CN106046289A - Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material - Google Patents

Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material Download PDF

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Publication number
CN106046289A
CN106046289A CN201610530907.8A CN201610530907A CN106046289A CN 106046289 A CN106046289 A CN 106046289A CN 201610530907 A CN201610530907 A CN 201610530907A CN 106046289 A CN106046289 A CN 106046289A
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CN
China
Prior art keywords
parts
environment
foam material
polyethers
friendly foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610530907.8A
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Chinese (zh)
Inventor
朱章娣
朱凌宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YANGZHONG TIANZHENG SYNTHETIC MATERIAL RESEARCH CENTER
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YANGZHONG TIANZHENG SYNTHETIC MATERIAL RESEARCH CENTER
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Priority to CN201610530907.8A priority Critical patent/CN106046289A/en
Publication of CN106046289A publication Critical patent/CN106046289A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333Esters of phosphonic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

The invention discloses an environment-friendly foam material with high flame retardance for shells of toy cars for children and a method for preparing the environment-friendly foam material. The environment-friendly foam material comprises isocyanate and combination materials. A mass ratio of the isocyanate to the composition materials is 1:1.55, the combination materials comprise, by weight, 15-25 parts of polyester, 25-35 parts of polyether 4113, 15-20 parts of polyether 450, 10-20 parts of polyether 403, 2.5-3.0 parts of silicone oil 8807, 45-55 parts of glass fibers, 1.2-1.8 parts of catalysts DMP-30, 1.3-1.7 parts of balance catalysts HP-12, 1.1-1.5 parts of catalysts HP-54, 3-4.5 parts of water and 36-38 parts of flame retardants DMMP. The environment-friendly foam material and the method have the advantages that the environment-friendly foam material prepared by the aid of the method is high in flame-retardant property and is difficult to combust when in contact with fire, and accordingly the personal and property safety can be guaranteed; raw materials for the environment-friendly foam material are environment-friendly raw materials and are reasonably matched with one another, and the environment-friendly foam material is free of release of substances which are toxic and harmful for human bodies.

