
The preparation method of a kind of above-mentioned automobile instrument interior trim environmental protection high flame-retardant foamed material, including following preparation process: first
Prepare premixed systems: by the stabilizer AK8803 of the polyethers 1300,4 parts of the polyethers 3450,42 parts of the polyethers 4110,26 parts of 52 parts,
The water addition reactor of the catalyst HP11 of 1.1 parts, the fire retardant TCPP of 41 parts and 3.6 parts carries out hybrid reaction, stirring speed
Degree 100r/min, mixing time 7h premixed systems, the most again isocyanates is mixed by the mass ratio of 1:1.7 with premixed systems
Uniformly, can be prepared by described expanded material.
Embodiment four:
The preparation method of a kind of above-mentioned automobile instrument interior trim environmental protection high flame-retardant foamed material, including following preparation process: first
Prepare premixed systems: by the stabilizer AK8803 of the polyethers 1300,5 parts of the polyethers 3450,45 parts of the polyethers 4110,28 parts of 55 parts,
The water addition reactor of the catalyst HP11 of 1.3 parts, the fire retardant TCPP of 45 parts and 4.2 parts carries out hybrid reaction, stirring speed
Degree 120r/min, mixing time 8h premixed systems, the most again isocyanates is mixed by the mass ratio of 1:1.7 with premixed systems
Uniformly, can be prepared by described expanded material.
It is below the fire resistance test result of automobile instrument interior trim environmental protection high flame-retardant foamed material of the present invention:
Touchstone requires: the burning velocity of fire proofing should be not more than 100mm/min, if there is following situations, respectively by wanting
Seeking mark result of the test, assay is divided into A, B, C, D, E5 grade:
A:(0mm/min): sample is exposed to 15S in flame, extinguish burning things which may cause a fire disaster sample still unburned, or sample can burn, but flame
Extinguish before reaching the first measurement graticule, can count without burning extent.
B: when tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then it is assumed that meet
Standard-required.
C: burning velocity measured value (mm/min)
When tester, flame is measured at two and is extinguished between graticule, and when being unsatisfactory for the 2nd article of situation, then presses standard meter
Calculate burning velocity.
D: burning velocity measured value (mm/min)
When tester, flame combustion arrives the second graticule, or from the beginning of timing, the long-time smoulder of sample, then may be used
With termination test during 20min when tester, and record burning time and burning extent and by criterion calculation burning velocity.
E: sample has burnt in flame ignition 15s and has arrived the first graticule, then it is assumed that sample can not meet burning speed
The requirement of degree.
Assay: A-B(0mm/min), use automobile instrument interior trim environmental protection high flame-retardant foamed prepared by the present embodiment
Material meets fire resistance requirement.
Claims (3)
1. an automobile instrument interior trim environmental protection high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: group
Closing material=1:1.7, the composition of described premixed systems is based on following mass fraction, and concrete mass fraction is as follows:
Polyethers 4110 48-55 part
Polyethers 3450 25-28 part
Polyethers 1300 40-45 part
Stabilizer AK8803 4-5 part
Catalyst HP11 0.9-1.3 part
Water 3.0-4.2 part
Fire retardant TCPP 38-45 part.
2. according to the environmental protection high flame-retardant foamed material of the automobile instrument interior trim described in claim 1, it is characterised in that: described isocyanide
Acid esters is Mitsui MR200.