Description

A kind of children toy car car girdle protects high flame-retardant foamed material and preparation method thereof
Technical field
The present invention relates to a kind of composite and preparation method thereof, specifically a kind of children toy car car girdle protects height Flame-retardant foam material and preparation method thereof.
Background technology
Children toy car is the toy that child likes, its fire savety it is critical that, and for child, In addition to the highest to fire savety requirement, it is necessary to the feature of environmental protection of toy is had the highest requirement, but, existing The harm that the feature of environmental protection of the material of children toy car can not reach higher requirement, effect on environment and child is very big, Attempt the various material material as children toy car to meet above two requirement simultaneously for these people, but often chasing after Also make safety reduce while asking environmental protection, the most usually there will be easy initiation fire situation when meeting with an accidet and occur Not only met the demand of environmental protection but also there is fire resistance thus ensured that safety is an insoluble technical problem.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of fire resistance is high, lightweight and the children toy car car of environmental protection Girdle protects high flame-retardant foamed material and preparation method thereof.
In order to solve above-mentioned technical problem, the children toy car car girdle of the present invention protects high flame-retardant foamed material, by following Quality proportioning component is constituted, and isocyanates: premixed systems=1:1.55, the composition of described premixed systems is based on following mass fraction, specifically Mass fraction is as follows:
Practice and rise polyester 15-25 part
Polyethers 4113 25-35 part
Polyethers 450 15-20 part
Polyethers 403 10-20 part
Silicone oil 8807 2.5-3.0 part
Glass fibre 45-55 part
Catalyst DMP-30 1.2-1.8 part
Equilibrium catalyst HP-12 1.3-1.7 part
Catalyst HP-54 1.1-1.5 part
Water 3-4.5 part
Fire retardant DMMP 36-38 part.
Described isocyanates is Bayer 44V20.
Described glass fibre is reinforcing glass fiber.
A kind of above-mentioned children toy car car girdle protects the preparation method of high flame-retardant foamed material, including following preparation process: First premixed systems is prepared: white silk is risen polyester, polyethers 4113, polyethers 450, polyethers 403, silicone oil 8807, glass fibre, catalyst DMP-30, equilibrium catalyst HP-12, catalyst HP-54, fire retardant DMMP and water addition reactor carry out hybrid reaction, Mixing speed 80-120r/min, mixing time 6-8h premixed systems, the most again isocyanates and premixed systems are pressed 1:1.85 Quality than mix homogeneously, can be prepared by described expanded material.
After using above-mentioned material and method, due to recipe ingredient collocation, rationally and preparation method is proper so that preparation Expanded material fire resistance is high, meets fiery nonflammable, thus has ensured the person and property safety, further, since expanded material Raw material is used to be environmental protection raw material and arrange in pairs or groups rationally, because of without discharging material poisonous and hazardous to human body.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the children toy car car girdle of the present invention is protected high flame-retardant foamed material and system thereof Preparation Method is described in further detail.
Embodiment one:
A kind of children toy car car girdle protects high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: combination Material=1:1.85, described isocyanates is Bayer 44V20, the composition of a combination thereof material based on following mass fraction, concrete mass parts Number is as follows:
Practice and rise polyester 15-25 part
Polyethers 4113 25-35 part
Polyethers 450 15-20 part
Polyethers 403 10-20 part
Silicone oil 8807 2.5-3.0 part
Reinforcing glass fiber 45-55 part
Catalyst DMP-30 1.2-1.8 part
Equilibrium catalyst HP-12 1.3-1.7 part
Catalyst HP-54 1.1-1.5 part
Water 3-4.5 part
Fire retardant DMMP 36-38 part.
Embodiment two:
A kind of above-mentioned children toy car car girdle protects the preparation method of high flame-retardant foamed material, including following preparation process: first Prepare premixed systems: by the white silk liter polyester of 15 parts, the polyethers 403,2.5 parts of the polyethers 450,10 parts of the polyethers 4113,15 parts of 25 parts The glass fibre of silicone oil 8807,45 parts, the catalyst DMP-30 of 1.2 parts, the equilibrium catalyst HP-12 of 1.3 parts, 1.1 parts The water addition reactor of catalyst HP-54, the fire retardant DMMP of 36 parts and 3 parts carries out hybrid reaction, mixing speed 80r/ Min, mixing time 6h premixed systems, the most again isocyanates is mixed homogeneously by the quality ratio of 1:1.85 with premixed systems, Can be prepared by described expanded material.
Embodiment three:
A kind of above-mentioned children toy car car girdle protects the preparation method of high flame-retardant foamed material, including following preparation process: first Prepare premixed systems: by the white silk liter polyester of 20 parts, the polyethers 403,2.7 parts of the polyethers 450,15 parts of the polyethers 4113,17 parts of 30 parts The glass fibre of silicone oil 8807,50 parts, the catalyst DMP-30 of 1.5 parts, the equilibrium catalyst HP-12 of 1.4 parts, 1.4 parts The water addition reactor of catalyst HP-54, the fire retardant DMMP of 37 parts and 3.7 parts carries out hybrid reaction, mixing speed 100r/min, mixing time 7h premixed systems, the most again isocyanates is mixed by the mass ratio of 1:1.85 with premixed systems Uniformly, can be prepared by described expanded material.
Embodiment four:
A kind of above-mentioned children toy car car girdle protects the preparation method of high flame-retardant foamed material, including following preparation process: first Prepare premixed systems: by the white silk liter polyester of 25 parts, the polyethers 403,3.0 parts of the polyethers 450,20 parts of the polyethers 4113,20 parts of 35 parts The glass fibre of silicone oil 8807,55 parts, the catalyst DMP-30 of 1.8 parts, the equilibrium catalyst HP-12 of 1.7 parts, 1.5 parts The water addition reactor of catalyst HP-54, the fire retardant DMMP of 38 parts and 4.5 parts carries out hybrid reaction, mixing speed 120r/min, mixing time 8h premixed systems, the most again isocyanates is mixed by the mass ratio of 1:1.85 with premixed systems Uniformly, can be prepared by described expanded material.
It is below the fire resistance test result of children toy car car girdle of the present invention guarantor's high flame-retardant foamed material:
Touchstone requires: the burning velocity of fire proofing should be not more than 100mm/min, if there is following situations, respectively by wanting Seeking mark result of the test, assay is divided into A, B, C, D, E5 grade:
A:(0mm/min): sample is exposed to 15S in flame, extinguish burning things which may cause a fire disaster sample still unburned, or sample can burn, but flame Extinguish before reaching the first measurement graticule, can count without burning extent.
B: when tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then it is assumed that meet Standard-required.
C: burning velocity measured value (mm/min)
When tester, flame is measured at two and is extinguished between graticule, and when being unsatisfactory for the 2nd article of situation, then presses standard meter Calculate burning velocity.
D: burning velocity measured value (mm/min)
When tester, flame combustion arrives the second graticule, or from the beginning of timing, the long-time smoulder of sample, then may be used With termination test during 20min when tester, and record burning time and burning extent and by criterion calculation burning velocity.
E: sample has burnt in flame ignition 15s and has arrived the first graticule, then it is assumed that sample can not meet burning speed The requirement of degree.
Assay: A-B(0mm/min), the children toy car car girdle using the present embodiment to prepare protects high flame-retardant foamed Material meets fire resistance requirement.

Claims (4)

1. children toy car car girdle protects a high flame-retardant foamed material, is made up of following quality proportioning component, isocyanates: group Closing material=1:1.85, the composition of described premixed systems is based on following mass fraction, and concrete mass fraction is as follows:
Practice and rise polyester 15-25 part
Polyethers 4113 25-35 part
Polyethers 450 15-20 part
Polyethers 403 10-20 part
Silicone oil 8807 2.5-3.0 part
Glass fibre 45-55 part
Catalyst DMP-30 1.2-1.8 part
Equilibrium catalyst HP-12 1.3-1.7 part
Catalyst HP-54 1.1-1.5 part
Water 3-4.5 part
Fire retardant DMMP 36-38 part.
2. protect high flame-retardant foamed material according to the children toy car car girdle described in claim 1, it is characterised in that: described isocyanide Acid esters is Bayer 44V20.
3. protect high flame-retardant foamed material according to the children toy car car girdle described in claim 1, it is characterised in that: described glass Fiber is reinforcing glass fiber.
4. children toy car car girdle as claimed in claim 1 protects a preparation method for high flame-retardant foamed material, and its feature exists In, including following preparation process: first prepare premixed systems: white silk is risen polyester, polyethers 4113, polyethers 450, polyethers 403, silicone oil 8807, glass fibre, catalyst DMP-30, equilibrium catalyst HP-12, catalyst HP-54, fire retardant DMMP and water add anti- Answer and still carry out hybrid reaction, mixing speed 80-120r/min, mixing time 6-8h premixed systems, the most again by isocyanide Acid esters is mixed homogeneously by the quality ratio of 1:1.85 with premixed systems, can be prepared by described expanded material.
CN201610530907.8A 2016-07-07 2016-07-07 Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material Pending CN106046289A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610530907.8A CN106046289A (en) 2016-07-07 2016-07-07 Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610530907.8A CN106046289A (en) 2016-07-07 2016-07-07 Environment-friendly foam material with high flame retardance for shells of toy cars for children and method for preparing environment-friendly foam material

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107298744A (en) * 2017-06-30 2017-10-27 扬中市天正合成材料研究中心 A kind of low-position bumper guard environmental protection flame retardant expanded material and preparation method
CN107312143A (en) * 2017-06-29 2017-11-03 扬中市天正合成材料研究中心 A kind of bumper environmental protection flame retardant expanded material and preparation method
CN107325247A (en) * 2017-07-04 2017-11-07 扬中市天正合成材料研究中心 A kind of secondary battery jar assembly polyurethane rings environment friendly flame-retardant expanded material and preparation method
CN108752558A (en) * 2018-06-25 2018-11-06 扬中市天正合成材料研究中心 A kind of radiator environmental protection flame retardant polyurethane foam material and preparation method thereof
CN108929420A (en) * 2018-06-28 2018-12-04 扬中市天正合成材料研究中心 Environmental protection flame retardant polyurethane foam material and preparation method thereof for ceiling before car

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530358A (en) * 2014-10-31 2015-04-22 扬中市天正合成材料研究中心 Environment protective and high flame-resistant heat insulating material for lunar spacecraft bulkhead and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530358A (en) * 2014-10-31 2015-04-22 扬中市天正合成材料研究中心 Environment protective and high flame-resistant heat insulating material for lunar spacecraft bulkhead and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312143A (en) * 2017-06-29 2017-11-03 扬中市天正合成材料研究中心 A kind of bumper environmental protection flame retardant expanded material and preparation method
CN107298744A (en) * 2017-06-30 2017-10-27 扬中市天正合成材料研究中心 A kind of low-position bumper guard environmental protection flame retardant expanded material and preparation method
CN107325247A (en) * 2017-07-04 2017-11-07 扬中市天正合成材料研究中心 A kind of secondary battery jar assembly polyurethane rings environment friendly flame-retardant expanded material and preparation method
CN108752558A (en) * 2018-06-25 2018-11-06 扬中市天正合成材料研究中心 A kind of radiator environmental protection flame retardant polyurethane foam material and preparation method thereof
CN108929420A (en) * 2018-06-28 2018-12-04 扬中市天正合成材料研究中心 Environmental protection flame retardant polyurethane foam material and preparation method thereof for ceiling before car

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Application publication date: 20161026

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