3. a preparation method for automobile instrument interior trim environmental protection high flame-retardant foamed material as claimed in claim 1, its feature exists
In, including following preparation process: first prepare premixed systems: by polyethers 4110, polyethers 3450, polyethers 1300, stabilizer AK8803,
Carrying out hybrid reaction in catalyst HP11, fire retardant TCPP and water addition reactor, mixing speed 80-120r/min, during stirring
Between 6-8h premixed systems, the most again isocyanates is mixed homogeneously by the quality ratio of 1:1.7 with premixed systems, can be prepared by institute
State expanded material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610527978.2A CN106008884A (en) | 2016-07-07 | 2016-07-07 | Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610527978.2A CN106008884A (en) | 2016-07-07 | 2016-07-07 | Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106008884A true CN106008884A (en) | 2016-10-12 |
Family
ID=57108045
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610527978.2A Pending CN106008884A (en) | 2016-07-07 | 2016-07-07 | Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106008884A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298747A (en) * | 2017-06-30 | 2017-10-27 | 扬中市天正合成材料研究中心 | Polyurethane foam material for Auto Instrument desk and preparation method thereof |
| CN107383309A (en) * | 2017-06-29 | 2017-11-24 | 扬中市天正合成材料研究中心 | A kind of high ferro luggage carrier environmentally friendly high fire-retardance PU expanded materials and preparation method thereof |
| CN108774303A (en) * | 2018-06-25 | 2018-11-09 | 扬中市天正合成材料研究中心 | A kind of radiator environmental protection flame retardant PU expanded materials and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530348A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Automobile air-conditioning ventilated pipe composite material and preparation method thereof |
| CN104530687A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Full-water-blown highly flame-retardant vehicle bumper composite material and preparation method thereof |
| CN105237709A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for air-conditioned bus lavatory covers, and preparation method thereof |
| CN105237706A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Switch cabinet section bar composite material and preparation method thereof |
-
2016
- 2016-07-07 CN CN201610527978.2A patent/CN106008884A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530348A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Automobile air-conditioning ventilated pipe composite material and preparation method thereof |
| CN104530687A (en) * | 2014-10-31 | 2015-04-22 | 扬中市天正合成材料研究中心 | Full-water-blown highly flame-retardant vehicle bumper composite material and preparation method thereof |
| CN105237709A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for air-conditioned bus lavatory covers, and preparation method thereof |
| CN105237706A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Switch cabinet section bar composite material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383309A (en) * | 2017-06-29 | 2017-11-24 | 扬中市天正合成材料研究中心 | A kind of high ferro luggage carrier environmentally friendly high fire-retardance PU expanded materials and preparation method thereof |
| CN107298747A (en) * | 2017-06-30 | 2017-10-27 | 扬中市天正合成材料研究中心 | Polyurethane foam material for Auto Instrument desk and preparation method thereof |
| CN108774303A (en) * | 2018-06-25 | 2018-11-09 | 扬中市天正合成材料研究中心 | A kind of radiator environmental protection flame retardant PU expanded materials and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106008873A (en) | Environment-friendly high-flame-retardant foaming material for tap water pipe and preparation method of environment-friendly high-flame-retardant foaming material | |
| CN106188460A (en) | A kind of sanitary ware environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106146795A (en) | A kind of automobile-used face shield environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106046298A (en) | Packing bucket environment-friendly high-flame-retardancy foam material and preparation method thereof | |
| CN106117495A (en) | A kind of concrete boat Inner wall of ship body polyurethane environmental protection high flame-retardant foamed material and preparation method | |
| CN106084168A (en) | A kind of petroleum pipeline environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106008878A (en) | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material | |
| CN106046296A (en) | Environmentally friendly high-flame-retardant foaming material of garbage bin and preparation method of environmentally friendly high-flame-retardant foaming material | |
| CN106146793A (en) | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106084169A (en) | A kind of greening bark moulding environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106008888A (en) | Environment-friendly high-flame-retardance polyurethane foam material for square stools and tables and chairs and preparation method of material | |
| CN106188459A (en) | A kind of auto lamp bowl polyester foamed material of environmental protection high fire-retardance and preparation method thereof | |
| CN106046289A (en) | Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material | |
| CN106008885A (en) | Environment-friendly high-flame-resistance polyurethane foaming material for fender and preparing method thereof | |
| CN106008884A (en) | Environment-friendly high-flame-retardance foaming material for automobile instrument trim and preparing method of environment-friendly high-flame-retardance foaming material | |
| CN107325247A (en) | A kind of secondary battery jar assembly polyurethane rings environment friendly flame-retardant expanded material and preparation method | |
| CN106008887A (en) | High-toughness elastomer environment-friendly high-flame-retardancy foaming material and preparation method thereof | |
| CN107474213A (en) | Thick stick environmental protection flame retardant polyurethane foam material and preparation method under a kind of bumper | |
| CN104530351A (en) | Environment-friendly high-flame-retardant automotive interior soft roof composite material and preparation method thereof | |
| CN106008874A (en) | Environment-friendly and highly-flame-retardant foam material for goods shelf and preparation method of foam material | |
| CN106146782A (en) | A kind of pedal environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106146794A (en) | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106084165A (en) | A kind of packaging environmental protection high flame-retardant foamed material and preparation method thereof | |
| CN106046300A (en) | Environment-friendly foam material with high flame retardance for shells of agricultural spraying machines and method for preparing environment-friendly foam material | |
| CN106046306A (en) | Environmentally friendly high-flame-retardant polyurethane foaming material for tank body of oil tank truck and preparation method of environmentally friendly high-flame-retardant polyurethane foaming material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |
|
| RJ01 | Rejection of invention patent application after publication |